Direction: Answer the following in a short bond paper. Erasures are NOT allowed. Show complete solution, if needed.
Deadline: April 25, 2019, 2:30 PM
1. Which substances are included in the equilibrium constant expression, Kc?
A. Only pure liquids B. Only pure solids and liquids C. Only gases and dissolved substances D. All participating substances
2. Write the correct equilibrium constant expression for the following reaction. FeO(s) + H2(g) Fe(s) + H2O(g)
3. Write the correct equilibrium constant expression for the following reaction. 2BrCl3(g) Br2(g) + 3Cl2(g)
4. Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl4(g) + ½O2(g) COCl2(g) + Cl2(g), Kc = 4.4 × 109 at 1000 K Deermine the Kc for the following reaction? 2CCl4(g) + O2(g) 2COCl2(g) + 2Cl2(g)
5. A 6.0-L vessel was found to contain 1.0 mol BrCl3, 2.0 mol Br2 and 6.0 mol Cl2. Calculate the equilibrium constant, Kc, for this equilibrium mixture for the reaction 2BrCl3(g) Br2(g) + 3Cl2(g)
6. Hydrogen peroxide may decompose to form water and oxygen gas according to the following reaction. 2H2O2(g) 2H2O(g) + O2(g) In a particular experiment, 1.75 moles of H2O2 were placed in a 2.5-L reaction chamber at 307ºC. After equilibrium was reached, 1.20 moles of H2O2 remained. What is Kc for the reaction?
7. Phosgene, COCl2, a poisonous gas, decomposes as follows.
COCl2(g) CO(g) + Cl2(g). At 900.ºC, Kc = 0.083. What is KP at this temperature? (R = 0.08206 L • atm/K • mol)
8. For the following reaction at 25ºC, is 3 × 1024.
2SO2(g) + O2(g) 2SO3(g) What is Kc at this temperature? (R = 0.08206 L • atm/K • mol)
9. Which statement is correct?
A. If Q < K, then products must be converted to reactants. B. If Q > K, then reactants must be converted to products. C. If Q = K, then the system is at equilibrium. D. If Q < K, then more reactants are produced.
10. A mixture of 0.500 mole of carbon monoxide and 0.400 mole of bromine was placed into a rigid 1.00-L container and the system was allowed to come to equilibrium. The equilibrium concentration of COBr2 was 0.233 M. Calculate Kc for this reaction. CO(g) + Br2(g) COBr2(g)
11. At a certain temperature the reaction CO2(g) + H2(g) CO(g) + H2O(g) has Kc = 2.50. If 2.00 mol of carbon dioxide and 1.50 mol of hydrogen are placed in a 5.00-L vessel and equilibrium is established, what is the equilibrium concentration of carbon monoxide?
12. The equilibrium constant, Kc, for the reaction PCl3(g) + Cl2(g) PCl5(g) is 49 at 230°C. If 0.70 mol of PCl3 is added to 0.70 mol of Cl2 in a 1.00-L reaction vessel at 230°C, what is the concentration of PCl3 when equilibrium has been established?
13. The equilibrium constant, KP, for the reaction H2(g) + I2(g) 2HI(g) is 55.2 at 425°C. A rigid cylinder at that temperature contains 0.127 atm of hydrogen, 0.134 atm of iodine, and 1.055 atm of hydrogen iodide. Is the system at equilibrium? A. Yes. B. No, the forward reaction must proceed to establish equilibrium. C. No, the reverse reaction must proceed to establish equilibrium. D. I need to know the volume of the container before deciding. E. Need to know the starting pressures of all substances before deciding.
14. At 400ºC, Kc = 64 for the equilibrium H2(g) + I2(g) 2HI(g). If 3.00 mol H2 and 3.00 mol I2 are introduced into an empty 4.0-L vessel, what is the equilibrium concentration of HI at 400ºC?
