Objective Time:20:00 Minuets

Name: Roll No: Group: Marks: 17

Q. 1: Circle the correct answer. No credit for cutting and for ink-remove
1) Which of the hydrogen halides has the highest percentage of ionic character
(a) HF (b) HBr
(c) HCl (d) HI
2) Which of the following molecules has unpaired electrons in anti–bonding molecular orbitals
(a) O2 (b) N2
(c) Br2 (d) F2
3) A chemical bond formed between two similar atoms is purely
(a) ionic (b) covalent
(c) metallic (d) coordinate
4) Some covalent compounds dissolve in water due to
(a) hydrolysis (b) hydration
(c) hydrogen bonding (d) metallic bonding
5) Which of the following molecules has a coordinate bond?
(a) NH4Cl (b) NaCl
(c) HCl (d) AlCl3
6) The bond order in O2 molecule is
(a) 1 (b) 2
(c) 3 (d) zero
7) Which one of the following is diamagnetic
(a) B2 (b) C2
(c) N2 (d) O2–
8) Covalent bonds are
(a) rigid and directional (b) rigid and non–directional
(c) neither rigid nor directiona (d) non–rigid and directional
9) The half of the single bond length between two atoms in a molecule is called
(a) ionic radius of an elemen (b) covalent radius of an element
(c) both ionic and covalent (d) none of these
10) One of the causes of reactions is that the systems attains the energy state which is of
(a) higher in energy (b) lower in energy
(c) balanced in energy (d) equal in energy
11) which of the following molecule have multiple bonds.
(a) CCl4 (b) CH4 (c) C2H6 (d) C2H2
12) The change in heat energy of a chemical reaction at constant temperature and pressure is called
(a) enthalpy change (b) bond energy
(c) heat of sublimation (d) internal energy change
13) For the reaction NaOH + HCl  NaCl + H2O, the change in enthalpy is called as:
(a) heat of reaction (b) heat of formation
(c) heat of neutralization (d) heat of combustion
14) Calorie is equivalent to
(a) 0.4184 J (b) 41.84 J
(c) 4.184 J (d) 418.4 J
15) Hess’s law is also called
(a) first law of thermodynamics (b) second law of thermodynamics
(c) first law of thermochemistry (d) second law of thermochemistry
16) Pressure – volume work is
(a) Pv (b) Fxd
(c) hv (d) H+pv
17) Glass calorimeter is used to determine
(a) enthalpy of combustion (b) enthalpy of reaction
(c) pressure–volume work (d) none of above
Ray Tariq Javaid.
Lec. In Chemistry
Beaconhouse
BEST OF LUCK college arifwala
 Subjective
Time: 2:10 Hours Marks: 68
Note: While writing the answers write question numbers carefully. No credit will be rewarded
in case of irregularity in question numbers.
SECTION-1

Q. 2: Answer any eights parts from the followings. (8×2=16)

1. What is electronegativity? Give its importance.
2. Ionization energy is an index to metallic character. Give reason.
3. Why the first electron affinity is negative but the second electron affinity of the elements of
all the elements is positive?
4. BF3 has zero dipolemoment.why
5. Cationic radius is smaller than that of atomic radius, but anionic radius is greater. Why
6. Differentiate b/w sigma bond and pi bonds.
7. What are spontaneous and non-spontaneous processes. Give examples.
8. Define exothermic and endothermic reaction. Give exmples.
9. Is it true that burning of candle is a spontaneous process.

Q. 3: Answer any eight parts from following. (8×2=16)

1. What is meaning of compromise distance is bond formation.
2. No bond in chemistry is 100% ionic. Justify it.
3. Why MOT is superior to VBT.
4. Pi bonds are more diffused than Sigma bond. Why?
5. Define polar covalent bond with example.
6. NH3 and NF3 have different bond angles. Justify it.
7. Enthalpy of any strong acid and base is same. Give comments.
8. Differentiate between internal energy and enthalpy
9. Energy of system and surrounding remain conserved. Which law favor this statement.

Q. 4: Answer any six parts from the following. (6×2=12)

1. Why repulsive forces are less between bond pair as compared to lone pairs.
2. What is bond order. How it is calculated.
3. Why dipolemoment of CO2 is zero but H2O is 1.85 rather both of these are triatomic
molecules.
4. Differentiate between bomb calorimeter and glass calorimeter.
5. What is importance of lattice energy.
6. What is difference between positive and negative works? Illustrate with example.
7. Is it true that a non-spontaneous process happen in universe.

SECTION-II

NOTE: Attempt any three Question. (8×3=24)

Q. 5: (a) what is hybridization? Explaine the geometry of H2O with sp3 hybridization.
(b) Define and explaine the first law of thermodynamics.
Q.6: (a) Write a note of VSEPR theory Ray Tariq Javaid.
(b) Describe the Born-Haber cycle for NaCl. Lec. In Chemistry
Q.7: (a) Define dipole moment. Give its various units. Also give its significance. Beaconhouse
(b) State the construcation and the working of the bomb calorimeter. college arifwala
Q.8: (a) predict the shapes of the following molecules on the base of vsepr theory.
1) NF3 2) SO2 3)PCl5 4) NH3
(b) Define and explaine the Hess’s of constant heat summation.