21.7 The composition of a liquid-phase reaction 2 A + Bwas followed by a spectrophotometric method with the following results: thmin o wm 2% 30 40 ° [BJ(moldm) 0 0.089 0.153 0.200 0.230 0.312 Determine the order of the reaction and its rate constant. 21.9 Cyclopropane isomerizes into propene when heated to 500°C in the gas phase. The extent of conversion for various initial pressures has been followed by gas chromatography by allowing the reaction to proceed for a time with various initial pressures: pylTorr 200-200 400-400-600 600 ts 100 200-100-200 100-200 piTorr 180173373347 559520 where py is the initial pressure and p is the final pressure of cyclopropane. What is the order and rate constant for the reaction under these conditions? 16.31 The reaction »-CjH,Br + S,0}- — CH,S,03 + Br jin agucous solution is first order in C3H;Br and first-order in S,02-. At 37.5°C, the following data were obtained (where c= 1 molidm? and 1 ks = 10° 5): 105[S,0}-Je> 904 | 863 | 766 | 668 tks, 0 | 1110 | 2010 | 5.052 | 11.23: ‘The initial C3H,Br concentration was 39.5 mmol/dm*. Find the rate constant using a graphical method. 16.35 For the reaction A — products, data for a run with [A]o = 0.600 mol dm are: [AVA TATA 0 1 400 osiL 100 0.829 600 0.385 200 0.688 1000 0.248 300 0.597 (@) Find the order of the reaction () Find the rate constant.