JEE Main 2019 Chemistry April Attempt Shift - 2 (09th April, 2019)

PAPER-1 (B.E./B. TECH.
JEE (Main) 2019

COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 9 April, 2019 (SHIFT-2) | TIME: 02.30 P.M. to 05.30 P.M.
Duration: 3 Hours | Max. Marks: 360

SUBJECT: CHEMISTRY
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| JEE (MAIN) 2019 | DATE : 09-04-2019 (SHIFT-2) | PAPER-1 | ORIGINAL PAPER | CHEMISTRY
PART : CHEMISTRY
1. In an acid-base titration , 0.1 M HCI solution was added to the NaOH solution of unknown strength .
which of the following correctly shows the change of pH of the titration mixture in this experiment?
,d vEy {kkjd vuqekiu esa 0.1 M HCI fo;yu dks ,d vKkr lkekF;Z okys NaOH ds foy;u esa feyk;k x;kA bl
iz;ksx esa fuEu esa ls dkSu vuqekiu feJ.k ds pH ifjorZu dks lgh lgh iznf'kZr djrk gS\
pH pH
V(mL) V(mL)
pH pH
V(mL) V(mL)
(1) (B) (2) (A) (3) (C) (4) (D)

Ans. (2)
Sol. HCl + NaOH  NaCl + H2O
at equivalent point pH = 7 and at end point solution will be acidic
rqY;kad fcUnq ij pH = 7 rFkk vfUre fcUnq ij foy;u vEyh; gksxkA
2. Increasing order of reactivity of the following compounds for SN1 substitution is :

SN1 izfrLFkkiu ds fy, fuEu ;kSfxdksa dh vfHkfØ;k'khyrk dk c<+ rk Øe gS%
CH3
CH2 – CI H3C CI
(A) (B)
CH3
CI CI
(C) (D)
H3CO
(1) (B) < (C) < (A) < (D) (2) (A) < (B) < (D) < (C)
(3) (B) < (C) < (D) < (A) (4) (B) < (A) < (D) < (C)
Ans. (4)
Sol. The SN1 reactivity is proportional to stability of carbocations formed in the rate determining step.
SN1 vfHkfØ;k dh fØ;k'khyrk nj fu/kkZjd in esa cuus okys dkcZ/kuk;u ds LFkkf;Ro ds lekuqikrh gksrk gSA

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3. The correct statements among I to III regarding group 13 element oxides are,
(I) Boron trioxide is acidic
(II) Oxides of aluminum and gallium are amphoteric.
(III) Oxides of indium and thallium are basic
(1) (I) and (II) Only (2) (I) and (III) Only
(3) (I), (II) and (III) (4) (II) and (III) Only
xzqi 13-rRoksa ds vkWDlkbMksa ls lEcfU/kr I ls III esa ls lgh dFku gS%
(I) cksjkWu VªkbvkWDlkbM vEyh; gS A (II) ,Ykqfefu;e rFkk xSfy;e ds vkWDlkbM mHk;/kehZ gSA
(III) bufM;e rFkk FkSfy;e ds vkWDlkbM {kkjh; gSaA

(1) (I) rFkk (II) ek=k (2) (I) rFkk (III) ek=k
(3) (I), (II) rFkk (III) (4) (II) rFkk (III) ek=k
Ans (3)
Sol. B2O3 is acidic oxide
Al2O3 and Ga2O3 are amphoteric oxides
In2O3 and Tl2O3 are basic oxides.
B2O3 vEyh; vkWDlkbM gS
Al2O3 rFkk Ga2O3 mHk;èkehZ vkWDlkbM gS A
In2O3 rFkk Tl2O3 {kkjh; vkWDlkbM gSA
4. During compression of a spring the work done is 10 kJ and 2 kJ escaped to the surroundings as heat.
The change in internal energy, U(in kJ) is :
,d fLizax dks laIkhfMr djus esa fd;k x;k dk;Z 10 kJ gS rFkk 2 kJ Å"ek ds :Ik esa okrkoj.k dks pyk tkrk gSA
vkarfjd ÅtkZ esa ifjorZu U(in kJ) esa gksxkA
(1) 8 (2) –12 (3) 12 (4) –8
Ans. (1)
Sol. q = – 2kJ
w = + 10 kJ
U = q + w = –2 + 10 = + 8 kJ
5. A solution of Ni(NO3)2 is electrolyzed between platinum electrodes using 0.1 Faraday electricity. How
many mole of Ni will be deposited at the cathode?
0.1 QSjkMs fo|q r dk iz ;ksx djrs gq,] IysfVue bys DVªksMksa ds chp Ni(NO3)2 ds foy;u dks fo|q r vi?kfVr fd;k
x;kA dSFkksM+ ij Ni dk fdruk eksy fu{ksfir gksxk\

(1) 0.20 (2) 0.15 (3) 0.10 (4) 0.05
Ans. (4)
Sol. Ni(NO3)2  Ni 2+ + 2NO3–
at cathode:
dSFkksM+ ij
Ni2+ + 2e–  Ni
2F  1mole
0 .1
0.1F  = 0.05 mole
2

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6. Which one of the following about an electron occupying the 1s orbital in a hydrogen atom is incorrect?
(The Bohr radius is represented by a0).
(1) The total energy of the electron is maximum when it is at a distance a0 from the nucleus.
(2) The magnitude of the potential energy is double that of its kinetic energy on an average.
(3) The probability density of finding the electron is maximum at the nucleus.
(4) The electron can be found at a distance 2a0 from the nucleus.
gkbMªkstu ijek.kq ds 1s d{kd esa mifLFkr bysDVªkWu ds ckjs esa fuEu esa ls dkSu lk lgh ugha gS\ (cksj f=kT;k dks a0
}kjk iznf'kZr fd;k x;k gSA)
(1) bysDVªkWu dh dqy ÅtkZ mPpre rc gksxh tc og ukfHkd ls a0 nwjh ij gSA
(2) vkSlru] fLFkfrt ÅtkZ dk eku blds xfrt ÅtkZ ds eku nqxquk gSA
(3) bysDVªkWu ds ik;s tkus dk izkf;drk ?kuRo ukfHkd ij lokzf /kd gSA
(4) bysDVªkWu] ukfHkd ls 2a0 dh nwjh ij ik;k tk ldrk gS A
Ans. (1)
Sol. (1) Total energy of electron is minimum in first orbit i.e. at a0 distance from nucleus.
K Z e2
(2) P.E. = –
r
2
1 K Ze
K.E. = |P.E.| = 2|K.E.|
2 r
1s
2
(3) 2 is maximum at nucleus
r
(4) Electron can be found at any distance from nucleus.
1s
P
P  Probability function.
7. The structures of beryllium chloride in the solid state and vapour phase, respectively are:
(1) Chain and chain (2) chain and dimeric
(3) dimeric and chain (4) dimeric and dimeric
csjhfy;e DyksjkbM dh lajpuk,a Bksl voLFkk rFkk ok"Ik izkoLFkk esa Øe'k% gS%
(1) Jà[kyk rFkk J`a[kyk (2) Jà[kyk rFkk f}r;h
(3) f}r;h rFkk J`a[kyk (4) f}r;h rFkk f}r;h

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Ans. (1)
Sol. BeCl2 in solid phase
Cl Cl Cl
Be Be Be
Cl Cl Cl
Chain
Cl
BeCl in vapour phase  Cl–Be Be–Cl
Cl
dimeric
8. The maximum number of possible oxidation states of actinoides are shown by :

(1) berkelium (Bk) and californium (Cf)
(2) nobelium (No) and lawrencium (Lr)
(3) actinium (Ac) and thorium (Th)
(4) neptunium (Np) and plutonium (Pu)
,DVhUok;M+ksa dh lEHko vkWDlhdj.k voLFkkvksa dh mPPkre la[;k fuEuesa ls fdlds }kjk iznf'kZr gksrh gS\
(1) cdsZfy;e (Bk) rFkk dyhQksfuZ ;e (Cf)
(2) ukscsfy;e (No) rFkk ykjsfZUl;e (Lr)
(3) ,DVhfu;e (Ac) rFkk Fkksfj;e (Th)
(4) usIV;wfu;e (Np) rFkk IyqVksfu;e (Pu)
Ans (4)
Sol. Bk & Cf : + 3 & + 3, + 4, respectively
No & Lr : + 3
Ac & Th : + 3 & + 4 respectively
Np & Pu : + 3, + 4, + 5, + 6, + 7
Bk rFkk Cf : Øe'k% + 3 & + 3, + 4

No rFkk Lr : + 3
Ac rFkk Th : Øe'k%+ 3 & + 4
Np rFkk Pu : + 3, + 4, + 5, + 6, + 7
9. 10 mLof 1 mM surfactant solution forms a monolayer covering 0.24 cm2 on a polar substrate. If the
polar head is approximated as a cube, what is its edge length?
1 mM i`"B lafØ;d fo;yu dk 10 mL ,d iksyj voLrj ij ,d eksuksys;j cukdj 0.24 cm2 ?ksjrk gS A ;fn iksyj
gsM dks ,d ?kud :Ik esa ekuk tk; rks blds dksj dh yEckbZ D;k gksxh\
(1) 1.0 pm (2) 2.0 nm (3) 0.1 nm (4) 2.0 pm
Ans. (4)
Sol. Total area = area covered by one particle × Number of particles
dqy {ks=kQy = ,d d.k }kjk ?ksjk x;k {ks=kQy × d.kksa dh la[;k

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10 –3  10
 0.24 = a2 ×  NA
10 3
a = 2 × 10–10 cm = 2pm
10. Hinsberg's reagent is :

fgalcxZ vfHkdeZd gS&
(1) SOCI2 (2) C6H5COCI (3) (COCI)2 (4) C6H5SO2CI
Ans. (4)
Sol. Hinsberg reagent is benzene sulphonyl chloride (C6H5SO2Cl)
csUthu lYQksfuy DyksjkbM (C6H5SO2Cl) dks fgUlcxZ vfHkdeZd dgrs gSA
11. The correct statements among I to III are

(I) Valence bond theory cannot explain the color exhibited by transition metal complexes.
(II) Valence bond theory can predict quantitatively the magnetic properties of transition metal
complexes.
(III) Valence bond theory cannot distinguish ligands as weak and strong field ones.
(1) (I) and (III) Only (2) (I) and (II) Only
(3) (I), (II) and (III) (4) (II) and (III) Only
I ls III esa ls lgh dFku gS %
(I) laØe.k /kkrq ladjksa }kjk iznf'kZ r ja x dks la ;kstdrk vkcU/k fl)kUr le>k ugha ldrkA
(II) laØe.k /kkrq la djksa ds pqEcdh; xq .kksa dh ek=kkRed izkxqfDr la;kstdrk vkcU/k fl)kUr dj ldrk gSA
(III) la;kstdrk vkcU/k fl)kUr nq cZy rFkk izcy {ks=k ds fyxUMksa ds chp vUrj ugha crk ldrkA
(1) (I) rFkk (III) ek=k (2) (I) rFkk (II) ek=k
(3) (I), (II) rFkk (III) (4) (II) rFkk (III) ek=k
Ans (1)
Sol. VBT does not explain the colour exhibited by co-ordination compounds.
VBT does not explains and gives quantitative interpretation of magnetic data.
VBT does not distinguish between weak field ligand and strong field ligand.
VBT milgla ;kstd ;kSfxdksa }kjk iznf'kZr ja x dks ugha le>krk gSA
VBT pqEcdh; vkWdM+ksa ds xq.kkRed Li"Vhdj.k dks ugha le>krk gSA
VBT nq cZy {ks=k fyxs .M rFkk iz cy {ks=k fyxs.M ds e/; varj ugha djrk gS A
12. The peptide that gives positive ceric ammonium nitrate and carbylamines tests is :
og isIVkbM tks ldkjkRed lsfjd veksfu;e ukbVªsV rFkk dkfcZy,sehu ijh{k.k nsrk gS] og gS%
(1) Asp-Gln (2) Lys-Asp
(3) Ser-Lys (4) Gln-Asp
Ans. (3)

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Sol. In Ser – Lys, alcoholic and amine groups are present respectively hence it will show positive test with
cerric ammonium nitrate and carbyl amine.
Ser-Lys esa] Øe'k% ,Ydksgkfyd rFkk ,ehu lew g mifLFkr gS] vr% ;g lSfjd veksfu;e ukbVªsV ,oa dkfcZy ,ehu ds
lkFk /kukRed ijh{k.k nsrk gSA
13. The amorphous form of silica is :

flfydk dk vfØLVyh; :Ik gS%
(1) quartz DokVZ~l (2) tridymite VªkbMkekbV
(3) cristobalite fØLVks csykbV (4) kieselguhr fdtsyxwj
Ans. (4)
Sol. The amorphous form of silica is kieselguhr.
fdtsyxwj flfydk dk vfØLVyh; :Ik gSA
14. The major product of the following reaction is :

fuEu vfHkfØ;k dk eq[; mRikn gS%
OH
CH2OH
H2SO4(cat.) (mRizsjd½
CO2Et CHCI3
OH OH
(1) (2) (3) OEt (4)

CO2Et O O COOH
Ans. (2)
OH
OH
H2SO4 (Cat.)
OH 
Sol.  O
CHCl3
COOEt O
It is acid catalysed intramolecular trans esterification reaction.
;g vEy mRizsfjr vUr%v.kqd Vªkal ,LVjhdj.k vfHkfØ;k gSA
15. Among the following species, the diamagnetic molecule is :

fuEu Lih'kht esa] izfrpqEcdh; v.kq gS %
(1) CO (2) B2
(3) NO (4) O2
Ans. (1)
Sol. According to MOT, O2 , B2 & NO are paramagnetic, only CO is diamagnetic.
MOT ds vuqlkj O2, B2 rFkk NO vuqpqEcdh; gS ds oy CO izfrpqEcdh; gSA

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16. Molal depression constant for a solvent is 4.0 K kg mol–1.The depression in the freezing point of the
solvent for 0.03 mol kg–1 solution of K2SO4 is : (Assume complete dissociation of the electrolyte)
,d foyk;d ds fy, eksyy voueu fLFkjkad 4.0 K kg mol–1 gSA K2SO4 ds 0.03 mol kg–1 foy;u ds fy,
foyk;d ds fgekad esa fxjkoV gksxh] (eku yhft, fo|qr vi?kVu dk fo;kstu iw.kZ :is.k gSA)
(1) 0.12 K (2) 0.24 K
(3) 0.36 K (4) 0.18 K
Ans. (3)
Sol. Tf = iKfm
= 3 × 4 × 0.03
= 0.36 K
17. The maximum possible denticities of a ligand given below towards a common transition and inner-
transition metal ion, respectively are,
 OOC COO 
N N N
 OOC COO 
COO 
(1) 6 and 8 (2) 6 and 6
(3) 8 and 6 (4) 8 and 8
lkekU; VªkfUt'ku rFkk buj&VªkfUt'ku /kkrq ds izfr uhps fn;s x;s fyxS.Mdh vf/kdre lEHko nfUrdrk;sa Øe'k% gS%
 OOC COO 
N N N
 OOC COO 
COO 
(1) 6 rFkk 8 (2) 6 rFkk 6
(3) 8 rFkk 6 (4) 8 rFkk 8
Ans. (1)
Sol. Common CN of transition elements = 6
Common CN of inner transition elements = 8 to 12
laØe.k rRoksa dh lkekU; CN = 6
var% laØe.k rRoksa dh lkekU; CN = 8 ls 12
18. The one that is not a carbonate ore is :

og ,d tks dkcksZusV v;Ld ugha gS] og gS%
(1) bauxite ckWDlkbV (2) malachite esykdkbV
(3) siderite flMsjkbV (4) calamine dsykekbu
Ans (1)

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Sol. Bauxite ckWDlkbV: AlOx (OH)3–2x (0 < x < 1)
Malachite esysdkbV: CuCO3 Cu (OH)2
Siderite flMsjkbV: FeCO3
Calamine dSykekbu: ZnCO3
19. The major products A and B for the following reactions are respectively:
fuEufyf[kr vfHkfØ;kvksa ds eq[; mRikn A rFkk B Øe'k% gS%
O
I KCN
|A] H2/pd |B]
DMSO
O O O OH
CN CH2NH2 CN CH2NH2
(1) ; (2) ;
HO CN HO CH2– NH2 HO CN OH CH2– NH2

I H I
(3) ; (4) I
;
Ans. (2)
Sol.
O OH
O I CN CH2NH2
KCN H2, Pd
DMSO
SN2 reaction
20. HF has highest boiling point among hydrogen halides, because it has:
(1) Strongest van der Waals' interactions
(2) Lowest ionic character
(3) Strongest hydrogen bonding
(4) Lowest dissociation enthalpy
HF dk DoFkukad gkbMªkstu gSykbMksa esa mPPre gks rk gS] bldk dkj.k gS%
(1) izcyre ou Mj okYl vU;ksU;fØ;k
(3) izcyre gkbMªkstu vkcU/ku
(2) fuEure vk;fud LoHkko
(4) fuEure fo;kstu ,UFkSYih
Ans (3)

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Sol. Due to Hydrogen bonding HF has high Boiling point amongst Hydrogen halides.
gkbMªkstu ca/ku ds dkj.k HF lHkh gkbMªkstu gSykbMksa esa mPp DoFkukad j[krk gSA
21. What would be the molality of 20% (mass/mass) aqueous solution of KI? (molar mass of KI = 166 g
mol–1)
KI ds 20% (nzO;eku@nzO ;eku½ tyh; foy;u dh eksyyrk D;k gksxh\ (KI dk eksyj nzO;eku= 166 g mol–1)
(1) 1.35 (2) 1.08 (3) 1.48 (4) 1.51

Ans. (3)
Sol. 20 gm KI is present in 100 gm solution
Weight of solvent = 100 – 20 = 80 gm
20
moles of solute =
166
20
molality (m) =  1000  1.51
166  80
Sol. 20 gm KI, 100 gm foy;u esa mifLFkr gS A
foyk;d dk Hkkj = 100 – 20 = 80 gm
20
foys; ds eksy =
166
20
eksysfyfV (m) =  1000  1.51
166  80
O
22. Which of the following compounds is a constituent of the polymer [ HN – C – NH – CH2]n
?
(1) Methylamine (2) N-Methyl urea
(3) Formaldehyde (4) Ammonia
O
fuEu esa ls dkSu lk ,d ;kSfxd] cgqyd [ HN – C – NH – CH2]n dk la?kVd gS\
(1) esfFky ,sehu (2) N- esfFky ;wfj;k
(3) QkesZYMhgkbM (4) veksfu;k
Ans. (3)
Sol. It is urea formaldehyde polymer and it's monomers are urea and formaldehyde.
;g ;wfj;k QkWeZsfYMgkbM cgqyd gS rFkk ,dyd ;wfj;k ,oa QkWeZsfYMgkbM gSA

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23. Consider the given plot of enthalpy of the following reaction between A and B. A + B  C + D.
Identify the incorrect statement.
20
15
Enthalpy 10
(kj mol–1) D
5
A+B C
Reaction Coordinate
(1) C is the thermodynamically stable product
(2) Formation of A and B from C has highest enthalpy of activation.
(3) Activation enthalpy to form C is 5 kJ mol–1 less than that to form D.
(4) D is kinetically stable product.
fuEufyf[kr A ,oa B ds chp vfHkfØ;k dh ,UFkSYih ds fn;s x;s IykV ij fopkj dhft,A
A + B  C + D.
rFkk xyr dFku dks crkb;sA
20
15
,UFkSYih 10
(kj mol–1) D
5
A+B C
vfHkfØ;k funsZ'kkad
(1) C Å"ekxfrdh; :Ik esa fLFkj mRikn gS A
(2) C ls A rFkk B ds cuus esa lafØ;.k ,UFkSYih mPpre gS A

(3) C dks cukus esas lafØ;.k ,UFkSYih D dks cukus esa yxus okyh lafØ;.k ,UFkSYih ls 5 kj mol–1 de gS A
(4) D xfrdr LFkk;h mRikn gSA
Ans. (3)
Sol. ED – EC = 15 – 5 = 10 kJ/mol
 Ea to form C = 15 kJ/mol
Ea to form D = 10 kJ/mol
Ea to form C is 5 kJ/mol higher than to form D.
 C is thermodynamically stable product as it has lesser enthalpy.
 D is kinetically stable product as it is formed at a faster rate (lesser Ea required to form product)
24. The layer of atmosphere between 10 km to 50 km above the sea level is called as:
(1) stratosphere (2) mesosphere (3) thermosphere (4) troposphere
leqæry ls 10 ls 50 Km Åpk¡bZ ij mifLFkr lrg dks dgk tkrk gSA
(1) lerki e.My (2) ehtks LQh;j (3) FkeksZ LQh;j (4) {kksHk e.My
Ans. (1)

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Sol. Stratosphere lies between 10 to 50 Km. from sea level.
leqæry ls 10 ls 50 Km Åpk¡bZ ij lerki e.My ik;k tkrk gSA
25. Which of the following potential energy (PE) diagrams represents the SN1 reaction?
fLFkfrt ÅtkZ dk fuEu esa ls dkSulk vkjs[k SN1 vfHkfØ;k dks vfHkO;DRk djrk gS%&
PE PE
(1) (2)
Progress of reaction Progress of reaction
PE PE
(3) (4)
Progress of reaction Progress of reaction
fLFkfrt
fLFkfrt ÅtkZ
(1) ÅtkZ (2)
vfHkfØ;k esa izxfr

vfHkfØ;k esa izxfr
fLFkfrt fLFkfrt
ÅtkZ ÅtkZ
(3) (4)
vfHkfØ;k esa izxfr vfHkfØ;k esa izxfr

Ans. (3)
Sol. SN1 is a two step reaction in which first step is rate determining step. Hence the peak of first step is
higher than second step.
SN1 vfHkfØ;k f)ifn; vfHkfØ;k gks rh gS ftlesa izFke in nj fu/kkZjd in gks rk gS A vr% izFke in dk 'kh"kZ f}rh;
in ls T;knk gksrk gSA

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26. Assertion : For the extraction of iron, hematite ore is used.
Reason : Haematite is a carbonate ore of iron.
(1) Both the assertion and reason are correct and the reason is the correct explanation for the
assertion.
(2) Only the reason is correct.
(3) Both the assertion and reason are correct, but the reason is not the correctly explanation for the
assertion
(4) Only the assertion is correct.
dFku: vk;ju ds fu"d"kZ.k ds fy, gsekVkbV v;Ld iz;qDr gksrk gSA
dkj.k: gsesVkbV vk;ju dk dkcksZusV v;Ld gS
(1) dFku vkSj dkj.k nksuksa lR; gS vkSj dkj.k dFku dh lgh O;k[;k djrk gSA
(2) ek=k dkj.k lR; gS A
(3) dFku vkSj dkj.k nksuksa lR; gS ijUrq dkj.k dFku dh lgh O;k[;k ugha djrk gS A
(4) ek=k dFku lR; gS A
Ans (4)
Sol. Haematite gsesVkbV: Fe2O3
27. At a given temperature T, gases Ne, Ar, Xe and Kr are found to deviate from ideal gas behavior. Their
RT
equation of state is given as P  at T. Here, b is the van der Waals constant Which gas will exhibit
V b
steepest increase in the plot of Z (compression factor) vs p ?
fn; x;s rki T ij ;g ik;k x;k fd Ne, Ar, Xe rFkk Kr xSlsa vkn'kZ xSl O;ogkj ls fopfyr gksrh gSA mudk
RT
voLFkk lehdj.k bl izdkj fn;k gS P  at T. ;gka b okUMj fLFkjkad gSA dkSu lh xSl Z (laihMUkdkjd) rFkk p
V b
ds IykV esa lokZf/kd [kM+h o`f) iznf'kZr djsxh?

(1) Xe (2) Ar (3) Kr (4) Ne
Ans. (1)
Pb
Sol. Z = 1
RT
At constant T, slope of Z vs P graph  b
Xe has the maximum radius, maximum b & hence its graph will be steepest.
Pb
Sol. Z = 1
RT
fu;r T ij Z vs P xzkQ dk <ky  b
Xe vf/kdre f=kT;k j[krk gS rFkk blfy, vf/kdre b blfy, bldk xzkQ mPpre gksxkA

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28. p-Hydroxybenzophenone upon reaction with bromine in carbon tetrachloride gives:
dkcZu&VsVªk DyksjkbM esa czksehu ds lkFk vfHkfØ;k djus ij p- gkbMªksDlh csatksQsuksu nsrk gS%
Br O O
Br
(1) (2)
HO HO
O O
Br
Br
(3) (4)
HO HO
Ans. (3)
O O
Br2
Sol. HO CCl4 HO
Br
29. In the following reaction –

HCl
carbonyl compound + MeOH acetal
Rate of the reaction is the highest for –
(1) Acetone as substrate and methanol in excess
(2) Propanal as substrate and methanol in excess
(3) Acetone as substrate and methanol in stoichiometric amount
(4) Propanal as substrate and methanol in stoichiometric amount
fuEu vfHkfØ;k esa &
HCl
dkcksZfuy ;kSfxd + MeOH ,flVsy
vfHkfØ;k dh nj fuEu esa ls fdlds fy, mPpre gS\
(1) ,lhVksu voLrj ds :i esa rFkk es FksukWy vkf/kD; esa
(2) izksisuy voLrj ds :i esa rFkk esFksukWy vkf/kD; esa
(3) ,lhVksu voLrj ds :i esa rFkk esFksukWy LVkWbfd;ksehVªh ek=kk esa
(4) izksisuy voLrj ds :i esa rFkk esFksukWy LVkWbfd;ksehVªh ek=kk esa
Ans. 2
Sol. Aldehydes are more reactive than ketones.
Higher the concentration of alcohol rate of reaction is also high.
30. Noradrenaline is a/an :
(1) Neurotransmitter (2) Antacid (3) Antidepressant (4) Antihistamine
Ukj,sMªhusfyu gS ,d
(1) ra=kdh; lapkyd (2) izfrvEy (3) izzfr&volknd (4) izfrfgLVkfeu
Ans. (1)
Sol. Noradrenaline is one of the example of Neurotransmitter.
ukWj&,Mªsusfyu] raf=kdk lapkyd dk mnkgj.k gSA

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JEE Main 2019 Chemistry April Attempt Shift - 2 (09th April, 2019)

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Duration: 3 Hours | Max. Marks: 360

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(1) (B) (2) (A) (3) (C) (4) (D)

2. Increasing order of reactivity of the following compounds for SN1 substitution is :

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(III) bufM;e rFkk FkSfy;e ds vkWDlkbM {kkjh; gSaA

x;kA dSFkksM+ ij Ni dk fdruk eksy fu{ksfir gksxk\

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(4) bysDVªkWu] ukfHkd ls 2a0 dh nwjh ij ik;k tk ldrk gS A

(3) f}r;h rFkk J`a[kyk (4) f}r;h rFkk f}r;h

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8. The maximum number of possible oxidation states of actinoides are shown by :

(2) ukscsfy;e (No) rFkk ykjsfZUl;e (Lr)

(3) ,DVhfu;e (Ac) rFkk Fkksfj;e (Th)

(4) usIV;wfu;e (Np) rFkk IyqVksfu;e (Pu)

Bk rFkk Cf : Øe'k% + 3 & + 3, + 4

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10. Hinsberg's reagent is :

11. The correct statements among I to III are

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13. The amorphous form of silica is :

(3) cristobalite fØLVks csykbV (4) kieselguhr fdtsyxwj

14. The major product of the following reaction is :

(1) (2) (3) OEt (4)

15. Among the following species, the diamagnetic molecule is :

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(1) 6 rFkk 8 (2) 6 rFkk 6

(3) 8 rFkk 6 (4) 8 rFkk 8

18. The one that is not a carbonate ore is :

(3) siderite flMsjkbV (4) calamine dsykekbu

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HO CN HO CH2– NH2 HO CN OH CH2– NH2

(1) izcyre ou Mj okYl vU;ksU;fØ;k

(3) izcyre gkbMªkstu vkcU/ku

(2) fuEure vk;fud LoHkko

(4) fuEure fo;kstu ,UFkSYih

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(1) 1.35 (2) 1.08 (3) 1.48 (4) 1.51

(3) QkesZYMhgkbM (4) veksfu;k

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(2) C ls A rFkk B ds cuus esa lafØ;.k ,UFkSYih mPpre gS A

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Progress of reaction Progress of reaction

Progress of reaction Progress of reaction

vfHkfØ;k esa izxfr

vfHkfØ;k esa izxfr vfHkfØ;k esa izxfr

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(2) ek=k dkj.k lR; gS A

(4) ek=k dFku lR; gS A

ds IykV esa lokZf/kd [kM+h o`f) iznf'kZr djsxh?

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29. In the following reaction –

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