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SPE

Society of Petroleum Engineers

SPE 18977

Summary Results of C02 EOR Field Tests, 1972-1987


by W.R. Brock and L.A. Bryan. Exxon Co. U.S.A.
SPE Members

Copyright 1989. Society of Petroleum Engineers, Inc.

This paper was prepared for presentation at the SPE Joint Rocky Mountain Regional/Low Permeability Reservoirs Symposium and Exhibition held in Denver, Colorado, March 6-8, 1989.

This paper was selected for presentation by an SPE Program Committee following review of information contained in an abstract submitted by the author(s). Contents of the paper,
as presented, have not been reviewed by the Society of Petroleum Engineers and are subject to correction by the author(s). The material, as presented, does not necessarily reflect
any position of the Society of Petroleum Engineers, its officers. or members. Papers presented at SPE meetings are subject to publication review by Editorial Committees of the Society
of Petroleum Engineers. Permission to copy is restricted to an abstract of not more than 300 words. Illustrations may not be copied. The abstract should contain conspicuous acknowledgment
of where and by whom the paper is presented. Write Publications Manager, SPE, P.O. Box 833836, Richardson, TX 75083-3836. Telex, 730989 SPEDAL.

ABSTRACT recover additional crude oil includes immiscible


flooding and an individual well stimulation
Since the early 1970s, numerous presentations have technique known as "huff 'n' puff." This paper
been made and articles written about pilot tests summarizes 21 miscible floods, 4 immiscible
and field-scale enhanced oil recovery projects multi-well floods and 5 immiscible "huff 'n' puff"
using carbon dioxide (C02) as a solvent_ This projects.
paper summarizes publicly available data on 30 The ori gi na 1 intent of thi s paper was to present
projects. The use of C02 has grown significantly both successful and unsuccessful projects so that
since the early-1980s, especially in the Permian comparisons could be made. However, the search of
Basin, as reliable supplies of C02 became more available data banks for papers published on
available. Today, even with depressed crude oil unsuccessful projects was fruitless. It is likely
markets, the use of C02 continues to grow. The use that some of the projects discussed could be
of C02 in the Rocky Mountain region is increasing, considered marginally economic with depressed crude
primarily among those with prior C02 flooding oil pri ces even though they were techni cal
experience in the Permian Basin. As the demand for successes. Thi s paper does not attempt to draw
C02 increases in the Rocky Mountains, so will the conclusions of the projects reviewed but instead
supply, and the same growth experienced in the presents, without interpretation, conclusions as
Permian Basin should be seen. As with any major published in the individual references. The reader
project in the oil industry, the enhanced recovery should bear in mind while reviewing this paper that
of oil requires thorough advance planning to many of the extrapolations of incremental
determine the optimum EOR method. This summary of recoveries and other factors are based on
C02 projects is intended to provide a brief on each performance data from relatively early in a
project, describe the reservoir parameters, and project's 1ife.
review the conclusions of the individual authors,
in addition to providing a quick reference of DEFINITIONS
available papers to which those interested may turn
for greater detail. Since the use of C02 has been Terminology used in this paper is consistent with
successfully tried in a wide range of reservoirs that used in the EOR arena. The term "incremental
and under a variety of operating conditions, the oi 1" refers to the oi 1 production in excess of a
application of C02 in Rocky Mountain reservoirs base decline curve for continued operations. Gross
shoul d be every bl t as successful as it has been utilization of C02 is defined as the total injected
elsewhere. volume of C02, including any recycled volumes,
divided by the total incremental recovery. The net
INTRODUCTION utilization is the purchased volume of C02 divided
by the tota 1 incrementa 1 recovery. Mi sc i b1e
The use of C02, both miscibly and immiscibly, has flooding refers to the use of C02 at a reservoir
grown dramatically since the start of this decade, pressure greater than that necessary for the C02 to
spurred by the installation of C02 pipelines in the mix with the reservoir oil, commonly referred to as
Permian Basin in the early-1980s. While many the minimum miscibility pressure (MMP). Immiscible
cha 11 enges still face the user of C02, the flooding or stimulation uses C02 at pressures less
increased use of C02 to recover residual oil than the MMP and re 1i es more on the reduct i on of
evidences the optimism the industry has towards viscosity and interfacial tension, and the swelling
enhanced oil recovery using C02' The use of C02 to of the oi 1 contacted by the C02' In discuss i ng
various C02 floods, the volume of C02 injected is
commonly referred to in terms of percent of
References and illustrations at end of paper. hydrocarbon pore volumes (HCPV).
499
2 SUMMARY RESULTS OF CO 2 EOR FIELD TESTS 1972-1987 SPE 18977
MISCIBLE--FIELD-SCALE in September 1985, gives all indications of being
successful. Incremental recovery is projected to
The first group reviewed are field-scale miscible be 8 percent OOIP following a WAG injection of a
floods whose parameters are summarized in Table 1. 30 percent HCPV at a 2:1 ratio. Since injection
These projects employ either continuous slugs or commenced, the oil production decline has been
water-alternating-gas (WAG) injection schemes. The arrested and oil production appears to be on the
11 projects discussed are in a variety of different increase. The project has experienced an increased
reservoirs ranging from the shallow to the deep, occurrence of calcium sulfate scale, and the
from the tight to the very permeable, and in both precipitation of asphaltenes and paraffins in wells
carbonate and sandstone. experiencing C02 breakthrough. Although the
increase in calcium sulfate is concurrent with C02
Some of the projects ut i 1i ze purchased C02 very breakthrough, it is postulated by Phillips that
efficiently as noted by low net C02 utilizations, these occur concurrently due to the dissolution of
while others appear less efficient. In all of the anhydrite stringers by the water. The calcium
these, it has been qual itatively proven that C02 sulfate problem has required periodic inhibition
can enhance oil recovery; however, it should be squeezes using a low pH phosphonate scale
noted that the quantity of incremental oil in most inhibitor. The asphaltene/paraffin depositions are
cases is based on extrapolations of data very early treated using heavy aromatic solvents to dissolve
in the 1ife of the project. Projected incremental the build-up. The total injection of 230 Bcf
recoveries ranged from around 7 percent (billion cubjc feet) of C02 will yield a gross
Original-Oil-In-Place (OOIP) to 22 percent OOIP on utilization of 11.1 mcf/STB. Since an estimated
net utilizations of 2.4 mcf (thousand cubic feet) 100 Bcf will be recycled, the net utilization
C02 per stock tank barrel (STB) of incremental oil should approach 6.3 mcf/STB.
to 11 mcf C02/STB.
FORD-GERALDINE3 Conoco initiated a miscible C02
DOLLARHIDE DEVONIANI UNOCAL initiated a phased flood of the Ford Geraldine Unit located in Reeves
miscible C02 project in the Dollarhide Devonian and Culberson Counties, Texas in February 1981 when
field located in Andrews County, Texas in May 1985. it became apparent that unless tert i ary recovery
The project was designed around a low permeability, was initiated, the Unit would have to be abandoned.
tripol itic chert Devonian reservoir at a depth of The poor waterfl ood performance, as evi denced by
7800 feet with high conformance and mi nima 1 the 0.25:1 secondary-to-primary recovery ratio,
heterogeneities. During waterflooding an left an estimated 77 percent OOIP in the reservoir.
exceptionally high sweep efficiency was realized Buoyed by the success at the nearby, and s imil ar,
with greater than a 2: 1 secondary-to-primary Twofreds C02 project and by their own feasibil ity
recovery ratio. This high sweep efficiency is study, injection commenced using an erratic C02
expected to be exhibited in tertiary recovery supply from a gas plant for the first five years
operat ions. To date greater than 99.5 percent of during which oil production remained relatively
the C02 has been retained in the reservoir after flat. When a stable C02 supply was obtained in
more than 5.8 percent HCPV of C02 injection. The 1ate 1985, the production increased dramatically
fi rst breakthrough of C02 did not occur unt i 1 17 from 381 bopd to 1160 bopd. The project is bei ng
months after the start of injection. According to staged with the second stage to be implemented as
UNO CAL , the tot a1 1ack of premature C02 excess C02 becomes available and as the first stage
breakthrough is indicative of unusually high C02 is placed on a brine flush following injection of a
sweep efficiency. Originally designed for a 30 percent HCPV slug. This relatively shallow, 2680
25 percent HCPV slug chased by water, the project foot Ramsey Sand reservoir is anticipated to yield
was modifi ed to benefit from the mobil ity control an incremental 17 percent 001 P due to the tert i ary
of WAG injection while still capturing the benefits project. C02 utilization is expected to be 9
of acceleration from the slug process. Following mcf/STB on a gross basis and around 5 mcf/STB on a
the i nit i a1 slug of 9 percent HCPV, the project net basis.
wi 11 be placed on a 21 percent HCPV 1: 1 WAG. The
phasing of the project will decrease peak C02 KELLY-SNYDER (SACROC)4 The Scurry Area Canyon Reef
purchase requirements by spreading C02 requirements Operators Committee (SACROC) has been conducting a
over a longer peri od of time and wi 11 all ow for miscible C02 flood in the Kelly-Snyder field in
maximum use of less expensive recycled C02. The Scurry County, Texas since 1972. Much of the
wide difference between the 1600 psi MMP and the SAC ROC C02 project was implemented coincident with
fracture pressure of 5500 psi allows for the a pattern waterflood. However, the two areas
injection of C02 at the waterflood reservoir discussed below are believed to reflect tertiary
pressure of 3200 psi. Although C02 utilization will recovery since these areas were near watered-out
be 1ess effi c i ent at 3200 ps i than at a lower from waterflooding.
pressure, it will be possible to reinject the
contaminated gas stream whose MMP is less than 3200 These two multi-pattern areas were studied in-depth
psi but greater than 1600 psi without costly to better understand the flood efficiency and
up-front investments necessary to clean-up the C02 anticipated recoveries. The two areas are referred
and without the risk of losing production due to an to as the 4 pattern area (4PA) and the 17 pattern
inability to maintain MMP. The field was infill area (17PA). The 4PA contains 24 wells and covers
drilled to 40-acre, five-spot patterns which is 603 acres. This area was at a 95 percent watercut
anticipated to increase recovery about 5 percent when placed on C02 injection in mid-1981. Using a
OOIP. The 30 percent HCPV of C02 injected is cumulative 3:1 WAG injection ratio, the 4PA was
anticipated to increase the ultimate recovery by fl ooded wi th a 30 percent HCPV of C02 through May
14.p~rce~t OOIP, resulting in an estimated C02 1986. Estimated incremental recoveries are
utlllZatlon of 2.4 mcf/STB. No C02 injectivity 9.8 percent OOIP with a gross C02. util ization of
problems have been encountered. 9.5 mcf/STB and a net of 3.2 mcf/~TB. The larger
17PA covered roughly 2700 acres and contained over
EAST VACUUM GRAYBURG/SAN ANDRES2 This miscible C02 100 wells. This pattern was also started on C02 in
flood of the San Andres 001 it i c dolomite in Lea mid-1981 and through December 1987, a 17.5 percent
County, New Mexico initiated by Phillips Petroleum HCPV of C02 had been injected resulting in a
500
SPE 18977 W. R. BROCK, L. A. BRYAN 3

cumulative WAG ratio of 5:1. The ultimate ult imate recovery through secondary operat ions is
incrementa 1 recovery is anti ci pated to reach rough ly 50 percent of 001 P. The major operat i ona 1
7.5 percent OOIP. The current gross C02 utilization challenges facing this project are the development
in this pattern is 9.7 mcf/STB with an estimated of effective diversion techniques such as polymers
net utilization of 6.5 mcf/STB. and foam diverters to control C02 injection and the
improvement of scale inhibition treatment life and
MEANS SAN ANDRESS This miscible C02 project in costs. The occurrence of bari um sulfate, present
Andrews County, Texas, operated by Exxon Company prior to the C02 flood, has increased as the lower
U.S.A., commenced injection of C02 in November 1983 pH has resulted ina reduced effect i ve 1ife of
and is expected to recover 7.1 percent of the OOIP. scale treatments. This miscible project in the 6500
This project is utilizing a 2:1 WAG injection in foot deep Weber sandstone is anticipated to have a
the San Andres dolomite, with an estimated gross C02 utilization of 9.2 mcf/STB and a net
55 percent HCPV to be injected. This higher WAG utilization on the order of 4-6 mcf/STB.
ratio was used to improve sweep efficiency. Not
included in the estimated tertiary recovery is an SOUTH WELCHl1 The simulation of the initial phase
additional 9.2 percent OOIP to be recovered by of this miscible C02 flood by Cities Service (now
improved secondary performance through i nfi 11 OXY USA) in the San Andres dolomite in Dawson
drilling, and improved reservoir management, County, Texas indicates that an incremental
associated with the tertiary recovery project. The recovery on the order of 7 percent 00 I P can be
gross C02 utilization is estimated to be expected. The simulation of this project, which had
15 mcf/STB. No apparent WAG injectivity problems been infilled to 10-acre spacing, concludes that
were encountered in the laboratory or pilot studies the single variable which most influences
and none have been encountered in the full- sca 1e incremental recovery is the volume of C02 injected.
project. It was also determined that if a strong water
blocking phenomena exists, a continuous slug
N.E.PURDY UNIT6 Cities Service (now OXY USA) process would be more efficient than a WAG process.
initiated a full-scale miscible C02 flood in the Simulation of South Welch indicates an estimated
Springer "A" sandstone of the N. E. Purdy Unit in ultimate recovery through secondary of 40.1 percent
Garvin County, Oklahoma in September 1982. The OOIP whereas a C02 flood util izing a 25 percent
majority of the field is being processed with a HCPV 2:1 WAG would ultimately recover 47.7 percent
30 percent HCPV slug wh i 1e three patterns are on OOIP. No data indicating the anticipated C02
WAG injection. These patterns were placed on WAG utilizations were presented.
injection to 1) raise the pattern pressure or 2)
due to unfavorabl e product i on characteri st i cs of TWOFREDS12 This full-scale miscible C02 flood
offset producing wells. Most of the wells in the located in Loving, Reeves and Ward Counties, Texas
project had shown response to C02 injection was the fi rst such fl ood ina sandstone format i on
following the injection of 15 percent of the HCPV in Texas. C02 injection commenced in early-1974 in
of C02. Peak oi 1 product i on rates of two to four thi s reservoi r with an average depth of 4820 feet
times the pre-response rates were commonly observed and is projected to yield an additional
while the water-oil ratio was reduced from 30 to 8. 15.6 percent OOIP. The C02 was followed by a
Observation well logging indicated good vertical water-alternating-exhaust gas (84.4 percent N2,
sweep at a distance of 265 feet from the injector 8.6 percent C02 & 7 percent CH4) since 1980 as a
and also indicated a reduction of oil saturations flush. The need to use exhaust gas instead of the
from 44 percent to 25 percent. C02 injectivity originally planned water was due to the low
appears to have improved with the cumul at i ve C02 injectivity capacity of the injectors as compared
injection whereas post-C02 water injection appears to the productive capacity of the producers and the
to be comparable to the pre-C02 injectivity. Gross hi gher vi scos ity of the water as compared to the
utilization of C02 is estimated to be 6.5 mcf/STB C02. While the initial C02 was slugged, the
while the net utilization should approach operator, HNG (now Enron), used WAG injection in
4.6 mcf/STB. The anticipated incremental recovery the post-C02 flood in order to control the viscous
is 7.5 percent OOIP. fingering of the exhaust. No apparent injectivity
problems occurred and the injectivity of the
NORTH CROSS7,8,9 The floodi.ng of this tripolitic exhaust gas was 29 percent greater than water
chert reservoi r located 1n Crane and Upton following C02. Net utilization of C02 is estimated
Counties, Texas was initiated by Shell in 1972 to approach 13 mcf/STB. Corros i on of tubul ars and
follo~ing primary depletion by augmenting the wellheads has been controlled with a chemical
so 1ut lOn gas dri ve with gas injection. The treatment program using an oil-soluble blend of
decision to forgo secondary waterflooding of this dimertrimer acid and imidazoline. This program has
reser~oi~ was based on ~niformly low permeability. resulted in no specialized metallurgy being
The m1sc1ble use of C02 1S expected to result in an required for the wellhead, downhole or surface
incremental recovery of roughly 22 percent OOIP equipment.
with a gross C02 util ization of over 18 mcf/STB:
The estimated nef utilization will be between 7 and WERTZ13 The performance of this project since its
8 mcf/STB. start-up in the fall of 1986, clearly indicates
that miscible C02 is displacing significant amounts
RANGELY 10 This .miscible C02 flood operated by of tertiary oil. This Amoco-operated project in
Chevron U.S.A. 1n northwestern Colorado in Rio central Wyoming has experienced better than
Blanco Co~nty has shown a significant, rapid anticipated C02 injectivity with only limited
response Slnce start-up in the fall of 1986. The deterioration of water injectivity following the
tertiary project is designed for the 1:1 WAG C02. Log analysis indicate that both the vertical
i nject ~ on of a 30 percent HCPV of C02 in and areal sweep efficiencies are favorable. The
approx1mately 20 equal cycles. The incremental antici~ate~ incremental recovery from the Tensleep
recovery attributable to CO~ is forecast to be 106 format10n 1S 10 percent of OOIP in the processed
MMbo of the 1413 MMbo OOIP 1n the project area, or area. The gross C02 utilization factor is expected
7.5 percent. As of the fall of 1987 the production to be between 13 and 15 mcf/STB. The net
build-up was in excess of 5000 bopd. Estimated utilization factor will be considerably less due to
501
4 SUMMARY RESULTS OF CO 2 EOR FIELD TESTS 1972-1987 SPE 18977
the recycling of C02 and should be less than with the C02, the effect i ve mobil ity ratio of the
10 mcf/STB. displacement would be decreased thereby increasing
the volumetric sweep efficiency.
MISCIBLE--PRODUCING PILOTS
MALJAMAR18,19 A 5-acre inverted 5-spot pilot,
This second group consists of 8 miscible producing operated by Conoco, in the Maljamar Cooperat~ve
pilots, whose various parameters are summarized in Agreement Unit located in Lea County, New Mexl co
Table 1. These projects employed either continuous tested the potent i a1 of mi sc i b1e C02 flood i ng of
slugs or water-alternating-gas (WAG) injection the Grayburg and San Andres reservoirs. The
schemes, and were in a variety of different 30 percent HCPV slug of C02 injected between May
reservoirs ranging from the shallow to the deep, and December 1983 resulted in recoveries of
from low to high permeability, and in both 17.7 percent OOIP from the Grayburg and 8.2 percent
carbonate and sandstone. In all of these it has OOIP from the San Andres. The lower recovery from
been qualitatively proven that C02 can enhance oil the anhydritic dolomite San Andres as compared to
recovery, however, it should be noted that the the dolomitic sandstone Grayburg, is attributed to
quant ity of incremental oil in some cases is based C02 moving out-of-zone below the target interva~.
on data from a much smaller area than might be This flooding of a greater pore volume resul~ed ln
represent at i ve of a commerci a1 app 1i cat i on. Some a smaller slug size (about 14 percent HCPV) ln the
of the projects ut i 1i zed purchased C02 very San Andres sublayers than intended which caused the
efficiently as noted by low net C02 util izations, lower recovery. In general, the Grayburg responded
while others appeared less efficient. Projected quicker than did the San Andres, approximately 100
incremental recoveries ranged from around 8 percent days versus 200 days. Reservoir "plugging" by
OOIP to 21 percent OOIP on net utilizations of asphaltene preCipitation, carbonate plugging .or
2.4 mcf C02/STB to near 13 mcf C02/STB. depos it i on caused by the interact i on of corros lOn
inhibitors with C02, may have incre.ased the
GARBER FIELD14 This central Oklahoma field, volumetric sweep efficiency over that estlmated for
operated by ARCO Oi 1 & Gas Company, had a the waterflood. Net C02 utilizations are estimated
successful miscible C02 pilot in the waterflooded to be roughly 6 mcf/STB for the Grayburg and
Crews Sand at an average depth of 1950 feet 11 mcf/STB for the San Andres. Water inject i vity
(MMP=1075 psig). The pilot area has recovered an fo 11 owi ng C02 decreased in compari son to pre-C02
estimated 14 percent OOIP since initiating C02 injectivity in both the Grayburg and the San
injection in October, 1981. This pilot was Andres.
originally designed to inject a 25 percent HCPV of
C02, yet a total of 35 percent HCPV was injected. NORTH COLES lEVEE20 ARCO Oil and Gas Company
The initial plan called for the injection of a initiated the first application of C02 injection in
7 percent HCPV slug followed by a 1:1 WAG to the Kern River Valley of California in June 1981.
control an anticipated severe gravity override. The pilot is in an area where many deep, light oil
When the gravity override did not material ize, a reservoirs are approaching their economic 1imit.
continuous slug was injected. Following injection While a technical success, this pilot, consisting
of the 25 percent HCPV slug, numerous producers had of two 5-acre inverted five-spot patterns and one
yet to show response so the slug was increased to 10-acre 1i ne dri ve pattern, was plagued with many
35 percent HCPV. Once th is 1arger slug had been supply and mechanical problems that masked
injected C02 injection was terminated in June, 1982 incremental oil recoveries. Pilot patterns were
and the inJectors put on water, since the optimum also badly out of balance due to either a
slug size had been attained even though production directional permeability trend or mechanical
had yet to show a decline trend. No injectivity problems, which resulted in reduced oil recovery.
probl ems were encountered after the conversi on to Using simulation, this 9200 foot deep sandstone
water. Reservoi r heterogeneit i es appear to have reservoi r, with a net pay thi ckness of 136 feet,
contributed to the control of the anticipated was predicted to produce an incremental
gravity override. The pilot demonstrated that it 15-20 percent OOIP with gross C02 util ization of
was feasible to C02 flood fields at depths of less 8-31 mcf/STB and a slug size of 63 percent HCPV.
than 2000 feet and that good oil recovery was The simulation showed gravity override into the
possible even when waterflood residual oil upper zone of the Stevens Main Western sand
saturations were as low as 25 percent PV. Net C02 domi nated the di sp 1acement effi ci ency. Simul ator
utilization is estimated to approach 6 mcf/STB. results i ndi cated that the simultaneous injection
of C02 low in the reservoir and water high in the
LITTLE CREEK15,16,17 The Shell operated C02 pilot reservoi r woul d greatly enhance sweep effi ci ency.
in the Little Creek field in southwestern The C02 supply was from an area refinery that had
Mississippi in the mid-1970s demonstrated that C02 occasional upsets during the pilot, thereby
can effectively recover tertiary oil from a limiting the supply and causing the pilot to be
thoroughly waterflood depleted sandstone reservoir terminated in mid-1984.
such as the 10,400 foot deep Tuscaloosa Denkman.
The average waterflood residual oil saturation in QUARANTINE BAy21 The pilot flood of the Quarantine
this pilot was estimated to be 21 percent. A large Bay 4RC field in Plaquemines Parish, Louisiana
(160 percent HCPV) slug of C02 was injected during demonstrated that the C02-WAG process is
the pilot without alternating water slugs. The technically viable for mobilizing considerable
ultimate tertiary recovery was estimated to be as amounts of residual oil from the watered-out
high as 45 percent of the waterflood residual oil Mi ocene semi -conso 1i dated sand reservoi rs of the
in the area, including the area between the pilot Gulf Coast of Louisiana. ARCO Oil and Gas Company,
injectors and producers and the nearby field the operator, started injecting C02 in October 1981
pinchout. This equates to nearly 21 percent OOIP in a 57-acre area of the field located southeast of
~e~overed due·to tertiary. Due to the large slug New Orleans. Injection continued on a 1:1 WAG
lnJected the gross C02 utilization approached until a total of 18.9 percent HCPV of C02 had been
27 mcf/STB and the net was around 13 mcf/STB. injected. In February 1983 injection was converted
Subsequent simulation of this pilot showed that if to water and anticipated recovery is expected to
water were injected cycl ically or simultaneously reach 15.8 percent OOIP. The net utilization of
502
SPE 18977 w. R. BROCK, L. A. BRYAN 5

C02 is slightly less than 3 mcf/STB. The small of three pil ot producers 1ed to the concl us i on by
slug size was selected because larger slug sizes Conoco that a waterflood injector should not be
could not be economically justified. Reservoir converted to a tert i ary producer wi thout careful
simulations indicated the incremental recoveries consideration.
for slug sizes between 15 and 35 percent HCPV did
not vary significantly and therefore the smaller MISCIBLE--NON-PROOUCING PILOTS
slug size and resulting lower utilization would
improve economics. Because of the dissolution of These two non-producing pilots were conducted with
carbonate cementation by the carbonic acid, the observation wells offsetting the injection well to
injectivity appears to have increased. This has monitor the movement of the C02 in the reservoir.
also led to the increased occurrence of sand By logging these wells the operator is able to
production not previously noticed in the field. detect the changes in residual oil saturations as
This flood experienced some mechanical problems the C02 front passes. Combined with pre- and
related to corrosion which resulted in the post-pil ot core ana lyses, the data from the
premature shut-in of producers. The operator observation wells is used to simulate the recovery
est imated the incremental recovery coul d have process. Based on these simulations, predictions
approached 20 percent OOIP had these problems been are made of expected incremental recoveries and
avoided. anticipated injected volumes. As with the
predictions of other projects, these pilots proved
SLAUGHTER ESTATEI6,22 This miscible WAG pilot in
the carbonate San Andres reservoi r underl yi ng the that C02 can mobilize waterflood residual oil.
Sl aughter Estate Uni t operated by Amoco in Hockl ey However, due to the nature of the data these
County, Texas has shown that significant quantities predictions should be used with caution.
of tertiary oil can be recovered using a solvent of
72 percent C02 and 28 percent H2S. The water CEDAR CREEK ANTICLINE25 The non-producing miscible
alternat i ng sol vent inject i on resulted in reduced C02 pi 1ot conducted by Shell in the South Pi ne
injectivity during the solvent phase but subsequent field of the Cedar Creek Anticline in eastern
oil production has shown that the alternating Montana between 1983 and 1985, showed that tertiary
sequence of injection provided excellent areal oil can be effectively mobilized and displaced by
sweep. A 26 percent HCPV of the solvent gas was C02. The residual oil saturation after waterflood
injected between August 1976 and October 1979. This was estimated to be between 38 percent and
so 1vent injection was then chased by a 30 percent 40 percent, and after miscible C02 injection
HCPV slug of nitrogen. The projected solvent averaged 20 percent. The test also showed that
utilization, not including the nitrogen, is vert i ca 1 conformance of C02 was the same as for
anticipated to be in the range of 3-5 mcf/STB. brine in the pre-flush leading to the conclusion by
Incremental recovery is estimated by simulation to Shell that the volumetric sweep efficiency of a C02
be at least 20 percent OOIP. flood in this Red River crystalline dolomite would
be similar to that of the waterflood, provided the
WEEKS ISLAN023 The Weeks Island S Sand Reservoir B effective mobility of CO2 is controlled. It was
in New Iberia Parish, Louisiana, typical of many also concluded that the waterflood behavior of the
piercement salt-dome fields in the Gulf Coast area, Red River formation could be profitably studied to
was the target of a gravity stable C02 pilot test predict C02 flood behavior. The injectivity of C02
by Shell in October 1978. This pilot demonstrated was found to be roughly 14 times that of the brine
that a gravity stable C02 flood is very effective in the pre-flush.
in these reservoirs which have highly efficient
~t\ong. wa~er-drives. At .the s~art of the C02 LITTLE KNIFE26 This five-acre inverted four-spot,
lnJectlon ln 1978, the resldual 011 saturation was non-producing pilot conducted by Gulf (now Chevron)
estimated to be 22 percent. The very permeable in 1980-1981 was in the dolomitic Mission Canyon
(1200 md), steeply dipping (26°) sandstone Formation. Located in the Williston Basin of North
reservoir received an initial C02 slug equal to Dakota, this 9800 foot deep reservoir was C02
24 percent HCPV mixed with about six mole percent flooded using a 1:1 WAG injection. With data
of natural gas, pri marily methane. The C02 was obtained from logging of observation wells and from
diluted to lessen the risk of gravity instability. pre- and post-flood core analyses, simulation using
When gas production rates began to increase in both a black oil and compositional simulators was
1983, the C02 contaminated gas was re-injected. conducted. The results of these simulations
This pilot is expected to recover an estimated revea 1ed that the WAG inject i on of a 22 percent
8.9 percent OOIP. Gross C02 utilization is HCPV of C02 into this highly stratified and
projected to be 7.9 mcf/STB at the end of the relatively flat reservoir would improve the
pilot, with net utilization around 3.3 mcf/STB. ultimate recovery by 8 percent of OOIP, if flooded
on 160-acre spacing. The simulation also predicted
WEST SUSSEX24 This oil-in-the-tank pilot by Conoco net C02 util ization of a commercial scale flood
su~ports the feasibility of miscibly C02 flooding would be around 5 mcf/STB.
thlS Shannon sandstone and other similar low
residual, light oil reservoirs in the Powder River IMMISCIBLE--FIELO-SCALE
Basin of Wyoming. Between mid-1982 and late-1985 a
30 percent HCPV slug of C02, preceded and followed T~e immiscibl~ use ?f. CO~ can be classified as
by water, was injected into this 9.6-acre pilot el ther a mult 1 -well 1 nJect 1 on of a cont i nuous slug
without any apparent inject i vity impai rment. The or WAG, or as individual well stimulations referred
option of using WAG was left open during the pilot to as "Huff 'n' Puff". The primary recovery
should premature C02 breakthrough justify a switch mechanisms of immiscible CO~ projects are the
from the sl ug. The est imated incremental recovery vi scos ity reduct i on and swe 111 ng of the contacted
from this 3000 foot deep watered out shaly marine crude oil. Reduction of the oil viscosity creates
sandstone is 8.9 percent of OOIP. The resultant a more favorable mobility ratio which in turn
gro~s utilization of C02 was 12.9 mcf/STB. It was results in improved sweep efficiency and a lower
~s~lmated that 20 percent of the cumulative C02 residual oil saturation to waterflooding at the
lnJected was produced. Lack of oil response in one economic limit. Oil swelling increases recovery by
503
6 SUMMARY RESULTS OF CO 2 EOR FIELD TESTS 1972-1987 SPE 18977
reducing the stock tank residual oil saturation permeability (3 md) does not prevent the injection
from waterflooding. of low-vi scos ity fl ui ds such as C02. It also
showed that when water cannot be injected at
The parameters of the field-scale immiscible floods economi ca 1 rates to repressure a reservoi r or to
are shown on Table 2. These two floods had displace the solvent slug in a tight dolomitized
predi cted incremental recoveri es between 9 and 10 limestone reservoir that C02 could possibly be
percent OOIP, and net C02 utilizations were between used. This pilot showed that although miscibility
5 and 12 mcf/STB. As with the field-scale miscible was only attained in the near welloore region of
floods, the incremental recoveries are in some the injectors, the swell ing of the oil, the
cases based on extrapolations of early performance vi scos ity reduction and the increase in reservoi r
data and should be used with caution. energy due to C02 injection resulted in an
estimated 5 percent OOIP incremental recovery. The
HANSFORD MARMATON16,27 This project in Hansford estimated gross utilization was 6.4 mcf/STB.
County, Texas has proven that C02 can be used to Although the resultant incremental recovery was
repressure a depleted reservoir. ~lthough the time lower than for most C02 floods, the fact that
to repressure was considerably longer than with 95 percent of the C02 was still in the reservoir at
water, the existing free gas phase in the reservoir the time of the paper could continue to benefit
distributed the C02 throughout, contacting more of recovery.
the OOIP than would have been contacted by miscible
displacement given the unfavorable C02 mobility WI LMINGTON30 The use of i mmi sc i b1e C02 ina WAG
ratio. At start-up in mid-1980, the reservoir flood of highly viscous crude oils to enhance
pressure was an exceptionally low 250 psig. recovery has been demonstrated by Champlin
Immiscible injection of purchased C02 has raised Petroleum (now UPR) in the Wilmington Tar Zone in
the pressure to near the miscibility pressure after the Los Angeles Basin of California. The test
which the recycle gas will be injected in a yet to shows that the displacement efficiency of
be determi ned WAG sequence. Projected incremental immiscible C02 on viscous crudes is not as good as
recovery due to the i mmi sc i b1e effects of C02 is the miscible displacement of lighter crudes by C02.
about 9 percent OOIP with a net utilization of However, since waterflood residual oil saturations
12 mcf/STB. As thi s project starts the tert i ary are typically much higher for the viscous crude
miscible recovery phase, the field is producing oils, opportunities still exist for Significant
over 550 bopd as compared to 30 bopd at the start increased oil recovery. The Tar Zone crude, with a
of C02 injection. The final net utilization of C02 vi scos ity of 283 cp, is swollen to about
is anticipated to be less than 7 mcf/STB, which 105 percent of original volume when contacted with
based on a purchase of 13.7 Bcf of C02 transl ates C02. The viscosity is reduced dramatically to
to an incremental recovery from C02 inject i on of 18 cp when contacted at a pressure of 1080 ps i g.
about 15.6 percent OOIP, immiscible and miscible. By chasing the swollen and less viscous crude oil
with water, the anticipated incremental recovery
LICK CREEK16,28 This full scale C02 flood in will approach 11 percent OOIP. The gross
Bradl ey and Un i on Counties, Arkansas by Ph i 11 ips utilization of C0.2 is calculated to be 6 mcf/STB
Petroleum has successfully proven the viability of with much of th1S supplied through the recycl~
an immiscible WAG process for the recovery of process.
tertiary oil from thin, heavy oil sands. Started
in 1976 using C02 from an ammonia plant, this IMMISCIBLE "HUFF 'N' PUFF"
project is ant i ci pated to recover an incremental
10 percent of the 17°API, 160 cp oil Immiscible Huff 'n' Puff well stimulations appear
originally-in-place in this high permeability to be gaining in popularity possibly due to their
Meakin sandstone reservoir. Injection of a relatively quick payout nature. These single well
40 percent HCPV slug of C02 on a 1:1 WAG ratio was recovery projects util ize C02 from a variety of
done in three phases. The first phase involved sources which is typically trucked to the well
cycl ic C02 injection into all the producers and si~e. This tertiary recovery method is ideally
many of the i nj ectors. Th is helped increase the sU1ted for small leases which cannot stand the
reservoir pressure and allowed wells to be flowed l~rge ~p-front invest~ents associated with many
naturally. The second phase involved injection of fleld-w1de floods. Wh11e the procedure is similar
large ~olumes of C02 into the permanent injectors. to the steam stimulations in the heavy oil basins
The th1rd phase alternated C02 and water injection these cyclic C02 projects are not limited to heavy
into the injectors. After fhis phase, the unit oil since the technique has been successfully used
wi 11 be waterfl ooded. The expected gross to recover 1 ighter oils. While incremental
utilization of C02 is 8.8 mcf/STB, which will net recoveries as a percent of OOIP are not available
to approximately 5.3 mcf/STB. the consensus of the papers reviewed is that thes~
project~ ~o r~cover incremental oil with relatively
IMMISCIBLE--PRODUCING PILOTS low ut111zat10ns of C02. The incremental oil
recovered was production in excess of the base
These two produci ng pil ots, whose parameters are production decline curve and in most cases the
also shown in Table 2, have projected incremental wells were at or near the economic limit prior to
recoveri es of 5 and 10 percent OOIP. In both of the test.
these pilots, it has been qualitatively proven that
C02 can enhance oil recovery, however, it should be The general procedure is to inject large volumes of
noted that the quantity of incremental oil in some C02 down a producing wellbore and then shut-in the
cases is based on data from a much smaller area we Tl fpr a f.ew weeks to allow the COe to soak.
than might be representative of a commercial Follow1ng th1S soak, the well is returned to
application. produ~tion. Some increases in oil rate were
susta1ned for up to 48 months. The efficiencies of
HILLY UPLAND29 This mini test in West Virginia ~he process . are measured by the mcf/STB of
conducted by the All eghany Land & Mi nera 1 Company ~ n~rementa 1 011 recovered and also by the volume
in conjunction with the Department of Energy 1nJected per foot of pay. Utilizations ranged
Morgantown Energy Technology Center showed that low between 1 mcf/STB and slightly over 3 mcf/STB while
504
SPE 18977 W. R. BROCK, L. A. BRYAN 7

stimulations ranged between 0.1 MMcf/ft to TIMBALIER BAy34 This immiscible Huff 'n' Puff test
0.4 MMcf/ft. Shown on Table 3 are some parameters conducted by Chevron, proves the feasibility of
of the projects discussed below. using C02 in this bottomwater-drive sandstone
reservoir in Louisiana. The test in two wells
APPALACHIAN BAIN3l Huff 'n' Puff C02 field tests showed that when properly administered the C02 Huff
on 65 wells in a pressure depleted Appalachian 'n' Puff process can provide for a quick payout
Bas i n reservoi r in eastern Kentucky i nd i cate the with a low capital investment. The results
economi c vi abil ity for 1i ght oil recovery. These indicate that incremental oil was recovered through
tests were conducted in conjunction with a the oil swelling and viscosity reduction effects on
laboratory evaluation at Louisiana State University fractional-flow. As in similar immiscible
which addressed the potential of recovering 1ight appl ications of C02, the process was to inject a
oil with the application of immiscible cyclical C02 large volume of C02 in the producer and then
injection. The field tests targeted the unnamed shut-in for a soak period after which it was
Appalachian field because of the low permeability returned to production. These two tests measured
formation and disappointing pilot waterflood C02 stimulation efficiencies of 0.3-0.36 MMcf/foot
results. The procedure used was to first pull the of pay and C02 utilizations of 1.1-3.2 mcf/STB. The
rods from the well and inject large volumes of C02 tests also showed that for thi s part i cul ar
down the tubing at the rate of several barrels per reservoir a soak period of about 7 weeks did better
minute. The well was then shut-in without than a 4-week soak on one well.
corrosion inhibitors for approximately one week.
After the initial soak period, the well was then WEST COTE BLANCHE BAy32 This C02 Huff 'n' Puff
placed back on production. Response was a sharp project was one of el even such tests conducted by
rise in oil production which continued for 15 to 48 Texaco in South Louisiana between 1984 and 1985 to
months after which production returned to the evaluate tertiary recovery. The results from this
original hyperbol ic decl ine curve. The resulting test in the 14 Sand Reservoir 312 indicate that
low C02 ut i 1i zat ions of about 1 mcf/STB attest to tertiary oil can be effectively recovered using
the economic viability of Huff 'n' Puff in light cyclical C02' The process was the
oil reservoirs. Field tests suggest that the inject-soak-proQuce method of previously discussed
response improves with thicker pay, that C02 huff 'n' puff tests. This particular test involved
reduced the water cut and that a second cyc 1i ca 1 the injection of 8 MMcf of C02 in 16 hours in March
application could recover additional reserves. 1984. Fo 11 owi ng a soak of about four weeks, the
well was placed on continuous production. Within
PARADIS32 This C02 Huff 'n' Puff project was one two weeks, product i on had increased from 6 bopd
of eleven wells in five fields which Texaco tested prior to the test to 170 bopd. The well produced
in South Louisiana during 1984 and 1985. The incrementa 1 oil unt il February 1985. A tot a1 of
results from this test west of New Orleans in the 3267 barrels of incremental oil were produced at a
Paradis Main Pay Sand, Reservoir T, indicate that net C02 utilization of only 2.4 mcf/STB. This test
cyclical use of C02 is effective in the tertiary and others showed that the higher the rate of C02
recovery of 1ight oil. The process i nvo 1ved the inject ion into the reservoi r the further out it
injection of C02 in the well, followed by a soak would finger thereby contacting more oil. Texaco
period after which the well was returned to concluded that the C02 Huff 'n' Puff process of
production. In this particular case, two cycles of cycl i ca 1 injection can recover incremental oil in
C02 were utilized. The first cycle involved the reservoirs of various rock and fluid properties in
injection of 18 MMcf of C02 over a three-day period South Louisiana.
in March 1984 followed by a three week soak. After
being returned to production, the initial rate was SUMMARY
150 bopd as compared to 23 bopd prior to the test.
The well produced 9000 barrels of oil in excess of A variety of methods qualitatively prove the use of
the base decline curve prior to receiving an C02 does enhance the recovery of residual oil from
additional 21 MMcf of C02 in February 1985 over a reservoirs of different depositional environments.
fi ve day peri od. After Dei ng opened up in March These range from the immiscible Huff 'n' Puff
1985, the well flowed 228 bopd. The cumulative single well stimulation to the full-scale miscible
incremental recovery from these two cycles was projects. It has also been used in 1i eu of the
20.7 Mbo. This resulted in a net C02 utilization traditional secondary waterflood. Incremental
of only 1.9 mcf/STB. The tests showed that the recoveries predicted by the various operators
faster the rate of inject i on the further the C02 reviewed ranged from 5 to 22 percent of
will finger out into the reservoir thus contacting original-oil-in-place. Some of these projects were
more oil. more efficient than others as evidenced by the C02
utilization values, which ranged from a 2.4 mcf/STB
TEXAS GULF COAST33 Texaco tested the feasibil ity to 13 mcf/STB on a net basis. Phasing of a project
of an immiscible CO~ Huff 'n' Puff on 28 wells in may minimize the purchased C02 requirements by
Texas Gulf Coast Mlocene Reservoi rs. From these spreading same over a greater period of time and
tests in twelve unnamed oil fields, viscosity may also maximize the use of less expensive
reduct i on and oil swe 11 i ng appear to be the recycled C02.
principal mechanisms of recovery since no
compositional changes were noticed in the produced These projects do show a need for adequate data
oil. These tests were conducted on gravities management in the pri mary and secondary recovery
ranging from 23 to 30 API, and viscosities of
0 0
stages as well as in the tertiary process. This
1.6-33.4 cpo Increased recoveries were only will permit the operators to properly evaluate
slightly improved for the more viscous crudes and appropriate enhanced recovery methods prior to
for lower API gravities. No correlation was seen depletion. Knowledge gained from projects or tests
between the pre-test oil cuts or permeabil it i es, in other parts of the country can be used as a
and the result i ng oil recoveri es. Based on guide in formulating an enhanced recovery plan.
incremental recovery, these tests did show that for However, the predicted recoveries and efficiencies
these reservoi rs a soak peri od of 2 to 3 weeks reported by other projects shoul d be vi ewed
seemed better than shorter or longer times. qualitatively rather than quantitatively since most
505
8 SUMMARY RESULTS OF CO 2 EOR FIELD TESTS 1972-1987 SPE 18977
of the performance extrapolations are from data 11. Keeling, R.J.:"C02 Miscible Flooding Evaluation
relatively early in a project's life. As the of the South Welch Unit, Welch San Andres
projects currently in operation age the performance Field," Paper SPE/DOE 12664 presented at t~e
predictions will be further refined and will become SPE/DOE Fourth Sympos i urn on Enhanced 0,1
more quantitative. Recovery, Tulsa, Oklahoma, April 15-18, 1984.
ACKNOWLEDGEMENT 12. Kirkpatrick, R.K., Flanders, W.A. and DePauw,
R.M.:"Performance of the Twofreds C02 Injection
The authors wish to thank Exxon Company U.S.A. for Project," Paper SPE 14439, presented at the
the permission to publish this paper, and the 60th Annual Technical Conference and Exhibition
i ndi vi dua 1 authors of the reference materi a1 for of the Society of Petroleum Engineers, Las
publishing the results of their EOR projects. They Vegas, Nevada, September 22-25, 1985.
a1so thank those i nvo 1ved in the revi ew of the
paper and Shirley Keesey for her assistance in 13. Kleinsteiber, S.W. :"The Wertz Tensleep C02
preparing the manuscript. Flood: A Review of the Engineering Design and
Initial Performance," Paper SPE 18067 presented
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Basin Oil and Gas Recovery Conference, Midland, Waterflooded Shallow Pennsylvaman Sand in
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Technical Conference and Exposition, Las Vegas,
3. Pittaway, K.R. and Runyan, E.E.:"The Ford Nevada, September 23-26, 1979.
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Paper SPE 17278 presented at the SPE Permi an 16. Cox, B. and Schubert, J.: 1986 EOR Project
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SAC ROC Unit," Paper SPE/DOE 17321 presented at Petroleum Engineers (1983) pp147-151.
the SPE/DOE Enhanced Oil Recovery Sympos i urn,
Tulsa, Oklahoma, April 17-20, 1988. 18. Pittaway, K.R., Albright, J.C. and Hoover,
J.W.:"The Maljamar Carbon Dioxide Pilot: Review
5. Magruder, J.B., Stiles, L.H. and Yelverton, and Results," Paper SPE/DOE 14940 presented at
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Full-Scale C02 Tertiary Project," Paper SPE/DOE Recovery, Tulsa, Oklahoma, April 20-23, 1986.
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Recovery Sympos i urn, Tul sa, Okl ahoma, April 19. Moore, J.S. and Clark, G.C.: "History Match of
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6. Fox, M.J., Simlote, V.N., Stark, K.L. and Oil Recovery Sympos i urn, Tul sa, Okl ahoma, April
Brinlee, L.D.:"Review of C02 Flood, Springer 17-20, 1988.
"A" Sand, NE Purdy Unit, Garvin County,
Oklahoma," Paper SPE/DOE 14938 presented at the 20. McAllister, D.J. :"Evaluation of C02 Flood
SPE/DOE Fifth Symposium on Enhanced Oil Performance: North Coles Levee C02 Pilot, Kern
Recovery, Tulsa, Oklahoma, April 20-23, 1986. County, Cal iforni a," Paper SPE 15'l99 presented
at the 61st Annual Technical Conference and
7. Henderson, L. E. : "The Use of Numeri ca 1 Exhibition of the Society of Petroleum
Simulation to Design a Carbon Dioxide Miscible Engineers, New Orleans, Louisiana, October 5-8,
Displacement Project," Journal of Petroleum 1986.
Technology (December 1974) 1327-1334.
21. Hsie, J.C. and Moore, J.S.:"The Quarantine Bay
8. Pontius, S.B. and Tham, M.J.: "North Cross 4RC C02-WAG Pilot Project: A Post-Flood
(Devonian) Unit C02 Flood -- Review of Flood Eva 1uat ion," Paper SPE 15498 presented at the
Performance and Numerical Simulation Model," 61st Annual Technical Conference and Exhibition
Journal of Petroleum Technology (December 1978) of the Society of Petroleum Engineers, New
1706-1714. Orleans, Louisiana, October 5-8, 1986.
9. "Crosset Devonian Field, North Cross (Devonian) 22. Rowe, H.G., York, S.D. and Ader,
Unit," Enhanced Oil Recovery Field Reports, J.C.:"Slaughter Estate Unit Tertiary Pilot
SPE, Volume 13, No.2 (September 1988) Performance," Paper SPE 9796 presented at the
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Tulsa, Oklahoma, April 5-8, 1981.
10. Larsen, W.K.:"Rangely Weber Sand C02 Project: A
Case History," presented at the Denver SPE 23. Johnston, J.R.:"Weeks Island Gravity Stable C02
MiniSymposium, November 18, 1987. Pilot," Paper SPE/DOE 17351 presented at the
506
SPE 18977 " , W. R. BROCK, L. A. BRYAN 9

SPEjDOE Enhanced Oil Recovery Symposium, Tulsa,


Oklahoma, April 17-20, 1988.
24. Hoiland, R.C., Joyner, H.D. and Stalder,
J. L. : "Case hi story of a Successful Rocky
Mounta in Pil ot CO~ Flood," Paper presented at
the Second Wyoml ng Enhanced Oil Recovery
Symposium, Casper, Wyoming, May 15-16, 1986.
25. Good, P.A. and Downer, D.G.: "Cedar Creek
Anticline Carbon Dioxide Injectivity Test:
Design, Implementation, and Analysis," Paper
SPEjDOE 17326 presented at the SPEjDOE Enhanced
Oil Recovery Symposium, Tulsa, Oklahoma, April
17-20, 1988.
26. Thakur, G.C., Lin, C.J. and Patel, Y.R.:"C02
Minitest, Little Knife Field, ND: A Case
Hi story," Paper SPEjDOE 12704 presented at the
SPEjDOE Fourth Sympos i urn on Enhanced Oil
Recovery, Tulsa, Oklahoma, April 15-18, 1984.
27. Flanders, W.A., Stanberry, W.A. and Martinez,
M. :"Review of C02 Performance of the Hansford
Marmaton Unit," Paper SPEjDOE 17327 presented
at the SPEjDOE Enhanced Oil Recovery Symposium,
Tulsa, Oklahoma, April 17-20, 1988.
28. Reid, T.B. and Robinson, H.J.:"Lick Creek
Meakin Sand Unit Immiscible C02jWaterflood
Project," Paper SPE 9795 presented at the
SPEjDOE Enhanced Oil Recovery Symposium, Tulsa,
Oklahoma, April 6-7, 1981.
29. Watts, R.J., Gehr, J.B., Wasson, J.A., Evans,
D. E. and Locke, C.D.: "A Single C02 Injection
We 11 Mi nitest ina Low- Permeabil ity Carbonate
Reservoir," Paper SPE 9430 presented at the
55th Annual Technical Conference and
Exhibition, Dallas, Texas, September 21-24,
1980.
30. Saner, W. B. and Patton, J. T. : "C02 Recovery of
Heavy Oil: The Wilmington Field Test," Paper
SPE 12082 presented at the 58th Annual
Technical Conference and Exhibition, San
Francisco, California, October 5-8, 1983.
31. Monger, T.G., Ramos, J.C. and Thomas, J.:"Light
Oil Recovery From Cyclic C02 Injection:
Infl uence of Low Pressures, Impure C02, and
Reservoir Gas," Paper SPE 18084 presented at
the 63rd Annual Technical Conference and
Exhibition, Houston, Texas, October 2-5, 1988.
32. Palmer, F.S., Landry, R.W. and Bou-Michael,
S.:"Design and Implementation Of Immiscible
Carbon Dioxide Displacement Projects (C0 2
Huff-Puff) in South Louisiana," Paper SPE 15497
presented at the 61st Annual Technical
Conference and Exhibition, New Orleans,
Louisiana, October 5-8, 1986.
33. Haskin, H.K. and Alston, R.B.:"An Evaluation of
C02 Huff 'n' Puff Field Tests in Texas," Paper
SPE 15502 presented at the 61st Annual
Technical Conference and Exhibition, New
Orleans, Louisiana, October 5-8, 1986.
34. Simpson, M.R.:"The C02 Huff 'n' Puff Process in
a Bottomwater-Drive Reservoir," Paper SPE 16720
presented at the 62nd Annual Technical
Conference and Exhibition, Dallas, Texas,
September 27-30, 1987.

507
SPE 18977

TABLE I
MISCIBLE C02 FLOOD RESERVOIR & FLUID PARAMETERS

RES. NET OIL INCR. GR. NET


DEPTH TEMP. POROS. PERM. PAY GRAV. VISCOS. %HCPV REC. UTll. UTlL.
FIELD NAME STATE RESERVOIR LITHOLOGY ~ DEG.F ~ ~ EL. Ilf."-Ml ----'L INJECT. l!QQJ.E IillLill1 MCF /STB

****F I ELD~ seAL E****


OOLLARHIDE TX DEVONIAN TRIP. CHERT 7,800 120 17.0 9.0 48 40 0.4 30 14.0 2.4
EAST VACUUM NM SAN ANDRES OOLITIC OOLO 4,400 101 11.7 11.0 71 38 1.0 30 8.0 11.1 6.3
FORD GERAL01NE TX DELAWARE SANDSTONE 2,680 83 23.0 64.0 23 40 1.4 30 17.0 9.0 5.0
MEANS TX SAN ANORES OOLOMITE 4,400 100 9.0 20.0 54 29 6.0 55 7.1 15.2 11.0
NORTH CROSS TX DEVONIAN TRIP. CHERT 5,400 106 22.0 S.O 60 44 0.4 40 22.0 18.0 7.8
NORTHEAST PURDY OK SPRINGER SANOSTONE 8,200 148 13.0 44.0 40 35 1.5 30 7.5 6.5 4.6
RANGEL Y CO WEBER SANDSTONE 6,500 160 15.0 5-50.0 110 32 1.6 30 7.5 9.2 5.0
SACROC (17 PATTERN) TX CANYON REEF CARBONATE 6,400 130 9.4 3.0 139 41 0.4 30 7.5 9.7 6.5
SACROC (4 PATTERN) TX CANYON REEF CARBONATE 6,400 130 9.4 3.0 139 41 0.4 30 9.8 9.5 3.2
SOUTH WELCH TX SAN ANDRES DOLOMITE 4,850 92 12.8 13.9 132 34 2.3 25 7.6
TWOFREDS TX DELAWARE SANDSTONE 4,820 104 20.3 33.4 18 36 1.4 40 15.6 15.6 8.0
WERTZ WY TENSLEEP SANDSTONE 6,200 165 10.7 16.0 185 35 1.3 60 10.0 13.0 10.0

***PROOUCING PILOTS***
GARBER OK CREWS SANOSTONE 1,950 95 17.0 57.0 21 47 2.1 35 14.0 6.0
LITTLE CREEK MS TUSCALOOSA SANDSTONE 10,400 248 23.4 75.0 30 39 0.4 160 21.0 27.0 12.6
MALJAMAR NM SAN ANDRES ANHYD. DDLO. 4,050 90 10.0 11.2 49 36 0.8 30 8.2 11.6 10.7
MALJAMAR NM GRAYBURG DOLOMITlC SS 3,700 90 11.0 13.9 23 36 0.8 30 17 .7 8.1 6.1
NORTH COLES LEVEE CA STEVENS SANDSTONE 9,200 235 15.0 9.0 136 36 0.5 63 15.0 7.4
QUARANTINE BAY LA 4SAND (RC) SANDSTONE 8,180 183 26.4 230.0 15 32 0.9 19 20.0 2.4
SLAUGHTER ESTATE TX SAN ANDRES DOLDMITE 4,985 105 12.0 8.0 75 32 2.0 26 20.0 16.7 3.7
WEEKS ISLAND LA S SAND R (B) SANDSTONE 13,000 225 26.0 1200.0 186 33 0.3 24 8.7 7.9 3.3
WEST SUSSEX WY SHANNON SANDSTONE 3,000 104 19.5 28.5 22 39 1.4 30 12.9 8.9

*NON-PROOUCING PILOTS·
LITTLE KNIFE ND MISSION CANYON SUCR. DOLO. 9,800 245 21.0 30.0 16 41 0.2 22 8.0 5.0
SOUTH PINE MT RED RIVER CRYST. DOLO. 9,000 205 17.0 10.0 11 32 1.8 (1)

(1) .. Sor was reduced from 38% after waterflood to 20% after COZ_

TABLE 2
IMMISCLBLE CO2 FLOOO RESERVOIR & FLUID PARAMETERS

RES. NET OIL 1NCR. GR. NET


DEPTH TEMP. POROS. PERM. PAY GRAV. VISCOS. REC. UTIL. UTll.
FIELD NAME STATE RESERVOIR LITHOLOGY IlIhI ~ ~ EL. Ilf."-Ml ----'L l!QQJ.E MCF/STB MCF/STB
~
****F I ELD- SCAl E****
HANSFORD TX MARATHON SANDSTONE 6,500 142 18.1 48.0 20 38 2.2 9.9* 12.0*
LICK CREEK AK MEAKIN SANDSTONE 2,550 118 33.0 1200.0 9 17 160.0 10.1 8.8 5.3

***PRODUCING PILOTS****
HILL Y UPLAND WV GREENBRIER LIMESTONE 1,950 77 14.0 3.0 13 42 1.7 5.0 6.4
WILMINGTON CA TAR ZONE SANDSTONE 2,500 123 24.0 465.0 42 14 283.0 11.0 6.0

* Immiscible results only; does not include miscible effects.

TABLE 3
IMMISCIBLE CO2 HUFF 'N' PUFF RESERVOIR & FLUID PARAMETERS

RES. NET OIL NET


DEPTH TEMP. POROS. PERM. PAY GRAV. VISCOS. INJECTED UTIL.
FIELD NAME illIT RESERVOIR LITHOLOGY DEG.F ~%_'- ~_M_D~ ~ DEG API __C_P~ MMCF/STB MCF/STB
~
****FI ELO- SCALE****
APPALACHIAN BASIN KY UNNAMED SANDSTONE 1,300 68 15.0 10.0 40 32 <0.1 1.0
PARADIS LA RESERVOIR T SANDSTONE 10,300 195 28.0 1033.0 50 38 0.5 0.4 1.9
TEXAS GULF COAST TX MIOCENE SANOSTONE (A) 116-175 23-32.0 15-1700.0 7-68 23-30 1.6-33.4 .1-.7 1.1-33.8
TIMBALIER BAY LA 4900 R(BA) SANDSTONE 4,878 138 32.0 500-2500.0 32 2.8 .3- .4 1. 1-3. 2

(A) Varied from 2,600 feet to 7,756 feet deep.

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