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Nahrain
Universi
ty
College
of
Enginee
ring
Chemical Engineering Department
NITROBENZENE PRODUCTION
by
SARAH RASHEED Ghayeb
Jumada II 1430
June 2009
Abstract
Nitrobenzene is manufacture
commercially by the direct nitration of benzene
using a mixture of nitric acid and sulfuric acid,
many processes for this manufacture but the
more safety, economic and lower capital cost is
the continuous isothermal nitration process.
I
List of Contents
Content
Page
Abstract
I
List of Content
II
List of Figures
VI
List of Tables
VII
Nomenclature
VIII
Chapter One: Introduction
1.1 History
1
1.3 Identity
4
1.4 Physical Properties
4
1.6 Uses
11
II
2.5 Non-Industrial Sources
21
III
Chapter Five: Equipment Design
5.1 Nitrator Design
64
109
7.4 Utilities
119
IV
Chapter Eight: Toxicity and Effects of
Nitrobenzene
8.1 General
123
124
125
8.4 Hazard and risk evaluation
126
8.5 Industrial safety
128
References
129
Appendixes
Appendix A: Physical Properties
A-1
Appendix B: Equilibrium Data
B-1
V
List of Figures
VI
List of Tables
VII
Nomenclature
Symbol Definition
Unit
Aa Active Area
m2
VIII
de Equivalent Diameter
m
dh Diameter of Hole
mm
di Inside Tube Diameter
m
dm Diameter of Manholes
mm
do Outside Tube Diameter
m
dp Droplet Diameter
µm
FC Flow Controller
-
FLV Liquid Vapor Factor
-
Ft Correction factor for ∆TLm
-
FW Wind Load
N/m
f Material Tensile Strength
N/mm2
Gt Mass Velocity of the Fluid Tube Side
Kg/m2.s
Gs Mass Velocity of the Fluid Shell Side
Kg/m2.s
HA Height of agitator
m
HL Height of the nitrator content
m
hap Height of bottom edge of the apron above the
mm
plate
hb Downcomer back-up
mm
hbc Clear liquid back-up
mm
hd Pressure drop through the tray plate
mm Liquid
hdc Head loss in downcomer
mm Liquid
hi Inside (tube) Heat Transfer coefficient
W/m2.oC
hid Inside tube foaling coefficient
W/m2.oC
ho outside (shell) Heat Transfer coefficient
W/m2.oC
IX
hod Outside tube foaling coefficient
W/m2.oC
how Weir Crest (height of the liquid over weir)
mm Liquid
hr Residence Head
s
hT Total Height of Distillation Column
m
ht Total plate drop head
mm
hv Heat transfer to vessel
W/m2.oC
hw Weir Height
mm
J Joined Efficiency
-
jf Friction Factor
-
Kf Thermal Conductivity
W/m.oC
LC Level Control
-
Lc Continuous phase Volumetric flowrate
m3/s
Lm Liquid mass flowrate
Kg/s
Ln Liquid mass flowrate
Kg/s
LW Weir Length
m
lB Baffle spacing
mm
lp Hole Pitch
mm
Ms Bending moment at any plane
N.m
m Mass flowrate
Kg/s
N Agitator Speed
rps
Np Power Number
-
Np Number of passes
-
Nt Number of Tubes
-
P Pressure Design
N/mm2
X
PA Shaft Power
W
Pch Sugden’s Parachor
-
Pt Pitch
mm
Pw Wind Pressure (Load per unit area)
N/m2
r Blade Length
m
S Distance measured from the free end
m
T Temperature of the fluid in shell side
o
C
TC Temperature Controller
-
TM Measuring Element
-
t Temperature of the fluid in tube side
o
C
tr Residence time
s
Uo Overall Heat Transfer coefficient
W/m2.oC
uc Velocity of Continuous phase
m/s
ud Settling velocity through hole
m/s
uf Flooding Velocity
m/s
uh Vapor Velocity through Hole
m/s
umin Actual minimum Velocity of the Vapor
m/s
ut Linear Velocity of the Fluid flow in Tube
m/s
uv Corrected Flooding Vapor Velocity
m/s
V Volume of Nitrator
m3
Vm Vapor mass flowrate
Kg/s
Vn Vapor mass flowrate
Kg/s
XI
Greek Notation
µ Viscosity
Pa.s
τ Residence Time
min
σ Surface Tension
mJ/m2
ρ Density
Kg/ m3
XII
Dimensionless Groups
Nu = h d /K Nusselt Number
Pr = cp µ / K Prandtle Number
Re = ρ u d / µ Reynolds Number
XIII
Cha
pter
One
Intro
ducti
on
C
h
a
p
t
e
r
O
n
e
I
n
t
r
o
d
u
c
t
i
o
n
1.1 History
Nitrobenzene [98-95-3](oil of
mirbane),C6H5NO2, is colourless to pale
yellow oily liquid with on odour resembling that
of bitter almonds or "shoe
polish." Depending on the purity, its color varies
from pale yellow to yellowish
brown [2 & 3].
3
1.3 Identity [5]
Com NIOSH
mon RTECS
name: Synonyms:
Chem
ical
1.4 Physical
formu
properties
la:
Chemical structure:
Relative
molecular
mass: CAS
name:
IUPAC name:
CAS
registry
number:
nitrobenzene
r
C6H5NO2
o
b
e
n
123.11
z
n
e
i
n
t
e
r
o
9
b
8
e
-
n
9
z
5
e
-
n
3
e
DA6475000
nitrobenzol, mononitrobenzol,
n MNB, C.I. solvent black 6,
essence of mirbane, essence of
i myrbane, mirbane oil, oil of
t mirbane, oil of myrbane,
nigrosine spirit soluble B
4
Table 1-3 Some Physical Properties of
Nitrobenzene [1,2,3&5]
Solu
Mp. Co bility
Bp. C
o in
Viscosity pa.sec wate
Thermal r
conductivity mg/li
W/m C o ter
Surface At
tension (20 C)o 20 oC
mN/m Specific At 25 oC
heat J/goC Solubi
At 25 C o lity in
At 30 C o organi
Latent heat of c
fusion J/g solven
Latent heat of t
vaporization J/g Densit
Heat of y
combustion (at (25oC)
constant Kg/m3
volume)MJ/mol
Flash point (closed cup) 1.5 Chemical
o
C
properties
Auto ignition
temperature oC
Explosive limit in
air (93 oC)vol%
Vapor pressure pa
At 20 oC
At 25 oC
At 30 oC
5.58 88
210.9
1.900599219 482
*10-3 1.8
0.14473
43.35 20
38
1.473 47
1.418
94.1 1900
331 2090
3.074 Freely soluble in ethanol,
acetone, ether
1198.484586
5
The reduction of the nitro group to yield aniline
is the most commercially
important reaction of the nitrobenzene. Usually the
reaction is carried out by the
catalytic hydrogenation of nitrobenzene, either in the gas
phase or in solution, or by
using iron borings and dilute hydrochloric acid (the
Bechamp process). Depending on
the conditions, the reduction of nitrobenzene can lead
to variety of products. The
series of reduction products is shown in figure
1-1 Nitrosobenzen, N-
phenylhydroxylamine, and aniline are primary reduction
products. Azoxybenzene is
formed by the condensation of nitrosobenzene and N-
phenylhdroxylamine in alkaline
solutions, and azoxybenzene can be reduced to
form azobenzene and
hydrazobenzene. The reduction products of nitrobenzene
under various conditions are
given in Table 1-4 [2].
Figure 1-1 Reduction products of
nitrobenzene [1, 2&14]
6
Table 1-4 Reduction products of
nitrobenzene [2]
Reagent Product
Fe, Zn or Sn + HCL aniline
H2 + metal catalyst + heat (gas phase or aniline
solution)
SnCL2 + acetic acid aniline
Zn + NaOH hydrazobenzene, azobenzene
Zn + H2O N-phenylhydroxylamine
Na3AsO3 azoxybenzene
LiALH4 azoxybenzene
Na2S2O3 + Na3PO4 Sodium phenylsulfamate, C 6H5NHSO3Na
7
very low solubility in the mixed and spent acids. The
overall stoichiometry for the reaction of benzene and
nitric acid to form nitrobenzene and water is
NO2
9
atom, the product being phenol and the nitrosyl ion, NO +.
The phenol then reacts with
nitric acid, possibly through a complex between the
nitrosyl ion and the phenol, to
form nitrophenol and nitrous acid, HNO 2. The one-
to-one molar ratio between
nitrophenol and nitrous acid is confirmed through
experiment. Nitrophenol is further
nitrated to dinitrophenol and picric acid. The rates for
this di- and trinitration are
relatively fast; there is usually only a trace of
mononitrophenol found in the crude
nitrobenzene. The stoichiometry of the reactions is
shown in the following equations
[2]:
Other by-products are formed from trace impurities in
the benzene feedstock or in
the recycle sulfuric acid. There is also the possibility that
very small amounts of
10
benzene and nitrobenzene undergo other reactions.
Most of these by-products are
removed in the washing stage of the process together
with the nitrophenols. The yield
loss caused by these side reactions is negligible. Of
more concern is the fast that
some of these trace impurities from surface-active
compounds which can
oceasionally lead to the formation of stable emulsions in
the washing section [4].
1.6 Uses
11
Dinitrobenzene 4 000
Others (solvents, dyes) 4 000
Total 398 300
• 2,5-dichloronitobenzene
• 2,5-dimethoxynitrobenzene
• Dinitrobenzene
• O-nitrobenzene
12
• M-nitrobenzenesulfonic acid, sodium salt
• O-nitrochlorobenzene
• P-nitrochlorobenzene
• M-nitrochlorobenzene [15].
• 1,3,5-Trinitrobenzene
• 1, 3-Dinitrobenzene [1].
2.1General
14
Capacities for nitrobenzene production are
available for several Western European countries
and are shown in Table 3-1 Production for Western
Europe was reported as 670 000 tones in 1990 [5].
15
2.2Batch process
Material
Quantity, kg
Benzene 650
Sulfuric acid 720
Nitric acid 520
Water 110
Sodium carbonate 10
The separation of the nitrobenzene is accomplished in
large conical-
bottomed lead tanks, each capable of holding one or
more charges. The nitrator
charges are permitted to settle here for 4-12 hr, when
the spent acid is drawn off
from the bottom of the lead tanks and delivered
to the spent-acid tanks for
additional settling or for treatment with benzene
next to be nitrated, in order to
16
extract the residual nitrobenzene. The
nitrobenzene is then delivered to the neutralizing
house [9].
17
The tubular reactor [i.e., plug-flow reactor
(PFR)] is relatively easy to maintain (no moving
parts), and it usually produces the highest
conversion per reactor volume of any of the flow
reactors. The disadvantage of the reactor and hot
spots can occur when the reaction is exothermic.
The tubular reactor is commonly found either in
the form of one long tube or as one of a number of
shorter reactors arranged in a tube bank [10].
18
Figure 2-1 production of Nitrobenzene-
continuous process [1]
19
achieved by circulating a large volume of sulfuric
acid through the nitrators, absorbing the heat of
nitration without undue temperature rise. the spent
acid is then flash concentrated under vacuum [4].
20
2.4.2 Isothermal Continuous Process
21
measured in the five hazardous waste landfills were
0.05, 0.65, 2.7, 1.0 and 6.6
µg/m3. The maximum level recorded was 51.8
µg/m3. At the sanitary landfill,
nitrobenzene was below the detection limit (0.25
µg/m3) at all locations [5].
22
2.6 Process Selection
23
two functions: it reacts with nitric acid to form the
nitronium ion, and it absorbs the water formed
during the reaction, which shifts the equilibrium
to the formation of nitrobenzene [4, 8, 13, &14]
24
nitration vessel [16]. Nitration vessels are
usually made of stainless steel, although cast iron
stands up well against mixed acids [16&18].
25
Benzene
Na2CO3
it
r CaSO4
a
ti Benzene
n
g
a Crude
c nitrobenzene
i Acid separation 1st washing
d 2nd washing
N Distillation
it
r
i
c
H 2O
ac Spent acid NaSO4
id Gypsum
6 Nitrobenzene
4
H2CO3
w
t
S
.
%
u
l
nitrator
f
u
Fresh
sulfuric
acid r
98
i
wt.
%
c
a
c
(
i
E
d
v
a
r
p
e
o
c
r
o
a
n
t
c
o
e
r
n
)
t
t
Fig. 2-4 Typical continuous
i
nitrobenzene process
o
26
Chapte
r Three
Material
Balance
C
e
M
n
c
Main Reaction
C6H5NO2 +H2O … (3.1)
C6H6 H 2 SO
4
+
HNO3
Ca
pa
cit
70
00
to
n/
ye
ar
[5]
Ye
ar
30
or
ki
ng
da
= 233.333333 ton/day
= 9722.222222 Kg/day
= 78.9718188 Kg.mol/hr
No nitric acid
acid [2&14]
Conversion = 100 %
[2&14,1&4]
From stoichiometry:
27
3.2 Material Balance on Nitrator
4
3 5
Nitrator
199.8590691
Kg/hr
Total nitric acid input = 78.97183188 * 63.02= 4976.804845
Kg/hr
Nitrating acid composition H2SO4 60 wt %,
HNO3 25 wt %, & H 2O 15 wt %
[2&21].
28
Water output in Stream 5 =
2986.082907 + 1423.07241
4409.155317 Kg/hr
3 4 5
Component [Kg/hr] [Kg/hr] [Kg/hr]
HNO3 4976.804845 - -
C6H5NO2 - - 9722.222222
19907.21938 6368.348857
Total 26275.56824
26275.56824
29
3.3 Separator Material Balance
7
5
Aid Separation
4409.155317 + 11944.33163
16353.48695 kg/hr
199.8590691 Kg/hr
N.B. = 9722.222222 kg/hr
30
Wt. of sulfuric acid in stream 7 =119.4433163 Kg/h
Wt. water in stream 7 = 163.5348695 * 0.2696156076 =
44.09515532 Kg/hr
11824.88831 Kg/hr
16189.9520 * 0.2696156076
4365.063767 Kg/hr
HNO3 - - -
16189.95208 10085.61616
Total
26275.56824 26275.56824
31
3.4 Washing Process Material Balance
Na2CO3
8
7 10
1st
Was
hing
From stoichiometry
8 Mole of Na2SO4 =
1.217815215 Kg.mol/hr
Wt. of
Na2SO4 =
1.217815215
* 142.05
Wt. of
Na2SO4 =
172.9906513
Kg/hr
32
Mole of H2CO3 = 1.217815215 Kg.mol/hr
Wt. of
H2CO3 =
1.21781521
5 * 62.03
Wt. of
H2CO3 =
75.4510778
Kg/hr
44.0915532 Kg/hr
HNO3 - - - -
H2SO4 119.4433163 - - -
Na2CO3 - 129.0884128 - -
Na2SO4 - - 172.9906513 -
H2CO3 - - 75.4510778 -
Total
10214.70457 10214.70457
33
3.4.2 2nd Washing process Material Balance
CaSO4
11
10 13
2nd Washing
12
C
a
S
O
4
.
2
H
2
(
G
y
p
s
u
m
)
From stoichiometry
34
Table 3-4 Material Balance on 2nd
Washing Unit
10 11 12 13
Component [Kg/hr] [Kg/hr] [Kg/hr] [Kg/hr]
HNO3 - - - -
H2SO4 - - - -
H2O 44.0915532 - - -
CaSO4 - 166.5544965 - -
CaSO4.2H2O - - 210.6460497 -
18
1
1st mixing point
3
2 mixing point
nd
2
1
H2O
6
16
d
t
r r
e a
c t
o i
n o
c n
e
35
n
The concentrated of nitric acid added in
stream 1 is 64wt. %, and the
concentrated of sulfuric acid added in
stream 2 is 98 wt. % [4].
= 4976.804845 Kg/hr
removed
2799.452725 +
2.4376187
= 2801.890344 Kg/hr
input
36
= 2986.082907 -
2801.890344 = 184.1925633
removed in stream17
in stream17
= 4365.063767 - 184.1925633
4180.8
71204
Kg/hr
stream
16
Materia
l
balance
on
reconce
ntrator
Stream
6 =
stream
16 +
stream
17
Stream 17 = 16189.95208 -
184.1925633 Kg/hr
12009.08088 - 184.1925633 Wt of
11824.88831 Kg/hr
Material balance on 1st mixing
point
Stream 18 = 12009.08088 +
184.1925633 + 2.4376187
=186.630182 Kg/hr
11944.33163 Kg/hr
37
Table 3-5 Material Balance on
Reconcentrator
6 16 17 18 2 1 3
component [Kg/hr] [Kg/hr] [Kg/hr] [Kg/hr] [Kg/hr] [Kg/hr] [K
14
13
Distillation
Stream 13 =
97722.081291 Kg/hr
15
stream 13 =
9722.222222 Kg/hr
Purity between 96 -
38
Select purity = 99 wt. %
Benzene in stream 15 =
9820.426487 -
9722.222222 Benzene in
stream 15 =
98.20426486 Kg/hr
199.8590691 - 98.20426486
101.6548042 Kg /hr
13 14 15
Component [Kg/hr] [Kg/hr] [Kg/hr]
Total 9922.081291
9922.081291
39
3.7 Overall Material Balance
Table 3-7
Overall Material
Balance
In ( Kg/hr)
Stream
1 2 4 8 11 9
Comp. No.
[Kg/hr] [Kg/hr] [Kg/hr] [Kg/hr] [Kg/hr] [Kg/hr]
C 6H 6 - - 6368.348857 - - -
HNO3 4976.804845 - - - - -
H2SO4 - 119.4433163 - - - -
H2 O 2799.452725 2.376187 - - - -
C6H5NO2 - - - - - -
Na2CO3 - - - 129.0884128 - -
H2CO3 - - - - - 75.4510778
Na2SO4 - - - - - 172.9906513
CaSO4 - - - - 166.5544965 -
CaSO4.2H2O - - - - - -
7776.25757 121.880935 6368.348857 129.0884128 166.5544965 248.5317291
Total 14562.13027
40
T
a
b
l
e
3
-
8
a
l
l
S
t
r
e
a
m
s
o
f
M
a
t
e
r
i
a
l
B
a
l
a
n
c
e
s
Stream 1 2 3
4 5 6 7
NO.
Na2CO3 - - -
- -
H2CO3 - - - - - -
Na2SO4 - - - - - -
CaSO4 - - - - - -
CaSO4.2H2O - - - - - -
41
Chapt
er Four
Energy
Balanc
e
C
h
a
p
t
e
r
F
o
u
r
E
n
e
r
g
y
B
a
l
a
n
c
e
30oC
C.W
H.W C.w
o
70 C 30oC
H.W
60 5
Q3 = * ∆Hi * ni
∆Hi = cpi dT
*10-3 (325.153 -
298.153) = 2745.87058
KJ/Kg.mol
42
QHNO3 = *2745.87058 = 216846.4298 KJ/hr
(323.153-298.153) - *10-9(323.154-298.154)
Q3 = 216846.4298 + 139,821.6844 +
∆H4 * nBZ.
(303.153-298.153) + *10-8(303.154-298.154) =
416.7382512 KJ/Kg.mol
Q4 = * 416.7382512 = 33976.886 KJ/hr
Q5 = * ∆Hi * ni
∆Hi = cpi dT
*10-4(323.153-298.153) + *10-8(323.154-298.154)
43
∆HBZ. = 2160.861183 KJ/Kg.mol
(323.153-298.153) - *10-9(323.154-298.154)
Q5 = 5528.96818 + 441294.3716 +
206456.2648 + 361752.5534 Q 5 =
1015032.158 KJ/hr
The over all heat balance around nitrator
44
Qcooling = 11,421,664.11 KJ/hr
QCoil =
0.25*11,421,664.11 =
2,855,416.028 KJ/hr
T=65oC.
mjacket = 129,913.2326
Kg/hr flow rate of water in
jacket Water inter coil at
T=30oC and leaves at
T=70oC.
45
4.2 Separator Energy Balance
7 6
r
5
Q6 = * ∆Hi * ni
∆Hi = cpi dT
(323.153-298.153) - *10-9(323.154-298.154)
46
QH2O = * 843.7765567 = 204391.7023 KJ/hr
Q7 = * ∆Hi * ni
∆Hi = cpi dT
(323.153-298.153) + *10-8(323.154-298.154)
(323.153-298.153) - *10-9(323.154-298.154)
*
4580.779561 =361752.5534 KJ/hr
47
Q7 = 5528.96818 + 4412.943716
+2064.562649 + 361752.5534 Q 7 =
373759.0279 KJ/hr
16
13
HNO
6
3
64wt.
%
18
Steam
H2SO4 250oC
98 wt. 250oC
%
2 3973000 pa
17 Out 17 In
Q6 =
641273.13
KJ/hr
Q17 = * ∆Hi * ni
∆Hi = cpi dT
48
∆HH2SO4 = 139.1(100-25) + * (1002-252) = 11163.28125
KJ/Kg.mol
Cooling water
30oC
17 17
65.5 oC 100oC
50oC
49
Q17(In H.Ex.) = 1,787,752.684 KJ/hr
(338.653-298.153) - *10-9(338.654-298.154)
*10-5(323.153-303.153) - *10-9(323.154-303.154)
50
Q2 = * ∆Hi * ni
∆Hi = cpi dT
(303.153-298.153) - *10-9(303.154-298.154)
Q18= Q17(Out..Ex.) + Q2
51
4.4 Washing Process Energy Balance
4.4.1 1st Washing process Energy Balance
-699.65 -
1413.891
1131.546
∆Hro =
-170.485
KJ/g.mol
∆Hr
∆Hro
∆HPr
oduct -
∆HRe
actant
∆HNa
2CO3 =
111.
08
∆T
.
1
2
8
∆Hr = -170,485 +
254.3418611 ∆T -
4,179.05625 ∆Hr =
-174,664.0563 +
254.3418611 ∆T
Qr = 1.217815215 [-
174,664.0563 +
254.3418611 ∆T] Qr =
-212,708.5452 +
309.7413883 ∆T
Q7 = 373759.0279 KJ/hr
52
∆H8 = 111.08 * (30 - 25) = 555.4 KJ/Kg.mol
Q9 = * ∆Hi * ni
∆Hi = cpi dT
∆HNa2SO4 = 128.229 ∆T
∆HH2CO3 = 126.1128611 ∆T
* 126.1128611 ∆T]
Q9 = [ * 128.229
∆T] + [
Q9 = 156.1592272 ∆T +
153.5821611∆T Q9 =
309.7413883 ∆T
Q10 = ∆HMixture * ni
∆HMixture = cpMixture dT
53
Q10 = 23,312.48936 ∆T - 34.56096004 ∆T 2 +
0.04463361 ∆T3 + 4.340897832 *
10 ∆T
-8 4
T = 62.88295021 oC
3
7
=
6
=
1
1
0
r
Q
J
/
∆Hro = -2,024.021
+ (2* 286.025) +
1,435.097 ∆Hro =
-16.874 KJ/g.mol
54
∆Hr = ∆Hro + ∆HProduct - ∆HReactant∆HH2O = 32.243 (336.0329502 -
298.15) +
*10-3 (336.0395022-
298.152) + *10-5(336.03295023-298.153) -
*10-9
(336.03295024-
298.154)
∆HH2O =
1,280.433889
KJ/Kg.mol ∆HCaSO4
∆HCaSO4 =
498.65
KJ/Kg.mol
∆HCaSO4.2H2O =
186.149 ∆T
3,059.517779
Qr =
-24,386.7
8579 +
227.7358
085∆T
Q10 =
563,676.1
122 KJ/hr
Q12 = * 186.149 ∆T
Q12 = 227.7358085 ∆T
55
Q13 = ∆HMixture * ni
∆HMixture = cpMixture dT
*10-9 ∆T4
T= 63.33466274 oC
Qr -15,656.61038 KJ/hr
14
R 80.1oC D
13 IN 13 Out
63.335oC 192.1oC
15
200.87oC
section.
Steam
13 63.334
In
Q13(IN H.EX.) = 250oC 13 Out
567,379.1321 KJ/hr
192.1oC
Steam
210oC
57
Q13 (OUT H.EX.) = * ∆Hi * ni
∆Hi = cpi dT
∆HLquid = cpi dT
*10-1(353.252-298.152) -
∆HLiquid = -33.917
(353.25-298.15) +
*10-8(353.254-298.154)
*10-4(353.253-
298.153) +
∆HLiquid =
5,012.048424
KJ/Kg.mol λ = 30,781
KJ/Kg.mol
∆HVapour = cpi
dT
58
Q13(IN
H.EX.) +
QHeating
= Q13
(OUT
H.EX.)
QHeating
= Q13
(OUT
H.EX.) -
Q13(IN
H.EX.)
QHeating = 2,864,650.036 -
567,379.1321= 2,279,270.904
m= = 765,756.968 Kg/hr
QReboiler = Q14 +
Q15 + QCondencer
Material Balance
on Condenser
R = Reflux ratio =
Rm = [ -α ]
α = poBZ./ PoN.B
α= = 19.54121672
Rm = [ -19.54121672 *
1
8
2
R
8
V
L = Ractual * D
59
L =
2.06
2272
268
101.
6548
042
L =
209.
6398
836
Kg/h
r
L = 2.68390582 Kg.mol/hr
V =
209.
6398
836
+
101.
6548
042
V =
311.
2946
878
Kg/h
8
9
=
V
QConde
ncer =
3.985
3371
89 *
30,78
QConde
ncer =
122,6
72.66
KJ/hr
Q14 =
∆HBZ.
* ni
∆HBZ. = -33.917 (353.25-298.15) + *10-1(353.252-
298.152) -
*10-4(353.253-298.153) + *10-8(353.254-298.154)
Q15 = * ∆Hi * ni
∆Hi = cpi dT
∆HLquid = cpi dT
60
*10-4(353.253-298.153) + *10-8(353.254-298.154)
λ = 30,781 KJ/Kg.mol
∆HVapour = cpi dT
QReboiler = Q14 +
Q15 + QCondencer
QReboiler = Q14 +
Q15 + QCondencer -
242,862.4479 KJ/hr
61
T
a
b
l
e
4
-
1
a
l
l
S
t
r
e
a
m
s
o
f
E
n
e
r
g
y
B
a
l
a
n
c
e
s
Stream 1 2 3 4 5 6 7 8
NO.
COMP.
[KJ/hr] [KJ/hr] [KJ/hr] [KJ/hr] [KJ/hr] [KJ/hr] [KJ/hr] [KJ/hr
C6H6 - - - 33976.886 5528.96818 - - -
Na2CO3 - - - - - - - 676.3745
H2CO3 - - - - - - - -
Na2SO4 - - - - - - - -
CaSO4 - - - - - - - -
CaSO4.2H2O - - - - - - - -
Temperature 30 30 50 30 50 50 50 30
o
C
62
Feed
Benzene 8
4
7
Washing Tank
1nd 13
3 7
10
9
1
Settler
18 5
10
Nitrator 6
11
2
Washing Tank 13
2st
12
17 17
Vaporizer
Cooling
63
Chapter
Five
Equipment
Design
Chapter Five
Equipment Design
Resi
denc
time
=τ=
10
min
[29]
τ =
0.16
6666
666
hr
τ =
νo = stream 3 + stream 4
νo = [ + + +
]
=
2
r
V
V = 0.166666666 * 20.37924292
64
V = 3.396540473 m3 = 897.1088536 gal
0
4
7
3
=
2
i
t
DA = D/3
DA =
2.1810709
78/3 =
0.7270236
59 m HA =
D/3
HA =
2.1810709
78/3 =
0.7270236
59 m
r = D/4
r =
2.18107
0978/4 =
0.54526
7744 m
a =
2.18107
0978/5 =
0.43621
4195 m
HL = D = 2.181070978 m
65
Als
use
fou
sy
mm
etri
baff
les
b =
wid
th
of
baff
le =
D/1
b = 2.181070978/10 = 0.2181070978 m
0.218
2.181
0.73
0.7
2.181
PA = NP* ρ * N3 *D5A
66
Assume the agitator rotation per minute (N) = 100 rpm =1.67 rps.
Re =
Re =
8.074454885
suitable]
NP = 5
PA = 5 *
1173.870615 *
(1.67)3 *
(0.727023659)5
PA = 5,519.239048
watt = 5.519239048
Kwatt
pitch
67
de = = 133.333mm
[32]:
0.64225.
u= *
u = 1.823958001m/s
Re =
Re = = 62,867.15905
68
Re = 4.180355498 * 105
Nu = 0.023 *
(418,035.5498
)0.8 * (3.74)0.33
Nu =
1,116.21033
Nu =
hj = = 5,376.659075 W/m2.oC
∆p = 8 jf ( )( )
∆p = 8 * (2 * 10-3) ]* ]
∆p = 12,177.17195 pa =
69
di = 76.1- 3.65 = 68.8mm
=C [ ]a [ ]b [ ]c
C = 1.1, a =
0.62, b =
0.33, c =
0.14 [23]
Neglect the
viscosity
correction
term.
= 1.1 [ ] 0.62
[ ]
2
1
e
s
t= = 50oC
70
2
A
=
d
i
A= * (68.8)2
A = 3717.635083 mm2
u= * *
u = 2.869804254 m / s
(50)) (2.869804254)0.8 /
(68.8)0.2 hi = 9,841.95296
W / m 2. oC
= + + + *
= + + + *
= 7.705482183 * 10-4
8
W
o
∆
71
Ao = = 15.27941481 m2
Length of tube =
Mec
han
ical
Des
ign
[23&
30]
Calcu
lation
of the
cylin
drical
part
t= +C
t= +1
t = 1.817438078mm 2mm
72
Calculations of the Reactor cover thickness
t=
t=
t = 0.694606292mm
Rs = a2/b , Rs = Di = 2.181070978 m
2a = major axis = Do
Do = Di + 2(thickness)
Do =
2.181070978
+
2(1.81743807
8*10-3) Do =
2.184706233
2b = minor axis = 2h
h =
height
of head
from
tangent
line
a =
2.18470
6233/2
1.09235
3117m
b = a2/Rs
73
b =
1.0923531172/2.1847
06233 = 0.546176558
m h = 0.546176558
m height of cover
Calculati
on of the
volume
of
Nitrator
V =
0.05Di3 +
1.65 t D2
0.694606292*10-3 * 2.1810709782 V =
0.524227513 m3
Over all volume of Nitrator = volume of
3.73619452 + 2(0.524227513)
VTotal = 4.784649546 m3
2.181070978 + 2* 0.546176558
LTotal = 3.273424094 m
Calculat
ion of
the
weight
of
Nitrator
Wv =
240 Cv
Dm (Hv
+ 0.8
Dm ) t
Cv = 1.08, factor
to account weight
of nozzles Dm =
Di + t
Dm = 2.181070978 +
1.817438078*10-3 =
2.182888416 m Hv = Di =
2.181070978 m
74
Wv = 2222.130942 Kg
Wv = 2222.130942 Kg
[32].
V = D2 (8D) =2 D3
The volume of one leg
support =
D= =
0.525424043m
= 7,124.424796 Kg
= 0.911401405 m3
75
L = 8*
0.525424
043 =
4.203392
345m
Wind
load
o
a
f
P
Deff = Do = 2.184706233 m
Fw = 1280 *
2.184706233 =
2,796.423978 N/m
Bending moment at
any plane = Ms =
Fw / 2 *S2 S = Di =
2.181070978m
Ms = * (2.181070978)2 = 6,645.304084N.m
The Nitrator does not consider tall vessel so the effect of wind is
not high.
76
5.2 Settler Design [23]
16,189.95208 Kg/hr
ρd(Croude Nitrobenzene) =
1,173.870615 Kg/m3
= 1,582.722727 Kg/m3
[22,28&33].
µd(Croude Nitrobenzene) =
* 10-3 pa.s
Take dd = 150µm
(droplet diameter)
ud =
ud =
77
ud > uc ( the decanter vessel is sized on the
basis that the velocity of the continuous phase
must be less than settling velocity of the droplets
of the dispersed phace) [23].
Ai = Lc/uc
Ai = = 1.597184548 m2
Ai =
r= = 0.71302148 m
2.852085922 m
78
Velocity crude Nitrobenze phase = 1.494254608 * 10 -3 m/s
dd = (stock’s law)
dd =
Piping Arrangement
Flow-rate = *
79
Z1 = 0.9 *
2.85208592
2 =
2.56687733
Z3 = 0.5 *
2.85208592
2 =
1.42604296
Z2 =
Z2 = 2.272174706 m Proposed
Z2 = Design
+ 1.426042961
D = 1.4 m
Heavy liquid
take off
Crude N.B
Spent Acid Z2 =2
m
Z3 = 1.4 m
80
Mechanical Design
t= +C
J = 0.85, f = 145N/mm2, C
= 1mm, D = 1.426 *
= 0.1114575N/mm2
t= +1
the thicness
of domed
ends:
Select the
ellipsodial
heads
t=
t=
t = 0.644838821mm 0.645mm
81
5.3 Heat Exchanger Design [23]
Spent Acid
T2=65.5oC
S
p
e
n
t
A
c
i
d
T
1
=
1
0
0
o
Operating Condition
Temperature of a hot
100oC
Temperature of a cold
65.5oC
Temperature of a cold
Temperature of a hot
T1=100oC
∆T1 {
T2=65.5oC
o
T2=50 C
82
}∆T 2
t1=30oC
The hot spent acid & cold water passed
counter currently ( more efficient than co-current).
QCooling = 1,060,108.891
KJ/hr = 294.4746919
KWatt mH2O =
28,284.58611 Kg/hr =
7.856829475 Kg / s
Mean Temperature
Difference (∆Tm)
(T −t )− (T −t )
1 2 2 1
∆
Tlm (T1 − 2 )
=
ln t
(T − t)
2 1
(100−50)− ( =
∆ 42.336964 C
T 65.5−30) 35
l ( 100−3
m 0)
ln( 65.5−30 )
∆Tm = Ft ∆Tlm
R = ( T 1 - T 2 ) / ( t 2 - t1 )
t1 = 30 °C
S = ( t 2 - t1 ) / ( T 1 - t1 ) t2 = 50 °C
R = (100 - 65.5) / ( 50
T1 =100 °C
-30)= 1.725
S = ( 50 - 30 ) / (100 - 30 )
= 0.285714285
42.33696435 = 40.22011613oC
83
P
Q
=
A= = 9.151971708 m2
Pipe Dimension
Choose 20mm o.d, 16mm i.d, 4.88m long tube table (12.3) [23]
Number of tubes = Nt = A / At
30 tube
Use 1.25 Triangular pitch, this type of pitch is more
efficient than rectangular
pitch.
Db = bundle diameter = Pt
Flow
do (Nt / k1 ) 1/n1 From table
0.249)1/2.207
Db = 175.3490987 mm
Shell diameter; Ds =
175.3490987+ 30 = 205.3490987
mm
84
Tube - Side Coefficient
pass = 30 / 2 = 15
(G) = mH2O/At
7.856829475/
3.015928947*10-3 Mass
velocity (G) =
2,605.110934kg/m2.s
m/s Re = ρ ut d /µ
Re = 992.04 * 2.626014005 * 16 * 10 -3 / 6.556
(40)) (2.626014005)0.8 /
(16)0.2 hi = 11,227.97364
W/m2.oC
or
h d 0.14
i
=h . ( µ / w)
0
J 3µ
3
i
k Re Pr
f
85
hi = (0.6328/16 * 10-3) ( 3.1 * 10-3) (6.357805817 * 104) (4.334)
0.33
h
= 12,647.03674W/m2 °C
take the lower value
hi = 11,227.97364
W/m2.oC calculation
of tube teperature
hi (tw - t) = U (T - t)
tw = 43.03245965oC 43 oC
[ ] =[
0.14
]0.14 = 1.007864243 1[no
correction factor
needed]
lB = 0.2 *
205.3490987
=
41.06981914
mm
tube pitch =
1.25 do = 1.25
(20) = 25mm
As =
As = =
1.686730069*10-3m2
86
de = (252 - 0.917 * 202 ) = 14.201 mm
28&32]: Cp = 1.590330869
kJ/kg.°C
ρ = 1,748.959499 kg/m3
7
7
0
-
0
.
=
2
Re = = = 5.223851997 * 103
hs = jh Re pr1/3 [ ]0.14
hs = 4,559.6671 W /m2.oC
Calculati
on of the
Shell
Tempera
ture hS
(T-Tw) =
U (T - t)
tw = 75.24945243oC 75.25 oC
87
µw = 6.077856682* 10-3 pa.s at 75.25 oC
[ ] =[
0.14
]0.14 = 0.982977327 1[no
correction factor
needed]
1 1 do ln(do / do do 1
= + + + +
1 h h di )
i d hi
U o od 2 kw 1
di
h id
= + + + * + *
= 7.28006325 * 10-4
Uo = 1,373.614614 W/ m 2.oC (Above the
of Pressure Drop
Tube Side
∆Pt = 66,666.10822 pa =
∆Ps = 8jf
= 8* 5.7 * 10-3 *
( 3.3358558)0.52 *
( 1,748.959499)-0.37
dm = 33.30338513
mm
( 7.856829475)
0.52
* (992.04)-
0.37
dm =
64.13010051
mm
89
5.4 Distillation Design [23,30&35]
X Y
0 0
0.05 0.451
0.1 0.759
0.15 0.923
0.2 0.957
0.25 0.969
0.3 0.975
0.35 0.981
0.4 0.985
0.45 0.988
0.5 0.989
0.55 0.99
0.6 0.992
0.65 0.994
0.7 0.995
0.75 0.996
0.8 0.996
0.85 0.997
0.9 0.999
0.95 0.999
1 1
90
1
0.8
0.6
0.4
0.2
diagram (Isothermal) at 70 oC R =
2.062272268
Intercept = = = 0.326554895 0.33
91
assume column efficiency of 60 percent. Take
reboiler as equivalent to one
stage.
Diameter
Top
temperatu
re = 80.1
o
C =
353.25 K
Top
pressure =
101.325 *
103 pa
L ρ
F n V
V ρL
=
L
V
n
Ln = 209.6398836
Kg/hr =
0.058233301Kg/s
Vn =
311.2946878
Kg/hr =
0.086470746
Kg/s
P Mwt
ρV =
RT
ρV = = 2.694828052 Kg/m3
92
FLV = = 0.038722801
7.5 * 10-2
0.013081
uf = (K1)correct
93
uf = 0.013081 = 0.227120984
m/s
uv = 0.85 *
0.227120984 =
0.193052836
m/s maximum
volumetric
flow-rate =
An = = 0.16621184 m2
Ac = = = 0.188877091 m2
Dc = = 0.490393497 m 0.5 m
L ρ
F m V
V ρ
=
L
V
m L
94
Lm = Vm + stream 15
Vm = Vn = 0.086470746 Kg/s
Stream 15 = 9,820.426487
Kg/ hr = 2.727896246
Kg/s Lm = 0.086470746 +
2.727896246 =
1002.856487 Kg/m3 at
200.87 oC [28]
ρV(mix.) =
FLV = = 1.847096398
= 1.8 * 10-2
Correction for surface tension
4
σ= * 10-12
95
4
σBZ. = * 10-12
ρV BZ. = = 3.266436233Kg/m3
4
σN.B = * 10-12
(K1)correct = [3.408625139*10-3]0.2 *
7.5 * 10-2
(K1)correct = 0.012635206
uf = (K1)correct
+ (3.439273426*10-3 *
uf = 0.013081 =
0.219920976m/s
96
uv = 0.85
*0.219920976
= 0.186932829
m/s maximum
volumetric
flow-rate =
An = = 0.140198909 m2
Ac = = = 0.159316942 m2
Dc = = 0.450387201 m
Ah = 0.1 * Aa
Ah = 0.1 * 0.14922565
Ah = 0.014922565 m2
97
Weir length from figure (11.31) [23], at
0.5 =0.38 m
Take: weir height hw = 50mm
Hole diameter dh = 5 mm
Plate thickness = 5 mm Check weeping
how = 750
[ ]2/3
98
actual minimum vapour velocity = 0.7 * 0.02607778 /
0.014922562
Second Trial
Take: dh = 4.167 mm
vapor
velocity
through
holes
uh =
uh = = 8.737700255 m/s
hd = 51 [ ]2 [ ]
[23], at Ah / AP Ah / Aa
=0.03,
diameter = 5 / 4.167 =
1.2
99
Co = 0.81
hd = 51 [ ]2 [ ] = 19.30499388 mm
Liquid
hr = = = 12.46439562 mm Liquid
P
r
d
+
r
ht = 19.30499388 + (50 +
28.4424389) +
12.46439562 ht =
110.2118279 mm liquid
L
i
o
m
Take hap =
hw - 10 =
50 - 10 =
40 mm Aap
= hap lw =
Am
hdc = 166 [ ]2
100
hb = ( hw + how ) + ht + hdc
hb = (50 + 28.4424389) +
110.2118279 +
5.65854496 hb =
194.3128113 mm =
0.1943128112 m
wier hight)
y
s
.
C
tr =
tr =
tr =
1.631438149s
satifactory)
Check
Entrainment
uv = = 0.15167627 m/s
percentage flooding =
Layout
101
50mm wide callming zones.
Perforated Area 50 mm
From
figure
θ D = 0.5 m
(11.32) lw= 0.38
α
[23],
At lw / Dc
50 mm
= 0.76
θo = 99o
mean length of
Ap = 0.14922565 - (0.031808625 +
0.028 ) = 0.089416724 m2
0.089416724 = 0.03337757
lp/dh = 4
lp = 4 *
4.167
16.668
mm
(pitch).
Numbe
r of
holes
= (π/4) (0.004167) 2
= 1.363756653*10-5 m2
102
Number of holes = hole area / area of one hole
hT = (Tray Spacing *
of plate hT = (0.45 *
5) + 0.005 = 2.255m
103
Chap
ter Six
Contro
l
Syste
m
C
h
a
p
t
e
r
S
i
x
C
o
n
t
r
o
l
S
y
s
t
e
m
6.1 Introduction
3. Product quality:
4. Cost:
104
To operate at the lowest production cost,
commensurate with the other objectives.
105
strength produced, must be integrated with the
nitration section [4], figure 6-1 illustrated the
control of isothermal nitrator [23].
FC
Feed
FC
TC
TC
FC
LC
FC
Liquid- light
tak Heavy liquid
e Crude N.B take off
off
Feed
Spent Acid
Liquid- light
Feed
LC
Heavy liquid
107
6.4 Vaporizer Control
Level control is often used for vaporizers; the
controller controlling the
steam supply to the heating surface, with the liquid
feed to the vaporizer on flow
control, as shown in figure 6-4. An increased the
feed results in an automatic
increase in steam to the vaporizer to vaporize the
increased flow and maintain
the level constant [23].
TC
LC
Feed
Steam
Trap
TC
109
6.6 Distillation column control
110
Figure 6-6 Temperature pattern
control
111
Figure 6-8 Composition
control
S
e
v
e
n
P
l
a
n
t
L
a
y
o
u
t
1) Marketing area
For materials that are produced in bulk
quantities; such as cement, mineral
acids, and fertilisers, where the cost of the product
per tonne is relatively low and
the cost of transport a significant fraction of the
sales price, the plant should be
located close to the primary market. This
consideration will be less important for
low volume production, high-priced products; such
as pharmaceuticals.
2) Raw materials
113
3) Transport
4) Availability of labor
5) Utilities (services)
115
9) Climate
2. Maintenance workshops.
116
6. Utilities: steam boilers, compressed air, power
generation, refrigeration, transformer stations.
117
Cooling towers should be sited so that under
the prevailing winds the plume of condensate
spray drifts away from the plant area and
adjacent properties. The main storage areas should
be placed between the loading and unloading
facilities and the process units they serve. Storage
tanks containing hazardous materials should be
sited at least 70m (200ft) from the site boundary. A
typical plot plant is shown in figure 7-1.
1. Economic considerations:
118
2. The process requirements.
3. Convenience of operation.
4. Convenience of maintenance.
5. Safety.
6. Future expansion.
7. Modular construction.
1. Electricity.
3. Cooling water.
5. Demineralised water.
6. Compressed air.
7. Inert-gas supplies.
8. Refrigeration.
119
7.5 Environmental Consideration [23]
2. Waste management.
3. Smells.
4. Noise.
5. The visual impact.
120
discharged to the atmosphere through vents
normally protected by bursting discs and relief
values.
121
2. Discharge to foul water sewer (with the
agreement of the appropriate authority).
122
Chapter
Eight
Toxicity and
Effects of
Nitrobenzen
e
Chapter Eight
Toxicity and Effects of
Nitrobenzene
8.1 General
Nitrobenzene is very toxic substance;
the maximum allowable
concentration for nitrobenzene is 1 ppm or 5
mg/m3. It was exposed for eight
hours to 1 ppm nitrobenzene in the working
atmosphere, about 25 mg of
nitrobenzene would be absorbed, of which about
one-third would be by skin
absorption and the remainder by inhalation. The
primary effect of nitrobenzene
is the conversion of hemoglobin to
methemoglobin; thus the conversion
eliminates hemoglobin from the oxygen-
transport cycle. Exposure to
nitrobenzene may irritate the skin and eyes.
Nitrobenzene affects the central
nervous system and produces fatigue, headache,
vertigo, vomiting, general
weakness and in some cases unconsciousness and
coma. There generally is a
latent period of 1-4 hours before signs or symptoms
appear. Nitrobenzene is a
powerful methemoglobin former, and cyanosis
appears when the methemoglobin
level reaches 15%. Chronic exposure can lead to
spleen and liver damage,
jaundice, and anemia. Alcohol ingestion tends to
increase the toxic effects of
nitrobenzene; thus alcohol in any form should not
be ingested by the victim of
nitrobenzene poisoning for several days after the
nitrobenzene poisoning or
exposure. Impervious protective clothing should be
worn in areas where risk of
splash exists. Ordinary work clothes that have been
splashed should be removed
immediately, and the skin washed thoroughly with
soap and worm water. In
areas of high vapor concentration (>1 ppm), full face
mask with organic-vapor
123
consters or air-supplied respirators should be used.
Clean work clothing should be worn daily, and
showering after each shift should be mandatory
[2&3].
124
orally exposed persons have also included those
symptoms, as well as apnoea and coma [5].
(24- to
48-h LC50 values)
ranged from 24 mg/litre for the water flea
(Daphnia magna) to 140 mg/litre for
the snail (Lymnaea stagnalis). For marine
invertebrates, the lowest acute toxicity
value reported was a 96-h LC 50 of 6.7 mg/litre for
the mysid shrimp (Mysidopsis
bahia). The lowest chronic test value reported
was a 20-day NOEC of 1.9
mg/litre for Daphnia magna, with an EC50, based
on reproduction, of 10 mg/litre
[5].
125
8.4 Hazard and Risk Evaluation
126
risk for non-neoplastic effects. If exposure values
are low enough to avoid non-
neoplastic effects, it is expected that carcinogenic
effects will not occur [5].
127
highest reported concentrations (67 µg/litre),
nitrobenzene is unlikely to be of concern to
freshwater species [5].
128
References
129
20- John A. Dean, (1999), “Lange’s Handbook of
Chemistry”, Fifteenth Edition,
McGraw-Hill, INC.
21- David R. Lide, (2000-2001), “CRC
Handbook of Chemistry & Physics”,
editor-in-chief.
22- Donald Q. Kern, (2005), “Process Heat
Transfer”, Twelfth reprint 2005.
Tata McGraw-Hill Edition.
23- Coulson & Richardson’s, (2005), “Chemical
Engineering Design”, Vol.6,
Fourth Edition.
24- David M. Himmelblau, (1989), “Basic Principles
& Calculation in Chemical
Enginnring”, Fifth Edition.
25- Jack Winnick, (1997), “Chemical
Engineering Thermodynamics”, John
Wily & Sons, Inc.
26- J M Smith & H C Van Ness, (2003), “Introduction to Chemical
Engineering
Thermodynamics”, Sixth Edition, Tata McGraw-Hill Publishing Company
Limited.
27- Reid & Prausintz, (1987), “The Properties
of Gases & Liquids”, Fourth
Edition.
28- Chemicad 6.0.1 Program.
29- Stanley M. Walas, (1990), “Chemical Process Equipment Selection &
Design”, Butterworth-Heinemann Series in Chemical Engineering.
30- H. R. Backhurts & J. H. Harker, (1973) “Process Design”, Heinemamm
Education Books.
Cp = A + BT + CT2 + DT3
Comp. A B C D
C6H6 (L) -33.917 4.743 * 10-1 -3.017 * 10-4 7.130 * 10-9
HNO3 (L) 131.250 -0.1219 0.1704 *10-3 -
H2O (L) 32.243 1.923 * 10-3 1.055 * 10-5 -3.596 *10-9
C6H5NO2 (L) 295.3 -0.8907 1.705 * 10-3 -
A-1
Specific Heat Capacity of
[24] Cp = A + BT
Comp. A B
H2SO4 (L) 139.1 0.1559
Cp = K (Mwt.) a
For
Aci
ds:
K=
0.9
1, a
=
-0.1
52
Cp
=0.
91*
(63.
03)-
0.152
Cpig / R = A + BT + CT 2 +
DT-2
Comp. A B C
A-2
4- Density of
Liquids ,
[Kg.mol / m3]
[28]
ρ=
Comp. A B C D Range
Tempera
K
C6H6 (L) 1.0259 0.26666 562.05 0.28394 279-56
HNO3 (L) 1.5943 0.2311 520 0.1917 232-37
H2SO4 (L) 0.8322 0.19356 925 0.2857 284-36
H2O (L) 5.4590 3.0542*10-1 6.4713*102 8.1*10-2 273-33
C6H5NO2 (L) 0.69123 0.24124 719 0.28135 279-71
A-3
6- Thermal Conductivity of Liquids, [W / m.oC]
K = A + BT + CT2 + DT3
Comp. A B C D Range
Temperature
K
C6H6 (L) 0.23444 -0.00030572 - - 279-413
HNO3 (L) 0.12107 0.0005383 - - 233-433
96wt.%
H2SO4 (L) 0.014247 0.0010763 - - 283-371
98wt.%
H2O (L) -0.4267 0.00569 -8.0065*10-6 1.815*10-9 273-633
C6H5NO2 (L) 0.1869 -0.0001305 - - 283-371
Ln po = A - [23]
T = Temperature in K
Comp. A B C Range
Temperatur
o
C
C6H6 (L) 15.9008 2788.51 -52.36 7-104
Log po = A - [25]
T = Temperature in oC
Comp. A B C Range
Temperature
o
C
C6H6 (L) 7.1156 1746.6 201.8 134-211
C6H5NO2 (L) 6.90565 1211.033 220.79 8-103
A-4
Appendix B
Equilibrium Data
Mole Fractions
T Deg C P atm X1 Y1 Gamma1 Gamma2 Phi1
Phi2
210.635 1.000 0.00000 0.00000 1.416 1.000
1.000 1.000
151.914 1.000 0.10000 0.82031 1.376 1.001
1.000 1.000
126.933 1.000 0.20000 0.93286 1.340 1.005
1.000 1.000
112.693 1.000 0.30000 0.96616 1.303 1.013
1.000 1.000
103.357 1.000 0.40000 0.98015 1.261 1.031
1.000 1.000
96.798 1.000 0.50000 0.98727 1.214 1.063
1.000 1.000
92.010 1.000 0.60000 0.99139 1.162 1.123
1.000 1.000
88.401 1.000 0.70000 0.99406 1.108 1.228
1.000 1.000
85.524 1.000 0.80000 0.99603 1.057 1.418
1.000 1.000
82.944 1.000 0.90000 0.99781 1.017 1.778
1.000 1.000
80.129 1.000 1.00000 1.00000 1.000 2.529
1.000 1.000
B-1
B-2
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