Parameters for Antoine Eqn

Código Nombre Formula A B C ∆Hn

1 Acetone C3H6O 14.3145 2756.22 228.060 29.1
2 Acetic acid C2H4O2 15.0717 3580.8 224.650 23.7
3 Acetonitrile* C2H3N 14.8950 3413.1 250.523 30.19
4 Benzene C6H6 13.7819 2726.81 217.572 30.72
5 iso-Butane C4H10 13.8254 2181.79 248.870 21.3
6 n-Butane C4H10 13.6608 2154.7 238.789 22.44
7 1-Butanol C4H10O 15.3144 3212.43 182.739 43.29
8 2-Butanol* C4H10O 15.1989 3026.03 186.500 40.75
9 iso-Butanol C4H10O 14.6047 2740.95 166.670 41.82
10 tert-Butanol C4H10O 14.8445 2658.29 177.650 39.07
11 Carbon tetrachloride CCl4 14.0572 2914.23 232.148 29.82
12 Chlorobenzene C6H5Cl 13.8635 3174.78 211.700 35.19
13 1-Chlorobutane C4H9Cl 13.7965 2723.73 218.265 30.39
14 Chloroform CHCl3 13.7324 2548.74 218.552 29.24
15 Cyclohexane C6H12 13.6568 2723.44 220.618 29.97
16 Cyclopentane C5H10 13.9727 2653.9 234.510 27.3
17 n-Decane C10H22 13.9748 3442.76 193.858 38.75
18 Dichloromethane CH2Cl2 13.9891 2463.93 223.240 28.06
19 Diethyl ether C4H10O 14.0735 2511.29 231.200 26.52
20 1,4-Dioxane C4H8O2 15.0967 3579.78 240.337 34.16
21 n-Eicosane C20H42 14.4575 4680.46 132.100 57.49
22 Ethanol C2H6O 16.8958 3795.17 230.918 38.56
23 Ethylbenzene C8H10 13.9726 3259.93 212.300 35.57
24 Ethylene glycol* C2H6O2 15.7567 4187.46 178.650 50.73
25 n-Heptane C7H16 13.8622 2910.26 216.432 31.77
26 n-Hexane C6H14 13.8193 2696.04 224.317 28.85
27 Methanol CH4O 16.5785 3638.27 239.500 35.21
28 Methyl acetate C3H6O2 14.2456 2662.78 219.690 30.32
29 Methyl ethyl ketone C4H8O 14.1334 2838.24 218.690 31.3
30 Nitromethane* CH3NO2 14.7513 3331.7 227.600 33.99
31 n-Nonane C9H20 13.9854 3311.19 202.694 36.91
32 iso-Octane C8H18 13.6703 2896.31 220.767 30.79
33 n-Octane C8H18 13.9346 3123.13 209.635 34.41
34 n-Pentane C5H12 13.7667 2451.88 232.014 25.79
35 Phenol C6H6O 14.4387 3507.8 175.400 46.18
36 1-Propanol C3H8O 16.1154 3483.67 205.807 41.44
37 2-Propanol C3H8O 16.6796 3640.2 219.610 39.85
38 Toluene C7H8 13.9320 3056.96 217.625 33.18
39 Water H2O 16.3872 3885.7 230.170 40.66
40 o-Xylene C8H10 14.0415 3358.79 212.041 36.24
41 m-Xylene C8H10 14.1387 3381.81 216.120 35.66
42 p-Xylene C8H10 14.0579 3331.45 214.627 35.67
tn
56.2
117.9
81.6
80
−11,9
−0,5
117.6
99.5
107.8
82.3
76.6
131.7
78.5
61.1
80.7
49.2
174.1
39.7
34.4
101.3
343.6
78.2
136.2
197.3
98.4
68.7
64.7
56.9
79.6
101.2
150.8
99.2
125.6
36
181.8
97.2
82.2
110.6
100
144.4
139.1
138.3
 Código Nombre Formula A B C
4 Benzene C6H6 13.7819 2726.81 217.572

P(kPa) 101.325
T(◦c) 200
f=0 2.6334115489
∆Hn tn
30.72 80
 PROPIEDADES CARACTERISTICAS DE LAS SUSTANCIAS PURAS
Código Nombre Masa molar w Tc (k) Pc (bar)
1 Metano 16.043 0.012 190.6 45.99
2 Etano 30.070 0.1 305.3 48.72
3 Propano 44.097 0.152 369.8 42.48
4 n-Butano 58.123 0.2 425.1 37.96
5 n-Pentano 72.150 0.252 469.7 33.7
6 n-Hexano 86.177 0.301 507.6 30.25
7 n-Heptano 100.204 0.35 540.2 27.4
8 n-Octano 114.231 0.4 568.7 24.9
9 n-Nonano 128.258 0.444 594.6 22.9
10 n-Decano 142.285 0.492 617.7 21.1
11 Isobutano 58.123 0.181 408.1 36.48
12 Isooctano 114.231 0.302 544 25.68
13 Ciclopentano 70.134 0.196 511.8 45.02
14 Ciclohexano 84.161 0.21 553.6 40.73
15 Metilciclopentano 84.161 0.23 532.8 37.85
16 Metilciclohexano 98.188 0.235 572.2 34.71
17 Etileno 28.054 0.087 282.3 50.4
18 Propileno 42.081 0.14 365.6 46.65
19 1-Buteno 56.108 0.191 420 40.43
20 cis-2-Buteno 56.108 0.205 435.6 42.43
21 trans-2-Buteno 56.108 0.218 428.6 41
22 1-Hexeno 84.161 0.28 504 31.4
23 Isobutileno 56.108 0.194 417.9 40
24 1,3-Butadieno 54.092 0.19 425.2 42.77
25 Ciclohexeno 82.145 0.212 560.4 43.5
26 Acetileno 26.038 0.187 308.3 61.39
27 Benceno 78.114 0.21 562.2 48.98
28 Tolueno 92.141 0.262 591.8 41.06
29 Etilbenceno 106.167 0.303 617.2 36.06
30 Cumeno 120.194 0.326 631.1 32.09
31 o-Xileno 106.167 0.31 630.3 37.34
32 m-Xileno 106.167 0.326 617.1 35.36
33 p-Xileno 106.167 0.322 616.2 35.11
34 Estíreno 104.152 0.297 636 38.4
35 Naftaleno 128.174 0.302 748.4 40.51
36 Bifenilo 154.211 0.365 789.3 38.5
37 Formaldehído 30.026 0.282 408 65.9
38 Acetaldehído 44.053 0.291 466 55.5
39 Acetato de metilo 74.079 0.331 506.6 47.5
40 Acetato de etilo 88.106 0.366 523.3 38.8
41 Acetona 58.080 0.307 508.2 47.01
42 Metil etil cetona 72.107 0.323 535.5 41.5
43 Éter dietílico 74.123 0.281 466.7 36.4
44 Éter metíl t-butílico 88.150 0.266 497.1 34.3
45 Metanol 32 0.564 512.6 80.97
46 Etanol 46 0.645 513.9 61.48
47 1-Propanol 60 0.622 536.8 51.75
48 1-Butanol 74 0.594 563.1 44.23
49 1-Hexanol 102 0.579 611.4 35.1
50 2-Propanol 60 0.668 508.3 47.62
51 Fenol 94 0.444 694.3 61.3
52 Etilenglicol 62 0.487 719.7 77
53 Ácido acético 60 0.467 592 57.86
54 Ácido n-Butírico 88 0.681 615.7 40.64
55 Ácido Benzoico 122 0.603 751 44.7
56 Acetonitrilo 41 0.338 545.5 48.3
57 Metilarnina 31 0.281 430.1 74.6
58 Etilarnina 45 0.285 456.2 56.2
59 Nitrometano 61 0.348 588.2 63.1
60 Tetracloruro de carbono 154 0.193 556.4 45.6
61 Cloroformo 119 0.222 536.4 54.72
62 Dic1orometano 85 0.199 510 60.8
63 Cloruro de metilo 50 0.153 416.3 66.8
64 Cloruro de etilo 65 0.19 460.4 52.7
65 Clorobenceno 113 0.25 632.4 45.2
66 Tetrafiuoroetano 102 0.327 374.2 40.6
67 Argón 40 0 150.9 48.98
68 Kriptón 84 0 209.4 55.02
69 Xenón 131.3 0 289.7 58.4
70 Helio 4 4.003 -0.39 5.2 2.28
71 Hidrógeno 2.016 -0.216 33.19 13.13
72 Oxígeno 31.999 0.022 154.6 50.43
73 Nitrógeno 28.014 0.038 126.2 34
74 Airet 28.851 0.035 132.2 37.45
75 Cloro 70.905 0.069 417.2 77.1
76 Monóxido de carbono 28.010 0.048 132.9 34.99
77 Dióxido de carbono 44.010 0.224 304.2 73.83
78 Disulfuro de carbono 76.143 0.111 552 79
79 Sulfuro de hidrógeno 34.082 0.094 373.5 89.63
80 Dióxido de azufre 64.065 0.245 430.8 78.84
81 Trióxido de azufre 80.064 0.424 490.9 82.1
82 Óxido nítrico (NO) 30.006 0.583 180.2 64.8
83 Óxido nitroso (N2O) 44.013 0.141 309.6 72.45
84 Cloruro de hidrógeno 36.461 0.132 324.7 83.1
85 Cianuro de hidrógeno 27.026 0.41 456.7 53.9
86 Agua 18.015 0.345 647.1 220.55
87 Amoniaco 17.031 0.253 405.7 112.8
88 Ácido nítrico 63.013 0.714 520 68.9
89 Ácido sulfúrico 98.080 924 64 0.147
CIAS PURAS
Zc Vc (cm3mol-1) Tn (k)
0.286 98.6 111.4
0.279 145.5 184.6
0.276 200 231.1
0.274 255 272.7
0.27 313 309.2
0.266 371 341.9
0.261 428 371.6
0.256 486 398.8
0.252 544 424
0.247 600 447.3
0.282 262.7 261.4
0.266 468 372.4
0.273 258 322.4
0.273 308 353.9
0.272 319 345
0.269 368 374.1
0.281 131 169.4
0.289 188.4 225.5
0.277 239.3 266.9
0.273 233.8 276.9
0.275 237.7 274
0.265 354 336.3
0.275 238.9 266.3
0.267 220.4 268.7
0.272 291 356.1
0.271 113 189.4
0.271 259 353.2
0.264 316 383.8
0.263 374 409.4
0.261 427 425.6
0.263 369 417.6
0.259 376 412.3
0.26 379 411.5
0.256 352 418.3
0.269 413 491.2
0.295 502 528.2
0.223 115 254.1
0.221 154 294
0.257 228 330.1
0.255 286 350.2
0.233 209 329.4
0.249 267 352.8
0.263 280 307.6
0.273 329 328.4
0.224 118 337.9
0.24 167 351.4
0.254 219 370.4
0.26 275 390.8
0.263 381 430.6
0.248 220 355.4
0.243 229 455
0.246 191 470.5
0.211 179.7 391.1
0.232 291.7 436.4
0.246 344 522.4
0.184 173 354.8
0.321 154 266.8
0.307 207 289.7
0.223 173 374.4
0.272 276 349.8
0.293 239 334.3
0.265 185 312.9
0.276 143 249.1
0.275 200 285.4
0.265 308 404.9
0.258 198 247.1
0.291 74.6 87.3
0.288 91.2 119.8
0.286 118 165
0.302 57.3 4.2
0.305 64.1 20.4
0.288 73.4 90.2
0.289 89.2 77.3
0.289 84.8
0.265 124 239.1
0.299 93.4 81.7
0.274 94
0.275 160 319.4
0.284 98.5 212.8
0.269 122 263.1
0.255 127 317.9
0.251 58 121.4
0.274 97.4 184.7
0.249 81 188.2
0.197 139 298.9
0.229 55.9 373.2
0.242 72.5 239.7
0.231 145 356.2
177 610
 CAPACIDADES CALORIFICAS DE GASES
T (kelvin) desde EN EL
298 hasta ESTADO DE GAS IDEAL
Tmáx

(cpgi/R)=A+BT+CT2+DT-2
Código Especie Química Fórmula Tmax Cpgi(298)/R A 103B
1 Metano CH4 1500 4.217 1.702 9.081
2 Etano C2H6 1500 6.369 1.131 19.225
3 Propano C3Hg 1500 9.011 1.213 28.785
4 n-Butano C4HlO 1500 11.928 1.935 36.915
5 iso-Butano C4HlO 1500 11.901 1.677 37.853
6 n-Pentano CSHI2 1500 14.731 2.464 45.351
7 n-Hexano C6HI4 1500 17.550 3.025 53.722
8 n-Heptano C7HI6 1500 20.361 3.570 62.127
9 n-Octano CgHlg 1500 23.174 4.108 70.567
10 Etileno C2H4 1500 5.325 1.424 14.394
11 Propileno C3H6 1500 7.792 1.637 22.706
12 l-Buteno C4Hg 1500 10.520 1.967 31.630
13 l-Penteno CSHlO 1500 13.437 2.691 39.753
14 l-Hexeno C6H12 1500 16.240 3.220 48.189
15 l-Hepteno C7Hl4 1500 19.053 3.768 56.588
16 1-Octeno CgHl6 1500 21.868 4.324 64.960
17 Acetaldehído C2H40 1000 65.060 1.693 17.978
18 Acetileno C2H2 1500 5.253 6.132 1.952
19 Benceno C6H6 1500 10.259 -0.206 39.064
20 1,3-Butadieno C4H6 1500 10.720 2.734 26.786
21 Ciclohexano C6HI2 1500 13.121 -3.876 63.249
22 Etanol C2H60 1500 8.948 3.518 20.001
23 Etilbenceno CgHIO 1500 15.993 1.124 55.380
24 Óxido de etileno C2H40 1000 5.784 -0.385 23.463
25 Formaldehído CH20 1500 4.191 2.264 7.022
26 Metanol CH40 1500 5.547 2.211 12.216
27 Estireno CgHg 1500 15.534 2.050 50.192
28 Tolueno C7Hg 1500 12.922 0.290 47.052
29 Aire 2000 3.509 3.355 0.575
30 Amoniaco NH3 1800 4.269 3.578 3.020
31 Bromo Br2 3000 4.337 4.493 0.056
32 Monóxido de carbono CO 2500 3.507 3.376 0.557
33 Dióxido de carbon CO2 2000 4.467 5.457 1.045
34 Disulfuro de carbono CS2 1800 5.532 6.311 0.805
35 Cloro CI2 3000 4.082 4.442 0.089
36 Hidrógeno H2 3000 3.468 3.249 0.422
37 Sulfuro de hidrógeno H2S 2300 4.114 3.931 1.490
38 Cloruro de hidrógeno HCl 2000 3.512 3.156 0.623
39 Cianuro de hidrógeno HCN 2500 4.326 4.736 1.359
40 Nitrógeno N2 2000 3.502 3.280 0.593
41 Óxido nitroso N2O 2000 4.646 5.328 1.214
42 Óxido nítrico NO 2000 3.590 3.387 0.629
43 Dióxido de nitrógeno NO2 2000 4.447 4.982 1.195
44 Tetraóxido de dinitrógeno N2O4 2000 9.198 11.660 2.257
45 Oxígeno O2 2000 3.535 3.639 0.506
46 Dióxido de azufre SO2 2000 4.796 5.699 0.801
47 Trióxido de azufre SO3 2000 6.094 8.060 1.056
48 Agua H2O 2000 4.038 3.470 1.450
EAL

106C 10-5D
-2.164
-5.561
-8.824
-11.402
-11.945
-14.111
-16.791
-19.486
-22.208
-4.392
-6.915
-9.873
-12.447
-15.157
-17.847
-20.521
-6.158
-1.299
-13.301
-8.882
-20.928
-6.002
-18.476
-9.296
-1.877
-3.450
-16.662
-15.716
-0.016
-0.186
-0.154
-0.031
-1.157
-0.906
-0.344
0.083
-0.232
0.151
-0.725
0.04
-0.928
 0.014
-0.792
-2.787
-0.227
-1.015
-2.028
0.121
 (cpgi/R)=A+BT+CT2+DT-2
Código Nombre Fórmula Tmáx Cpgi(298)/R A B
1 Metano CH4 1500 4.217 1.702 0.009081
2 Etano C2H6 1500 6.369 1.131 0.019225
3 Propano C3H8 1500 9.011 1.213 0.028785
4 n-Butano C4H10 1500 11.928 1.935 0.036915
5 iso-Butano C4H10 1500 11.901 1.677 0.037853
6 n-Pentano C5H12 1500 14.731 2.464 0.045351
7 n-Hexano C6H14 1500 17.55 3.025 0.053722
8 n-Heptano C7H16 1500 20.361 3.57 0.062127
9 n-Octano C8H18 1500 23.174 4.108 0.070567
10 Etileno C2H4 1500 5.325 1.424 0.014394
11 Propileno C3H6 1500 7.792 1.637 0.022706
12 1-Buteno C4H8 1500 10.52 1.967 0.03163
13 1-Hexeno C6H12 1500 16.24 3.22 0.048189
14 Acetaldehído C2H40 1000 6.506 1.693 0.017978
15 Acetileno C2H2 1500 5.253 6.132 0.001952
16 Benceno C6H6 1500 10.259 -0.206 0.039064
17 1,3-Butadieno C4H6 1500 10.72 2.734 0.026786
18 Ciclohexano C6H12 1500 13.121 -3.876 0.063249
19 Etanol C2H60 1500 8.948 3.518 0.020001
20 Etilbenceno C8H10 1500 15.993 1.124 0.05538
21 Formaldehído CH20 1500 4.191 2.264 0.007022
22 Metanol CH40 1500 5.547 2.211 0.012216
23 Estireno C8H8 1500 15.534 2.05 0.050192
24 Tolueno C7H8 1500 12.922 0.29 0.047052
25 Aire 2000 3.509 3.355 0.000575
26 Amoniaco NH3 1800 4.269 3.578 0.00302
27 Monóxido de carbono CO 2500 3.507 3.376 0.000557
28 Dióxido de carbono CO2 2000 4.467 5.457 0.001045
29 Disulfuro de carbono CS2 1800 5.532 6.311 0.000805
30 Cloro CI2 3000 4.082 4.442 0.000089
31 Hidrógeno H2 3000 3.468 3.249 0.000422
32 Sulfuro de hiddrógeno H2S 2300 4.114 3.931 0.00149
33 Cloruro de hiddrógeno HCl 2000 3.512 3.156 0.000623
34 Cianuro de hiddrógeno HCN 2500 4.326 4.736 0.001359
35 Nitrógeno N2 2000 3.502 3.28 0.000593
36 Óxido nitroso N20 2000 4.646 5.328 0.001214
37 Óxido nitrico NO 2000 3.59 3.387 0.000629
38 Oxígeno O2 2000 3.535 3.639 0.000506
39 Dióxido de azufre SO2 2000 4.796 5.699 0.000801
40 Trióxido de azufre SO3 2000 6.094 8.06 0.001056
41 Agua H2O 2000 4.038 3.47 0.00145
(cpgi/R)=A+BT+CT2+DT-2
C D Masa molar ω Tc (K) Pc (bar) Zc
-2.16E-06 0 16.043 0.012 190.6 45.99 0.286
-5.56E-06 0 30.07 0.1 305.3 48.72 0.279
-8.82E-06 0 44.097 0.152 369.8 42.48 0.276
-1.14E-05 0 58.123 0.2 425.1 37.96 0.274
-1.19E-05 0 58.123 0.181 408.1 36.48 0.282
-1.41E-05 0 72.15 0.252 469.7 33.7 0.27
-1.68E-05 0 86.177 0.301 507.6 30.25 0.266
-1.95E-05 0 100.204 0.35 540.2 27.4 0.261
-2.22E-05 0 114.231 0.4 568.7 24.9 0.256
-4.39E-06 0 28.054 0.087 282.3 50.4 0.281
-6.92E-06 0 42.081 0.14 365.6 46.65 0.289
-9.87E-06 0 56.108 0.191 420 40.43 0.277
-1.52E-05 0 84.161 0.28 504 31.4 0.265
-6.16E-06 0 44.053 0.291 466 55.5 0.221
0 -129900 26.038 0.187 308.3 61.39 0.271
-1.33E-05 0 78.114 0.21 562.2 48.98 0.271
-8.88E-06 0 54.092 0.19 425.2 42.77 0.267
-2.09E-05 0 84.161 0.21 553.6 40.73 0.273
-6.00E-06 0 46.069 0.645 513.9 61.48 0.24
-1.85E-05 0 106.167 0.303 617.2 36.06 0.263
-1.88E-06 0 30.026 0.282 408 65.9 0.223
-0.00000345 0 32.042 0.564 512.6 80.97 0.224
-1.67E-05 0 104.152 0.297 636 38.4 0.256
-1.57E-05 0 92.141 0.262 591.8 41.06 0.264
0 -1600 28.851 0.035 132.2 37.45 0.289
0 -18600 17.031 0.253 405.7 112.8 0.242
0 -3100 28.01 0.048 132.9 34.99 0.299
0 -115700 44.01 0.224 304.2 73.83 0.274
0 -90600 76.143 0.111 552 79 0.275
0 -34400 70.905 0.069 417.2 77.1 0.265
0 8300 2.016 -0.216 33.19 13.13 0.305
0 -23200 34.082 0.094 373.5 89.63 0.284
0 15100 36.461 0.132 324.7 83.1 0.249
0 -72500 27.026 0.41 456.7 53.9 0.197
0 4000 28.014 0.038 126.2 34 0.289
0 -92800 44.013 0.141 309.6 72.45 0.274
0 1400 30.006 0.583 180.2 64.8 0.251
0 -22700 31.999 0.022 154.6 50.43 0.288
0 -101500 64.065 0.245 430.8 78.84 0.269
0 -202800 80.064 0.424 490.9 82.1 0.255
0 12100 18.015 0.345 647.1 220.55 0.229
Vc (cm3mol-1) Tn (K)
98.6 111.4
145.5 184.6
200 231.1
255 272.7
262.7 261.4
313 309.2
371 341.9
428 371.6
486 398.8
131 169.4
188.4 225.5
239.3 266.9
354 336.3
154 294
113 189.4
259 353.2
220.4 268.7
308 353.9
167 351.4
374 409.4
115 254.1
118 337.9
352 418.3
316 383.8
84.8
72.5 239.7
93.4 81.7
94 0
160 319.4
124 239.1
64.1 20.4
98.5 212.8
81 188.2
139 298.9
89.2 77.3
97.4 184.7
58 121.4
73.4 90.2
122 263.1
127 317.9
55.9 373.2
 Código Nombre Formula A B C D
28 Dióxido de carbono CO2 5.457 0.001045 0 -115700
R(bar.m3/mol.k) 8.31E-05 Pgi (bar) 1
Estado 1 ∆H(1-A) 0.028242363
T(k) 313 ∆H(A-B) -0.02231099
P(bar) 70 ∆H(B-2) -0.00593138
Estado 2 ∆H=0 -7.74258E-09
T(k) 250.2113374989
P(bar) 10

Gráfica
Temperatura Presión
Estado 1 313 70
Estado 2 250.2113374989 10
80

70

60

50
Presión(bar)

40

30

20

10

0
240 250 260 270 280 290 300 310 320
Temperatura(k)
ᵚ Tc Pc
0.224 304.2 73.83
 Código Nombre Formula A B C D
6 n-Pentano C5H12 2.464 0.045351 -0.000014111 0
R(pa.m3/mol.k) 8.314472 CTE VDW V.Gas Ideal Volumen RT
Presión(pa) Temperatura(K) a b 0.001696152 0.0013289958 4240.38072
2500000 510 1.909256861 0.000144856
RT= 4240
ᵚ Tc Pc
0.252 469.7 33.7
 Valores de Z0
Pr 0.01 0.05 0.1 0.2 0.4 0.6 0.8
Tr
0.3 0.0029 0.0145 0.0290 0.0579 0.1158 0.1737 0.2315
0.35 0.0026 0.0130 0.0261 0.0522 0.1043 0.1564 0.2084
0.4 0.0024 0.0119 0.0239 0.0477 0.0953 0.1429 0.1904
0.45 0.0022 0.0110 0.0221 0.0442 0.0882 0.1322 0.1762
0.5 0.0021 0.0103 0.0207 0.0413 0.0825 0.1236 0.1647
0.55 0.9804 0.0098 0.0195 0.0390 0.0778 0.1166 0.1553
0.6 0.9849 0.0093 0.0186 0.0371 0.0741 0.1109 0.1476
0.65 0.9881 0.9377 0.0178 0.0356 0.0710 0.1063 0.1415
0.7 0.9904 0.9504 0.8958 0.0344 0.0687 0.1027 0.1366
0.75 0.9922 0.9598 0.9165 0.0336 0.0670 0.1001 0.1330
0.8 0.9935 0.9669 0.9319 0.8539 0.0661 0.0985 0.1307
0.85 0.9946 0.9725 0.9436 0.8810 0.0661 0.0983 0.1301
0.9 0.9954 0.9768 0.9528 0.9015 0.7800 0.1006 0.1321
0.93 0.9959 0.9790 0.9573 0.9115 0.8059 0.6635 0.1359
0.95 0.9961 0.9803 0.9600 0.9174 0.8206 0.6967 0.1410
0.97 0.9963 0.9815 0.9625 0.9227 0.8338 0.7240 0.5580
0.98 0.9965 0.9821 0.9637 0.9253 0.8398 0.7360 0.5887
0.99 0.9966 0.9826 0.9648 0.9277 0.8455 0.7471 0.6138
1 0.9967 0.9832 0.9659 0.9300 0.8509 0.7574 0.6355
1.01 0.9968 0.9837 0.9669 0.9322 0.8561 0.7671 0.6542
1.02 0.9969 0.9842 0.9679 0.9343 0.8610 0.7761 0.6710
1.05 0.9971 0.9855 0.9707 0.9401 0.8743 0.8002 0.7130
1.1 0.9975 0.9874 0.9747 0.9485 0.893 0.8323 0.7649
1.15 0.9978 0.9891 0.978 0.9554 0.9081 0.8576 0.8032
1.2 0.9981 0.9904 0.9808 0.9611 0.9205 0.8779 0.833
1.3 0.9985 0.9926 0.9852 0.9702 0.9396 0.9083 0.8764
1.4 0.9988 0.9942 0.9884 0.9768 0.9534 0.9298 0.9062
1.5 0.9991 0.9954 0.9909 0.9818 0.9636 0.9456 0.9278
1.6 0.9993 0.9964 0.9928 0.9856 0.9714 0.9575 0.9439
1.7 0.9994 0.9971 0.9943 0.9886 0.9775 0.9667 0.9563
1.8 0.9995 0.9977 0.9955 0.991 0.9823 0.9739 0.9659
1.9 0.9996 0.9982 0.9964 0.9929 0.9861 0.9796 0.9735
2 0.9997 0.9986 0.9972 0.9944 0.9892 0.9842 0.9796
2.2 0.9998 0.9992 0.9983 0.9967 0.9937 0.991 0.9886
2.4 0.9999 0.9996 0.9991 0.9983 0.9969 0.9957 0.9948
2.6 1.0000 0.9998 0.9997 0.9994 0.9991 0.999 0.999
2.8 1.0000 1.0000 1.0001 1.0002 1.001 1.0013 1.0021
3 1.0000 1.0002 1.0004 1.0008 1.002 1.0030 1.0043
3.5 1.0001 1.0004 1.0008 1.0017 1.004 1.0055 1.0075
4 1.0001 1.0005 1.0010 1.0021 1.004 1.0066 1.0090
Valores de Z1
Pr 0.01 0.05 0.1 0.2 0.4 0.6 0.8
 Tr
0.3 -0.0008 -0.0040 -0.0081 -0.0161 -0.0323 -0.0484 -0.0645
0.35 -0.0009 -0.0046 -0.0093 -0.0185 -0.0370 -0.0554 -0.0738
0.4 -0.001 -0.0048 -0.0095 -0.0190 -0.0380 -0.0570 -0.0758
0.45 -0.0009 -0.0047 -0.0094 -0.0187 -0.0374 -0.0560 -0.0745
0.5 -0.0009 -0.0045 -0.0090 -0.0181 -0.0360 -0.0539 -0.0716
0.55 -0.0314 -0.0043 -0.0086 -0.0172 -0.0343 -0.0513 -0.0682
0.6 -0.0205 -0.0041 -0.0082 -0.0164 -0.0326 -0.0487 -0.0646
0.65 -0.0137 -0.0772 -0.0078 -0.0156 -0.0309 -0.0461 -0.0611
0.7 -0.0093 -0.0507 -0.1161 -0.0148 -0.0294 -0.0438 -0.0579
0.75 -0.0064 -0.0339 -0.0744 -0.0143 -0.0282 -0.0417 -0.0550
0.8 -0.0044 -0.0228 -0.0487 -0.1160 -0.0272 -0.0401 -0.0526
0.85 -0.0029 -0.0152 -0.0319 -0.0715 -0.0268 -0.0391 -0.0509
0.9 -0.0019 -0.0099 -0.0205 -0.0442 -0.1118 -0.0396 -0.0503
0.93 -0.0015 -0.0075 -0.0154 -0.0326 -0.0763 -0.1662 -0.0514
0.95 -0.0012 -0.0062 -0.0126 -0.0262 -0.0589 -0.1110 -0.0540
0.97 -0.001 -0.005 -0.0101 -0.0208 -0.0450 -0.0770 -0.1647
0.98 -0.0009 -0.0044 -0.009 -0.0184 -0.0390 -0.0641 -0.1100
0.99 -0.0008 -0.0039 -0.0079 -0.0161 -0.0335 -0.0531 -0.0796
1 -0.0007 -0.0034 -0.0069 -0.0140 -0.0285 -0.0435 -0.0588
1.01 -0.0006 -0.003 -0.006 -0.0120 -0.024 -0.0351 -0.0429
1.02 -0.0005 -0.0026 -0.0051 -0.0102 -0.0198 -0.0277 -0.0303
1.05 -0.0003 -0.0015 -0.0029 -0.0054 -0.0092 -0.0097 -0.0032
1.1 0.0000 0.0000 0.0001 0.0007 0.0038 0.0106 0.0236
1.15 0.0002 0.0011 0.0023 0.0052 0.0127 0.0237 0.0396
1.2 0.0004 0.0019 0.0039 0.0084 0.019 0.0326 0.0499
1.3 0.0006 0.003 0.0061 0.0125 0.0267 0.0429 0.0612
1.4 0.0007 0.0036 0.0072 0.0147 0.0306 0.0477 0.0661
1.5 0.0008 0.0039 0.0078 0.0158 0.0323 0.0497 0.0677
1.6 0.0008 0.004 0.008 0.0162 0.033 0.0501 0.0677
1.7 0.0008 0.004 0.0081 0.0163 0.0329 0.0497 0.0667
1.8 0.0008 0.004 0.0081 0.0162 0.0325 0.0488 0.0652
1.9 0.0008 0.004 0.0079 0.0159 0.0318 0.0477 0.0635
2 0.0008 0.0039 0.0078 0.0155 0.031 0.0464 0.0617
2.2 0.0007 0.0037 0.0074 0.0147 0.0293 0.0437 0.0579
2.4 0.0007 0.0035 0.007 0.0139 0.0276 0.0411 0.0544
2.6 0.0007 0.0033 0.0066 0.0131 0.026 0.0387 0.0512
2.8 0.0006 0.0031 0.0062 0.0124 0.0245 0.0365 0.0483
3 0.0006 0.0029 0.0059 0.0117 0.0232 0.0345 0.0456
3.5 0.0005 0.0026 0.0052 0.0103 0.0204 0.0303 0.0401
4 0.0005 0.0023 0.0046 0.0091 0.0182 0.027 0.0357
Valores de Z0
1 1.2 1.5 2 3 5 7 10

0.2892 0.3479 0.4335 0.5775 0.8648 1.4366 2.0480 2.8507

0.2604 0.3123 0.3901 0.5195 0.7775 1.2902 1.7987 2.5539
0.2379 0.2853 0.3563 0.4744 0.7095 1.1758 1.6373 2.3211
0.2200 0.2638 0.3294 0.4384 0.6551 1.0841 1.5077 2.1338
0.2056 0.2465 0.3077 0.4092 0.6110 1.0094 1.4017 1.9801
0.1939 0.2323 0.2899 0.3853 0.5747 0.9475 1.3137 1.8520
0.1842 0.2207 0.2753 0.3657 0.5446 0.8959 1.2398 1.7440
0.1765 0.2113 0.2634 0.3495 0.5197 0.8526 1.1773 1.6519
0.1703 0.2038 0.2538 0.3364 0.4991 0.8161 1.1341 1.5729
0.1656 0.1981 0.2464 0.326 0.4823 0.7854 1.0787 1.5047
0.1626 0.1942 0.2411 0.3182 0.4690 0.7598 1.0400 1.4456
0.1614 0.1924 0.2382 0.3132 0.4591 0.7388 1.0071 1.3943
0.1630 0.1935 0.2383 0.3114 0.4527 0.7220 0.9793 1.3496
0.1664 0.1963 0.2405 0.3122 0.4507 0.7138 0.9648 1.3257
0.1705 0.1998 0.2432 0.3138 0.4501 0.7092 0.9561 1.3108
0.1779 0.2055 0.2474 0.3164 0.4504 0.7052 0.9480 1.2968
0.1844 0.2097 0.2503 0.3182 0.4508 0.7035 0.9442 1.2901
0.1959 0.2154 0.2538 0.3204 0.4514 0.7018 0.9406 1.2835
0.2901 0.2237 0.2583 0.3229 0.4522 0.7004 0.9372 1.2772
0.4648 0.2370 0.2640 0.3260 0.4533 0.6991 0.9339 1.2710
0.5146 0.2629 0.2715 0.3297 0.4547 0.6980 0.9307 1.2650
0.6026 0.4437 0.3131 0.3452 0.4604 0.6956 0.9222 1.2481
0.688 0.5984 0.4580 0.3953 0.4770 0.6950 0.9110 1.2232
0.7443 0.6803 0.5798 0.4760 0.5042 0.6987 0.9033 1.2021
0.7858 0.7363 0.6605 0.5605 0.5425 0.7069 0.8990 1.1844
0.8438 0.8111 0.7624 0.6908 0.6344 0.7358 0.8998 1.1580
0.8827 0.8595 0.8256 0.7753 0.7202 0.7761 0.9112 1.1419
0.9103 0.8933 0.8689 0.8328 0.7887 0.8200 0.9297 1.1339
0.9308 0.9180 0.9000 0.8738 0.8410 0.8617 0.9518 1.1320
0.9463 0.9367 0.9234 0.9043 0.8809 0.8984 0.9745 1.1343
0.9583 0.9511 0.9413 0.9275 0.9118 0.9297 0.9961 1.1391
0.9678 0.9624 0.9552 0.9456 0.9359 0.9557 1.0157 1.1452
0.9754 0.9715 0.9664 0.9599 0.955 0.9772 1.0328 1.1516
0.9865 0.9847 0.9826 0.9806 0.9827 1.0094 1.0600 1.1635
0.9941 0.9936 0.9935 0.9945 1.0011 1.0313 1.0793 1.1728
0.9993 0.9998 1.0010 1.0040 1.0137 1.0463 1.0926 1.1792
1.0031 1.0042 1.0063 1.0106 1.0223 1.0565 1.1016 1.1830
1.0057 1.0074 1.0101 1.0153 1.0284 1.0635 1.1075 1.1848
1.0097 1.0120 1.0156 1.0221 1.0368 1.0723 1.1138 1.1834
1.0115 1.0140 1.0179 1.0249 1.0401 1.0747 1.1136 1.1773
Valores de Z1
1 1.2 1.5 2 3 5 7 10
-0.0806 -0.0966 -0.1207 -0.1608 -0.2407 -0.3996 -0.5572 -0.7915
-0.0921 -0.1105 -0.1379 -0.1834 -0.2738 -0.4523 -0.6279 -0.8863
-0.0946 -0.1134 -0.1414 -0.1879 -0.2799 -0.4603 -0.6365 -0.8936
-0.0929 -0.1113 -0.1387 -0.184 -0.2734 -0.4475 -0.6162 -0.8608
-0.0893 -0.1069 -0.133 -0.1762 -0.2611 -0.4253 -0.5831 -0.8099
-0.0849 -0.1015 -0.1263 -0.1669 -0.2465 -0.3991 -0.5446 -0.7521
-0.0803 -0.096 -0.1192 -0.1572 -0.2312 -0.3718 -0.5047 -0.6928
-0.0759 -0.0906 -0.1122 -0.1476 -0.216 -0.3447 -0.4653 -0.6346
-0.0718 -0.0855 -0.1057 -0.1385 -0.2013 -0.3184 -0.427 -0.5785
-0.0681 -0.0808 -0.0996 -0.1298 -0.1872 -0.2929 -0.3901 -0.525
-0.0648 -0.0767 -0.094 -0.1217 -0.1736 -0.2682 -0.3545 -0.474
-0.0622 -0.0731 -0.0888 -0.1138 -0.1602 -0.2439 -0.3201 -0.4254
-0.0604 -0.0701 -0.084 -0.1059 -0.1463 -0.2195 -0.2862 -0.3788
-0.0602 -0.0687 -0.081 -0.1007 -0.1374 -0.2045 -0.2661 -0.3516
-0.0607 -0.0678 -0.0788 -0.0967 -0.131 -0.1943 -0.2526 -0.3339
-0.0623 -0.0669 -0.0759 -0.0921 -0.124 -0.1837 -0.2391 -0.3163
-0.0641 -0.0661 -0.074 -0.0893 -0.1202 -0.1783 -0.2322 -0.3075
-0.0680 -0.0646 -0.0715 -0.0861 -0.1162 -0.1728 -0.2254 -0.2989
-0.0879 -0.0609 -0.0678 -0.0824 -0.1118 -0.1672 -0.2185 -0.2902
-0.0223 -0.0473 -0.0621 -0.0778 -0.1072 -0.1615 -0.2116 -0.2816
-0.0062 -0.0227 -0.0524 -0.0722 -0.1021 -0.1556 -0.2047 -0.2731
0.0220 0.1059 0.0451 -0.0432 -0.0838 -0.137 -0.1835 -0.2476
0.0476 0.0897 0.163 0.0698 -0.0373 -0.1021 -0.1469 -0.2056
0.0625 0.0943 0.1548 0.1667 0.0332 -0.0611 -0.1084 -0.1642
0.0719 0.0991 0.1477 0.199 0.1095 -0.0141 -0.0678 -0.1231
0.0819 0.1048 0.142 0.1991 0.2079 0.0875 0.0176 -0.0423
0.0857 0.1063 0.1383 0.1894 0.2397 0.1737 0.1008 0.035
0.0864 0.1055 0.1345 0.1806 0.2433 0.2309 0.1717 0.1058
0.0855 0.1035 0.1303 0.1729 0.2381 0.2631 0.2255 0.1673
0.0838 0.1008 0.1259 0.1658 0.2305 0.2788 0.2628 0.2179
0.0814 0.0978 0.1216 0.1593 0.2224 0.2846 0.2871 0.2576
0.0792 0.0947 0.1173 0.1532 0.2144 0.2848 0.3017 0.2876
0.0767 0.0916 0.1133 0.1476 0.2069 0.2819 0.3097 0.3096
0.0719 0.0857 0.1057 0.1374 0.1932 0.272 0.3135 0.3355
0.0675 0.0803 0.0989 0.1285 0.1812 0.2602 0.3089 0.3459
0.0634 0.0754 0.0929 0.1207 0.1706 0.2484 0.3009 0.3475
0.0598 0.0711 0.0876 0.1138 0.1613 0.2372 0.2915 0.3443
0.0565 0.0672 0.0828 0.1076 0.1529 0.2268 0.2817 0.3385
0.0497 0.0591 0.0728 0.0949 0.1356 0.2042 0.2584 0.3194
0.0443 0.0527 0.0651 0.0849 0.1219 0.1857 0.2378 0.2994
 Parameters for Antoine Eqn
Código Nombre Formula A B C ∆Hn
14 Chloroform CHCl3 13.7324 2548.74 218.552 29.24
20 1,4-Dioxane C4H8O2 15.0967 3579.78 240.337 34.16
Isotérmico
Temperatura(oc) P.Satrutación(Kpa)
Diagrama EVL
50 Chloroform 69.5276197
1,4-Dioxane 15.9101782
65.00
X1 Y1 P
0 0 15.9101782 55.00
0.0932 0.309938002 20.9073238
0.1248 0.3839123572 22.6016349

Presión(Kpa)
45.00
0.1757 0.4822595723 25.3307627
0.2 0.5221032534 26.6336665
0.2626 0.6087989622 29.9901183 35.00
0.3615 0.7121615509 35.2928833
0.475 0.7981354797 41.3784629
0.5555 0.8452319561 45.6946669 25.00

0.6718 0.8994476652 51.9303754

0.878 0.9691831082 62.9862918 15.00
0.9398 0.9855536214 66.2998497 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0

1 1 69.5276197
X1,Y1
 tn
61.1
101.3

Diagrama EVL

Col umn C
Col umn C

4 0.5 0.6 0.7 0.8 0.9 1

X1,Y1
 Parameters for Antoine Eqn
Código Nombre Formula A B C ∆Hn
34 n-Pentane C5H12 13.7667 2451.88 232.014 25.79
42 p-Xylene C8H10 14.0579 3331.45 214.627 35.67
Isobarico
Presión(Kpa) Temperaturasat(k)
200 n-Pentane 57.5194453
p-Xylene 165.6936316
5
Temp.sat P1.sat P2.sat X1 Y1 175.00
57.5194453 200 6.1503737004 1 1 170.00
165.00
62.5194453 230.9212254 7.6703308745 0.861495626 0.994688128
160.00
67.5194453 265.3464863 9.491334993 0.744595776 0.987879365
155.00
72.5194453 303.5156754 11.657856167 0.645321562 0.979326049 150.00
77.5194453 345.6712343 14.218497047 0.560506769 0.968755334 145.00
82.5194453 392.0573612 17.22608505 0.4876165 0.955868191 140.00
87.5194453 442.919234 20.737741287 0.424609467 0.9403385 135.00
92.5194453 498.5022545 24.814925754 0.369832722 0.921812229 130.00
125.00
97.5194453 559.0513167 29.523458682 0.321940647 0.899906714

Temperatura(K)
120.00
102.5194453 624.810104 34.93351821 0.279832232 0.874210031
115.00
107.5194453 696.0204182 41.119614802 0.242602215 0.844280474 110.00
112.5194453 772.9215417 48.160543061 0.209502798 0.809646127 105.00
117.5194453 855.7496365 56.139311808 0.179913495 0.76980454 100.00
122.5194453 944.7371799 65.143053439 0.153317243 0.7242225 95.00
127.5194453 1040.112439 75.262913755 0.129281388 0.672335901 90.00
85.00
132.5194453 1142.098982 86.59392356 0.107442476 0.61354971
80.00
137.5194453 1250.915234 99.234853411 0.08749402 0.547238014 75.00
142.5194453 1366.774062 113.28805299 0.069176637 0.472744168 70.00
147.5194453 1489.882411 128.85927658 0.052270032 0.38938101 65.00
152.5194453 1620.440963 146.05749626 0.036586482 0.296431168 60.00
157.5194453 1758.643847 164.99470416 0.021965497 0.193147433 55.00
0 0.1 0.2 0.3 0.4 0.5
162.5194453 1904.678376 185.7857056 0.008269448 0.078753199
165.6936316 2001.533054 200 -6.31056E-17 -6.3154E-16 X1,Y1

Li nea de l i qui do
 tn
36
138.3

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X1,Y1

Li nea de l i qui do Li nea de Va por

 Parameters for Antoine Eqn
Código Nombre Formula A B C ∆Hn
1 Acetone C3H6O 14.3145 2756.22 228.06 29.1
3 Acetonitrile* C2H3N 14.895 3413.1 250.523 30.19
30 Nitromethane* CH3NO2 14.7513 3331.7 227.6 33.99
35 Phenol C6H6O 14.4387 3507.8 175.4 46.18
Temperatura(oc) 200 F 100 V 71.88821656 L
Compuesto Zi Pisat Ki 1/(ki-1) Xi Yi
Acetone 0.4 2632.36060044 2.0253737718 0.975254124 0.230265801 0.466374314
Acetonitrile* 0.3 1508.90298881 1.1609703235 6.21232522 0.268884981 0.312167483
Nitromethane* 0.2 1053.28834923 0.8104142709 -5.27465862 0.23155915 0.18765884
Phenol 0.1 163.127773023 0.1255127101 -1.1435272 0.269290139 0.033799335
Presión de burbuja Presión de rocio Presión de Op.
1732.5855839656 866.7969468925 1299.69126543
KND -9.90685184E-08
 tn
56.2
81.6
101.2
181.8
28.11178344 V/F 0.718882166
 Parameters for Antoine Eqn
Código Nombre Formula A B C
11 Carbon tetrachloride CCl4 14.0572 2914.23 232.148
4 Benzene C6H6 13.7819 2726.81 217.572
39 Water H2O 16.3872 3885.7 230.17
Temperatura(oc) 40 F 100 V 14.75941805
Compuesto Zi Pisat Ki 1/(ki-1) Xi
Carbon tetrachloride 0.2 28.4726981303 1.78836929 1.268441087 0.17915388
Benzene 0.3 24.4176623383 1.533672618 1.873807962 0.27809528
Water 0.5 7.4244166801 0.466327382 -1.87380796 0.54275084
Presión de burbuja Presión de rocio Presión de Op.
16.7320466676 11.5399058895 15.9210395092
KND -7.37742006374E-09
14.13597628
 ∆Hn tn
29.82 76.6
30.72 80
40.66 100
L 85.24058195 V/F 0.147594181
Yi
0.320393304
0.426507111
0.253099579
 Datos de EVL para cloroformo(1)/1,4-dioxano(2) a 50oC
P/kPa x1 y1 ḟ1 ḟ2 ln y1 ln y2 GE/RT
15.79 0 0 0 15.79 0 0
17.51 0.0932 0.1794 3.141294 14.368706 -0.72166796 0.003509179 -0.06407733
18.15 0.1248 0.2383 4.325145 13.824855 -0.69382184 0.000394078 -0.08624407
19.3 0.1757 0.3302 6.37286 12.92714 -0.6482847 -0.00682711 -0.11953121
19.89 0.2 0.3691 7.341399 12.548601 -0.636343 -0.00662409 -0.13256787
21.37 0.2626 0.4628 9.890036 11.479964 -0.61065923 -0.01414878 -0.17079242
24.95 0.3615 0.6184 15.42908 9.52092 -0.48556305 -0.05725174 -0.21208628
29.82 0.475 0.7552 22.520064 7.299936 -0.38046321 -0.12715423 -0.247476
34.8 0.5555 0.8378 29.15544 5.64456 -0.27878215 -0.21787935 -0.25171086
42.1 0.6718 0.9137 38.46677 3.63323 -0.19172098 -0.35512267 -0.24534941
60.38 0.878 0.986 59.53468 0.84532 -0.02264265 -0.82368262 -0.12036952
65.39 0.9398 0.9945 65.030355 0.359645 -0.00236798 -0.97193175 -0.06073572
69.36 1 1 69.36 0 0 0
MODELO
Pendiente Intercepto
-0.42249234 -0.75660031
A12 A21
-0.75660031 -1.17909266

x1 GE/x1x2RT GE/RT ln y2 ln y1 ḟ1 ḟ2 y1
0 -0.75660031 0 0 -0.75660031 0 15.79 0
0.0932 -0.7959766 -0.06727098 -0.00358621 -0.68689918 3.252433846 14.26711534 0.185645978
0.1248 -0.80932736 -0.08839875 -0.0068462 -0.66031216 4.472534966 13.72512074 0.245775337
0.1757 -0.83083222 -0.12032902 -0.01489723 -0.61496436 6.588783185 12.82323633 0.339417709
0.2 -0.84109878 -0.13457581 -0.0201242 -0.59238224 7.671331354 12.38033195 0.382578305
0.2626 -0.8675468 -0.16799284 -0.03834114 -0.5320643 10.69870511 11.20556914 0.48843002
0.3615 -0.9093313 -0.2098898 -0.08358044 -0.43298394 16.26203347 9.273517772 0.636838943
0.745 -1.07135711 -0.20353107 -0.53483406 -0.09013206 47.21951286 2.358559467 0.952427366
0.5555 -0.99129481 -0.24477027 -0.24794329 -0.24223127 30.24081158 5.477387811 0.846649946
0.6718 -1.04043067 -0.22939911 -0.40698195 -0.14264309 40.40173123 3.449615511 0.921333875
0.878 -1.12754859 -0.12077849 -0.82947467 -0.02230363 59.55486686 0.840438014 0.986084382
0.9398 -1.15365862 -0.06526934 -0.99647507 -0.00561986 64.8192275 0.350925556 0.994615241
1 -1.17909266 0 -1.17909266 0 69.36 0 1
 GE/x1x2RT Propiedades de fase liquida de datos de EVL
0
-0.75818813 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

-0.78960037
-0.82532359
-0.8285492 -0.2

-0.88200439
-0.91884737
-0.99238495 -0.4
-1.01940349
-1.11277266
-1.12373057
-0.6
-1.07352519

-0.8

-1

P/kPa
15.79
17.51954918
X1
18.1976557
19.41201951
20.05166331
21.90427425
25.53555124
Diagrama EVL
49.57807232 Li qui do Idea l Li near (Li qui do Ideal ) Vapor
35.71819939 Pol ynomi a l (Va por) Li qui do Real Pol ynomia l (Li qui do Real )
43.85134675
65.00
60.39530487
65.17015305
69.36
55.00

45.00
Presion(kPa)

35.00

25.00

15.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
35.00

25.00

15.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X1
 70
EVL
0.8 0.9 1
60

50

40

30

20

10

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X1

qui do Real )

0.9 1
0.9 1
 Datos de EVL para cloroformo(1)/1,4-dioxano(2) a 50oC
P/kPa x1 y1 ḟ1 ḟ2 ln y1 ln y2 GE/RT
15.79 0 0 0 15.79 0 0
17.51 0.0932 0.1794 3.141294 14.368706 -0.72166796 0.003509179 -0.06407733
18.15 0.1248 0.2383 4.325145 13.824855 -0.69382184 0.000394078 -0.08624407
19.3 0.1757 0.3302 6.37286 12.92714 -0.6482847 -0.00682711 -0.11953121
19.89 0.2 0.3691 7.341399 12.548601 -0.636343 -0.00662409 -0.13256787
21.37 0.2626 0.4628 9.890036 11.479964 -0.61065923 -0.01414878 -0.17079242
24.95 0.3615 0.6184 15.42908 9.52092 -0.48556305 -0.05725174 -0.21208628
29.82 0.475 0.7552 22.520064 7.299936 -0.38046321 -0.12715423 -0.247476
34.8 0.5555 0.8378 29.15544 5.64456 -0.27878215 -0.21787935 -0.25171086
42.1 0.6718 0.9137 38.46677 3.63323 -0.19172098 -0.35512267 -0.24534941
60.38 0.878 0.986 59.53468 0.84532 -0.02264265 -0.82368262 -0.12036952
65.39 0.9398 0.9945 65.030355 0.359645 -0.00236798 -0.97193175 -0.06073572
69.36 1 1 69.36 0 0 0
MODELO
Pendiente Intercepto H1 H2 X P X
-0.42249234 -0.75660031 32.54780786 4.856335647 0 0 0
A12 A21 1 32.54780786 1
-0.75660031 -1.17909266

x1 GE/x1x2RT GE/RT ln y2 ln y1 ḟ1 ḟ2 y1
0 -0.75660031 0 0 -0.75660031 0 15.79 0
0.0932 -0.7959766 -0.06727098 -0.00358621 -0.68689918 3.252433846 14.26711534 0.185645978
0.1248 -0.80932736 -0.08839875 -0.0068462 -0.66031216 4.472534966 13.72512074 0.245775337
0.1757 -0.83083222 -0.12032902 -0.01489723 -0.61496436 6.588783185 12.82323633 0.339417709
0.2 -0.84109878 -0.13457581 -0.0201242 -0.59238224 7.671331354 12.38033195 0.382578305
0.2626 -0.8675468 -0.16799284 -0.03834114 -0.5320643 10.69870511 11.20556914 0.48843002
0.3615 -0.9093313 -0.2098898 -0.08358044 -0.43298394 16.26203347 9.273517772 0.636838943
0.475 -0.95728418 -0.23872274 -0.1659417 -0.31916494 23.94369223 7.022210876 0.773227642
0.5555 -0.99129481 -0.24477027 -0.24794329 -0.24223127 30.24081158 5.477387811 0.846649946
0.6718 -1.04043067 -0.22939911 -0.40698195 -0.14264309 40.40173123 3.449615511 0.921333875
0.878 -1.12754859 -0.12077849 -0.82947467 -0.02230363 59.55486686 0.840438014 0.986084382
0.9398 -1.15365862 -0.06526934 -0.99647507 -0.00561986 64.8192275 0.350925556 0.994615241
1 -1.17909266 0 -1.17909266 0 69.36 0 1

70

F1vs X
1
60 F2vs X
1
F1(m)
vs X1
F2(m)
70

F1vs X
1
60 F2vs X
1
F1(m)
vs X1
F2(m)
50 vs X1
L-R(1)
L-R(2)
LH(1)
LH(2)
40
f

30

20

10

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
 GE/x1x2RT fid1 fid2
80
0 15.79
-0.758188132 6.464352 14.318372
-0.7896003705 8.656128 13.819408
-0.8253235915 12.186552 13.015697
70
-0.8285492036 13.872 12.632
-0.882004392 18.213936 11.643546
-0.9188473654 25.07364 10.081915
-0.9923849507 32.946 8.28975
-1.0194034922 38.52948 7.018655 60
-1.1127726622 46.596048 5.182278
-1.1237305706 60.89808 1.92638
-1.0735251877 65.184528 0.950558
69.36 0 50

P
4.8563356468
0
P(Kpa)
40

P/kPa
15.79 30
17.519549181
18.1976557045
19.4120195137
20.051663309
20
21.9042742464
25.535551245
30.9659031026
35.7181993871
43.8513467458 10

60.3953048724
65.1701530547
69.36
0
0 0.1 0.2 0.3 0.4

0.0125
0 0.1 0.2 0.3 0.4 0.5 0.6

-0.1875
 0.0125
0 0.1 0.2 0.3 0.4 0.5 0.6

-0.1875

-0.3875

-0.5875

-0.7875

-0.9875

-1.1875
1

-1.3875

x1
 Pvs Xi
Pvs Yi
P(m)vs Xi
P(m)vs Xi

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X1,Y1

0.5 0.6 0.7 0.8 0.9 1

 0.5 0.6 0.7 0.8 0.9 1

Gevs X1 (EXP)
GeVs X1 (m)
GEvs X1 (EXP)
GEvs X1 (m)
l ny1Vs X1 (exp)
l ny1vs X1 (M)
l ny2vs X1 (EXP)
l ny2vs X1 (m)

x1
 Entalpías estándar y energías de Gibbs de formación a 298.15 K
Especie química Formula Estado ∆H⁰298 ∆G⁰298
Código
Parafinas
1 Metano CH4 (g) -74520 -50460
2 Etano C2H6 (g) -83820 -31855
3 Propano C3H8 (g) -104680 -24290
4 n-Butano C4H10 (g) -125790 -16570
5 n-Pentano CSH12 (g) -146760 -8650
6 n-Hexano C6H14 (g) -166920 150
7 n-Heptano C7H16 (g) -187780 8260
8 n-Octano C8H18 (g) -208750 16260
l-Alquenos
9 Etileno C2H4 (g) 52510 68460
10 Propileno C3H6 (g) 19710 62205
11 l-Buteno C4H8 (g) -540 70340
12 l-Penteno C5H10 (g) -21280 78410
13 l-Hexeno C6H12 (g) -41950 86830
14 l-Hepteno C7H14 (g) -62760
Orgánicos diversos
15 Acetaldehído C2H4O (g) -166190 -128860
16 Ácido Acético C2H4O2 (l) -484500 -389900
17 Acetileno C2H2 (g) 227480 209970
18 Benceno C6H6 (g) 82930 129665
19 Benceno C6H6 (l) 49080 124520
20 1,3-Butadieno C4H6 (g) 109240 149795
21 Ciclohexano C6H12 (g) -123140 31920
22 Ciclohexano C6H12 (l) -156230 26850
23 1,2-Etanodiol C2H602 (l) -454800 -323080
24 Etanol C2H6O (g) -235100 -168490
25 Etanol C2H6O (l) -277690 -174780
26 Etilbenceno C8H10 (g) 29920 130890
27 Óxido de etileno C2H40 (g) -52630 -13010
28 Formaldehído CH20 (g) -108570 -102530
29 Metanol CH40 (g) -200660 -161960
30 Metanol CH40 (l) -238660 -166270
31 MetilcicIohexano C7H14 (g) -154770 27480
32 MetilcicIohexano C7H14 (l) -190160 20560
33 Estireno C8H8 (g) 147360 213900
34 Tolueno C7H8 (g) 50170 122050
35 Tolueno C7H8 (l) 12180 113630
Inorgánicos diversos
36 Amoniaco NH3 (g) -46110 -16450
37 Amoniaco NH3 (aC) -26500
38 Carburo de calcio CaC2 (s) -59800 -64900
39 Carbonato de calcio CaC03 (s) -1206920 -1128790
40 Cloruro de calcio CaCl2 (s) -795800 -748100
41 Cloruro de calcio CaCl2 (aC) -8101900
42 Cloruro de calcio CaC12·6H20 (s) -2607900
43 Hidróxido de calcio Ca(OHh (s) -986090 -898490
44 Hidróxido de calcio Ca(OHh (aC) -868070
45 Óxido de calcio CaO (s) -635090 -604030
46 Dióxido de carbono CO2 (g) -393509 -394359
47 Monóxido de carbono CO (g) -110525 -137169
48 Ácido clorhídrico HCl (g) -92307 -95299
49 Cianuro de hidrógeno HCN (g) 135100 124700
50 Sulfuro de hidrógeno H2S (g) -20630 -33560
51 Oxido de hierro FeO (s) -272000
52 Oxido de hierro (h) Fe203 (s) -824200 -742200
53 Oxido de hierro (m) Fe304 (s) -1118400 -1015400
54 Sulfuro de hierro (p) FeS2 (s) -178200 -166900
55 Cloruro de litio LiCl (s) -408610
56 Cloruro de litio LiCl·H20 (s) -712580
57 Cloruro de litio LiCl·2H20 (s) -1012650
58 Cloruro de litio LiCl·3H20 (s) -1311 300
59 Acido nítrico HNO3 (l) -174100 -80710
60 Acido nítrico HNO3 (aC) -111250
61 Óxidos de nitrogeno NO (g) 90250 86550
62 NO2 (g) 33180 51310
63 N2O (g) 82050 104200
64 N204 (g) 9160 97540
65 Carbonato de sodio Na2C03 (s) -1130680 -1044440
66 Carbonato de sodio Na2C03·lOH20 (s) -4081320
67 Cloruro de sodio NaCl (s) -411153 -384138
68 Cloruro de sodio NaCl (aC) -393133
69 Hidróxido de sodio NaOH (s) -425609 -379494
70 Hidróxido de sodio NaOH (aC) -419150
71 Dioxido de azufre S02 (g) -296830 -300194
72 Trióxido de azufre S03 (g) -395720 -371060
73 Trióxido de azufre S03 (l) -441040
74 Acido sulfúrico H2S04 (l) -813989 -690003
75 Acido sulfúrico H2S04 (aC) -744530
76 Agua H20 (g) -241818 -228572
77 Agua H20 (l) -285830 -237129
 Datos de formación
Código Código Nombre Formula Estado ∆H⁰298
33 48 Cloruro de hiddrógeno HCl (g) -92307
38 - Oxígeno O2 (g) 0
41 76 Agua H2O (g) -241818
30 - Cloro CI2 (g) 0
To 298.15 T 773.15 P 200000
∆H⁰298 -114408 R(Pa.m3/mol.k) ∆A ∆B ∆C
∆G⁰298 -75707 8.314 -0.439 0.00008 0
∆G⁰773/RT -1.87413311
K 6.515168713 KND 6.514999746
s de formación (cpgi/R)=A+BT+CT2+DT-2
∆G⁰298 A B C D ʋi
-95299 3.156 0.000623 0 15100 -4
205 3.639 0.000506 0 -22700 -1
-228572 3.47 0.00145 0 12100 2
223 4.442 0.000089 0 -34400 2
e 0.837348632
∆D ʃ1 ʃ2 HCl O2 H2O CI2
-82300 -357.758203 -0.77438638 ʋi -4 -1 2 2
ni,o 5 1 0 0
ni 1.650605471 0.162651368 1.674697265 1.674697265
γi 0.319720499 0.031505394 0.324387053 0.324387053
 Código Código Nombre Formula
35 - Nitrógeno N2
15 17 Acetileno C2H2
34 49 Cianuro de hiddrógeno HCN

To 298.15 T 923.15
Σ ∆H⁰298 42720 R(Pa.m /mol.k)
3
∆A
-1 ∆G⁰298 39238.4 8.314 0.06
6 ∆G⁰773/RT 4.146985598
5.162651368 K 0.015812008 KND 0.015809342
 Datos de formación (cpgi/R)=A+BT+CT2+DT-2
Estado ∆H⁰298 ∆G⁰298 A B C D ʋi
(g) 0 191.6 3.28 0.000593 0 4000 -1
(g) 227480 209970 6.132 0.001952 0 -129900 -1
(g) 135100 124700 4.736 0.001359 0 -72500 2

P 101325 e 0.059149045
∆B ∆C ∆D ʃ1 ʃ2 N2 C2H2
0.000173 0 -19100 60.15484605 0.079710892 ʋi -1 -1
ni,o 1 1
ni 0.940850955 0.940850955
γi 0.470425477 0.470425477
 Código Código
14 15
31 -
19 24

To 298.15
HCN 0 Σ ∆H⁰298 -68910
2 0 0 ∆G⁰298 -39760.7
0 0 2 ∆G⁰773/RT -1.36278832
0.11829809 0 2 K 3.907072284
0.059149045 0
 Datos de formación (cpgi/R)=A+BT+CT2+D
Nombre Formula Estado ∆H⁰298 ∆G⁰298 A
Acetaldehído C2H40 (g) -166190 -128860 1.693
Hidrógeno H2 (g) 0 130.7 3.249
Etanol C2H60 (g) -235100 -168490 3.518

T 623.15 P 100000 e 0.746456417

R(Pa.m /mol.k)
3
∆A ∆B ∆C ∆D ʃ1
8.314 -1.424 0.001601 0.000000156 -8300 -226.426474

KND 3.907000421
 (cpgi/R)=A+BT+CT2+DT-2
B C D ʋi
0.017978 -0.000006158 0 -1
0.000422 0 8300 -1
0.020001 -0.000006002 0 1

ʃ2 C2H40 H2 C2H60 0 Σ
-0.54207733 ʋi -1 -1 1 0 -1
ni,o 1 1.5 0 0 2.5
ni 0.253543583 0.753543583 0.746456417 0 1.753543583
γi 0.144589268 0.429726178 0.425684554 0