JEE Main 2019 Chemistry April Attempt Shift - 1 (10th April, 2019)

PAPER-1 (B.E./B. TECH.
JEE (Main) 2019

COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 10 April, 2019 (SHIFT-1) | TIME: 09.30 A.M. to 12.30 P.M.
Duration: 3 Hours | Max. Marks: 360

SUBJECT: CHEMISTRY
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| JEE (MAIN) 2019 | DATE : 10-04-2019 (SHIFT-1) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
PART : CHEMISTRY
1. The correct order of catenation is :
J`a[kyu dk lgh Øe gS %
(1) C > Sn > Si  Ge (2) Si > Sn > C > Ge (3) Ge > Sn > Si > C (4) C > Si > Ge  Sn
Ans. (4)
Sol. The decreasing order of catenation Ja`[kyu dk ?kVrk Øe : C > Si > Ge ~ Sn
2. The major product of the following reaction is :

fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
OH , fFky QkesV
CH3CHCH2CH2NH2
ethylformate (1eq.)
 
 Z  ¼1 rqY ;½

triethylamin e Vª kbZ, fFky,es hu
O H
(1) (2) CH3CH = CH – CH2NH2
CH3CHCH2CH2NH2
OH
(3) (4) OH
CH3–CH–CH=CH2
CH3CHCH2CH2NHCHO
Ans. (4)
OH O O
NEt3
Sol. CH3–CH–CH2–CH2–NH2 + H–C–OEt CH3–CH–CH2–CH2–NH–C–H
OH
3. At 300 K and 1 atmospheric pressure, 10mL of a hydrocarbon required 55 mL of O2 for complete

combustion, and 40 mL of CO2 is formed. The formula of the hydrocarbon is :
300 K rFkk 1 ok;qeaMyh; nkc ij] gkbMªksdkcZu ds 10mL ds iw.kZ ngu ds fy, 55 mL O2 dh vko';drk gks rh gS
rFkk 40 mL CO2 mRiUu gksrh gSA gkbMªksdkcZu dk lw=k gS %
(1) C4 H7Cl (2) C4H6 (3) C4H10 (4) C4H8
Ans. (2)
 y y
Sol. CxHy +  x   O2   xCO2 + H2O
 4 2
10 ml 55 ml 40 ml
10 40
   x=4
1 x
10 55 10 55
=  = y = 6
1  y 1  y
 x  4 
 4  
 4 
Hydrocarbon is (gkbMªksdckZu gS A) C4H6
4. The synonym for water gas when used in the production of methanol is :
(1) Natural gas (2) fuel gas (3) laughing gas (4) syn gas
Ans. (4)

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Sol. CO + H2 is synthesis gas or syn gas. Methanol is prepared by catalytic hydrogenation of carbon
monoxide at high pressure and temperature and in the presence of ZnO – Cr2O3 catalyst.

g
O
HI(excess)

NC O
OH I OH I
(1) (2) (3) (4)

NC I NC OH NC OH NC I
Ans. Official Answer by NTA is (3)
Reso answer is (1)
O OH
H ( excess) H ¼vkf/kD;½
Sol.    
heat( SN 2 reaction) xeZ ¼ S 2 vfHkfØ;k½
N
NC O NC 
6. The graph between |  |2 and r(radial distance) is shown below. This represents:
|  |2 rFkk r (jsfM;y nwjh) ds chp xzkQ uhps iznf'kZ r gS A ;g n'kkZrk gS %
|  |2
r
(1) 1s orbital d{kd (2) 3s orbital d{kd (3) 2p orbital d{kd (4) 2s orbital d{kd
Ans. (4)
Sol. By the graph since 2 is not zero at r = 0 it must be s orbital
also n –  –1 = 1
n = 2 (  = 0)
it is 2s orbital
xzkQ ds vuqlkj pwdh r = 0 ij 2 dk eku 'kwU; ugh gSA vr% ;g s d{kd gksuk pkfg,s
rFkk n –  –1= 1
n = 2 (  = 0)
;g 2s d{kd gSA

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7. Major products of the following reaction are :
CHO
(i) 50% NaOH
+HCHO
(ii) H3O+
CH2OH COOH CH2OH

and
HCOOH and
(1) (2)
COOH
CH3OH and
(3) (4) CH3OH and HCO2H
fuEu vfHkfØ;k ds eq[; mRikn gS %

CHO
(i) 50% NaOH
+HCHO
(ii) H3O+
CH2OH COOH CH2OH

rFkk HCOOH rFkk
(1) (2)
COOH
(3)
CH3OH rFkk (4) CH3OH rFkk HCO2H
Ans. (2)
Sol. Major product is obtained through cross Cannizzaro reaction.
eq[; mRikn ØkWl (cross) dSfutkjks vfHkfØ;k ls izkIr gksrs gSA
COOH CH2OH
(i) 50% NaOH

+ HCHO   + HCOOH
(ii) H2O
8. At room temperature, a dilute solution of urea is prepared by dissolving 0.60 g of urea in 360 g of water.
If the vapour pressure of pure water at this temperature is 35 mm Hg, lowering of vapour pressure will
be :
(molar mass of urea = 60 g mol–1)
d{k rki ij] ;wfj;k dk ,d rqu foy;u 0.60 g ;wfj;k dks 360 g ty esa ?kksydj cuk;k tkrk gSA bl rki ij ;fn
'kq) ty dk ok"i nkc 35 mm Hg gks rks ok"i nkc dk voueu gksxk %
(;wfj;k dk eksyj nzO ;eku = 60 g mol–1)
(1) 0.027 mmHg (2) 0.028 mmHg (3) 0.017 mmHg (4) 0.031 mmHg
Ans. (3)

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P  Ps
0
n
Sol. 
P0 nN
n
Lowering in V.P.= P0 ×
nN
0.6
= 35 × 60 = 0.017 mm of Hg.
0.6 360

60 18
9. A baclerial infection in an internal wound grows as N(t) = N0 exp(t), where the time t is in hours, A dose
of antibiotic, taken orally, needs 1 hour to reach the wound. Once it reaches there, the bacterial
dN N
population goes down as = –5N2. What will be the plot of 0 vs. t after 1 hour ? 
dt N
,d vkarfjd ?kko esa cSDVhfj;k laØe.k bl izdkj c<+rk gS N(t) = N0 exp(t) tgk¡ le; t ?kaVs esa gSA eq[k ls
,UVhck;Vhd dh ,d [kqjkd yssus ij ,aVhck;fVd ?kku rd igq¡pus esa ,d ?kaVs ysrh gSA ,d ckj og ogk¡ igq¡p tkrh gS
dN N
rks cSDVhfj;k dh la[;k uhsps bl izdkj , = –5N2 pyh tkrh gSA 0 lkis{k t xzkQ ,d ?kaVs ckn gksxk %
dt N
N0 N0
N N
(1) (2)
t(h) t(h)
N0 N0
N N
(3) (4)
t(h) t(h)
Ans. (2)
N0
Sol. After injecting drug N(t) will decrease so will increase.
N
vkS"k/kh nsus ds i'pkr~ N(t) esa deh gksxh blfy, esa o`f) gksxhA
10. Match the refining methods (Column-I) with metals (Column-II)

(Column-I) (Column-II)
(Refining methods) (Metals)
(I) Liquation (a) Zr
(II) Zone Refining (b) Ni
(III) Mond Process (c) Sn
(IV) Van Arkel Mehtod (d) Ga
(1) (I) - (c); (II) - (d) ; (III) - (b) ; (IV) - (a)
(2) (I) - (b); (II) - (c) ; (III) - (d) ; (IV) - (a)
(3) (I) - (b); (II) - (d) ; (III) - (a) ; (IV) - (c)
(4) (I) - (c); (II) - (a) ; (III) - (b) ; (IV) - (d)
Ans. (1)

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Sol. (a) Mond process  Ni
(b) Van-Arkel  Zr
(c) Liquation  Sn
(d) Zone refining  Ga
(a) ekW.M iz Øe  Ni
(b) okWu -vkdZy  Zr
(c) nzohdj.k  Sn
(d) e.My ifj'kks/ku  Ga
11. Three complexes,

[CoCl(NH3)5]2+ (I), [Co(NH3)5 H2O]3+(II) and [Co(NH3)6]3+ (III)
absorb light in the visible region. The correct order of the wavelength of light absorbed by them is :
(1) (III) > (I) > (II) (2) (II) > (I) > (III) (3) (I) > (II) > (III) (4) (III) > (II) > (I)
Three complexes,
[CoCl(NH3)5]2+ (I), [Co(NH3)5 H2O]3+(II) and [Co(NH3)6]3+ (III)
absorb light in the visible region. The correct order of the wavelength of light absorbed by them is :
(1) (III) > (I) > (II) (2) (II) > (I) > (III) (3) (I) > (II) > (III) (4) (III) > (II) > (I)
Ans. (3)
Sol.  absorbed depends on strength of ligand. For stronger ligand, 0 will be higher,  will be lesser.
NH3 > H2O > Cl– decreasing order of strength of ligand.
vo'kksf"kr fyxs.M ds lkeF;Z ij fuHkZj djrk gSA Ikzcy fyxs.M ds fy 0 vf?kd gksxk RkFkk de gksxhA
NH3 > H2O > Cl– fyxs.M ds lkeF;Z rk dk ?kVrk Øe
12. Ethylamine (C2H5NH2) can be obtained from N-ethylphthalimide on treatement with :

fuEu esa ls fdlds lFk vfHkÑr fd;s tkus ij N-,fFkyFkSyhekbM ls ,fFky,sehu (C2H5NH2) izkIr fd;k tk ldrk
gS\
(1) CaH2 (2) H2O (3) NH2NH2 (4) NaBH4
Ans. (3)
Sol.
R is –C2H5–

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13. The isoelectronic set of ions is :
vk;uksa dk lebysDVªkWfudh lsV gS %&
(1) F– , Li+ , Na+ and Mg2+ (2) Li+ , Na+ , O2 – and F–
(3) N3– , Li+ , Mg2+ and O2 (4) N3– , O2– , F– and Na+
Ans. (4)
Sol. N3–, O2–, F– , Na+ are isoelectronic species each having 10 electrons
N3–, O2–, F– , Na+ lHkh 10 bysDVªkWu ;qDRk gSA rFkk lebyDVªkWfud Lih'kht gSA
14. Amylopectin is composed of :

(1) -D-glucose, C1 – C4 and C2 – C6 linkages
(2) -D-glucose, C1-C4 and C2 – C6 linkages
(3) -D-glucose, C1-C4 and C1 – C6 linkages
(4) -D-glucose, C1-C4 and C1 – C6 linkages
,feyksisfDVu buls fufeZr gS %
(1) -D-Xywdkst, C1 – C4 rFkk C2 – C6 ca/k
(2) -D- Xywdkst, C1-C4 rFkk C2 – C6 ca/k
(3) -D- Xywdkst, C1-C4 rFkk C1 – C6 ca/k
(4) -D- Xywdkst, C1-C4 rFkk C1 – C6 ca/k
Ans. (3)
Sol. Amylopectin is composed by -D-glucose, C1-C4 and C1 – C6 linkages.

fuEu vfHkfØ;k dk eq[; mRikn gS %
CH3
CH3OH
CH3–C–CHCH3
H Br
CH3 CH3
CH3–C–CH CH3 CH3–C–CH=CH2

(1) (2)
H OCH3 H
CH3
CH3–C–CH2CH3 CH3
(3) (4)
OCH3 CH3–C=CH CH3
Ans. (3)
Cl OCH3
CH3OH
Sol. CH3–CH–C–CH3 CH3–C–CH2–CH3
SN1 reaction
CH3 H (SN1 vfHkfØ;k) CH3

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16. The increasing order of the reactivity of the following compounds towards electrophilic aromatic
substitution reactions is :
,jkseSfVd bysDVªkWuLusgh izfrLFkkiu vfHkfØ;kvksa esa fuEufyf[kr ;kSfxdksa dh c<+rh vfHkfØ;kRedrk dk lgh Øe gS%
Cl CH3 COCH3
(I) (II) (III)
(1) II < I < III (2) III < I < II (3) III < II < I (4) I < III < II
Ans. (2)
Sol. The rate of reaction of given compounds towards electrophilic aromatic substitution reaction depends
upon the electron density of benzene nucleus.
fn;s x;s ;kSfxdks ds fy;s bysDVªkWuLusgh ,sjksesfVd izfrLFkkiu vfHkfØ;k dh nj csUthu ukfHkd ds bysDVªkWu ?kuRo ij
fuHkZj djrh gSA
17. The regions of the atmosphere, where clouds form and where we live, respectively, are :
(1) Stratosphere and Troposphere (2) Stratosphere and Stratosphere
(3) Troposphere and Stratosphere (4) Troposphere and Troposphere
ok;qeaMy dk ogh Hkkx tgk¡ ckny curs gSa rFkk ftlesa ge jgrs gSa] mls Øe'k% dgrs gSa %
(1) LVsªVksLQh;j rFkk LVsVªksLQh;j (2) LVsªVksLQh;j rFkk VªksiksLQh;j
(3) VªksiksLQh;j rFkk LVsVªksLQh;j ¼lerkieaMy (4) VªksiksLQh;j ¼{kksHkeaMy½ rFkk VªksiksLQh;j
Ans. (4)
Sol. Fact.
18. The oxoacid sulphur that does not contain bond between sulphur atoms is :
lYQj dk og vkDlks,flM ftlesa lYQj ds ijek.kqvksa ds chp vkcU/k ugha gksrk] gS &
(1) H2S2O4 (2) H2S4O6 (3) H2S2O7 (4) H2S2O3
Ans. (3)
O O
HO—S—S—OH
HO—S—O—S—OH
Sol. O O
O O
(H2S2O4)
(H2S2O7)
S O O
HO—S—OH HO—S—S—S—S —OH
O O O
(H2S2O3) (H2S4O6)

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19. The principle of column chromatography is :
(1) Differential adsorption of the substances on the solid phase.
(2) Differential absorption of the substances on the solid phase.
(3) Gravitational force.
(4) Capillary action
dkWye ØksesVksxzkQh dk fl}kUr gS&
(1) Bksl izkoLFkk ij inkFkksZ dk vodyuh; vf/k'kks"k.k
(2) Bksl izkoLFkk ij inkFkksZ dk vodyuh; vo'kks"k.k
(3) xq:Roh; cy
(4) ds'khdh; fØ;k
Ans. (1)
Sol. The principle of column chromatography is differential adsorption of the substances on the solid phase.
dkWye ØksesVksxzkQh dk fl}kUr Bksl izkoLFkk ij inkFkksZ dk vodyuh; vf/k'kks"k.k gSA
20. The species that can have a trans-isomer is :

(en = ethane-1,2-diamine, ox=oxalate)
og Lih'kht ftldk ,d Vªkal&vkblksej gks ldrk gS] gS %
(en = ,Fksu-1,2-Mkb,ehu, ox=vkDtsysV)
(1) [Pt(en)Cl2] (2) [Pt(en)2Cl2]2+ (3) [Zn(en)Cl2] (4) [Cr(en)2(ox)]+
Ans. (2)
Sol. [Pt(en)2Cl2]2+
2+ 2+
Cl en
en Pt en en Pt
Cl Cl
Cl Cl
trans cis
all other do not show geometrical isomerism.
vU; T;kfefr leko;ork ugh n'kkZrs gSA
21. A gas undergoes physical adsorption on a surface and follows the given Freundlich adsorption isotherm
equation
x
= kp0.5
m
Adsorption of the gas increases with:
(1) Decrease in p and increase in T (2) increase in p and Decrease in T
(3) Decrease in p and decrease in T (4) increase in p and increase in T
,d xSl dk ,d i`"B ij HkkSfrd vf/k'kks"k.k gksrk gS vkSj og fn;s x;s Ýk;UMfyd vf/k'kks"k.k lerkih lehdj.k dk
vuqlj.k djrh gSA
x
= kp0.5
m
xSl dk vf/k'kks"k.k c<+sxk ;fn %
(1) p ?kVk;sa rFkk T c<+k;s (2) p c<+k;s rFkk T ?kVk;sa

(3) p ?kVk;sa rFkk T ?kVk;s (4) p c<+k;s rFkk T c<+k;saA
Ans. (2)
Sol. Physical adoption increases on increasing pressure but decreases on increasing temperature.
HkkSfrd vf/k'kks"k.k nkc esa o`f) ds lkFk c<rk gS ijUrq rki esa o`f) ds lkFk ?kVrk gSa A

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22. The alloy used in the construction of aircrafts is :
(1) Mg-Sn (2) Mg-Zn (3) Mg-Al (4) Mg-Mn
Ans. (3)
Sol. Mg – Aalloy is used in manufacturing of Aeroplane 
 Okk;q;ku (Aeroplane) ds fuekZ.k esa iz;qDr feJ /kkrq Mg – A gSA
23. A process will be spontaneous at all temperatures if :

(1) H > 0 and S > 0 (2) H < 0 and S < 0
(3) H < 0 and S > 0 (4) ) H > 0 and S < 0
,d izØe lHkh rkiksa ij Lor% gksxk ;fn %
(1) H > 0 rFkk S > 0 (2) H < 0 rFkk S < 0
(3) H < 0 rFkk S > 0 (4) ) H > 0 rFkk S < 0
Ans. (3)
Sol. For spontaneous process G = H – TS
Lor% izØe ds fy, G = H – TS
H < 0
S > 0
24. Consider the hydrated ions of Ti 2+ , V2+ , Ti3+ , and Sc3+. The correct of their spin-only magnetic
moments is :
Ti2+ , V2+ , Ti3+ , xzke Sc3+ ds ty;ksftr vk;uksa ij fopkj dhft;sA muds fLiu&ek=k pqEcdh; vk?kw .kkksZ dk lgh
Øe gS%
(1) Sc3+ < Ti3+ < Ti2+ < V2+ (2) Ti3+ < Ti2+ < Sc3+ < V2+
(3) V2+ < Ti2+ < Ti3+ < Sc3+ (4) Sc3+ < Ti3+ < V2+ < Ti2+
Ans. (1)
Sol.  = n(n  2) B.M.
For magnetic moment to be higher, number of unpaired electron must be higher
pqEcdh; vk?kw.kZ vf/kd gksus ds fy,] v;qfXer bysDVªkWu dh la[;k Hkh vf/kd gksuh pkfg,sA
Sc3+  3d0 =0
Ti2+  3d2  = 8 B.M.
Ti3+  3d1  = 3 B.M.
V2+  3d3  = 15 B.M.
25. Which of the following is a condensation polymer ?

(1) Buna-S (2) Nylon 6, 6 (3) Teflon (4) Neoprene
fuEu esa ls dkSul la?kuu cgqyd gS \
(1) C;wuk-S (2) uk;ykWu 6, 6 (3) Vs¶ykWu (4) fuvksizhu
Ans. (2)
Sol. Except Nylon-6,6 all other given polymers are addition polymers.
ukbyksu-6,6 ds vykok lHkh nwljs fn;s x;s cgqyd ;ksxt cgqyd gSA

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26. Consider the following table :
Gas a/(k Pa dm6 mol–1) b/(dm3 mol–1)
A 642.32 005196
B 155.21 0.04136
C 431.91 0.05196
D 155.21 0.4382
a and b are van der Waals constants. The correct statement about the gases is :
(1) Gas C will occupy more volume than gas A; gas B will be more compressible than gas D
(2) Gas C will occupy more volume than gas A; gas B will be lesser compressible than gas D
(3) Gas C will occupy lesser volume than gas A; gas B will be more compressible than gas D
(4) Gas C will occupy lesser volume than gas A; gas B will be lesser compressible than gas D
fuEu rkfydk ij fopkj dhft, %
xSl a/(k Pa dm6 mol–1) b/(dm3 mol–1)
A 642.32 005196
B 155.21 0.04136
C 431.91 0.05196
D 155.21 0.4382
a rFkk b okUMjokYl fLFkjka d gSaA xSlksa ds fo"k; esa lgh dFku gS %
(1) xSl C xSl A dh xqyuk esa T;knk vk;ru ?ksjsxh ; xSl B, xSl D dh rqyuk esa T;knk laihM~ ; gksxh
(2) xSl C xSl A dh xqyuk esa T;knk vk;ru ?ksjsxh ; xSl B, xSl D dh rqyuk esa de laihM~ ; gksxh
(3) xSl C xSl A dh xqyuk esa de vk;ru ?ksjsxh ; xSl B, xSl D dh rqyuk esa T;knk laihM~ ; gksxh
(4) xSl C xSl A dh xqyuk esa de vk;ru ?ksjsxh ; xSl B, xSl D dh rqyuk esa de laihM~ ; gksxh
Ans. (1)
Sol. For gases A & C , 'b' value is same so gas having higher value of 'a' i.e. higher force of attraction will
have lesser volume. Gas C will have higher volume.
For B & D, 'a' value is same, so gas having higher value of 'b' will be less compressible
a Pb
 Z = 1   gas B will be more compressible
VRT RT
Sol. xSl A rFkk C ds fy, 'b' ds eku leku gS vr% 'a' dk eku mPPk j[kus okyh xSl ds fy, vkdZ"kZ.k dk cy Hkh vf/kd
gksxk rFkk ;g de vk;ru okyh xSl gksxhA vr% xSl C vf/kd vk;ru j[krh gSA
xSl B rFkk D ds fy, 'a' dku leku gS vr% xSl ftlds fy, 'b' dk eku vf/kd gS og de lfEiM~; gksxh
a Pb
 Z = 1   vr% xSl B vf/kd lfEiM~; gksxh
VRT RT

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27. Increasing rate of SN1 reaction in the following compounds is :
fuEu ;kSfxdksa esa SN1 vfHkfØ;k dh c<+rh nj gksxh %
I I
MeO
(A) (B)
I I
H3C H3CO
(C) (D)
(1) (A) < (B) < (D) < (C) (2) (B) < (A) < (D) < (C)
(3) (A) < (B) < (C) < (D) (4) (B) < (A) < (C) < (D)
Ans. (4)
Sol. The SN1 reactivity is proportional to stability of carbocations formed in the rate determining step.
SN1 vfHkfØ;k dh fØ;k'khyrk nj fu/kkZjd in esa cuus okys dkcZu /kuk;u ds LFkkf;Ro ds lekuqikrh gks rk gS A
28. Consider the statements Statement-1 and Statement-2 :

Statement-1 : Conductivity always increases with decrease in the concentration of electrolyte.
Statement-2 : Molar conductivity always increase with decrease in the concentration of electrolyte.
The correct option among the following is :
(1) Both Statement-1 and Statement-2 are correct
(2) Both Statement-1 and Statement-2 are wrong
(3) Statement-1 is wrong and Statement-2 is correct
(4) Statement-1 is correct and Statement-2 is wrong
S-1 rFkk S-2 dFkuks ij fo;kj dhft, %
Statement-1 : fo|q r vi?kV~; dh lkUnz rk esa deh ds lkFk pkydrk lnS o c<+ rh gSA
Statement-2 : fo|q r vi?kV~; dh lkUnz rk esa deh vkus ds lkFk eksyj pkydrk ges'kk c<+ rh gSA
fuEu esa lgh fodYi gksxk %
(1) S-1 rFkk S-2 nksuks lgh gSA
(2) S-1 rFkk S-2 nksuks xyr gS A
(3) S-1 xyr gS rFkk S-2 lgh gSA
(4) S-1 lgh gS rFkk S-2 xyr gS A
Ans. (3)
Sol. Conductivity decreases on decreasing concentration of electrolyte.
Molar conductivity increases on decreasing concentration of electrolyte.
fo|qr vi?kV~; dh lkanzrk esa deh ds lkFk pkydRo esa deh gksrh gS
fo|qr vi?kV~; dh lkanzrk esa deh ds lkFk eksyj pkydrk esa o`f) gksrh gSA
29. During the change of O2 to O2– ,the incoming electron goes to the orbital :
O2 dks O2– esa ifjorZu ds le; vkus okyk bysDVªkWu ftl d{kd es tk;sxk ogh gS %
(1) 2py (2) * 2pz (3) * 2px (4)  2px
Ans. (3)

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Sol. O2  (1s)2 ( 1s)2 (2s)2 ( 2s)2 (2pz)2 (2px =2py) (2px =2py)
In O2– last electron will enter in  2px or 2py orbital
O2– esa vfUre bysDVªkWu  2px vFkok 2py d{kd esa Hkjk tkrk gS A
30. Consider the following statements

(a) The pH of a mixture containing 400 mL of 0.1 M H2SO4 and 400 mL of 0.1 M NaOH will be
approximately 1.3
(b) Ionic product of water is temperature dependent.
(c) A monobasic acid with Ka = 10–5 has a pH = 5. The degree of dissociation of this acid is 50%
(d) The Le Chatelier's principle is not applicable to common-ion effect.
The correct statements are :
(1) (b) and (c) (2) (a) and (b) (3) (a), (b) and (d) (4) (a), (b) and (c)
fuEu dFkuksa ij fopkj dhft;s &

(a) ml feJ.k dk pH, ftlesa 400 mL 0.1 M H2SO4 rFkk 400 mL 0.1 M NaOH gS] yxHkx 1.3 gksxkA
(b) ty dk vk;uh xq.kuQy rki ij vkfJr gSA
(c) Ka = 10–5 okys ,d ,d{kkj dh vEy dk pH = 5 gS] bl vEy dh fo;kstu ek=kk 50% gSA
(d) fy 'krkfy;s fl)kUr le vk;u izHkko ij ugha ykxw gksrk gSA
lgh dFku gSa %
(1) (b) rFkk (c) (2) (a) rFkk (b) (3) (a), (b) rFkk (d) (4) (a), (b) rFkk (c)
Ans. (4)
Sol. (a) millimoles of H+ = 0.1 × 400 × 2 = 80
millimoles of OH– = 0.1 × 400 = 40
40 1
[H+] =  = 5 × 10–2 pH = 1.3
800 20
(b) Ionic product of water (Kw) increases with increase in temperature.
(c) Ka = 10–5 [H+] = 10–5 M = C
C2 C.
Ka = 
(1  ) 1  
 1
10–5 = 10–5 . = (50%)
(1   ) 2
(d) Le–chatelier principle is applicable for common ion effect.
Sol. (a) H+ ds feyheksy = 0.1 × 400 × 2 = 80
OH– ds feyheksy = 0.1 × 400 = 40
40 1
[H+] =  = 5 × 10–2 pH = 1.3
800 20
(b) ty dk vk;fud xq .kuQy (Kw), rki esa o`f) ds lkFk c<rk gS A
(c) Ka = 10–5 [H+] = 10–5 M = C
C2 C.
Ka = 
(1  ) 1  
 1
10–5 = 10–5 . = (50%)
(1   ) 2
(d) le vk;u izHkko ds fy, yh&'ks rfy;s fy;j fl)ka r iz ;qDr gks rk gSA

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JEE Main 2019 Chemistry April Attempt Shift - 1 (10th April, 2019)

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PAPER-1 (B.E./B. TECH.

JEE (Main) 2019

Duration: 3 Hours | Max. Marks: 360

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2. The major product of the following reaction is :

3. At 300 K and 1 atmospheric pressure, 10mL of a hydrocarbon required 55 mL of O2 for complete

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5. The major product of the following reaction is :

(1) (2) (3) (4)

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CH2OH COOH CH2OH

fuEu vfHkfØ;k ds eq[; mRikn gS %

CH2OH COOH CH2OH

(i) 50% NaOH

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10. Match the refining methods (Column-I) with metals (Column-II)

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11. Three complexes,

12. Ethylamine (C2H5NH2) can be obtained from N-ethylphthalimide on treatement with :

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14. Amylopectin is composed of :

15. The major product of the following reaction is :

CH3–C–CH CH3 CH3–C–CH=CH2

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(I) (II) (III)

HO—S—OH HO—S—S—S—S —OH

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20. The species that can have a trans-isomer is :

(1) p ?kVk;sa rFkk T c<+k;s (2) p c<+k;s rFkk T ?kVk;sa

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23. A process will be spontaneous at all temperatures if :

25. Which of the following is a condensation polymer ?

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28. Consider the statements Statement-1 and Statement-2 :

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30. Consider the following statements

fuEu dFkuksa ij fopkj dhft;s &

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