Chemistry form 5

Section A
Bahagian A
[60 marks]
[60 markah]
Answer all questions
Jawab semua soalan

1. Diagram 1 shows the production of compound M.

Rajah 1 menunjukkan penghasilan bahan M.

Process X Sulphuric acid

Proses X Asid sulfurik

Compound M
Bahan M
Haber Process Compound L
Proses Haber Bahan L

Diagram 1/Rajah 1

a (i) Name process X.

Namakan proses X.

…………………………………………………………………………………………
[1 mark]

(ii) In process X, the catalyst and high temperature is used to increase the rate of reaction.
State the catalyst and the temperature used.
Dalam proses X, mangkin dan suhu yang tinggi digunakan untuk meningkatkan kadar
tindak balas. Nyatakan mangkin dan suhu yang digunakan.

Catalyst / Mangkin : ..........................................

Temperature / Suhu : ........................................

[2 marks]

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 Chemistry form 5

(iii) In process X, sulphur trioxide gas is not directly dissolved into water to form liquid
sulphuric acid. Explain why.
Dalam Proses X, gas sulfur trioksida tidak terus dilarutkan ke dalam air untuk
menghasilkan cecair asid sulfurik. Terangkan mengapa.

………………………………………………………………………………………

…………………………………………………………………………………………
[2 marks]

b (i) What is the name of compound L that is produced through Haber process?
Apakah nama bahan L yang terhasil melalui proses Haber?

…………………………………………………………………………………………
[1 mark]

(ii) Compound L is produced when nitrogen gas reacts with hydrogen gas.
What is the ratio of nitrogen gas and hydrogen gas reacted?
Bahan L terhasil apabila gas nitrogen bertindak balas dengan gas hidrogen.
Apakah nisbah gas nitrogen dan gas hidrogen yang bertindak balas?

…………………………………………………………………………………………
[1 mark]

c (i) Sulphuric acid reacts with compound L to produce compound M. Name compound M.

Asid sulfurik bertindak balas dengan bahan L untuk menghasilkan bahan M.

Namakan bahan M.

…………………………………………………………………………………………
[1 mark]

(ii) State one of the use of compound M.

Nyatakan satu kegunaan bahan M.

…………………………………………………………………………………………
[1 mark]
\

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 Chemistry form 5

2 Table 2 shows the number of proton and the number of neutron in atom R, S and T.
Jadual 2 menunjukkan bilangan proton dan bilangan neutron dalam atom R, S dan T.

Atom Number of proton Number of neutron

Atom Bilangan proton Bilangan neutron
R 11 12
S 11 13
T 12 12
Table 2
Jadual 2

(a) State three subatomic particles of an atom.

Nyatakan tiga zarah sub atom.

..............................................................................................................................
[1 mark]
]

(b) (i) What is meant by isotope?

Apakah yang dimaksudkan dengan isotop?

.....................................................................................................................

.....................................................................................................................
[1 mark]

(ii) Which atoms are isotopes?

Atom-atom yang manakah merupakan isotop?

.....................................................................................................................
[1 mark]

(iii) State the radioisotope that is used to treat cancer diseases.

Nyatakan radioisotop yang digunakan untuk merawat penyakit kanser.

.....................................................................................................................
[1 mark]

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 Chemistry form 5

(c) (i) Write the electron arrangement of atom R.

Tuliskan susunan elektron bagi atom R.

..............................................................................................................................
[1 mark]

(ii) What is valence electron of atom R?

Apakah elektron valens bagi atom R?

..............................................................................................................................
[1 mark]

A
(d) Write the symbol for atom S in the form of Z
S .

A
Tuliskan simbol bagi atom S dalam bentuk Z
S .

...........................................................................................................................................
[1 mark]

(e) (i) Draw the electron arrangement of atom T.

Lukiskan susunan elektron bagi atom T.

[1 mark]

(ii) State the position of element of atom T in the Periodic Table of Element.
Nyatakan kedudukan unsur bagi atom T dalam Jadual Berkala Unsur.

..............................................................................................................................

[1 mark]

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 Chemistry form 5

3 A student wanted to find out the concentration of methanoic acid (HCOOH) used in
coagulation of latex.The student did a titration to determine the concentration of methanoic
acid. Diagram 3 shows an apparatus set-up of titration of sodium hydroxide solution with
methanoic acid.
Seorang pelajar ingin mengetahui kepekatan asid metanoik (HCOOH) yang digunakan
dalam penggumpalan getah. Pelajar itu menjalankan penitratan bagi menentukan
kepekatan asid metanoik itu.
Rajah 3 menunjukkan susunan radas bagi pentitratan larutan natrium hidroksida dengan
asid metanoik.

Methanoic acid
Asid metanoik

40.55 cm3 of 0.493 mol dm-3

sodium hydroxide solution +
indicator
40.55 cm3 larutan natrium
hidroksida 0.493 mol dm-3 +
penunjuk

Diagram 3
Rajah 3

Table below shows the results of titration.

Jadual di bawah menunjukkan keputusan pentitratan

Initial burette reading / cm3 0.75

Bacaan awal buret
Final burette reading/ cm3 49.35
Bacaan akhir buret
(a) What is the meaning of end point?
Apakah maksud takat akhir ?

……………………………………………………………………………………….

……………………………………………………………………………………….
[1 mark]

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 Chemistry form 5

(b) State the name of a suitable indicator for this experiment.

Nyatakan nama satu penunjuk yang sesuai untuk eksperimen ini.

……………………………………………………………………………………….
[1mark]
(c) State the colour change of indicator at the end point of the reaction.
Nyatakan perubahan warna penunjuk pada takat akhir tindakbalas.

……………………………………………………………………………………….
[1mark]

(d) State the name of the reaction between sodium hydroxide solution and methanoic
acid.
Nyatakan nama tindakbalas antara larutan natrium hidroksida dengan asid
metanoik.

……………………………………………………………………………………….
[1 mark]

(e) Write a balanced chemical equation for reaction between sodium hydroxide and
methanoic acid.
Tulis satu persamaan seimbang bagi tindakbalas antara natrium hidroksida dan
asid metanoik.

……………………………………………………………………………………….
[2 marks]

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 Chemistry form 5

(f) State the volume of methanoic acid used in this experiment.

Nyatakan isipadu asid metanoik yang digunakan dalam eksperimen ini.

……………………………………………………………………………………….
[1 mark]
(g) Calculate the concentration of methanoic acid used in this experiment.
Hitungkan kepekatan asid metanoik yang digunakan dalam eksperimen ini.

[2 marks]
(h) Diagram 3 shows the latex added with ammonia gas was sent to factory.
Rajah 3 menunjukkan susu getah yang ditambah dengan gas ammonia dihantar
ke kilang.

3 hours journey to factory

Perjalanan 3 jam ke kilang

Diagram 3
Rajah 3
Give one reasons why ammonia gas is used to prevent coagulation of latex instead of
ammonia solution.
Berikan satu sebab mengapa gas ammonia dan bukannya larutan ammonia digunakan
untuk mencegah pembekuan susu getah.

……………………………………………………………………………………………….

……………………………………………………………………………………………….
[1 mark]

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 Chemistry form 5

4 Diagram 4 shows a flow chart of conversion of compound P to compound Q and R.

Compound P contain 3 carbon atom.
Rajah 4 menunjukkan carta alir bagi penukaran sebatian P kepada sebatian Q dan R.
Sebatian P mengandungi 3 atom karbon.

Hot Porcelain
Compound R chips Compound P Reagent X Compound Q

Sebatian R Serpihan porselin

Sebatian P Reagen X Sebatian Q
panas
C4H9OH
Diagram 4
Rajah 4

Based on Diagram 4, answer the following questions:

Berdasarkan Rajah 4, jawab soalan-soalan berikut:

(a) (i) Write the general formula of the homologous series of compound P.
Tuliskan formula umum bagi siri homolog sebatian P.

........................................................................................................................
[1 mark]
(ii) State the functional group for compound P.
Nyatakan kumpulan berfungsi bagi sebatian P.

........................................................................................................................
[1 mark]
(b) When bromine water is added to compound R, the brown bromine water is decolourised.
Apabila air bromin ditambah kepada sebatian R, warna perang air bromin
dinyahwarnakan.

(i) Name a compound R.

Namakan sebatian R.

..........................................................................................................................
[1 mark]

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 Chemistry form 5

(ii) Draw a structural formula for compound R

Lukiskan formula struktur bagi sebatian R

[1 mark]
(c) (i) When the mixture of compound P, reagent X and concentrated sulfuric acid is
gently heated it will produced compound Q. Compound Q also turns the colour of
blue litmus paper to red.
Apabila campuran sebatian P, reagen X dan asid sulfurik dipanaskan secara
perlahan-lahan ia akan menghasilkan sebatian Q. Sebatian Q juga dapat
menukarkan warna kertas litmus biru kepada merah.

Name the Reagent X

Namakan Reagent X

..........................................................................................................................
[1 mark]

(ii) State the colour change of the reagent at 4(c)(i) during the reaction.
Nyatakan perubahan warna bagi reagen di 4(c)(i) semasa tindakbalas berlaku.

..........................................................................................................................
[1 mark]

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 Chemistry form 5

(d) Compound R burns in excess oxygen to produce carbon dioxide and water.
Sebatian R terbakar dalam oksigen berlebihan menghasilkan carbon dioksida dan air.

(i) Write a balanced chemical reaction for the reaction.

Tuliskan persamaan kimia yang seimbang bagi tindakbalas tersebut.

…………….………………………………….………………………….........…
[2 marks]

(ii) Calculate the numbers of carbon dioxide molecules are formed when 11.2 g of
compound R burned in excess oxygen.
Hitungkan bilangan molekul carbon dioksida yang terbentuk apabila 11.2 g sebatian R
terbakar dalam oksigen berlebihan,

[Relative atomic mass C = 12, O = 16 ; Avogadro number = 6.03 x 1023]

[Jisim atom relatif C = 12, O = 16; Nombor Avogadro = 6.03 x 1023]

[2 marks]

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 Chemistry form 5

5 Diagram 5 shows the set up of the apparatus of an experiment to investigate the transfer of
electrons at a distance. Solution X is an oxidising agent and turns colour from purple to
colourless after a few minutes reacted.
Rajah 5 menunjukkan susunan radas eksperimen bagi mengkaji pemindahan elektron pada
satu jarak. Larutan X ialah agen pengoksidaan dan bertukar warna dari ungu kepada tidak
berwarna selepas beberapa minit bertindak balas.

Carbon Carbon
Karbon Karbon

Potassium iodide solution

X
Larutan kalium iodida

Dilute sulphuric acid

Asid sulfurik cair

Diagram 5
Rajah 5

The overall ionic equation that occurs at electrodes A and B is,

Persamaan ion keseluruhan bagi tindak balas yang berlaku pada elektod A dan B adalah,

2MnO4- + 16H+ + 10I- → 2Mn2+ + 8H2O + 5I2

(a) Name the solution X.

Namakan larutan X.

……………………………………………………………………………………..
[1 mark]
-
(b) Calculate the oxidation number of manganese in MnO4 ion.
Hitungkan nombor pengoksidaan bagi mangan dalam ion MnO4-.

[1 mark]

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 Chemistry form 5

(c) State the type of reaction that occurs at electrode A.

Nyatakan jenis tindakbalas yang berlaku pada elektod A.

...................................................................................................................................
[1 mark]
(d) Referring to the reaction that takes place at electrode B.
Merujuk kepada tindak balas yang berlaku pada elektrod B.
(i) State the observation?
Nyatakan pemerhatian?

……………………………………………………………………………...
[1 mark]
(ii) Write the half equation for the reaction.
Tulis persamaan setengah bagi tindakbalas.

.......................................................................................................................
[2 marks]
(iii) Explain the reaction that occurs in term of transfer of electron.
Terangkan tindak balas yang berlaku dari segi pemindahan elektron.

.......................................................................................................................
[1 mark]
(e) State the function of the dilute sulphuric acid in this experiment.
Nyatakan fungsi bagi asid sulfurik cair dalam eksperimen ini.

...................................................................................................................................
[1 mark]
(f) In other experiment you are given zinc strip, copper strip, copper (II) sulphate solution
and all apparatus required.
Draw a labelled diagram to show another set up of apparatus to investigate the transfer
of electron at a distance. In your diagram show the direction of electron flow.

Di dalam eksperimen lain anda dibekalkan dengan kepingan zink, kepingan kuprum,
larutan kuprum(II) sulfat dan semua radas yang diperlukan.
Lukiskan satu gambarajah berlabel untuk menunjukkan susunan radas bagi menyiasat
pemindahan elektron pada satu jarak. Tunjukkan arah pergerakan elektron pada rajah
anda.

[3 marks]

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 Chemistry form 5

6 An experiment is carried out to determine the rate of reaction between calcium carbonate
powder and dilute hydrochloric acid. The volume of carbon dioxide gas produced fixed
intervals are recorded. Table 5 shows the results of the experiment.

Satu eksperimen telah dijalankan untuk mengukur kadar tindak balas antara serbuk
kalsium karbonat dengan asid hidroklorik cair. Isipadu gas karbon dioksida yang
terhasil dalam tindak balas tersebut ditentukan pada satu sela masa tertentu.
Jadual 5 menunjukkan keputusan eksperimen tersebut.

Time / s 0 30 60 90 120 150 180 210 240 270

Masa / s
Volume of carbon dioxide
gas /cm3 0 16.0 25.0 30.0 34.0 36.0 38.0 39.0 39.0 39.0
Isipadu gas karbon dioksida
/ cm3

Table 5 / Jadual 5

Write a balanced chemical equation for the above reaction.

(a) Tuliskan persamaan kimia seimbang bagi tindak balas yang berlaku.

…………………………………………………………………………...............................
[2 marks]

(b) (i) Based on the results in Table 5, draw a graph of volume of gas against time on
the graph paper provided.
Berdasarkan keputusan dalam Jadual 5, lukiskan graf isipadu gas melawan
masa bagi eksperimen tersebut pada kertas graf yang disediakan.

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Chemistry form 5

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 Chemistry form 5

(ii) By referring to the graph in (b)(i) calculate the rate of reaction for experiment at
120 s.
Berdasarkan graf dalam (b)(i) hitungkan kadar tindak balas pada saat ke 120.

[2 marks]

(c) (i) On the graph in b(i), sketch the curve that would be obtained if the experiment is
repeated by replacing powder calcium carbonate with granulated calcium carbonate
(Other conditions of the experiment remains the same ).
Pada graf di b(i), lakarkan lengkung yang akan diperolehi jika eksperimen ini
diulangi dengan menggantikan serbuk kalsium karbonat dengan ketulan kalsium
karbonat.
( Keadaan lain dalam eksperimen adalah sama ).
[1 mark]

(ii) Based on the graph in (b) (i) and the curve in (c) (i) , explain why there is a
difference in the rate of reaction by using collision theory.
Berdasarkan graf dalam (b) (i) dan lengkung dalam (c) (i), terangkan mengapa
terdapat perbezaan dalam kadar tindak balas dengan menggunakan teori
perlanggaran

………………………………………………………………………………………

……………………………………………………………………………………….

………………………………………………………………………………………..
[3 marks]

15
 Chemistry form 5

Section B / Bahagian B
[20marks] / [20markah]

Answer any one question from this section

Jawab mana-mana satu soalan daripada bahagian ini

7 (a) Diagram 7.1 shows a series of reactions involving copper(II)nitrate salt.

Rajah 7.1 menunjukkan satu siri tindak balas melibatkan garam kuprum(II)nitrat.
Copper(II)nitrate

Kuprum(II)nitrat Heat up
Add sodium
hydroxide solution Panaskan
Add excess
Tambah larutan
ammonia
natrium hidroksida
solution
Solid J , colourless
Observation X Tambah larutan Gas K and Gas L
ammonia
Pemerhatian X Pepejal J , Gas K
berlebihan
tidak berwarna dan
Observation Y Gas L

Pemerhatian Y
Diagram 7.1
Rajah 7.1
i Explain observation X.
Write an ionic equation to support your explanation.
Terangkan pemerhatian X
Tulis persamaan ionik untuk menyokong penerangan anda
[3 marks]
ii State observation of Y and explain your answer.
Nyatakan pemerhatian Y dan terangkan jawapan anda
[2 marks]
iii Name the solid J, gas K and gas L
Namakan pepejal J, gas K dan gas L
[3 marks]
iv Write the chemical equation of heating copper(II)nitrate salt
Tulis persamaan kimia pemanasan garam kuprum(II)nitrat
[2 marks]

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 Chemistry form 5

(b) Table 7.2 shows the observation from some test carried out on salt Q
Jadual 7.2 menunjukkan pemerhatian ujian yang dijalankan ke atas Garam Q

Test / Ujian Observation / Pemerhatian

I. Heating of salt Q solid A metal oxide formed and a brown

Pemanasan pepejal garam Q gas is produced
Suatu oksida logam terbentuk dan
gas perang dibebaskan

II. Salt Q solution is mixed with A white precipitate which is

excess aqueous ammonia
Larutan garam Q dicampur
dengan ammonia akues berlebihan
insoluble in aqueous ammonia is
formed
Mendakan putih yang tidak larut
dalam ammonia akues berlebihan
terbentuk

Table 7.2 / Jadual 7.2

Based on information in Table 7.2;

Berdasarkan maklumat dalam Jadual 7.2;
(i) Identify an anion that is present in Test I and describe a chemical test to
verify the anion.
Kenal pasti satu anion yang hadir dalam Ujian I dan huraikan satu ujian
kimia untuk menentusahkan anion itu.
[4 marks]
(ii) Identify two cations that are present in Test II and describe a chemical test
to verify the cation.
Kenal pasti dua kation yang hadir dalam Ujian II dan huraikan satu ujian
kimia untuk menentusahkan kation itu.

[6 marks]

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 Chemistry form 5

8 Diagram 8 shows parts of the Periodic Table of elements.

Rajah 8 menunjukkan sebahagian unsur dalam Jadual Berkala

1 2 13 14 15 16 17 18

C O
Mg Al Cl
Diagram 8 / Rajah 8

a Write the electron arrangements for aluminium ion and oxide ion.
Tuliskan susunan elektron bagi ion aluminium dan ion oksida

[2 marks]
b Describe the formation of the following chemical bonds and draw the electron
arrangement of compounds formed.
Huraikan pembentukan bagi ikatan kimia berikut dan lukis susunan elektron bagi
sebatian yang terbentuk.

i Ionic bond between magnesium and chlorine .

Ikatan ionik di antara magnesium dengan klorin
[5 marks]
ii Covalent bond between carbon and chlorine .
Ikatan kovalen di antara karbon dengan klorin
[5 marks]
c Explain each of the following statements.
Terangkan setiap pernyataan berikut
i Compound formed in (b)(i) can conduct electricity in the molten state
while compound formed in (b)(ii) cannot conduct electricity in any state.
Sebatian yang terbentuk dalam (b)(i) boleh mengkonduksikan elektrik
dalam keadaan leburan manakala sebatian yang terbentuk dalam (b)(ii)
tidak dapat mengkonduksikan elektrik dalam semua keadaan
[4 marks]
ii The melting and boiling points for compound in (b)(i) is higher than
compound in (b)(ii).
Takat lebur dan takat didih bagi sebatian dalam (b)(i) lebih tinggi
daripada sebatian dalam (b)(ii).
[4 marks]

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 Chemistry form 5

Section C / Bahagian C
[20marks] / [20 markah]

Answer any one question from this section

Jawab mana-mana satu soalan daripada bahagian ini

9. (a) A group of students carried out experiments to investigate the factor

affecting the rate of reaction between metal P and an acid Q.
Sekumpulan pelajar telah menjalankan eksperimen untuk mengkaji
kesan fkctor yang mempengaruhi kadar tindak balas antara logam
P dan asid Q.
Table 9 shows the information about the reactants and the time
taken to collect 30cm3 of hydrogen gas.
Jadual 9 menunjukkan maklumat tentang bahan tindak balas dan
masa diambil untuk mengumpul 30 cm3 gas hidrogen.

Experimen Reactants Time taken to collect

t Bahan tindak balas 30cm3 of hydrogen
Eksperime gas/s
n Masa yang diambil
untuk mengumpul
30cm3 gas hydrogen/s
Powdered metal P and
50cm3 of 1.0 mol dm-3
acid Q
I 10
Serbuk logam P dan 50
cm3 asid Q 1.0 mol dm-3

Powdered metal P and

100cm3 of 0.5 mol dm-3
II acid Q 20
Serbuk logam P dan 100
cm3 asid Q 0.5 mol dm-3

Table/ Jadual 9
(i) Suggest the name of metal P and acid Q.
By using the named metal P and acid Q, write the chemical
equation.
Cadangkan nama logam P dan asid Q.
Menggunakan logam P dan asid Q yang dinamakan, tulis
persamaan kimia.
[4 marks]

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 Chemistry form 5

(ii) Calculate the average rate of reaction for Experiment I and

Experiment II.
Hitung kadar tindak balas purata bagi Eksperimen I dan
Eksperimen II.
[2 marks]

(iii) Explain the difference in the rate of reaction between Experiment I

and Experiment II based on the collision theory.
Terangkan perbezaan kadar tindak balas antara Eksperimen I dan
Eksperimen II berdasarkan teori perlanggaran.
[4 marks]

(b) Describe an experiment to show how temperature affect the rate of

reaction.
Huraikan satu eksperimen untukmenunjukkan bagaimana suhu
mempengaruhi kadar tindak balas.
[10 marks]

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 Chemistry form 5

10 (a) Table 10 shows the observation at the anode and cathode when the dilute
hydrochloric acid is electrolysed using carbon electrodes.
Jadual 10 menunjukkan pemerhatian pada anod dan katod apabila asid
hidroklorik cair dielektrolisiskan menggunakan karbon.

Electrode Observation
Elektrod Pemerhatian
Anode A colourless gas is released and relights a glowing splinter
Anod Gas tidak berwarna dibebaskan dan menyalakan kayu uji berbara

Cathode A colourless gas is released and gives a ‘pop’ sound when tested with
Katod a lighted wooden splinter
Gas tidak berwarna dibebaskan dan menghasilkan bunyi ‘pop’
apabila diuji dengan kayu uji bernyala

Table 10 / Jadual 10

i Identify the products formed at the anode and cathode.

Write the half-equation for the reactions that occur.
Kenalpasti hasil yang terbentuk di anod dan katod
Tulis setengah persamaan bagi tindak balas yang berlaku
[4 marks]

ii What happens to the dilute hydrochloric acid at the end of the electrolysis?
Give one reason for your answer.
Apakah yang berlaku kepada asid hidroklorik cair pada akhir elektrolisis?
Berikan satu sebab bagi jawapan anda.

[4 marks]
iii State the factor that determines the products formed at the electrodes in this
experiment.
Nyatakan faktor yang menentukan hasil yang terbentuk di elektrod dalam
eksperimen ini.

[2 marks]

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 Chemistry form 5

(b) A student intends to electroplate an iron ring with copper to make it more
attractive. Describe one laboratory experiment to electroplate the iron ring. Your
answer should include the following :
 Procedure of the experiment
 A labelled diagram showing the apparatus set-up
 The half equation for the reaction at the anode and cathode

Seorang murid ingin menyadur satu cincin besi dengan kuprum untuk
menjadikan cincin itu lebih menarik. Huraikan satu eksperimen makmal untuk
menyadur cincin besi itu. Jawapan anda perlu mengandungi perkara berikut :
 Prosedur eksperimen
 Gambar rajah berlabel yang menunjukkan susunan radas
 Setengah persamaan bagi tindak balas di anod dan katod.
[10 marks]

END OF QUESTION PAPER

KERTAS SOALAN TAMAT

Prepared by

(Ms.Kohela Aluemalai)

22