JEE Main 2019 Chemistry April Attempt Shift - 1 (08th April, 2019)

PAPER-1 (B.E./B. TECH.
JEE (Main) 2019

COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 8 April, 2019 (SHIFT-1) | TIME: 09.30 A.M. to 12.30 P.M.
Duration: 3 Hours | Max. Marks: 360

SUBJECT: CHEMISTRY
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| JEE (MAIN) 2019 | DATE : 08-04-2019 (SHIFT-1) | PAPER-1 | OFFICAL PAPER | CHEMISTRY
PART : CHEMISTRY
1. The major product of the following reaction is :

fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS&
OCH3 Conc HBr (excess) lkUnz HBr (vkf/kD; esa)
heat Å”"ek
CH = CH2
Br Br
(1) (2)
CH2CH2Br Br – CHCH3
OH OH
(3) (4)
CH2CH2Br Br – CHCH3
Ans. (4)
OCH3 O–CH3 
O—CH3
OCH3
H—Br Br HBr H
Sol.   Br

CH=CH2 CH–CH3 CH–CH3
CH–CH3
Br
Br
OH
+ CH3–Br
Br–CH–CH3
2. An organic compound 'X' showing the following solubility profile is :

Water
Insoluble
X
5% HCl
Insoluble
10% NaOH
Soluble
10% NaHCO3
3 Insoluble
(1) Benzamide (2) o – Toluidine (3) Oleic acid (4) m- Cresol

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,d dkcZfud ;kSfxd 'X' tks fuEu foys;rk dh :ijs[kk iznf'kr djrk gS] gksxk&
ty
vfoys;
X
5% HCl
vfoys;
10% NaOH
foys;
10% NaHCO3
3 vfoys;
(1) csatkekbM (2) o – VkWywMhu (3) vkWysbd vEy
(4) m- ØslkWy
Ans. (4)
Sol. Both Para-Cresol and Oleic acid form salt with 10% NaOH, but Para-Cresol salt is soluble whereas
Oleic acid salt is insoluble due to very long unsaturated carbon chain.
Sol. nksuks iSjk&fØlkWy vkSj vkWysbd vEy 10% NaOH, ds lkFk yo.k cukrs gS] ysfdu iSjk&fØlkWy yo.k ?kqyu'khy gksrs
gS] tcfd vkWysbd vEy yo.k cgqr yEch vlar`I r dkcZu Ja`[kyk ds dkj.k v?kqyu'khy gksrs gSA
3. For the reaction 2A + B  C , the values of initial rate at different reactant concentrations are given in
the table below. The rate law for the reaction is :
[A] (mol L–1) [B] (mol L–1) Initial Rate
(mol L–1s–1)
0.05 0.05 0.045
0.10 0.05 0.090
0.20 0.10 0.72
(1) Rate = k[A][B]2 (2) Rate = k[A]2[B] (3) Rate = k[A][B] (4) Rate = k[A]2[B]2
vfHkfØ;k 2A + B  C ds fy;s] vfHkdkjdksa dh fofHkUu lkUnzrkvksa ij izkjfEHkd nj ds eku uhps nh xbZ rkfydk esa
fn;s x;s gSaA vfHkfØ;k ds fy, nj fu;e gksxk&
[A] (mol L–1) [B] (mol L–1) izkjfEHkd nj
(mol L–1s–1)
0.05 0.05 0.045
0.10 0.05 0.090
0.20 0.10 0.72
(1) nj = k[A][B]2 (2) nj = k[A]2[B] (3) nj = k[A][B] (4) nj = k[A]2[B]2

Ans. (1)
Sol. Rate nj = K[A]x [B]y
r1 = k[A]1x [B]1y
r2 = k [ A ]2x [B]2y
x
r2  [ A ]2 
 
r1  [ A ]1 
x
0.09  0.1 
 
0.045  0.05 
2 = 2x x = 1
r3 = k [ A ] 3x [B] 3y
1 y
r3  [ A ]3   [B]3 
   
r2  [ A ]2 

 [B] 
 1

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1 y
0.72  0.2   0.1 
   
0.09  0.1   0.05 
8 = 21 2y
2y = 4
y = 2
 R = k[A] [B]2
4. Coupling of benzene diazonium choloride with 1-naphthol in alkaline medium will give :
{kkjh; ek/;e esa] csathu Mkbtksfu;e DyksjkbM dks 1-uS¶FkkWy ds lkFk ;qfXer djus ij izkIr gksrk gS&
OH
N
(1) (2) ||
N
N=N HO
OH
N
(3) || (4) N
N ||
N
OH
Ans. (3)
OH
Sol.
N
N
C6H5
Diazo coupling will take place from the least hindered (ortho, para) position of most activated phenolic
ring.
MkbZ,tks ;qXeu vfHkfØ;k vR;f/kd lfØ; Qhuksfyd oy; ds ml LFkku ¼vkWFkksZ] iSjk½ ij gksrh gS] tgk¡ ij f=kfoe ck/kk
lcls de gksrh gSA

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5. In order to oxidise a mixture of one mole of each of FeC2O4, Fe2(C2O4)3, FeSO4 and Fe2(SO4)3 in acidic
medium, the number of moles of KMnO4 required is :
vEyh; ek/;e esa] FeC2O4, Fe2(C2O4)3, FeSO4 rFkk Fe2(SO4)3 izR;sd ds ,d eksy feJ.k dks mipf;r djus ds
fy, vko';d KMnO4 ds eksyksa dh la[;k gksxh&
(1) 1.5 (2) 2 (3) 3 (4) 1
Ans. (2)
Sol. FeC2O4 + KMnO4 Fe3+ + CO2 + Mn2+
v.f.= 3 v.f = 5
1× 3 = mole × 5
3
Mole =
5
Fe 2 (C 2O 4 )3  KMnO 4 Fe3+ + CO2 + Mn2+
v. f = 6 v.f = 5
1 × 6 = mole × 5
6
Mole =
5
FeSO4 + KMnO4 Fe3+ + SO42–+ Mn2+
v.f = 1 v.f = 5
1 × 1 = moles × 5
1
Mole =
5
Fe2(SO4)3 doesn't oxidise (Fe2(SO4)3 vkWDlhd`r ugh gks rk gS A)
3 6 1
Total moles of KMnO4 (KMnO4 ds dqy eksy) =    2
5 5 5
6. Which is wrong with respect to our responsibility as a human being to protect our environment ?
(1) Using plastic bags (2) Restricting the use of vehicles
(3) A voiding the use of floodlighted facilities (4) Setting up compost tin in gardens
dkSulk gekjs i;kZoj.k dh j{kk djus ds fy, euq"; dh ftEesnkjh ds laxr xyr gS\
(1) IykfLVd csx dk iz ;ksx djds (2) okguksa ds fu"ksèk djds
(3) rst izdk'k dh ykb±V ds mi;ksx dks R;kxdj (4) cxhpksa esa [kk| fVu dh O;oLFkk djds
Ans. (1)
7. Which one of the following equations does not correctly represent the first law of thermodynamics for
the given processes involving an ideal gas ? (Assume non- expansion work is zero)
(1) Isothermal process : q = – w (2) Isochoric process : U = q
(3) Adiabatic process : U = – w (4) Cyclic process : q = – w
fuEu esa ls dkSu&lk lehdj.k FkeksZMk;ukfeDl ds izFke fl)kUr dks fn;s x;s izØeksa ds fy,] ftlesa vkn'kZ xSl gS]
lgh :i esa izLrqr ugha djrk gS (eku ysa fd vizlkj.k dk;Z 'kwU; gS)
(1) lerkih iz Øe : q = – w (2) lek;rfud izØe : U = q
(3) :nks"e izØe : U = – w (4) pØh; izØe : q = – w
Ans. (3)
Sol. From FLOT U = q + W
for adiabatic process q = 0
U = w
FLOT lsU = q + W
:)zks"eh; izØe ds fy, q = 0
U = w

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8. Maltose on treatment with dilute HCl gives :
(1) D-Fructose (2) D-Glucose and D-Fructose
(3) D-Glucose (4) D-Galactose
ekYVksl ruq HCl ds lkFk vfHkd`r djus ij nsrk gS&
(1) D-ÝDVkst (2) D-Xyqdksl rFkk D- ÝqDVkst
(3) D-Xyqdksl (4) D-xSysDVksl
Ans. (3)
Sol. Hydrolysis of maltose with dilute HCl gives only D-glucose.
ekYVksl dk ruq HCl ds lkFk ty vi?kVu djus ij dsoy D-Xyqdksl izkIr gksrk gSA

9. Given that fn;k x;k gS] EO  1.23V
2 / H2O
ES O2 – / SO 2  2.05 V
2 8 4

EBr / Br –
 1.09 V;
2
E Au3 / Au  1.4 V
The strongest oxidizing agent is :
izcyre vipk;d gS&
(1) O2 (2) Br2 (3) Au3+ (4) S 2O 82 –
Ans. (4)
Sol. Strongest oxidizing agent has highest value of SRP
izcyre vkWDlhdkjd mPPkre SRP eku j[krk gSA
10. The correct order of hydration enthalpies of alkali metal ions is :

{kkj /kkrq vk;uksa ds ty;kstu ,UFkSYih dk lgh Øe gS&
(1) Li > Na+ > K+ > Cs+ > Rb+ (2) Na > Li+ > K+ > Cs+ > Rb+
+ + + + +
(4) Na > Li > K > Rb > Cs (4) Li + > Na+ > K+ > Rb+ > Cb+
Ans. (4)
Sol. Hydration decreases with decrement in charge density of ion
vk;u ds vkos'k /kuRo es deh ds lkFk ty ;kstu ÅtkZ esa deh vkrh gSA
11. Element 'B' forms ccp structure and 'A' occupies half of the octahedral voids, while oxygen atoms
occupy all the tetrahedral voids. The structure of bimetallic oxide is :
rRo 'B', ccp lajpuk cukrk gS rFkk 'A' v"VQydh; fjfDr;ksa ds vk/ks esa mifLFkr gSA tcfd vkWDlhtu ijek.kq lHkh
prq"Qydh; fjfDr;ksa esa mifLFkr gSA f}/kkfRod vkWDlkbM dh lajpuk gS&
(1) A2BO4 (2) A2B2O (3) AB2O4 (4) A4B2O
Ans. (3)
Sol. Effective number of A = 4
1
Effective number of B = 4 ×  2
2
Effective number of O = 8
Formula is A4B2O8 or A2BO4
A dh izHkkoh la[;k = 4
1
B dh izHkkoh la[;k = 4 ×  2
2
O dh izHkkoh la[;k = 8
lw=k gS % A4B2O8 vFkok A2BO4

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12. An organic compound neither reacts with neutral ferric chloride solution nor with Fehling solution. It
however, reacts with Grignard reagent and gives positive iodoform test. The compound is :
,d dkcZfud ;kSfxd u rks mnklhu Qsfjd DyksjkbM foy;u ds lkFk vkSj u gh Qsfyax foy;u ds lkFk vfHkfØ;k
djrk gSA gkyk¡fd ;g ;kSfxd xzhU;kj vfHkdeZd ds lkFk vfHkfØ;k djrk gS rFkk ldkjkRed vk;MksQkeZ VsLV nsrk gSA
;g ;kSfxd gS&
O O
CH3
(1) H (2) C2H5
CH3
O O
OH
CH3 O
(3) C2H5 (4) CH3

O OH
Ans. (3)
Sol. Neutral FeCl3  –ve  phenol is absent.
Fehling solution  –ve –CHO is absent.
Iodoform reaction  +ve –COCH3 or –CH(OH)–CH3 is present.
Grignard reagent +ve Electrophilic center or acidic H is present.
OH
CH–CH3 obeys all above statements.
OCH3
Sol. mnklhu FeCl3  –ve  fQukWy vuqifLFkr gSA

Qsgfyax foy;u  –ve –CHO vuqifLFkr gSA
vk;MksQkWeZ vfHkfØ;k  +ve –COCH3 ;k –CH(OH)–CH3 mifLFkr gSA
fxzxukMZ vfHkdeZd +ve bysDVªkWuLusgh dsU nz ;k vEyh; H mifLFkr gSA
OH
CH–CH3 mi;qZDr lHkh dFkuks dk ikyu djrk gSA
OCH3
13. If solubility product of Zr3(PO4)4 is denoted by Ksp and its molar solubility is denoted by S, then which of
the following relation between S and Ksp is correct.
;fn Zr3(PO4)4 ds foys;rk xq.kuQy dks Ksp }kjk rFkk bldh eksyj foys;rk dks S }kjk vfHkO;Dr djrs gksa rks S
rFkk Ksp ds chp lgh lEcU/k gS&
1/ 7 1/ 9
 K sp   K sp 
(1) S   
 (2) S   

 6912   929 
1/ 7 1/ 6
 K sp   K sp 
(3) S   
 (4) S   

 216   144 
Ans. (1)

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Sol. Zr3(PO4)4 3Zr4+ + 4PO43–
3s 4s
Ksp = (3s)3 (4s)4
= 27 × 256 s7
= 6912s7
1/ 7
 K sp 
S   

 6912 
14. The mirror product of the following reaction is :

fuEu vfHkfØ;k dk eq[; mRikn gS&
O
Br NaBH4
MeOH, 25°C
OMe O
(1) (2)
OH OH
OMe Br
(3) (4)
Ans. (2)
O O
O
CH–CH2–Br CH—CH2
C NaBH4
Sol. CH2–Br 
MeOH
15. Diborane (B2H6) reacts independently with O2 and H2O to produce, respectively :
(1) HBO2 and H3BO3 (2) B2O3 and [BH4]– (3) B2O3 and H3BO3 (4) H3BO2 and B2O3
Mkbcksjsu (B2H6), O2 rFkk H2O ds lkFk Lora=k :i ls vfHkfØ;k djds Øe'k% mRikfnr djrh gS&
(1) HBO2 rFkk H3BO3 (2) B2O3 rFkk [BH4]– (3) B2O3 rFkk H3BO3 (4) H3BO2 rFkk B2O3
Ans. (3)
Sol. B2H6 + 3O2 B2O3 + 3H2O
B2H6 + 6H2O 2H3BO3 + 6H2
16. For sliver Cp(J K–1 mol–1) = 23 + 0.01T. If the temperature (T) of 3 moles of sliver is raised from 300 K
to 1000 K at 1 atm pressure, the value of H will be close to :
flYoj ds fy,] Cp(J K–1 mol–1) = 23 + 0.01T ;fn 1 atm nkc ij flYoj ds 3 eksy dk rki (T) 300 K ls c<+dj
1000 K gks tk; rks H dk eku fdlds utnhd gksxk\
(1) 13 kJ (2) 16kJ (3) 62kJ (4) 21kJ
Ans. (3)

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T2 1000
Sol. H = 
T1
nCp dT  n  (23  0.01T) dT
300
1000
 0.01T 2 
= 3 23T  
 2 
300
 2  23  700  9100 
=3  
 2 
= 61950 J/mol ~ – 62 kJ/mol
17. Assertion : Ozone is destroyed by CFCs in the upper stratosphere.

Reason : Ozone holes increase the amount of UV radiation reaching the earth.
(1)Assertion and reason are both correct, and the reason is the correct explanation for the assertion.
(2) Assertion is false, but the reason is correct.
(3) Assertion and reason are correct, but the reason is not the explanation for the assertion.
(4) Assertion and reason are incorrect.
dFku : LVsªVksLQh;j ds Åijh Hkkx esa CFCs }kjk vkstksu dk fouk'k gksrk gSA
dkj.k : vkstksuijr fNnzksa ls i`Foh ij igq¡p us okys UV fofdj.kksa dh ek=kk c<+rh gSA
(1) dFku rFkk dkj.k nksuksa lgh gSa vkSj dkj.k] dFku dh lgh O;k[;k djrk gS A
(2) dFku xyr gS ijUrq dkj.k lgh gS A
(3) dFku rFkk dkj.k lgh gSa ijUrq dkj.k] dFku dh lgh O;k[;k ugha gS A
(4) dFku rFkk dkj.k nksuksa xyr gS A
Ans. (3)
Sol. Ozone layer is depleted due to released of chloroflurocarbons (CFCs)
vkstksu ijr dk Dyksjks¶yksjksdkcZu (CFCs) ds fu"dklu ds dkj.k {k; gksrk gSA

CF2Cl 2(g)  C l (g)  F2Cl(g)
UV
 
C l (g)  O 3  CI O(g)  O2 (g)
 
CI O(g)  O(g)  C l  O 2
Due to depletion of ozone layer, more UV radiation filters into troposphere.
vkstksu ijr ds {k; ds dkj.k vf/kd UV fdj.ksa {kksHke.My es igq¡prh gSA
18. Which of the following amines can be prepared by Gabriel phthalimide reaction ?
(1) neo-pentylamine (2) triethylamine
(3) n-butylamine (4) t-butylamine
fuEu esa ls dkSu lk ,sehu xSfcz,y FkSfyekbM vfHkfØ;k }kjk rS;kj fd;k tk ldrk gS\
(1) fuvksisfUVy,sehu (2) VªkbZ,fFky,sehu
(3) n-C;wfVy,sehu (4) t-C;wfVy,sehu
Ans. (3)
Sol. Gabriel phthalimide reaction is used to prepare primary unhindered amine only.
xSfcz,y FkSykekbM vfHkfØ;k izkFkfed vckf/kr ,ehu cukus es iz;qDr dh tkrh gSA

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19. Adsorption of a gas follows Freundich adsorption isotherm. x is the mass of the gas adsorbed on mass
x x
m of the adsorbent. The plot of log versus log p is shown in the given graph. is proportional to :
m m
,d xSl dk vf/k'kks"k.k] Ýk;Umfyd vf/k'kks"k.k lerki dk ikyu djrk gSA vf/k'kks"kd ds m nzO;eku ij vf/k'kksf"kr
x x
xSl dk nzO;eku x gSA log ds fo:) log p dk IykV fn;s x;s xzkQ esa n'kkZ;k x;k gSA ftlds vuqikfrd gS]
m m
og gS&
x 2
log
m
3
Log P
(1) p3 (2) p2 (3) p2/3 (4) p3/2
Ans. (3)
x 1
Sol. From Freundlich isotherm log  log k  log p
m n
1 2
slope of curve is a
n 3
x 1
Ý.Mfy; lerkih ls log  log k  log p
m n
1 2
vkjs[k dk <ky a gSA
n 3
20. In the following compounds, the decreasing order of basic strength will be : GOC-2
fuEufyf[kr ;kSfxdksa esa] {kkjh; lkeF;Z dk ?kVrk Øe gksxk&
(1) (C2H5)2NH > C2H5NH2 > NH3 (2) (C2H5)2NH >NH3 > C2H5NH2
(3) NH3 > C2H5NH2 > (C2H5)2 NH (4) C2H5NH2 > NH3 > (C2H5)2 NH
Ans. (1)
 
Sol. (C 2H5 )2 N H > N(C 2H5 )3 > C2H5NH2 > NH3
This is experimental basic strength order. Which is the combined result of solvation and electronic
effect.
21. The lanthanide ion that would show colour is :

og ySUFkuk;M vk;u tks jax iznf'kZr djsxk] gS&
(1) La3+ (2) Lu3+ (3) Gd3+ (4) Sm3+
Ans. (4)
Sol. La3+ colourless (4f0) Gd3+ colourless (4f 7)
Lu3+ colourless (4f14) Sm+3 yellow(4f5)
Sol. La3+ jaxghu(4f0) Gd3+ jaxghu(4f7)
Lu3+ jaxghu(4f14) Sm+3 ihyk(4f5)

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22. The vapour pressures of pure liquids A and B are 400 and 600 mmHg, respectively at 298 K. On mixing
the two liquids, the sum of their initial volumes is equal to the volume of the final mixture. The mole
fraction of liquid B is 0.5 in the mixture. The vapour pressure of the final solution, the mole fractions of
components A and B in vapour phase, respectively are :
298 K ij 'kq) nzo A rFkk B ds ok"i nkc Øe'k% 400 rFkk 600 mmHg gSaA nksuksa nzoksa dks feykus ij muds izkjfEHkd
vk;ruksa dk ;ksx muds vafre feJ.k ds vk;ru ds cjkcj gSA feJ.k esa nzo B dk eksy v.kq 0.5 gSA vaf re foy;u
dk ok"i nkc ,oa A rFkk B vo;oksa dk ok"i izkoLFkk esa eksy v.kq va'k Øe'k% gksaxs&
(1) 500 mm Hg, 0.4, 0.6 (2) 450 mmHg, 0.4, 0.6
(4) 500 mm Hg, 0.5, 0.5 (4) 450 mmHg, 0.5, 0.5
Ans. (1)
Sol. PT = XA PA° + XBPB°
= 0.5 × 400 + 0.5 × 600
= 500 mm of Hg
1 yA 1 – yA
 
PT PA PB
1 y 1– yA
 A 
500 400 600
yA = 0.4 & yB = 1 – 0.4 = 0.6
23. 100 mL of a water sample contains 0.81 g of calcium bicarbonate and 0.73 g of magnesium
bicarbonate. The hardness of this water sample expressed in terms of equivalents of CaCO3 is :
(molar mass of calcium bicarbonate is 162g mol–1 and magnesium bicarbonate is 146 g mol–1)
,d ty izfrn'kZ ds 100 mL esa 0.81 g dSfY'k;e ckbdkcksZusV rFkk 0.73 g eSXuhf'k;e ckbdkcksZusV gSaA bl ty
izfrn'kZ dh dBksjrk CaCO3 ds lerqY; :i esa O;Dr djus ij gksxh&
(dSfY'k;e ckbdkcksZusV rFkk eSXuhf'k;e ckbdkcksZusV ds eksyj nz O ;eku Øe'k% 162g mol–1 rFkk 146 g mol–1 gSa)
(1) 100 ppm (2) 5,000 ppm (3) 10,000 ppm (4) 1,000 ppm
Ans. (3)
 0.73 0.81 
    100
ppm of CaCO3 (CaCO3 dk ppm)= 
146 162 
Sol.  10 6  10 4 ppm
100
24. With respect to an ore, Ellingham diagram helps to predict the feasibility of its
(1) Thermal reduction (2) Zone refining
(3) Electrolysis (4) Vapour phase refining
Bfyaxe vkjs[k ,d v;Ld ds fuEu esa ls fdlds gksus dh lEHkkouk dh izkxqf Dr djus esa gekjh enn djrk gS]
(1) rkih; vip;u (2) tksu ifj"dj.k
(3) fo|q r vi?kVu (4) ok"i izkoLFkk ifj"dj.k
Ans. (1)
Sol. With the help of Ellingham diagram we can select proper reducing agent (C(s) or CO or A) for metal
compound
,fyaxe vkjs[k dh lgk;rk ls ge /kkrq ;kSfxd ds fy, lgh ;k mi;qDr vipk;d (C(s) ;k CO ;k A) dk p;u dj
ldrs gSA

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25. The quantum number of four electrons are given below :
Pkj bysDVªkWuksa dh DokUVe la[;k;sa uhps nh xbZ gS&
(I) n = 4,  = 2, m = –2, ms = –1/2 (II) n = 3,  = 2, m = 1, ms = +1/2
(III) n = 4,  = 1, m = 0, ms = +1/2 (IV) n = 3,  = 1, m = 1, ms = –1/2
The correct order of their increasing energies will be :
budh c<+rh ÅtkZvksa dk lgh Øe gksxk&
(1) I < II < III < IV (2) I < III < II < IV (3) IV < II < III < I (4) IV < III < II < I
Ans. (3)
Sol. From n +  rule the increasing order of energies of electrons will be IV < II < III < I
n + fu;e bys DVªkWuksa dh c<+ rh ÅtkZvksa dk lgh Øe gksxk& IV < II < III < I
26. The IUPAC name of the following compound is

CH3 OH
H3C–CH–CH–CH2–COOH
(1) 3-Hydroxy-4-methylpentanoic acid (2) 2-Methyl-3-hydroxypentan-5-oic acid
(3) 4,4-Dimethyl-3-hydroxybutanoic acid (4) 4-Methyl-3-hydroxypentanoic acid
fuEu ;kSfxd dk vkbZ-;w-ih-,-lh- (IUPAC) uke gS&

CH3 OH
H3C–CH–CH–CH2–COOH
(1) 3-gkbMªkDlh- 4-esfFkyisUVkuksbd ,flM (2) 2-esfFky-3-gkbMªkDlhisUVsu-5-vksbd ,flM
(3) 4,4-MkbesfFky-3-gkbMªkDlhC;wVsuksbd ,flM (4) 4- esfFky-3-gkbMªkDlhisUVsuksbd ,flM
Ans. (1)
2
4 3 1 OH
Sol. 5
OH O
3-Hydroxy-4-methylpentanoic acid. (3-gkbMªkWDlh-4-esfFkyisUVsuksbZd vEy½
27. The following ligand is :

fuEufyf[kr layXuh gS&
NEt2
– –
O O
(1) bidentate (2) hexadentate (3) tridentate (4) tetradentate

(1) f}&na rqj (2) "kV~&narqj (3) f=k&narqj (4) prqjna rqj
Ans. (4)
Sol. The given ligand is tetradentate
fn;k x;k layXuh prqjnarqj gSA

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28. The major product of the following reaction is :
fuEu vfHkfØ;k dk eq[; mRikn gS&
O Cl
(i) AlCl 3, heat (i) AlCl3, Å"ek
O +
(ii) H2O (ii) H2O
O Cl
CO2H
Cl
(1) (2)
O O
O
O
(3) (4)
Cl
CO2H Cl O
Ans. (3)
O Cl O O
–
Sol. O + 
3

AlCl OAlCl3  
H 2O OH
Cl Cl
O
O O
29. The size of the iso-electronic species Cl–, Ar and Ca2  is affected by :
(1) Nuclear charge (2) Principal quantum number of valence shell
(3) azimuthal quantum number of valence shell (4) electron-electron interaction in the outer orbitals
fuEu esa ls fdlds }kjk lebysDVªkuh Lih'kht Cl–, Ar rFkk Ca2 dk vkdkj izHkkfor gksxk&
(1) ukfHkdh; vkos'k (2) la;kstdrk dks'k dh eq[; DokUVe la[;k
(3) la;kstdrk dks'k dh ,thewFky DokUVe la[;k (4) cká d{kdksa esa bysDVªkWu&bysDVªkWu vU;ksU;fØ;k
Ans. (1)
Sol. In isoelectronic species, number of electrons are same but size decrease with increase in atomic
number or nuclear charge
lebysDVªkWfud Lih'kht esa bysDVªksuks dh la[;k leku gksrh gS ijUrq ijek.kq Øekda ;k ukfHkdh; vkos'k es o`f) ds
lkFk lkFk vkdkj esa deh vkrh gSA

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30. The correct order of the spin-only magnetic moment of metal ions in the following low-spin
complexes,[V(CN)6]4–, [Fe(CN)6]4–, [Ru(NH3)6]3+, and [Cr(NH3)6]2+ is :
fn;s x;s fuEu&izpØ.k ladjksa [V(CN)6]4–, [Fe(CN)6]4–, [Ru(NH3)6]3+ rFkk [Cr(NH3)6]2+ esa /kkrq vk;uksa ds izpØ.k
ek=k pqEcdh; vk?kw.kksZ dk lgh Øe gS&
(1) V2 > Cr2+ > Ru3 > Fe2+ (2) Cr2+ > Ru3+ > Cr2+ > Fe2+
(3) V2 > Ru3+ > cr2+ > Fe2+ (4) Cr2+ > V2+ > Ru3+ > Fe2+
Ans. (1)
Sol.
Complex ion Electronic configuration Magnetic moment in
of metal ion in the B.M.
complex ion
4–
[V(CN)6] t2g1,1,1, eg0,0 15
4– 2,2,2
[Fe(CN)6] t2g , eg0,0 0
[Ru(NH3)6]3+ t2g2,2,1, eg0,0 3
[Cr(NH3)6]2+ t2g2,1,1, eg0,0 8

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1. The major product of the following reaction is :

2. An organic compound 'X' showing the following solubility profile is :

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(1) nj = k[A][B]2 (2) nj = k[A]2[B] (3) nj = k[A][B] (4) nj = k[A]2[B]2

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10. The correct order of hydration enthalpies of alkali metal ions is :

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(3) C2H5 (4) CH3

CH–CH3 obeys all above statements.

Sol. mnklhu FeCl3  –ve  fQukWy vuqifLFkr gSA

CH–CH3 mi;qZDr lHkh dFkuks dk ikyu djrk gSA

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14. The mirror product of the following reaction is :

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17. Assertion : Ozone is destroyed by CFCs in the upper stratosphere.

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21. The lanthanide ion that would show colour is :

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26. The IUPAC name of the following compound is

fuEu ;kSfxd dk vkbZ-;w-ih-,-lh- (IUPAC) uke gS&

27. The following ligand is :

(1) bidentate (2) hexadentate (3) tridentate (4) tetradentate

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