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ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb.

25 2019
Name:____________________________________ Date:_____________

Unit 1: MEASUREMENT, MATTER, AND ENERGY

You should be able to:

 Calculate density, mass, and volume using the density equation


 Define temperature, calculate Celsius and Kelvin
 Count significant figures and calculate answers using sig figs.
 Define and give examples of: physical change, chemical change, physical property, chemical
property.
 State energy changes when bonds are formed and broken.

1. Which statement describes a chemical property


of the element iodine?
1. Its crystals are a metallic gray. 4. An example of a heterogeneous mixture is
2. It dissolves in alcohol. 1. Soil
3. It forms a violet-colored gas. 2. Sugar
4. It reacts with hydrogen to form a gas. 3. carbon monoxide
4. carbon dioxide
2. Which substance can be decomposed by
chemical change? 5. Which is a characteristic of all mixtures?
1. beryllium 1. They are homogeneous.
2. boron 2. They are heterogeneous.
3. methanol 3. Their composition is a definite ratio.
4. magnesium 4. Their composition can be varied.
3. Compared to the average kinetic energy of one
mole of water at 0°C, the average kinetic
energy of 1 mole of water at 298 K is
1.the same and the number of molecules is the 6. In an equation, which symbol would indicate a
same mixture?
2.the same, but the number of molecules is 1. NH3(s)
greater 2. NH3( )
3.greater and the number of molecules is 3. NH3(aq)
greater 4. NH3(g)
4.greater, but the number of molecules is the
same
ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb. 25 2019

7. How many sig figs are in the following 8. Calculate to the correct # of sig figs:
values? 1. 3.5674 + 0.022 + 1.20000 + 3.2 =
1. 0.002 g ____________ _________________________
2. 12000 L _____________ 2. 3.4 x 1.204 x 0.03 =
3. 2.45 x 102 m _________ _________________________
4. 103040 g ____________

9. What is the volume of a liquid with a density of 1.5 g/ml and a mass of 78g?

10. What is the density of an object with a mass of 34g and a volume of 13 cm3?

11. What is the mass of an object with a density of 5.7 g/cm3 and a volume of 48 ml?

12. The density of Lead is 11.4 g/ml. If a sample of Lead has a mass of 91 g, what is the volume of this sample of
Lead?

13. Calculate the following:


1. 53.2 °C = ________K
2. 783.4 K = ________°C

14. When a bond is formed, energy is (released/absorbed)

When a bond is broken, energy is (released/absorbed)


ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb. 25 2019
Unit 2: ATOMIC STRUCTURE

You should be able to:

 Define proton, neutron, and electron


 State the charge and location of each subatomic particle
 Determine how many protons, neutrons, and electrons are present in an atom or ion given the

isotopic notation (ex: )


 Calculate average isotopic mass
 Name and describe contributions of scientists toward our current understanding of the atom
(ex: Dalton, Thompson, Rutherford…)
 Describe the wave mechanical model of the atom

1. In a sample of the element potassium, each atom 5. Neutral atoms of the same element can differ in
has their number of
1. 19 protons 1. neutrons
2. 20 neutrons 2. positrons
3. 39 protons and neutrons 3. protons
4. 39 neutrons 4. electrons

2. All samples of an element are composed of 6. If 75.0% of the isotopes of an element have a
mass of 35.0 amu and 25.0% of the isotopes
atoms with the same
have a mass of 37.0 amu, what is the atomic
1. atomic mass mass of the element?
2. atomic number 1. 35.0 amu
3. number of nucleons 2. 35.5 amu
4. number of neutrons 3. 36.0 amu
4. 37.0 amu
3. Which pair must represent atoms of the same
element? 7. What is the symbol for an atom containing 20
protons and 22 neutrons?
1. and
1.
2. and
2.
3. and
3.
4. and
4.
4. The atomic number of any atom is equal to the 8. Which symbol represents an isotope of carbon?
number of 1.
1. neutrons in the atom, only
2. protons in the atom, only 2.
3. neutrons plus protons in the atoms 3.
4. protons plus electrons in the atom 4.
ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb. 25 2019
9. What is the mass number of an atom which 14. Compared to the entire atom, the nucleus of the
contains 28 protons, 28 electrons and 34 atom is
neutrons? 1. smaller and contains most of the atom’s
1. 28 mass
2. 56 2. smaller and contains little of the atom’s
3. 62 mass
4. 90 3. larger and contains most of the atom’s
mass
10. In an experiment, alpha particles were used to 4. larger and contains little of the atom’s
bombard gold foil. As a result of this mass
experiment, the conclusion was made that the
nucleus of an atom is 15. All isotopes of a given element must have the
1. smaller than the atom and positively charged same
2. smaller than the atom and negatively 1. atomic mass
charged 2. atomic number
3. larger than the atom and positively charged 3. mass number
4. larger than the atom and negatively charged 4. number of neutrons

11. Neutral atoms of 35Cl and 37Cl differ with 16. An atom of carbon-14 contains
respect to their number of 1. 8 protons, 6 neutrons and 6 electrons
1. electrons 2. 6 protons, 6 neutrons and 8 electrons
2. protons 3. 6 protons, 8 neutrons and 8 electrons
3. neutrons 4. 6 protons, 8 neutrons and 6 electrons
4. positrons
17. Rutherford’s gold foil experiment illustrated
12. Which of the following atoms has the greatest that the atom
nuclear charge? 1. is mostly empty space
1. Al 2. is densely packed with electrons
2. Ar 3. cannot be penetrated by any radiation
3. Si 4. contains a negatively charged nucleus
4. Na
18. An experiment using alpha particles to
13. Which particles account for most of the mass bombard a thin sheet of gold foil indicated that
of the atom? most of the volume of the atoms in the foil is
1. protons and neutrons taken up by
2. protons and electrons 1. electrons
3. neutrons and electrons 2. protons
4. neutrons and positrons 3. neutrons
4. empty space

19. Which ion has the same electron configuration


as an H− ion?
1. Cl−
2. F−
3. K+
4. Li+
ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb. 25 2019
Unit 3: ELECTRON STRUCTURE AND PERIODIC TABLE

You should be able to:

 Describe trends in the periodic table


 Name specific groups found on the periodic table (eg: noble gases) and state where they are
located. Describe characteristic properties of each group.
 Define allotrope; compare properties of different allotropes (eg: diamond, graphite)
 Use table S to look up physical properties (ex: electronegativity, ionization energy, density)
 Define and describe electronegativity, ionization energy
 Draw Lewis Dot diagrams (electron dot diagrams)
 Define valence electron, ground state, excited state

1. In which reaction is the first ionization energy 5. Which element is a member of the halogen
greatest? family?
1. Na + energy → Na+ + e− 1. K
2. K + energy → K+ + e− 2. B
3. Mg + energy → Mg+ + e− 3. I
4. Al + energy → Al+ + e− 4. S

6. Most nonmetals have the properties of


2. Given the electron dot diagram: The valence 1. high ionization energy and poor electrical
electrons represented by the electron dot diagram conductivity
could be those of atoms in Group 2. high ionization energy and good electrical
1. 13 conductivity
2. 15 3. low ionization energy and poor electrical
3. 3 conductivity
4. 16 4. low ionization energy and good electrical
conductivity
3. Which term refers to the region of an atom where
an electron is most likely to be found? 7. A characteristic of most nonmetallic solids is that
1. orbital they are
2. orbit 1. brittle
3. quantum 2. ductile
4. spectrum 3. malleable
4. conductors of electricity
4. Which statement best describes an electron?
1. It has a smaller mass than a proton and a 8. The characteristic bright-line spectrum of sodium
negative charge. is produced when its electrons
2. It has a smaller mass than a proton and a 1. return to lower energy levels
positive charge. 2. jump to higher energy levels
3. It has a greater mass than a proton and a 3. are lost by the neutral atoms
negative charge. 4. are gained by the neutral atoms
4. It has a greater mass than a proton and a
positive charge.
ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb. 25 2019
9. Which particle contains the fewest number of
electrons?
1. K
2. K+
3. Cl 13. Which group contains an element that is liquid at
4. Cl− STP?
1. 1
10. To which group do the alkaline earth metals 2. 2
belong? 3. 16
1. 1 4. 17
2. 2
3. 11 14. What is the total number of valence electrons in a
4. 12 carbon atom in the ground state?
1. 6
11. Which three elements have the most similar 2. 2
chemical properties? 3. 12
1. Ar, Kr, Br 4. 4
2. K, Rb, Cs
3. B, C, N 15. Which element in Group 1 has the greatest
4. O, N, Si tendency to lose an electron?
1. cesium
12. Name the following groups from the PT: 2. rubidium
3. potassium
1. 1: ________________________ 4. sodium
2. 2: ________________________

3. 17: ________________________

4. 18: ________________________
ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb. 25 2019
Unit 4: BONDING

You should be able to:

 Define/describe ionic, covalent/molecular, network, and metallic bonds in terms of physical


properties of each, role of the electron in each, what type of element(s) each involves
 Name various shapes of molecules
 Describe the polarity of both shapes and bonds

1. Which compound contains ionic bonds? 6. What type of bond exists in a molecule of
1. N2O hydrogen iodide?
2. Na2O 1. a polar covalent bond with an
3. CO electronegativity difference of zero
4. CO2 2. a polar covalent bond with an
electronegativity difference between
2. A substance was found to be a soft, nonconducting zero and 1.7
solid at room temperature. The substance is most 3. a nonpolar covalent bond with an
likely electronegativity difference of zero
1. a molecular solid 4. a nonpolar covalent bond with an
2. a network solid electronegativity difference between
3. a metallic solid zero and 1.7
4. an ionic solid
7. A white crystalline salt conducts electricity when
3. Two atoms with an electronegativity difference of it is melted and when it is dissolved in water.
0.4 form a bond that is Which type of bond does this salt contain?
1. ionic, because electrons are shared 1. ionic
2. ionic, because electrons are transferred 2. metallic
3. covalent, because electrons are shared 3. covalent
4. covalent, because electrons are transferred 4. network

4. Which factor distinguishes a metallic bond from an 8. Which diagram best represents
ionic bond or a covalent bond? the structure of a water
1. the mobility of electrons molecule?
2. the mobility of protons 3.
3. the equal sharing of electrons
1. 4.
4. the unequal sharing of electrons

5. The electrons in a bond between two iodine atoms 2.


(I2) are shared
1. equally, and the resulting bond is polar
2. equally, and the resulting bond is nonpolar 9. In a nonpolar covalent bond, electrons are
3. unequally, and the resulting bond is polar 1. located in a mobile “sea” shared by
4. unequally, and the resulting bond is nonpolar many ions
2. transferred from one atom to another
3. shared equally by two atoms
4. shared unequally by two atoms
ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb. 25 2019
10. The correct electron dot formula
for hydrogen chloride is 3. 1. 3.
1. 4.
2. 2. 4.
11. What type of bonding is present within a
network solid? 14. When an atom of chlorine forms an ionic bond
1. hydrogen with an atom of sodium, the atom of chlorine
2. covalent 1. loses an electron
3. ionic 2. loses a proton
4. metallic 3. becomes an ion with a smaller radius
than the atom of chlorine
12. Which formula represents a substance that
4. becomes an ion with a larger radius
contains covalent bonds?
than the atom of chlorine
1. LiCl
2. CaCl2 15. The ability to conduct electricity in the solid
3. K2O state is a characteristic of metallic bonding.
4. CO2 This characteristic is best explained by the
presence of
1. high ionization energies
2. high electronegativities
3. mobile electrons
4. mobile protons

16. When ionic bonds are formed, metallic atoms


tend to
1. lose electrons and become negative ions
2. lose electrons and become positive ions
3. gain electrons and become negative
ions
4. gain electrons and become positive ions

13. Which electron-dot formula represents a polar


molecule?
ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb. 25 2019
Unit 5: COMPOUNDS, MOLES, AND REACTIONS

You should be able to:

 Names formulas (be able to use roman numerals, polyatomics, etc.)


 Calculate gram formula mass (gfm) for a given compound
 Grams moles for a given compound
 Convert between empirical and molecular formulas
 Determine mole ratios given a chemical equation
 Mole mole conversions given a chemical equation
 Define Hydrate, calculate gfm of a hydrate
 Calculate % composition by mass for molecules and hydrates
 Define and apply the law of conservation of mass
 Balance chemical equations
 Identify reaction types and predict products given the reactants

1. Which element can form a chloride with a general 5. Which equation illustrates conservation of mass?
formula of MCl2 or MCl3? 1. H2 + Cl2 → HCl
2. Fe 2. H2 + Cl2 → 2HCl
3. Al 3. H2 + O2 → H2O
4. Mg 4. H2 + O2 → 2H2O
5. Zn
2. Given the equation: __FeCl2 + __Na2CO3 → 6. Which quantity is equivalent to 17 grams of H2O2?
__FeCO3 + __NaCl When the equation is 1. 1.0 mole
correctly balanced using the smallest whole 2. 2.0 mole
numbers, the coefficient of NaCl is 3. 0.50 mole
1. 6 4. 1.5 mole
2. 2
3. 3 7. What is the molecular formula of a compound with
4. 4 the empirical formula P2O5 and a gram-molecular
mass of 284 grams?
3. Which is the correct formula for carbon (II) oxide? 1. P2O5
1. CO 2. P5O2
2. CO2 3. P10O4
3. C2O 4. P4O10
4. C2O3
4. When the equation 8. The formula for calcium cyanide is
__C8H16 + __O2 → __CO2 + __H2O 1. CaCN2
is correctly balanced using the smallest whole 2. CaSCN2
number coefficient, the coefficient of O2 is 3. Ca(CN)2
1. 1 4. Ca(SCN)2
2. 8
3. 12
ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb. 25 2019
9. When the equation: 16. What is the percent by mass of sulfur in sulfur
__Al2(SO4)3 + __ZnCl2 → __AlCl3 + __ZnSO4 is dioxide?
correctly balanced using the smallest whole number 1. 32
coefficients, the sum of the coefficients is 2. 33
1. 9 3. 50
2. 8 4. 67
3. 5
4. 4 17. Given the reaction: 4Na + O2 → 2Na2O
How many grams of oxygen are completely
10. What is the empirical formula of a compound consumed in the production of 1.00 mole of
that contains 0.20 mole of nitrogen atoms and 0.40 Na2O?
mole of oxygen atoms? 1. 16.0
1. NO2 2. 32.0
2. N2O 3. 62.0
3. N2O4 4. 124
4. N4O2
18. What is the percent by mass of nitrogen in the
11. Which is an empirical formula? compound NH4NO3 (formula mass = 80.)?
1. H2O2 1. 5.7%
2. H2O 2. 18%
3. C2H2 3. 29%
4. C3H6 4. 35%

12. What is the gram formula mass of Li2SO4? 19. What is the total mass in grams of 0.75 mole of
1. 54g SO2?
2. 55g 1. 16 g
3. 110g 2. 24 g
4. 206g 3. 32 g
4. 48 g
13. What is the empirical formula of a compound 20. A student obtained the following data to
consisting of 29.6% oxygen and 70.4% fluorine determine the percent by mass of water in a
by mass? hydrate.
1. OF
2. OF2
3. O2F
4. O2F4
14. Given the reaction:
Ca + 2H2O → Ca(OH)2 + H2
What is the total number of moles of Ca
needed to react completely with 4.0 moles of
H2O?
1. 1.0 What is the approximate percent by mass of the water
2. 2.0 in the hydrated salt?
3. 0.50
4. 4.0
1. 2.5%
15. What is the formula mass of Al2(SO4)3?
2. 12%
1. 123
3. 88%
2. 150.
4. 98%
3. 214
4. 342
ECPA-Chemistry Winter Break Review – February 2019 – Due date: Feb. 25 2019

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