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Phospholipids
A Simple Guide
to Use and Selection
ALC
About Lecithins
Lecithins are prepared by extracting and
purifying phospholipids from naturally
occurring products such as soybeans, eggs,
sunflower and canola seeds. Lecithins are
amphiphilic (they have different affinities
for oil and water), and their low production
costs make them invaluable in a broad
range of manufacturing processes.
Lecithins help make chocolate American Lecithin Company Natural and Organic Lecithin
smooth and powdered baby offers a wide range of Lecithin is the unique all-natural emulsifier.
formula dissolve easily in standard, refined and American Lecithin also offers organic lecithins
water. They help ink flow fractionated lecithins. under the Natural Organic Program (NOP).
from ball-point pens, spray Sold under the ALCOLEC ®
paints provide even coatings brand name, they are Chemical characteristics, product attributes,
and cooking sprays keep food available in liquid, granular classifications and labeling criteria in this
from sticking to hot surfaces. and powder form. brochure refer to American Lecithin soy-based
products. To learn about American Lecithin
products derived from other sources, contact us
at 203.262.7100.
2 3
How Lecithins Work
Lecithins are used mainly as emulsifiers. They are surface- in dip tanks and spray
active; simultaneous hydrophilic (water-loving) and applications. Water-filled dip
tanks usually contain up to
hydrophobic (water-repelling) properties enable lecithins to
10% de-oiled lecithin; pan
make stable blends of materials that otherwise do not mix or belt-release applications
easily and tend to separate. The amount of lecithin needed consist mainly of vegetable
to blend substances such as the soybean oil and water in oil with approximately 2%
lecithin.
margarine, or the pigment and latex in paint, depends on the
overall fat content in the end product. Separating Agents Shelf- Life Aids
When applied directly to
Incorporation of ALCOLEC
Lecithins also have characteristics that help: products such as processed
lecithin with the amylose
cheese slices, lecithins help
• Disperse and suspend powders into liquids portion of wheat flour slows
form a stable film barrier
• Control the viscosity of liquids and semi-liquids starch retrogradation.
that prevents them from
This process in effect extends
• Prevent foods from sticking to contact surfaces sticking together. When used
shelf life.
• Prevent adhesion of food products to one another directly in products such as
baked goods, they enhance
Nutritional Supplements
the ability to cut and shape
Lecithins have nutritional
products and reduce sticking
Lecithins can be: fat powders require lecithins value of their own. The
with lower HLB values (see to mixing vessels.
phospholipids they contain,
explanation on page 8) to such as phosphatidylcholine
Emulsifiers retard wetting rates; fatty Extrusion Aids (PC), phosphatidylserine
Emulsions are produced Extrusion technology uses
powders require higher HLB (PS) and derivatives such
by dispersing normally lecithin as a processing aid
values. as glycero- phosphocholine
unmixable material into to enhance extrusion rates
(alpha-GPC) have been
another by mixing, colloidal and throughput, resulting in
Viscosity Modifiers widely acknowledged
milling or homogenization. more economical production.
Lecithins greatly reduce by nutritionists, and
The surface-active qualities Examples of extruded
the surface tension of substantiated by numerous
of lecithins make them products include fat-free
fats, enabling particles of human clinical studies, as
effective emulsifying agents pretzels, reduced fat snacks
chocolate, sugar and milk beneficial to the function
that reduce mixing time and and pastas.
products, for example, of the liver, brain, heart,
maintain the stability of the
to be coated, improving flow and other organs. American
dispersion.
and mixability. Typical usage Anti-Dusting Agents Lecithin Company offers
levels are 0.2 – 0.6% of total Inclusion of ALCOLEC lecithins three products, ALCOLEC® PC,
Wetting and product weight. enhances wettability by ALCOLEC® PS and ALCOLEC®
Instantizing Agents reducing static interface. GPC, specifically for use in
Lecithins provide fast, Release Agents softgel, tablets, and hardcap
complete wetting of powders Lecithins promote separation nutritional supplements.
into aqueous systems. Low- of food from contact surfaces
4 5
Chemistry Soybean lecithins also contain
triglycerides, sterols, small
Oil-in-water emulsions typically
include lecithin at 5-10%, and
quantities of fatty acids and water-in-oil emulsions at 1-5%
carbohydrates. De-oiling of the oil’s weight.
Most of the performance benefits of soybean-based lecithins lecithin enhances the typical
come from the unique hydrophilic and hydrophobic surface- phospholipid composition as Most food products contain 1-2%
active properties of phospholipids, their primary component. shown in the accompanying salt; higher levels may affect
charts. Fractionating lecithin functionality.
(breaking up) these complex
These phospholipids are present in liquid lecithin: mixtures, or adding elements Particle size affects lecithin
such as refined oils or requirements in wetting and
Phosphatidylcholine (PC, 14–16%)
surfactants, can create new instantizing applications.
Phosphatidylethanolamine (PE,10–15%) products tailored for specific Larger particles have less surface
applications. Fractionated area and usually require up to
Phosphatidylinositol (PI, 10–15%)
phospholipid products are 0.25% lecithination; smaller
Phosphatidic acid (PA, 5–12%) enriched in phospholipid content. particles typically require
Very delicate applications require up to 2%.
the purest lecithin emulsifier
that contains more than 80% Lecithin can be derived from
phosphatidylcholine. various sources. Soybean-derived
Standard Liquid Lecithin De-Oiled Lecithin* lecithins have become the
(1%) H2O (1%) As emulsifiers, lecithins can be industry standard. For nutritional,
(3%) triglycerides
added to the oil phase or the water functional or labeling purposes,
phase during processing. Fluid leci- American Lecithin has developed
thins tend to disperse more easily products from alternate sources
(15%) glycolipids
in oil; de-oiled (powdered) leci- such as egg yolk, canola, and
thins more easily in water. Heating sunflower. Such lecithins have
triglycerides (37%) to 120oF helps the dispersion and distinct phospholipids and fatty
(8%) complexed sugars can improve handling and mixing acid composition that allow for
characteristics. an array of new applications.
(11%)
(7%) PA
Classification
glycolipids
Lecithin products are classified using attributes such as color,
(14%) PI viscosity, and the percentages of certain components. The terms
complexed sugars (5%)
used when specifying lecithins are:
minor phospholipids (2%)
PA (5%) Phosphatidylcholine (PC) afforded by ionizable groups of
Amphiphilic molecule and main phospholipids and free fatty acids
(10%) emulsifier in lecithin. PC is the major added to some liquid lecithins to
PI (20%) PE
component of biological membranes stabilize viscosity.
and supplements the diet with
natural choline. Color
PE (13%) Measured against the Gardner scale.
Acetone Insolubles (AI) Most lecithin products range from
Expressed as a percentage. This is a having a light honey (11 on the scale)
measure of the surface-active portion to dark amber (17 on the scale) color.
(24%) PC of a lecithin, comprised mainly of
(16%) phospholipids and glycolipids. Hexane Insolubles (HI)
PC
Expressed as a percentage (usually
Acid Value (AV) under 0.1%). Measures residual
Expressed as meq KOH/kg.
* Granular or powdered form; most This is a measure of total acidity continued
triglycerides and free fatty acids are
6 removed. 7
Classification continued
8 9
Labeling
ALCOLEC® soy lecithins are all-natural and certified as generally safe Labeling Lecithins
for use in food under various compliance standards worldwide. This chart shows typical nutritional information associated with various
The inherent nutritional value in soy and its association with good sources of lecithin.
health add value when source-labeling products.
residual GM DNA.
10 11
Selection
The chart on these pages and pages 14-15 can help you determine
which ALCOLEC® products are best suited for your applications.
More information follows in the Solvent Solubility Index on page 18.
Mixing/
Product Adds Crumb Dough Blending Surface O/W W/O Release Viscosity Wetting Anti- Softgels 2 piece Tablets
Lubricity Softener Conditioner Aid Coating Emulsifier Emulsifier Agent Modifier Agent Staling hard caps
ALCOLEC® Standard Fluid Grade
Stable, unrefined fluid S • • • •
blends of soybean oil BS • • • •
and phospholipids.
XTRA-A • • •
ALCOLEC® PC Enriched
Modified to provide higher 40-P • • •
levels of choline, widely PC35 •
recognized as a contributor
to good health.
ALCOLEC® Enzyme-Modified
EM • • •
Especially useful in food as
an instantizer and to help LPC 20 • • •
maintain freshness. LPC 20H • • •
ALCOLEC® — Gums
Lexin K • • •
ALCOLEC® — GPC GPC Compound • •
GPC 85F • •
GPC X • •
ALCOLEC® — PS PS 20 • •
PS 50 • •
PS 75 • •
Use levels are usually 0.2% based on finished product weight. If no specific information is available,
we recommend starting with 0.5% of finished product and adjust as necessary.
12 13
Use levels are usually 0.2% based on finished product weight.
A Guide to Applications If no specific information is available, start with 0.5% of finished
product and adjust as necessary.
Baked Goods
Bread and other yeast-raised products ALCOLEC® EM 0.5-1% based on flour in breads. Shelf life, dough conditioning.
Cookies ALCOLEC® F100 1-3% based on flour. Improves creaming. Also release benefits in high
Low fat cookies, crackers, pretzels ALCOLEC® F100 1% based on flour. For machinability. Improves sheeting, dough
Pizza crust ALCOLEC® F100 0.5-1% based on flour. Controls shrinkage, improves dough handling release.
Waffles, pancakes ALCOLEC® F100 Improves tenderness in no/low fat products. Reduces batter viscosity.
Caramel Corn ALCOLEC® LV-30, ALCOLEC® F100 ALCOLEC F100 at 0.5-1.0% can be added to the sugar syrup and 5-15% of
Cheese Release ALCOLEC® LV-30 Spray on surface to promote easy slice separation in low- and high-
Cheese Sauces ALCOLEC® F100 Add into oil at 3-5% based on total fat for smoothness and consistency.
Chewing Gum Lexin K, ALCOLEC® F100 0.7-3% in the gum base. Enhances product softness and smoothness;
Chocolate ALCOLEC® F100 Use at 0.2-5% level. Reduces viscosity; reduces fat requirement.
Cottage Cheese ALCOLEC® F100 Enhances curd formation to improve production yields.
Frostings ALCOLEC® F100 Acts in combination with polysorbate to provide excellent emulsification
Granola Bars ALCOLEC® F100 Blendable powder; low flavor binding material; high quality dietary fat source.
14 15
A Guide to Applications continued
Application Suggested Products Usage instructions & effect
Ice Cream Cones ALCOLEC® F100 0.5-1% based on flour. Mold release, viscosity control, emulsification.
Infant Formula ALCOLEC® EM, LPC 20, E 25 Effective oil-in-water emulsifier for a wide variety of oils. Use at 3-5% of
fat level.
Instantizing ALCOLEC® F100 Control hydration rate of hydrophilic powders. Use at 0.5-1.0%.
Margarine ALCOLEC® Xtra A Enhanced water-in-oil emulsifier. Use at 0.2-0.5% to prevent spattering.
Products like Chili ALCOLEC® F100 Dry, easy to use powder; blends in quickly at 0.25-0.5%; helps control
Milk Powders ALCOLEC® F100 Excellent wetting of whole milk powders. Use at 0.5-1.0%.
Non-Dairy Creamers ALCOLEC® F100 Acts as an emulsifier to replace mono and diglycerides.
Release
Oil based ALCOLEC® LV-30 Use at 5-15% level. Good solubility in pump and aerosol-type formulations.
Water based ALCOLEC® F100 Effective oil-in-water emulsifier for a wide variety of oils. Use at 25-30% of
oil/fat level.
Belt release ALCOLEC® Aquasperse A Water dispersible for use as a belt release in continuous cooking
Heat resistant Phospholipon® 80H For use at high temperature applications at 1% of finished product.
16 17
Selection continued
Oil-Free Fluid
ALC
cosmetic industries.
Hexane S S
lsooctane S S
American Lecithin’s ALCOLEC®
Isopropyl Ether S S
products are used in food
Kerosene S S
processing and a wide range
Methanol I I
of industrial applications. For
Methylene Chloride S S
more than 80 years, American 115 Hurley Road, Unit 2B
Methyl Ethyl Ketone I I Lecithin has continually Oxford, CT 06478
Methyl Isobutyl Ketone S S improved the basic properties Phone: 203.262.7100
Mineral Spirits S S of its lecithins, creating Fax: 203.262.7101
Petroleum Ether S S new products with better Toll-Free: 1.800.364.4416
Propylene Glycol I I performance in a broad range www.americanlecithin.com
Toluene S S of uses. We remain committed e-mail: customerservice@
to providing the very best americanlecithin.com
in quality, consistency and
D — Dispersible by use of hot water, slightly alkalized
technical support for our For information about lecithins
I — Insoluble
full range of products, from used in pharmaceuticals and
S — Soluble at 10% (w/w) at 25°C
standard grade lecithins to personal care products, visit
high-tech fractionations. www.lipoid.com.
18 19
ALC
115 Hurley Road, Unit 2B
Oxford, CT 06478
Phone: 203.262.7100
Fax: 203.262.7101
Toll-Free: 1.800.364.4416
www.americanlecithin.com
e-mail: customerservice@
americanlecithin.com