3.

KURVA ISA DAN KADAR AIR KESETIMBANGAN

Jenis Garam ERH(%) Aw g air/g padatan (setimbang)
NaOH 6.80 Lihat Sheet 2 gH
MgCl2 32.40
0.1000
K2CO3 43.20
NaBr 56.00 0.0900 f(x) = 0.0373032337x + 0
NaCl 75.10 R² = 0.9523235656
0.0800
KCl 83.60
0.0700
PERHITUNGAN UMUR SIMPAN 0.0600

g air/g padatan
Product
0.0500
Jenis Kemasan
Critical moisture content (Mc, g H2O/g solid) 0.0400
Surface area of packaging (two sides, A, m²) 0.0300
8
Moisture content in dry basis (Mi, %w/w)
WVTR (g H2O/m².day) at 38 ⁰C RH 95% 0.0200
Initial moisture content (Mi, g H2O/g solid) 0.0100
Initial solid weight per packaging (Ws, gram)
0.0000
Pure Water Vapor Pressure (Pₒ, mmHg) 0.30 0.40 0.50
at 38 ⁰C
Permeability (k/x): (g H2O/m².day/mmHg)
Linear curve of ISA

Moisture Equiblirium (Me, g H2O/g solid) at RH 70%

Moisture Equiblirium (Me, g H2O/g solid) at RH 80% Cari di pers.regresi
Product shelf-life at RH 70% and 30 ⁰C (Me-Mi)/(Me-Mc) Ln (Me-Mi)/(Me-Mc)

Day
Month
Product shelf-life at RH 80% and 30 ⁰C (Me-Mi)/(Me-Mc) Ln (Me-Mi)/(Me-Mc)

Day
Month
 g H₂O/g solid

f(x) = 0.0373032337x + 0.0599015863

R² = 0.9523235656

0.40 0.50 0.60 0.70 0.80 0.90 1.00

Aw
Determine Equiblirium Moisture Content (Me) --- CONTOH 0.955 Solid content (g solid/g total)

Saturated salt solvent. ERH (%) Berat sampel awal (g) Berat sampel saat setimbang (g) g H₂O/g solid

MgCl₂ 38 6.0000 6.1578

K₂CO₃ 47 6.0000 6.1890
Mg(NO₃)₂ 54 6.0000 6.1902
NaCl 75 6.0000 6.2240
KCl 82 6.0000 6.2669
BaCl2 90 6.0000 6.2852

Solid Content (g solid/g total) 0.955 Saturated salt solvent. Aw (ERH/100) g H₂O/g solid
NaCl MgCl₂ 0.38 0.0740
Weight product sample at equiblirium (gram) 6.224 K₂CO₃ 0.47 0.0790
Equiblirium Moisture Content (g H2O/g solid) 0.0848 Mg(NO₃)₂ 0.54 0.0793
Solid Weight (gram) 5.944 NaCl 0.75 0.0848
Moisture (gram) 0.2240 KCl 0.82 0.0917
Total Moisture (gram) 0.5040 BaCl2 0.90 0.0946

Solid Content (g solid/g total)

MgCl2 g H₂O/g solid
Weight product sample at equiblirium (gram) 0.1000
Equiblirium Moisture Content (g H2O/g solid) 0.0900 f(x) = 0.0373032337x + 0.0599015863
Solid Weight (gram) 0.0800 R² = 0.9523235656
0.0700
Moisture (gram)

g air/g padatan
0.0600
Total Moisture (gram) 0.0500
Solid Content (g solid/g total) 0.0400
K2CO3 0.0300
0.0200
Weight product sample at equiblirium (gram)
0.0100
Equiblirium Moisture Content (g H2O/g solid) 0.0000
Solid Weight (gram) 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
Moisture (gram) Aw
Total Moisture (gram)
 0.0000
0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
Aw

Solid Content (g solid/g total)

Mg(NO3)2
Weight product sample at equiblirium (gram)
Equiblirium Moisture Content (g H2O/g solid)
Solid Weight (gram)
Moisture (gram)
Total Moisture (gram)

Solid Content (g solid/g total)

KCl
Weight product sample at equiblirium (gram)
Equiblirium Moisture Content (g H2O/g solid)
Solid Weight (gram)
Moisture (gram)
Total Moisture (gram)

Solid Content (g solid/g total)

KCl
Weight product sample at equiblirium (gram)
Equiblirium Moisture Content (g H2O/g solid)
Solid Weight (gram)
Moisture (gram)
Total Moisture (gram)
1. KARAKTERISTIK AWAL PRODUK (Kadar Air Produk)/Mi
Ulangan W1 (g) W2(sampel) (g)
1 4.140 2.005
2 7.665 2.020
3 5.850 2.010

2.012

Ulangan Berat sampel awal (g)

Berat sampel akhir (g)
1 2.005 1.965
2 2.020 1.980
3 2.010 1.975

berat sampel aw
NaNO2 5.000
K2SO4 5.200
MgCl2 5.200
KCl 5.000

Garam H0 H1
NaNO2 24.900 30.900
K2SO4 21.000 28.300
MgCl2 27.500 33.400
KCl 21.200 28.600

NaNO2 6.000 5.800

K2SO4 7.300 7.500
MgCl2 5.900 5.900
KCl 7.400 7.600

2. PENENTUAN KADAR AIR KRITIS (Mc)

NaNO2
g padatan/g total 0.981
NaNO2 5.00
berat produk saat setimbang 5.900
g air/g padatan 5.7165
berat padatan 5.7876
berat air 0.9000
total berat air 1.0124

K2SO4
g padatan/g total 0.981
K2SO4 5.20
berat produk saat setimbang 8.500
g air/g padatan 1.7564
berat padatan 7.5191
berat air 3.3000
total berat air 4.2809

MgCl2
g padatan/g total 0.981
MgCl2 5.20
berat produk saat setimbang 5.800
g air/g padatan 3.0482
berat padatan 4.8191
berat air 0.6000
total berat air 1.5809

KCl
g padatan/g total 0.981
KCl 5.000
berat produk saat setimbang 7.900
g air/g padatan 1.7828
berat padatan 6.9191
berat air 2.9000
total berat air 3.8809

PERHITUNGAN UMUR SIMPAN

Product cookies sagu keju
Jenis Kemasan PET
Critical moisture content (Mc, g H2O/g solid) 0.024
Surface area of packaging (two sides, A, m²) 0.04239
Moisture content in dry basis (Mi, %w/w) 0.0194

WVTR (g H2O/m².day) at 30 ⁰C RH 95% 9.97

Initial moisture content (Mi, g H2O/g solid) 0.0194
Initial solid weight per packaging (Ws, gram) 200.00
Pure Water Vapor Pressure (Pₒ, mmHg)
at 30 ⁰C 31.82
Permeability (k/x): (g H2O/m².day/mmHg) 0.3133250
Linear curve of ISA Slope (b) Intercept

1.3146 -0.2015

Moisture Equiblirium (Me, g H2O/g solid) at RH 70% 2.7228

Moisture Equiblirium (Me, g H2O/g solid) at RH 80% 1.1534
Product shelf-life at RH 70% and 30 ⁰C (Me-Mi)/(Me-Mc) Ln (Me-Mi)/(Me-Mc)

Day 67.01
Month 2.2
Product shelf-life at RH 80% and 30 ⁰C (Me-Mi)/(Me-Mc) Ln (Me-Mi)/(Me-Mc)

Day 200.10
Month 6.7
UJI UMUR SIMPAN DENGAN METODE KADAR AIR KRITIS

W3 (g) ( setelah oven) W air (g) %KA (wb) %KA (db)

6.105 0.040 2.00 2.04
9.645 0.040 1.98 2.02
7.825 0.035 1.74 1.77
BUKAN GUMPAL 1.91 1.94
7.858

gram air g air/g padatan (db) g padatan/g total

0.040 0.020356234 0.980
0.040 0.020202020 0.980
0.035 0.017721519 0.983
0.0194 0.981
Mo

berat sampel saat setimbang

5.900
8.500
5.800
7.900

H2 H3 H4 H5 H6
30.700 31.200 30.900 30.800 30.800
28.500 28.500 28.900 29.000 29.600
33.400 33.400 33.300 33.400 33.400
28.800 28.800 28.900 29.100 29.100

6.300 6.000 5.900 5.900 5.800

7.500 7.900 8.000 8.600 8.500
5.900 5.800 5.900 5.900 5.800
7.600 7.700 7.900 7.900 7.900

Garam g air/ gram padatan

K2SO4 1.756
KCl 1.783
 MgCl2 3.048
NaNO2 5.717

Grafik Regreasi Linier

7.000

6.000
5.717
5.000
f(x) = 1.3145831139x - 0.210460398
R² = 0.8318779859 Col umn G
4.000
Li near (Col umn G)
3.000 3.048

2.000
1.756 1.783

1.000

0.000
K2SO4 KCl MgCl 2 NaNO2

Perhitungan
Me-Mi 2.7033
Me-Mc 2.6983
Me-Mi/Me-Mc 1.0018745531
0.0018727983

a/Ws 0.00021195
Po/b 24.2050813936

Umur Simpan 67.0130085093 Hari

2.2337669503 Bulan
0.1861472459 Tahun
 R2

0.53
Perhitungan
Me-Mi 1.1340
Me-Mc 1.1289
Me-Mi)/(Me-Mc) Me-Mi/Me-Mc 1.0044804714
0.0044704639
a/Ws 0.00021195
Po/b 30.2788086402
Me-Mi)/(Me-Mc)
Umur Simpan 200.1026966515 Hari
6.6700898884 Bulan

Garam g air/ gram padatan

K2SO4 1.756
KCl 1.783
MgCl2 3.048
NaNO2 5.717
 6.145
9.685
7.860
7.897

H7 H8 H9
30.700 30.800 30.800
29.500 29.200 29.500
33.300 33.300 33.300
29.100 29.000 29.100

5.900 5.900
8.200 8.500
5.800 5.800
7.800 7.900

Mc g padatan 0.981
berat awal sampel 7.858
berat sampel menggumpal 7.897
kadar air kritis 0.024
berat padatan 7.71
 berat air 0.04
total berat air 0.19

Col umn G
Li near (Col umn G)

pada RH 70%
suhu 30
pada RH 80%
pada suhu 30