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Electrolytes: Rhodium plating bath K4 (2.5 g Rh/ ltr.), Palladium plating bath
DEKOR NF, Electrolytic Anti-tarnish, Silver stripping bath H
Situation:
1. The silver castings have particularly many pores on the surfaces.
To 1: Very porous parts should be silver-plated for approximately 5-10 minutes and
be polished SMOOTHLY afterwards. Herewith pores of the surfaces are
closed. Thereafter such parts should not be cleaned ultra sonically as hard
and as long as normally because in this case pores of the surfaces may open
again. This special treatment does not work with fine and thin chains.
To 3: The rinsing process can be optimised by doing the rinsing between Palladium
plating and Rhodium plating by steaming instead of rinsing by dipping in
rinsing water (Chains MUST only be touched when wearing plastic gloves) and
doing additional ultra sonic cleaning, degreasing, acid dip treatment and final
rinsing in hot demineralised water after Rhodium plating.
To 6: Drying process must be done in a centrifugal hot-air dryer. The cotton inserts
inside the centrifugal dryer as well as parts to be dryed must be clean and
must not be covered with any rests of chemicals or any other substances.
To 7: The conductivity of the circulation water is too high. The last rinsing before the
actual electroplating must be done in demineralised/destilled water only. The
demineralised/destilled water has to be replaced by new
demineralised/destilled water every day.
To 10: In order to avoid too low concentrations of organic ingrediants inside the
Palladium plating bath filtering cartridges containing activated carbon should
be used MAXIMUM once every 3 weeks. In the meantime - in between this 3
weeks period - only normal filtering cartridges WITHOUT activated carbon
should be used.
To 11: We do not have any experience with special regeneration cycles which are
different to our standard regeneration instructions.
To 12: The platinised titanium anodes should be exchanged every 1-1.5 years or
when their surfaces become dark. If the electrolyte is not used for a longer
time the anodes should be taken out of the solution. Platinised titanium anodes
should be cleaned by ultra sonic cleaning only.
These tests are executed in different climates. Long-term tests are executed by
wearing necklaces and laying them into shop windows for a certain period. The “Mont
Blanc” test is recommended for tests within a short period.
Results:
In order to get representative results the anodes were cleaned first. The electrolyte
was heaten and 10 grams of potassium cyanide per litre were added. The
electropolishing tests were made at 20 V.
1. test Temperature 53 °C
+10 gr/ltr. potassium cyanide
20 V
- Bad result
2. test Temperature 53 °C
+10 gr/ltr. potassium cyanide
20 V
- Better result
3. test Temperature 55 °C
+10 gr/ltr. potassium cyanide
20 V
- Same result
4. test Temperature 60 °C
+10 gr/ltr. potassium cyanide
20 V
- Bad result; repeated electropolishing and moving of the goods during
electropolishing the results became much better
Result:
The electrolyte was too old. The shelf-life of the electropolishing solution is
amounting approximately 6-8 weeks. The solution gets also exhausted when 400-
500 grams of goods per litre electropolishing solution have been electropolished.
The electropolishing solution must be heated and used at 50-60 °C. If the solution is
older than 6-8 weeks potassium cyanide has to be added to the solution because the
free potassium cyanide inside the electropolishing solution disappears relatively
quickly. If goods to be electropolished are being moved during electropolishing
process the polishing results become much better. Electropolishing is a relatively
aggressive process which easily cracks hidden pores below surfaces resulting in
additional open pores and deepenings. This can cause problems afterwards when
electroplating such goods.
• Degreased
• Rinsed
• Acid dipped
• Rinsed
• Anti-tarnished (3min/3V)
• Rinsed
• Dried
• Tested in a sulphide containing silver blackening agent
• Degreased
• Rinsed
• Acid dipped
• Rinsed
• Anti-tarnished (5min/4V)
• Rinsed
• Dried
• Tested in a sulphide content silver black coloration
2. Corrosion chamber
“Novus”-exsikkator, diameter = 25 cm
Put parts to be tested on a suitable rack made of stainless steel and which is
isolated by a galvanic lacquer.
3. Corrosion atmosphere
Relative humidity = 80 %
Adjusted the humidity by filling 25 ml of nourished sodium sulfide solution into
a 50 ml beaker and put it into an exsikkator - below the hole plate inside the
exsikkator. Furthermore fill 25 ml Thioacetamid into an additional 50 ml beaker
and place it next to the beaker containing the nourished sodium sulfide
solution inside the exsikkator.
4. Corrosion development
Pores on surfaces of tested parts become dark coloured and well visible due
to reactions of sulfides. This test is suitable for substrates which are reacting
sensitively to materials containing sulphuric acid (Ms, Cu, Ag).
Level 1
Level 2