∆H of formation ∆H of solution n1 n2 x1 x2

CaCl2 -795.8 0 1 0 1 0
CaCl2 in 10 mol H2O -862.74 -66.94 1 10 0.090909 0.909091
CaCl2 in 15 mol H2O -867.85 -72.05 1 15 0.0625 0.9375
CaCl2 in 20 mol H2O -870.06 -74.26 1 20 0.047619 0.952381
CaCl2 in 25 mol H2O -871.07 -75.27 1 25 0.038462 0.961538
CaCl2 in 50 mol H2O -872.91 -77.11 1 50 0.019608 0.980392
CaCl2 in 100 mol H2O -873.82 -78.02 1 100 0.009901 0.990099
CaCl2 in 300 mol H2O -874.79 -78.99 1 300 0.003322 0.996678
CaCl2 in 500 mol H2O -875.13 -79.33 1 500 0.001996 0.998004
CaCl2 in 1000 mol H2O -875.54 -79.74 1 1000 0.000999 0.999001

-60
0 100 200 300 400 500 600 700 800 900 1000
∆H of solution (kJ/mol of solution)

-65

-70

-75

-80

-85

n ratio of water to CaCl2

n ratio of water to CaCl2 ∆H of mixing
0 0
10 -6.085454545
15 -4.503125
20 -3.536190476
25 -2.895
50 -1.511960784
100 -0.772475248
300 -0.262425249
500 -0.158343313
1000 -0.07966034
 EVAPORATO
Feed <F>
80°F
20% H2SO4
80% H2O
25 lbm/s

mass balance
Basis 25 lbm/s in feed
<F> <S> <P>
component
frac mass (lbm) frac mass (lbm) frac mass (lbm)
H2SO4 0.2 5 0 0 0.7 5
H2O 0.8 20 1 17.85714286 0.3 2.142857143
Total 1 25 1 17.85714286 1 7.142857143

energy balance
Q+∆H(feed)=∆H(steam)+∆H(product)
Q= rate ∆H
Q=∆H(steam)+∆H(product)-∆H(feed)

<F> <S> <P>

component
mass (lbm) Q mass (lbm) Q mass (lbm) Q
H2SO4 5 0 5
H2O 20 17.85714286 2.142857143
Total 25 -500 17.85714286 20648.05804 7.142857143 -312.3214286
 Steam <S>
217°F
1.5 psia
EVAPORATOR 100% H2O
superheated steam

Product <P>
217°F
70% H2SO4
Q 30% H2O

acc

0
0
0

interpolation for ∆H product

Q =rate ∆H (Btu/s)
T (°F) ∆H (Btu/lbm)
200 -46.7
217 -43.725
20835.7366071429 220 -43.2
interpolation for ∆H steam
the condition is superheated steam
P (btu/lbm) ∆H (Btu/lbm)
200°F 250°F
1 1150.2 1172.9
1.5 1147.813 1172.75
5 1131.1 1171.7

T (°F) ∆H (Btu/lbm)
200 1147.813
217 1156.291
250 1172.75