Universidad Nacional Autónoma de México

CURVAS DE VALORACIÓN
ÁCIDO-BASE
Química Analítica 1

Oscar Andrade Avila

Facultad de Estudios Superiores Cuautitlán Campus 1
Un

HOJA DE CALCULO DE LA VALORACION DE UN ACIDO DIPROTICO CON UN BASE FUERTE

Valoración de una solución de un ácido diprótico, C 0 (M)
Con una solución de una base fuerte, C T (M)
pKW pKA1 pKA2 C0 CT V0 V1erPE V2oPE
14 1 3 0.1 0.1 10 10 20
KW KA1 KA2
1E-14 0.1 0.001

6 7 1 2 3 4 5
f V pH [H3O+] [OH-] aH2A aHA- aA2- suma
- -
0.00274274 0.02742742 1.2 0.06309573 1.58489E-13 0.38313999 0.60723597 0.00962404 1
0.121536 1.21536001 1.3 0.05011872 1.99526E-13 0.32948136 0.65740175 0.01311689 1
0.24305748 2.43057475 1.4 0.03981072 2.51189E-13 0.27972168 0.70262908 0.01764924 1
0.35906971 3.59069712 1.5 0.03162278 3.16228E-13 0.23461634 0.74192202 0.02346163 1
0.46761881 4.67618808 1.6 0.02511886 3.98107E-13 0.19456915 0.77459372 0.03083713 1
0.56765228 5.67652282 1.7 0.01995262 5.01187E-13 0.15966634 0.80022729 0.04010637 1
0.65897947 6.58979467 1.8 0.01584893 6.30957E-13 0.12974072 0.81860857 0.05165071 1
0.74213307 7.42133067 1.9 0.01258925 7.94328E-13 0.10444694 0.8296515 0.06590156 1
0.81818182 8.18181818 2 0.01 1E-12 0.08333333 0.83333333 0.08333333 1
0.8885338 8.88533802 2.1 0.00794328 1.25893E-12 0.06590156 0.8296515 0.10444694 1
0.9547534 9.54753405 2.2 0.00630957 1.58489E-12 0.05165071 0.81860857 0.12974072 1
1.01840032 10.1840032 2.3 0.00501187 1.99526E-12 0.04010637 0.80022729 0.15966634 1
1.08089028 10.8089028 2.4 0.00398107 2.51189E-12 0.03083713 0.77459372 0.19456915 1
1.14337523 11.4337523 2.5 0.00316228 3.16228E-12 0.02346163 0.74192202 0.23461634 1
1.20664404 12.0664404 2.6 0.00251189 3.98107E-12 0.01764924 0.70262908 0.27972168 1
1.27105105 12.7105105 2.7 0.00199526 5.01187E-12 0.01311689 0.65740175 0.32948136 1
1.33648516 13.3648516 2.8 0.00158489 6.30957E-12 0.00962404 0.60723597 0.38313999 1
1.40239246 14.0239246 2.9 0.00125893 7.94328E-12 0.00696725 0.5534287 0.43960404 1
1.46785873 14.6785873 3 0.001 1E-11 0.00497512 0.49751244 0.49751244 1
1.53174433 15.3174433 3.1 0.00079433 1.25893E-11 0.00350408 0.44113715 0.55535877 1
1.59284906 15.9284906 3.2 0.00063096 1.58489E-11 0.002435 0.38592117 0.61164383 1
1.65007435 16.5007435 3.3 0.00050119 1.99526E-11 0.00167047 0.33330287 0.66502666 1
1.70255149 17.0255149 3.4 0.00039811 2.51189E-11 0.00113232 0.28442483 0.71444286 1
1.74971562 17.4971562 3.5 0.00031623 3.16228E-11 0.00075917 0.24007068 0.75917015 1
1.79132163 17.9132163 3.6 0.00025119 3.98107E-11 0.00050403 0.20065882 0.79883715 1
1.82741267 18.2741267 3.7 0.00019953 5.01187E-11 0.00033178 0.16628234 0.83338588 1
1.85825918 18.5825918 3.8 0.00015849 6.30957E-11 0.00021678 0.13677723 0.86300599 1
1.88428737 18.8428737 3.9 0.00012589 7.94328E-11 0.00014075 0.11180003 0.88805922 1
1.90601136 19.0601136 4 1E-04 1E-10 9.0901E-05 0.09090083 0.90900827 1
1.92397725 19.2397725 4.1 7.9433E-05 1.25893E-10 5.8449E-05 0.07358325 0.9263583 1
1.93872218 19.3872218 4.2 6.3096E-05 1.58489E-10 3.7447E-05 0.05934872 0.94061383 1
1.95074771 19.5074771 4.3 5.0119E-05 1.99526E-10 2.3919E-05 0.04772558 0.9522505 1
1.96050501 19.6050501 4.4 3.9811E-05 2.51189E-10 1.5242E-05 0.03828592 0.96169884 1
1.9683888 19.683888 4.5 3.1623E-05 3.16228E-10 9.6934E-06 0.03065313 0.96933717 1
1.97473727 19.7473727 4.6 2.5119E-05 3.98107E-10 6.1549E-06 0.02450322 0.97549063 1
1.97983543 19.7983543 4.7 1.9953E-05 5.01187E-10 3.9032E-06 0.01956223 0.98043387 1
1.98392053 19.8392053 4.8 1.5849E-05 6.30957E-10 2.4727E-06 0.01560162 0.9843959 1
1.98718811 19.8718811 4.9 1.2589E-05 7.94328E-10 1.5652E-06 0.01243272 0.98756572 1
1.98979809 19.8979809 5 0.00001 1E-09 9.901E-07 0.00990098 0.99009803 1
1.99188045 19.9188045 5.1 7.9433E-06 1.25893E-09 6.2598E-07 0.00788068 0.9921187 1
1.99354037 19.9354037 5.2 6.3096E-06 1.58489E-09 3.9561E-07 0.00627001 0.99372959 1
1.99486258 19.9486258 5.3 5.0119E-06 1.99526E-09 2.4994E-07 0.00498688 0.99501287 1
1.99591521 19.9591521 5.4 3.9811E-06 2.51189E-09 1.5786E-07 0.00396528 0.99603456 1
1.99675282 19.9675282 5.5 3.1623E-06 3.16228E-09 9.9685E-08 0.00315231 0.99684759 1
1.99741911 19.9741911 5.6 2.5119E-06 3.98107E-09 6.2938E-08 0.00250559 0.99749434 1
1.99794896 19.9794896 5.7 1.9953E-06 5.01187E-09 3.9731E-08 0.00199129 0.99800867 1
1.99837023 19.9837023 5.8 1.5849E-06 6.30957E-09 2.5079E-08 0.00158239 0.99841759 1
1.99870511 19.9870511 5.9 1.2589E-06 7.94328E-09 1.5829E-08 0.00125734 0.99874264 1
1.99897129 19.9897129 6 1E-06 1E-08 9.99E-09 0.000999 0.99900099 1
1.99918284 19.9918284 6.1 7.9433E-07 1.25893E-08 6.3046E-09 0.0007937 0.9992063 1
1.99935098 19.9935098 6.2 6.3096E-07 1.58489E-08 3.9786E-09 0.00063056 0.99936944 1
1.99948462 19.9948462 6.3 5.0119E-07 1.99526E-08 2.5106E-09 0.00050094 0.99949906 1
1.99959086 19.9959086 6.4 3.9811E-07 2.51189E-08 1.5843E-09 0.00039795 0.99960205 1
1.99967533 19.9967533 6.5 3.1623E-07 3.16228E-08 9.9968E-10 0.00031613 0.99968387 1
1.99974253 19.9974253 6.6 2.5119E-07 3.98107E-08 6.308E-10 0.00025113 0.99974887 1
1.99979603 19.9979603 6.7 1.9953E-07 5.01187E-08 3.9803E-10 0.00019949 0.99980051 1
1.99983867 19.9983867 6.8 1.5849E-07 6.30957E-08 2.5115E-10 0.00015846 0.99984154 1
1.99987273 19.9987273 6.9 1.2589E-07 7.94328E-08 1.5847E-10 0.00012588 0.99987412 1
1.99990001 19.9990001 7 1E-07 1E-07 9.999E-11 9.999E-05 0.99990001 1
1.99992197 19.9992197 7.1 7.9433E-08 1.25893E-07 6.3091E-11 7.9427E-05 0.99992057 1
1.99993977 19.9993977 7.2 6.3096E-08 1.58489E-07 3.9808E-11 6.3092E-05 0.99993691 1
1.99995437 19.9995437 7.3 5.0119E-08 1.99526E-07 2.5118E-11 5.0116E-05 0.99994988 1
1.99996653 19.9996653 7.4 3.9811E-08 2.51189E-07 1.5848E-11 3.9809E-05 0.99996019 1
1.99997692 19.9997692 7.5 3.1623E-08 3.16228E-07 9.9997E-12 3.1622E-05 0.99996838 1
1.99998607 19.9998607 7.6 2.5119E-08 3.98107E-07 6.3094E-12 2.5118E-05 0.99997488 1
1.99999448 19.9999448 7.7 1.9953E-08 5.01187E-07 3.981E-12 1.9952E-05 0.99998005 1
2.0000026 20.000026 7.8 1.5849E-08 6.30957E-07 2.5118E-12 1.5849E-05 0.99998415 1
2.00001086 20.0001086 7.9 1.2589E-08 7.94328E-07 1.5849E-12 1.2589E-05 0.99998741 1
2.0000197 20.000197 8 1E-08 1E-06 9.9999E-13 9.9999E-06 0.99999 1
2.00002959 20.0002959 8.1 7.9433E-09 1.25893E-06 6.3095E-13 7.9432E-06 0.99999206 1
2.00004105 20.0004105 8.2 6.3096E-09 1.58489E-06 3.981E-13 6.3095E-06 0.99999369 1
2.0000547 20.000547 8.3 5.0119E-09 1.99526E-06 2.5119E-13 5.0118E-06 0.99999499 1
2.00007126 20.0007126 8.4 3.9811E-09 2.51189E-06 1.5849E-13 3.9811E-06 0.99999602 1
2.00009161 20.0009161 8.5 3.1623E-09 3.16228E-06 1E-13 3.1623E-06 0.99999684 1
2.00011685 20.0011685 8.6 2.5119E-09 3.98107E-06 6.3096E-14 2.5119E-06 0.99999749 1
2.00014831 20.0014831 8.7 1.9953E-09 5.01187E-06 3.9811E-14 1.9953E-06 0.999998 1
2.00018767 20.0018767 8.8 1.5849E-09 6.30957E-06 2.5119E-14 1.5849E-06 0.99999842 1
2.00023702 20.0023702 8.9 1.2589E-09 7.94328E-06 1.5849E-14 1.2589E-06 0.99999874 1
2.000299 20.00299 9 1E-09 1E-05 1E-14 1E-06 0.999999 1
2.00037691 20.0037691 9.1 7.9433E-10 1.25893E-05 6.3096E-15 7.9433E-07 0.99999921 1
2.00047489 20.0047489 9.2 6.3096E-10 1.58489E-05 3.9811E-15 6.3096E-07 0.99999937 1
2.00059818 20.0059818 9.3 5.0119E-10 1.99526E-05 2.5119E-15 5.0119E-07 0.9999995 1
2.00075335 20.0075335 9.4 3.9811E-10 2.51189E-05 1.5849E-15 3.9811E-07 0.9999996 1
2.00094866 20.0094866 9.5 3.1623E-10 3.16228E-05 1E-15 3.1623E-07 0.99999968 1
2.00119454 20.0119454 9.6 2.5119E-10 3.98107E-05 6.3096E-16 2.5119E-07 0.99999975 1
2.00150411 20.0150411 9.7 1.9953E-10 5.01187E-05 3.9811E-16 1.9953E-07 0.9999998 1
2.0018939 20.018939 9.8 1.5849E-10 6.30957E-05 2.5119E-16 1.5849E-07 0.99999984 1
2.00238475 20.0238475 9.9 1.2589E-10 7.94328E-05 1.5849E-16 1.2589E-07 0.99999987 1
2.0030029 20.030029 10 1E-10 1E-04 1E-16 1E-07 0.9999999 1
2.00378145 20.0378145 10.1 7.9433E-11 0.000125893 6.3096E-17 7.9433E-08 0.99999992 1
2.00476216 20.0476216 10.2 6.3096E-11 0.000158489 3.9811E-17 6.3096E-08 0.99999994 1
2.0059977 20.059977 10.3 5.0119E-11 0.000199526 2.5119E-17 5.0119E-08 0.99999995 1
2.00755459 20.0755459 10.4 3.9811E-11 0.000251189 1.5849E-17 3.9811E-08 0.99999996 1
2.0095169 20.095169 10.5 3.1623E-11 0.000316228 1E-17 3.1623E-08 0.99999997 1
2.01199093 20.1199093 10.6 2.5119E-11 0.000398107 6.3096E-18 2.5119E-08 0.99999997 1
2.01511133 20.1511133 10.7 1.9953E-11 0.000501187 3.9811E-18 1.9953E-08 0.99999998 1
2.01904889 20.1904889 10.8 1.5849E-11 0.000630957 2.5119E-18 1.5849E-08 0.99999998 1
2.02402064 20.2402064 10.9 1.2589E-11 0.000794328 1.5849E-18 1.2589E-08 0.99999999 1
2.03030302 20.3030302 11 1E-11 0.001 1E-18 1E-08 0.99999999 1
2.03824928 20.3824928 11.1 7.9433E-12 0.001258925 6.3096E-19 7.9433E-09 0.99999999 1
2.04831249 20.4831249 11.2 6.3096E-12 0.001584893 3.9811E-19 6.3096E-09 0.99999999 1
2.0610765 20.610765 11.3 5.0119E-12 0.001995262 2.5119E-19 5.0119E-09 0.99999999 1
2.07729823 20.7729823 11.4 3.9811E-12 0.002511886 1.5849E-19 3.9811E-09 1 1
2.09796629 20.9796629 11.5 3.1623E-12 0.003162278 1E-19 3.1623E-09 1 1
2.12438396 21.2438396 11.6 2.5119E-12 0.003981072 6.3096E-20 2.5119E-09 1 1
2.15828943 21.5828943 11.7 1.9953E-12 0.005011872 3.9811E-20 1.9953E-09 1 1
2.20203473 22.0203473 11.8 1.5849E-12 0.006309573 2.5119E-20 1.5849E-09 1 1
2.25886049 22.5886049 11.9 1.2589E-12 0.007943282 1.5849E-20 1.2589E-09 1 1
2.33333333 23.3333333 12 1E-12 0.01 1E-20 1E-09 1 1
2.4320723 24.320723 12.1 7.9433E-13 0.012589254 6.3096E-21 7.9433E-10 1 1
2.56501714 25.6501714 12.2 6.3096E-13 0.015848932 3.9811E-21 6.3096E-10 1 1
2.74778052 27.4778052 12.3 5.0119E-13 0.019952623 2.5119E-21 5.0119E-10 1 1
3.00634949 30.0634949 12.4 3.9811E-13 0.025118864 1.5849E-21 3.9811E-10 1 1
3.38742589 33.8742589 12.5 3.1623E-13 0.031622777 1E-21 3.1623E-10 1 1
 Ácido Diprótico 1
14

12

10

0
-5 0 5 10 15 20 25 30 35 40
 HOJA DE CALCULO DE LA VALORACION DE UN ACIDO DIPROTICO CON UN BASE FUERTE
Valoración de una solución de un ácido diprótico, C 0 (M)
Con una solución de una base fuerte, C T (M)
pKW pKA1 pKA2 C0 CT V0 V1erPE V2oPE
14 1 5 0.1 0.1 10 10 20
KW KA1 KA2
1E-14 0.1 0.00001

6 7 1 2 3 4 5
f V pH [H3O+] [OH-] aH2A aHA- aA2- suma
-
-0.0108438 0.10843796 1.2 0.06309573 1.58489E-13 0.38682559 0.61307724 9.7166E-05 1
0.10999924 1.09999239 1.3 0.05011872 1.99526E-13 0.33381621 0.6660509 0.00013289 1
0.22700432 2.27004315 1.4 0.03981072 2.51189E-13 0.2846961 0.71512427 0.00017963 1
0.33718865 3.3718865 1.5 0.03162278 3.16228E-13 0.24019537 0.75956444 0.0002402 1
0.43832982 4.38329816 1.6 0.02511886 3.98107E-13 0.20069615 0.79898577 0.00031808 1
0.52906167 5.29061673 1.7 0.01995262 5.01187E-13 0.16626806 0.83331429 0.00041765 1
0.60882961 6.08829613 1.8 0.01584893 6.30957E-13 0.13673242 0.86272324 0.00054434 1
0.67775165 6.77751655 1.9 0.01258925 7.94328E-13 0.11173694 0.88755805 0.00070501 1
0.73643795 7.36437949 2 0.01 1E-12 0.09082652 0.90826521 0.00090827 1
0.78581108 7.85811077 2.1 0.00794328 1.25893E-12 0.07350183 0.92533324 0.00116493 1
0.82695307 8.26953071 2.2 0.00630957 1.58489E-12 0.05926259 0.9392488 0.00148861 1
0.86098979 8.60989789 2.3 0.00501187 1.99526E-12 0.04763621 0.95046736 0.00189643 1
0.88901271 8.89012706 2.4 0.00398107 2.51189E-12 0.03819424 0.95939587 0.00240989 1
0.91203245 9.12032447 2.5 0.00316228 3.16228E-12 0.03055975 0.96638427 0.00305598 1
0.93095649 9.30956488 2.6 0.00251189 3.98107E-12 0.02440858 0.97172293 0.0038685 1
0.9465837 9.46583702 2.7 0.00199526 5.01187E-12 0.01946665 0.97564355 0.0048898 1
0.95960972 9.59609716 2.8 0.00158489 6.30957E-12 0.01550536 0.97832185 0.00617279 1
0.97063863 9.70638632 2.9 0.00125893 7.94328E-12 0.01233597 0.97988057 0.00778347 1
0.98019802 9.8019802 3 0.001 1E-11 0.00980392 0.98039216 0.00980392 1
0.98875525 9.88755253 3.1 0.00079433 1.25893E-11 0.00778347 0.97988057 0.01233597 1
0.99673402 9.96734023 3.2 0.00063096 1.58489E-11 0.00617279 0.97832185 0.01550536 1
1.0045304 10.045304 3.3 0.00050119 1.99526E-11 0.0048898 0.97564355 0.01946665 1
1.01252806 10.1252806 3.4 0.00039811 2.51189E-11 0.0038685 0.97172293 0.02440858 1
1.02111246 10.2111246 3.5 0.00031623 3.16228E-11 0.00305598 0.96638427 0.03055975 1
1.0306835 10.306835 3.6 0.00025119 3.98107E-11 0.00240989 0.95939587 0.03819424 1
1.04166612 10.4166612 3.7 0.00019953 5.01187E-11 0.00189643 0.95046736 0.04763621 1
1.05451779 10.5451779 3.8 0.00015849 6.30957E-11 0.00148861 0.9392488 0.05926259 1
1.06973127 10.6973127 3.9 0.00012589 7.94328E-11 0.00116493 0.92533324 0.07350183 1
1.08783043 10.8783043 4 1E-04 1E-10 0.00090827 0.90826521 0.09082652 1
1.10935641 11.0935641 4.1 7.9433E-05 1.25893E-10 0.00070501 0.88755805 0.11173694 1
1.13484109 11.3484109 4.2 6.3096E-05 1.58489E-10 0.00054434 0.86272324 0.13673242 1
1.16476547 11.6476547 4.3 5.0119E-05 1.99526E-10 0.00041765 0.83331429 0.16626806 1
1.19950244 11.9950244 4.4 3.9811E-05 2.51189E-10 0.00031808 0.79898577 0.20069615 1
1.23924707 12.3924707 4.5 3.1623E-05 3.16228E-10 0.0002402 0.75956444 0.24019537 1
1.28394278 12.8394278 4.6 2.5119E-05 3.98107E-10 0.00017963 0.71512427 0.2846961 1
1.33321779 13.3321779 4.7 1.9953E-05 5.01187E-10 0.00013289 0.6660509 0.33381621 1
1.38635023 13.8635023 4.8 1.5849E-05 6.30957E-10 9.7166E-05 0.61307724 0.38682559 1
1.44227971 14.4227971 4.9 1.2589E-05 7.94328E-10 7.0156E-05 0.55727253 0.44265731 1
1.49967506 14.9967506 5 0.00001 1E-09 4.9998E-05 0.499975 0.499975 1
1.55705379 15.5705379 5.1 7.9433E-06 1.25893E-09 3.5163E-05 0.4426728 0.55729204 1
1.61293262 16.1293262 5.2 6.3096E-06 1.58489E-09 2.4409E-05 0.38685374 0.61312185 1
1.66597798 16.6597798 5.3 5.0119E-06 1.99526E-09 1.6732E-05 0.33385499 0.66612828 1
1.71512528 17.1512528 5.4 3.9811E-06 2.51189E-09 1.1336E-05 0.28474402 0.71524464 1
1.75964638 17.5964638 5.5 3.1623E-06 3.16228E-09 7.5974E-06 0.24025125 0.75974115 1
1.79916072 17.9916072 5.6 2.5119E-06 3.98107E-09 5.0428E-06 0.200759 0.79923596 1
1.83359999 18.3359999 5.7 1.9953E-06 5.01187E-09 3.3189E-06 0.16633698 0.8336597 1
1.86314387 18.6314387 5.8 1.5849E-06 6.30957E-09 2.1682E-06 0.13680659 0.86319124 1
1.88814544 18.8814544 5.9 1.2589E-06 7.94328E-09 1.4077E-06 0.11181561 0.88818298 1
1.90906037 19.0906037 6 1E-06 1E-08 9.0909E-07 0.09090901 0.90909008 1
1.92638844 19.2638844 6.1 7.9433E-07 1.25893E-08 5.8453E-07 0.07358751 0.9264119 1
1.94063024 19.4063024 6.2 6.3096E-07 1.58489E-08 3.7448E-07 0.05935092 0.9406487 1
1.9522586 19.522586 6.3 5.0119E-07 1.99526E-08 2.392E-07 0.04772671 0.95227305 1
1.96170215 19.6170215 6.4 3.9811E-07 2.51189E-08 1.5242E-07 0.0382865 0.96171335 1
1.96933793 19.6933793 6.5 3.1623E-07 3.16228E-08 9.6935E-08 0.03065343 0.96934648 1
1.97549022 19.7549022 6.6 2.5119E-07 3.98107E-08 6.155E-08 0.02450337 0.97549657 1
1.98043317 19.8043317 6.7 1.9953E-07 5.01187E-08 3.9032E-08 0.0195623 0.98043766 1
1.98439544 19.8439544 6.8 1.5849E-07 6.30957E-08 2.4727E-08 0.01560166 0.98439831 1
1.98756585 19.8756585 6.9 1.2589E-07 7.94328E-08 1.5652E-08 0.01243274 0.98756725 1
1.99009899 19.9009899 7 1E-07 1E-07 9.901E-09 0.00990099 0.990099 1
1.99212069 19.9212069 7.1 7.9433E-08 1.25893E-07 6.2598E-09 0.00788068 0.99211931 1
1.99373284 19.9373284 7.2 6.3096E-08 1.58489E-07 3.9561E-09 0.00627001 0.99372998 1
1.99501759 19.9501759 7.3 5.0119E-08 1.99526E-07 2.4994E-09 0.00498688 0.99501312 1
1.99604104 19.9604104 7.4 3.9811E-08 2.51189E-07 1.5786E-09 0.00396529 0.99603471 1
1.99685622 19.9685622 7.5 3.1623E-08 3.16228E-07 9.9685E-10 0.00315231 0.99684769 1
1.99750559 19.9750559 7.6 2.5119E-08 3.98107E-07 6.2938E-10 0.00250559 0.99749441 1
1.99802314 19.9802314 7.7 1.9953E-08 5.01187E-07 3.9731E-10 0.00199129 0.99800871 1
1.99843606 19.9843606 7.8 1.5849E-08 6.30957E-07 2.5079E-10 0.00158239 0.99841761 1
1.9987661 19.987661 7.9 1.2589E-08 7.94328E-07 1.5829E-10 0.00125734 0.99874266 1
1.99903069 19.9903069 8 1E-08 1E-06 9.99E-11 0.000999 0.999001 1
1.99924382 19.9924382 8.1 7.9433E-09 1.25893E-06 6.3046E-11 0.0007937 0.9992063 1
1.99941679 19.9941679 8.2 6.3096E-09 1.58489E-06 3.9786E-11 0.00063056 0.99936944 1
1.99955876 19.9955876 8.3 5.0119E-09 1.99526E-06 2.5106E-11 0.00050094 0.99949906 1
1.99967728 19.9967728 8.4 3.9811E-09 2.51189E-06 1.5843E-11 0.00039795 0.99960205 1
1.99977864 19.9977864 8.5 3.1623E-09 3.16228E-06 9.9968E-12 0.00031613 0.99968387 1
1.99986823 19.9986823 8.6 2.5119E-09 3.98107E-06 6.308E-12 0.00025113 0.99974887 1
1.99995081 19.9995081 8.7 1.9953E-09 5.01187E-06 3.9803E-12 0.00019949 0.99980051 1
2.00003078 20.0003078 8.8 1.5849E-09 6.30957E-06 2.5115E-12 0.00015846 0.99984154 1
2.00011239 20.0011239 8.9 1.2589E-09 7.94328E-06 1.5847E-12 0.00012588 0.99987412 1
2.0002 20.002 9 1E-09 1E-05 9.999E-13 9.999E-05 0.99990001 1
2.00029826 20.0029826 9.1 7.9433E-10 1.25893E-05 6.3091E-13 7.9427E-05 0.99992057 1
2.00041242 20.0041242 9.2 6.3096E-10 1.58489E-05 3.9808E-13 6.3092E-05 0.99993691 1
2.00054856 20.0054856 9.3 5.0119E-10 1.99526E-05 2.5118E-13 5.0116E-05 0.99994988 1
2.00071392 20.0071392 9.4 3.9811E-10 2.51189E-05 1.5848E-13 3.9809E-05 0.99996019 1
2.00091734 20.0091734 9.5 3.1623E-10 3.16228E-05 9.9997E-14 3.1622E-05 0.99996838 1
2.00116966 20.0116966 9.6 2.5119E-10 3.98107E-05 6.3094E-14 2.5118E-05 0.99997488 1
2.00148435 20.0148435 9.7 1.9953E-10 5.01187E-05 3.981E-14 1.9952E-05 0.99998005 1
2.0018782 20.018782 9.8 1.5849E-10 6.30957E-05 2.5118E-14 1.5849E-05 0.99998415 1
2.00237228 20.0237228 9.9 1.2589E-10 7.94328E-05 1.5849E-14 1.2589E-05 0.99998741 1
2.00299299 20.0299299 10 1E-10 1E-04 9.9999E-15 9.9999E-06 0.99999 1
2.00377358 20.0377358 10.1 7.9433E-11 0.000125893 6.3095E-15 7.9432E-06 0.99999206 1
2.00475591 20.0475591 10.2 6.3096E-11 0.000158489 3.981E-15 6.3095E-06 0.99999369 1
2.00599273 20.0599273 10.3 5.0119E-11 0.000199526 2.5119E-15 5.0118E-06 0.99999499 1
2.00755064 20.0755064 10.4 3.9811E-11 0.000251189 1.5849E-15 3.9811E-06 0.99999602 1
2.00951375 20.0951375 10.5 3.1623E-11 0.000316228 1E-15 3.1623E-06 0.99999684 1
2.01198843 20.1198843 10.6 2.5119E-11 0.000398107 6.3096E-16 2.5119E-06 0.99999749 1
2.01510935 20.1510935 10.7 1.9953E-11 0.000501187 3.9811E-16 1.9953E-06 0.999998 1
2.01904732 20.1904732 10.8 1.5849E-11 0.000630957 2.5119E-16 1.5849E-06 0.99999842 1
2.02401938 20.2401938 10.9 1.2589E-11 0.000794328 1.5849E-16 1.2589E-06 0.99999874 1
2.03030202 20.3030202 11 1E-11 0.001 1E-16 1E-06 0.999999 1
2.03824849 20.3824849 11.1 7.9433E-12 0.001258925 6.3096E-17 7.9433E-07 0.99999921 1
2.04831186 20.4831186 11.2 6.3096E-12 0.001584893 3.9811E-17 6.3096E-07 0.99999937 1
2.06107599 20.6107599 11.3 5.0119E-12 0.001995262 2.5119E-17 5.0119E-07 0.9999995 1
2.07729783 20.7729783 11.4 3.9811E-12 0.002511886 1.5849E-17 3.9811E-07 0.9999996 1
2.09796597 20.9796597 11.5 3.1623E-12 0.003162278 1E-17 3.1623E-07 0.99999968 1
2.1243837 21.243837 11.6 2.5119E-12 0.003981072 6.3096E-18 2.5119E-07 0.99999975 1
2.15828922 21.5828922 11.7 1.9953E-12 0.005011872 3.9811E-18 1.9953E-07 0.9999998 1
2.20203456 22.0203456 11.8 1.5849E-12 0.006309573 2.5119E-18 1.5849E-07 0.99999984 1
2.25886035 22.5886035 11.9 1.2589E-12 0.007943282 1.5849E-18 1.2589E-07 0.99999987 1
2.33333322 23.3333322 12 1E-12 0.01 1E-18 1E-07 0.9999999 1
2.43207221 24.3207221 12.1 7.9433E-13 0.012589254 6.3096E-19 7.9433E-08 0.99999992 1
2.56501706 25.6501706 12.2 6.3096E-13 0.015848932 3.9811E-19 6.3096E-08 0.99999994 1
2.74778046 27.4778046 12.3 5.0119E-13 0.019952623 2.5119E-19 5.0119E-08 0.99999995 1
3.00634944 30.0634944 12.4 3.9811E-13 0.025118864 1.5849E-19 3.9811E-08 0.99999996 1
3.38742584 33.8742584 12.5 3.1623E-13 0.031622777 1E-19 3.1623E-08 0.99999997 1
 Ácido Diprótico 2
14

12

10

0
-5 0 5 10 15 20 25 30 35 40
 HOJA DE CALCULO DE LA VALORACION DE UN ACIDO DIPROTICO CON UN BASE FUERTE
Valoración de una solución de un ácido diprótico, C 0 (M)
Con una solución de una base fuerte, C T (M)
pKW pKA1 pKA2 C0 CT V0 V1erPE V2oPE
14 6.2 10.3 0.1 0.1 10 10 20
KW KA1 KA2
1E-14 6.3096E-07 5.0119E-11

6 7 1 2 3 4 5 6
f V pH [H3O+] [OH-] aH2A aHA- aA2- suma
0.00115474 0.01154745 3.7 0.00019953 5.01187E-11 0.99684769 0.00315231 7.9182E-10 1
0.00237663 0.02376629 3.8 0.00015849 6.30957E-11 0.99603471 0.00396529 1.2539E-09 1
0.00372327 0.03723271 3.9 0.00012589 7.94328E-11 0.99501312 0.00498688 1.9853E-09 1
0.00526475 0.05264755 4 1E-04 1E-10 0.99372998 0.00627001 3.1425E-09 1
0.00708074 0.07080742 4.1 7.9433E-05 1.25893E-10 0.99211931 0.00788068 4.9724E-09 1
0.0092642 0.09264205 4.2 6.3096E-05 1.58489E-10 0.990099 0.00990099 7.8646E-09 1
0.0119256 0.11925598 4.3 5.0119E-05 1.99526E-10 0.98756725 0.01243274 1.2433E-08 1
0.01519755 0.15197546 4.4 3.9811E-05 2.51189E-10 0.98439832 0.01560166 1.9641E-08 1
0.01924006 0.19240056 4.5 3.1623E-05 3.16228E-10 0.98043767 0.0195623 3.1004E-08 1
0.02424619 0.24246189 4.6 2.5119E-05 3.98107E-10 0.97549658 0.02450337 4.8891E-08 1
0.03044799 0.30447985 4.7 1.9953E-05 5.01187E-10 0.9693465 0.03065343 7.6998E-08 1
0.03812222 0.38122217 4.8 1.5849E-05 6.30957E-10 0.96171338 0.0382865 1.2107E-07 1
0.04759522 0.47595216 4.9 1.2589E-05 7.94328E-10 0.9522731 0.04772671 1.9E-07 1
0.05924561 0.59245606 5 0.00001 1E-09 0.94064878 0.05935093 2.9746E-07 1
0.07350319 0.73503193 5.1 7.9433E-06 1.25893E-09 0.92641201 0.07358752 4.6431E-07 1
0.09084166 0.90841659 5.2 6.3096E-06 1.58489E-09 0.90909025 0.09090903 7.2212E-07 1
0.11176218 1.11762183 5.3 5.0119E-06 1.99526E-09 0.88818324 0.11181564 1.1182E-06 1
0.13676487 1.36764871 5.4 3.9811E-06 2.51189E-09 0.86319162 0.13680665 1.7223E-06 1
0.16630552 1.6630552 5.5 3.1623E-06 3.16228E-09 0.83366027 0.16633709 2.6363E-06 1
0.2007371 2.00737103 5.6 2.5119E-06 3.98107E-09 0.79923679 0.2007592 4.0057E-06 1
0.24023901 2.40239009 5.7 1.9953E-06 5.01187E-09 0.75974234 0.24025162 6.0348E-06 1
0.28474241 2.84742413 5.8 1.5849E-06 6.30957E-09 0.71524631 0.28474468 9.0044E-06 1
0.33386603 3.33866034 5.9 1.2589E-06 7.94328E-09 0.66613057 0.33385614 1.3291E-05 1
0.38688073 3.86880726 6 1E-06 1E-08 0.61312493 0.38685568 1.9389E-05 1
0.44272059 4.42720585 6.1 7.9433E-07 1.25893E-08 0.55729607 0.442676 2.7931E-05 1
0.50005035 5.00050345 6.2 6.3096E-07 1.58489E-08 0.49998014 0.49998014 3.9715E-05 1
0.55738454 5.57384537 6.3 5.0119E-07 1.99526E-08 0.4426637 0.55728058 5.5728E-05 1
0.61323785 6.13237846 6.4 3.9811E-07 2.51189E-08 0.38683332 0.6130895 7.7183E-05 1
0.66627549 6.66275491 6.5 3.1623E-07 3.16228E-08 0.33382533 0.6660691 0.00010556 1
0.71543245 7.15432447 6.6 2.5119E-07 3.98107E-08 0.28470662 0.71515069 0.00014269 1
0.75998094 7.59980942 6.7 1.9953E-07 5.01187E-08 0.24020723 0.75960196 0.0001908 1
0.79954168 7.9954168 6.8 1.5849E-07 6.30957E-08 0.20070928 0.79903804 0.00025268 1
0.83404858 8.34048581 6.9 1.2589E-07 7.94328E-08 0.16628234 0.83338588 0.00033178 1
0.86368471 8.63684706 7 1E-07 1E-07 0.13674773 0.86281984 0.00043243 1
0.88880783 8.88807827 7.1 7.9433E-08 1.25893E-07 0.11175314 0.88768676 0.00056009 1
0.90987993 9.09879926 7.2 6.3096E-08 1.58489E-07 0.09084349 0.90843491 0.0007216 1
0.92740899 9.27408988 7.3 5.0119E-08 1.99526E-07 0.07351945 0.925555 0.00092555 1
0.94190617 9.41906169 7.4 3.9811E-08 2.51189E-07 0.05928074 0.93953645 0.00118281 1
0.95385774 9.5385774 7.5 3.1623E-08 3.16228E-07 0.0476548 0.95083823 0.00150698 1
0.96370934 9.63709342 7.6 2.5119E-08 3.98107E-07 0.03821318 0.95987163 0.0019152 1
0.97185949 9.7185949 7.7 1.9953E-08 5.01187E-07 0.03057897 0.96699205 0.00242897 1
0.97865946 9.78659463 7.8 1.5849E-08 6.30957E-07 0.02442801 0.97249668 0.0030753 1
0.98441728 9.84417285 7.9 1.2589E-08 7.94328E-07 0.01948625 0.97662574 0.00388802 1
0.98940409 9.89404086 8 1E-08 1E-06 0.01552507 0.97956548 0.00490946 1
0.99386174 9.93861739 8.1 7.9433E-09 1.25893E-06 0.01235575 0.98145171 0.00619254 1
0.99801108 9.98011076 8.2 6.3096E-09 1.58489E-06 0.00982373 0.982373 0.00780327 1
1.00206031 10.0206031 8.3 5.0119E-09 1.99526E-06 0.00780327 0.982373 0.00982373 1
1.00621352 10.0621352 8.4 3.9811E-09 2.51189E-06 0.00619254 0.98145171 0.01235575 1
1.01067913 10.1067913 8.5 3.1623E-09 3.16228E-06 0.00490946 0.97956548 0.01552507 1
1.01567842 10.1567842 8.6 2.5119E-09 3.98107E-06 0.00388802 0.97662574 0.01948625 1
1.02145398 10.2145398 8.7 1.9953E-09 5.01187E-06 0.0030753 0.97249668 0.02442801 1
1.02827794 10.2827794 8.8 1.5849E-09 6.30957E-06 0.00242897 0.96699205 0.03057897 1
1.03645972 10.3645972 8.9 1.2589E-09 7.94328E-06 0.0019152 0.95987163 0.03821318 1
1.04635244 10.4635244 9 1E-09 1E-05 0.00150698 0.95083823 0.0476548 1
1.05835705 10.5835705 9.1 7.9433E-10 1.25893E-05 0.00118281 0.93953645 0.05928074 1
1.07292241 10.7292241 9.2 6.3096E-10 1.58489E-05 0.00092555 0.925555 0.07351945 1
1.090539 10.90539 9.3 5.0119E-10 1.99526E-05 0.0007216 0.90843491 0.09084349 1
1.11172348 11.1172348 9.4 3.9811E-10 2.51189E-05 0.00056009 0.88768676 0.11175314 1
1.13699106 11.3699106 9.5 3.1623E-10 3.16228E-05 0.00043243 0.86281984 0.13674773 1
1.16681319 11.6681319 9.6 2.5119E-10 3.98107E-05 0.00033178 0.83338588 0.16628234 1
1.20155999 12.0155999 9.7 1.9953E-10 5.01187E-05 0.00025268 0.79903804 0.20070928 1
1.24143067 12.4143067 9.8 1.5849E-10 6.30957E-05 0.0001908 0.75960196 0.24020723 1
1.28638006 12.8638006 9.9 1.2589E-10 7.94328E-05 0.00014269 0.71515069 0.28470662 1
1.33605582 13.3605582 10 1E-10 1E-04 0.00010556 0.6660691 0.33382533 1
1.38976467 13.8976467 10.1 7.9433E-11 0.000125893 7.7183E-05 0.6130895 0.38683332 1
1.44648538 14.4648538 10.2 6.3096E-11 0.000158489 5.5728E-05 0.55728058 0.4426637 1
1.50493844 15.0493844 10.3 5.0119E-11 0.000199526 3.9715E-05 0.49998014 0.49998014 1
1.56370788 15.6370788 10.4 3.9811E-11 0.000251189 2.7931E-05 0.442676 0.55729607 1
1.62139512 16.2139512 10.5 3.1623E-11 0.000316228 1.9389E-05 0.38685568 0.61312493 1
1.67677371 16.7677371 10.6 2.5119E-11 0.000398107 1.3291E-05 0.33385614 0.66613057 1
1.72891428 17.2891428 10.7 1.9953E-11 0.000501187 9.0044E-06 0.28474468 0.71524631 1
1.77725963 17.7725963 10.8 1.5849E-11 0.000630957 6.0348E-06 0.24025162 0.75974234 1
1.82164591 18.2164591 10.9 1.2589E-11 0.000794328 4.0057E-06 0.2007592 0.79923679 1
1.86228044 18.6228044 11 1E-11 0.001 2.6363E-06 0.16633709 0.83366027 1
1.8996949 18.996949 11.1 7.9433E-12 0.001258925 1.7223E-06 0.13680665 0.86319162 1
1.93469388 19.3469388 11.2 6.3096E-12 0.001584893 1.1182E-06 0.11181564 0.88818324 1
1.96831521 19.6831521 11.3 5.0119E-12 0.001995262 7.2212E-07 0.09090903 0.90909025 1
 2.0018137 20.018137 11.4 3.9811E-12 0.002511886 4.6431E-07 0.07358752 0.92641201 1
2.03667663 20.3667663 11.5 3.1623E-12 0.003162278 2.9746E-07 0.05935093 0.94064878 1
2.07467805 20.7467805 11.6 2.5119E-12 0.003981072 1.9E-07 0.04772671 0.9522731 1
2.11798256 21.1798256 11.7 1.9953E-12 0.005011872 1.2107E-07 0.0382865 0.96171338 1
2.16931679 21.6931679 11.8 1.5849E-12 0.006309573 7.6998E-08 0.03065343 0.9693465 1
2.2322427 22.322427 11.9 1.2589E-12 0.007943282 4.8891E-08 0.02450337 0.97549658 1
2.31159737 23.1159737 12 1E-12 0.01 3.1004E-08 0.0195623 0.98043767 1
2.41422358 24.1422358 12.1 7.9433E-13 0.012589254 1.9641E-08 0.01560166 0.98439832 1
2.55024281 25.5024281 12.2 6.3096E-13 0.015848932 1.2433E-08 0.01243274 0.98756725 1
2.73541159 27.3541159 12.3 5.0119E-13 0.019952623 7.8646E-09 0.00990099 0.990099 1
2.99582522 29.9582522 12.4 3.9811E-13 0.025118864 4.9724E-09 0.00788068 0.99211931 1
3.37825614 33.7825614 12.5 3.1623E-13 0.031622777 3.1425E-09 0.00627001 0.99372998 1
3.97599069 39.7599069 12.6 2.5119E-13 0.039810717 1.9853E-09 0.00498688 0.99501312 1

Ácido Diprótico 3
14

12

10

0
0 5 10 15 20 25 30 35 40 45
 HOJA DE CALCULO DE LA VALORACION DE UN ACIDO TRIPROTICO CON UN BASE FUERTE
Valoración de una solución de un ácido triprótico, C 0 (M)
Con una solución de una base fuerte, C T (M)
pKW pKA1 pKA2 pKA3 C0 CT V0 V1erPE V2oPE V3oPE
14 2 7 12 0.1 0.1 20 20 40 60
KW KA1 KA2 KA3
1E-14 0.01 0.0000001 1E-12

0.0268229 0.5364586 0.0251188 0.7152519 0.2847469

3 8 1.6 6 3.98107E-13 4 3 1.1336E-06 0 1
0.1119918 0.0199526 0.6661383 0.3338600
3 2.2398365 1.7 2 5.01187E-13 1 2 1.67326E-06 0 1
0.1971341 3.9426828 0.0158489 0.6131353 0.3868622
4 4 1.8 3 6.30957E-13 2 4 2.44094E-06 0 1
0.2813779 0.0125892 0.5573096 0.4426868
2 5.6275584 1.9 5 7.94328E-13 7 1 3.51639E-06 0 1
0.3636431 7.2728636
8 4 2 0.01 1E-12 0.4999975 0.4999975 4.99998E-06 0 1
0.4427222 8.8544450 0.0079432 0.4426852 0.5573077
5 7 2.1 8 1.25893E-12 6 2 7.01609E-06 0 1
0.5174083 10.348166 0.0063095 0.3868594 0.6131308
1 1 2.2 7 1.58489E-12 2 6 9.71747E-06 0 1
0.5866369 11.732738 0.0050118 0.3338561 0.6661305
4 7 2.3 7 1.99526E-12 4 7 1.32911E-05 2.7756E-15 1
0.6496039 12.992078 0.0039810 0.2847421
2 4 2.4 7 2.51189E-12 3 0.7152399 1.7966E-05 4.5519E-15 1
0.7058335 14.116670 0.0031622 0.7597286
3 6 2.5 8 3.16228E-12 0.2402473 7 2.40247E-05 7.6605E-15 1
0.7551898 15.103796 0.0025118 0.2007536 0.7992145
2 4 2.6 9 3.98107E-12 2 6 3.18173E-05 1.2768E-14 1
0.7978395 15.956791 0.0019952 0.1663305 0.8336276
8 7 2.7 6 5.01187E-12 8 4 4.17804E-05 2.0983E-14 1
0.8341851 16.683702 0.0015848 0.1367994
5 9 2.8 9 6.30957E-12 4 0.8631461 5.44608E-05 3.4417E-14 1
0.8647863 17.295727 0.0012589 0.1118078 0.8881215
9 9 2.9 3 7.94328E-12 8 7 7.0546E-05 5.6066E-14 1
0.0909008 0.9090082
0.8902872 17.805744 3 0.001 1E-11 3 7 9.09008E-05 9.0705E-14 1
0.9113552 18.227104 0.0007943 0.0735789 0.9263044 0.00011661
1 1 3.1 3 1.25893E-11 7 1 5 1.4666E-13 1
0.9286380 18.572761 0.0006309 0.9405088 0.00014906
8 6 3.2 6 1.58489E-11 0.0593421 4 1 2.3637E-13 1
0.9427355 18.854711 0.0005011 0.0477176 0.9520923 0.00018996
7 4 3.3 9 1.99526E-11 5 8 7 3.7892E-13 1
0.9541845 19.083690 0.0003981 0.0382772 0.9614812 0.00024151
1 2 3.4 1 2.51189E-11 6 3 3 6.0663E-13 1
0.9634534 19.269068 0.0003162 0.0306440 0.9690495
2 4 3.5 3 3.16228E-11 4 2 0.00030644 9.6911E-13 1
0.9709435 19.418871 0.0002511 0.0244938 0.9751179 0.00038820
6 2 3.6 9 3.98107E-11 6 4 1 1.5453E-12 1
0.9769938 19.539876 0.0001995 0.9799561 0.00049114
3 5 3.7 3 5.01187E-11 0.0195527 6 2 2.4616E-12 1
0.9818876 19.637753 0.0001584 0.0155919 0.9837872 0.00062072
7 4 3.8 9 6.30957E-11 8 9 8 3.9165E-12 1
0.0001258 0.0124229 0.9867931 0.00078383
0.9858608 19.717216 3.9 9 7.94328E-11 9 7 8 6.2264E-12 1
0.9891088 19.782176 0.9891196
2 3 4 1E-04 1E-10 0.0098912 8 0.00098912 9.8911E-12 1
0.9917944 19.835889 0.0078708 0.00124744
6 1 4.1 7.9433E-05 1.25893E-10 5 0.9908817 6 1.5704E-11 1
0.9940541 19.881083 0.0062601 0.9921673 0.00157247
7 3 4.2 6.3096E-05 1.58489E-10 5 7 9 2.4922E-11 1
0.9960040 19.920080 0.9930416 0.00198137
1 3 4.3 5.0119E-05 1.99526E-10 0.004977 2 9 3.9534E-11 1
0.9977449 19.954899 0.0039553 0.9935489 0.00249568
8 6 4.4 3.9811E-05 2.51189E-10 9 3 2 6.2689E-11 1
0.9993677 0.9937151 0.00314240
5 19.987355 4.5 3.1623E-05 3.16228E-10 0.0031424 9 3 9.9372E-11 1
0.0024956 0.9935489
1.0009571 20.019142 4.6 2.5119E-05 3.98107E-10 8 3 0.00395539 1.5747E-10 1
1.0025960 20.051921 0.0019813 0.9930416 0.00497699
6 2 4.7 1.9953E-05 5.01187E-10 8 2 8 2.4944E-10 1
1.0043700 20.087400 0.0015724 0.9921673 0.00626015
2 3 4.8 1.5849E-05 6.30957E-10 8 7 3 3.9499E-10 1
1.0063708 20.127416 0.0012474 0.00787085
4 7 4.9 1.2589E-05 7.94328E-10 5 0.9908817 3 6.252E-10 1
1.0087012 20.174024 0.0009891 0.9891196 0.00989119
3 6 5 0.00001 1E-09 2 8 7 9.8912E-10 1
20.229588 0.0007838 0.9867931
1.0114794 1 5.1 7.9433E-06 1.25893E-09 4 7 0.01242299 1.564E-09 1

1.0148441 20.296883 0.0006207 0.9837872 0.01559197

6 2 5.2 6.3096E-06 1.58489E-09 3 9 8 2.4712E-09 1
1.0189604 20.379208 0.0004911 0.9799561 0.01955269
1 3 5.3 5.0119E-06 1.99526E-09 4 6 6 3.9013E-09 1
1.0240251 20.480502 0.9751179 0.02449385 0.9999999
4 8 5.4 3.9811E-06 2.51189E-09 0.0003882 4 5 6.1526E-09 9
1.0302734 20.605469 0.0003064 0.9690495 0.03064403 0.9999999
8 5 5.5 3.1623E-06 3.16228E-09 4 1 6 9.6905E-09 9
1.0379846 20.759693 0.0002415 0.9614812 0.03827725 0.9999999
6 3 5.6 2.5119E-06 3.98107E-09 1 1 7 1.5238E-08 8
1.0474869 20.949739 0.0001899 0.9520923 0.04771765 0.9999999
8 7 5.7 1.9953E-06 5.01187E-09 7 6 3 2.3915E-08 8
21.183212 0.0001490 0.9405088 0.05934209 0.9999999
1.0591606 1 5.8 1.5849E-06 6.30957E-09 6 1 4 3.7442E-08 6
1.0734365 21.468730 0.0001166 0.9263043 0.9999999
3 7 5.9 1.2589E-06 7.94328E-09 1 6 0.07357897 5.8446E-08 4
 0.9090081 0.09090081 0.9999999
1.0907894 21.815788 6 1E-06 1E-08 9.0901E-05 9 9 9.0901E-08 1
1.1117210 22.234421 0.8881214 0.11180786 0.9999998
9 9 6.1 7.9433E-07 1.25893E-08 7.0546E-05 5 6 1.4076E-07 6
1.1367322 22.734644 0.8631459 0.13679940 0.9999997
4 8 6.2 6.3096E-07 1.58489E-08 5.4461E-05 1 8 2.1681E-07 8
1.1662789 23.325579 0.8336273 0.16633052 0.9999996
8 7 6.3 5.0119E-07 1.99526E-08 4.178E-05 6 6 3.3187E-07 7
24.014290 0.7992141
1.2007145 1 6.4 3.9811E-07 2.51189E-08 3.1817E-05 6 0.20075352 5.0427E-07 0.9999995
1.2402182 24.804364 0.24024711 0.9999992
4 8 6.5 3.1623E-07 3.16228E-08 2.4025E-05 0.7597281 9 7.5973E-07 4
1.2847212 25.694425 0.7152390 0.9999988
8 6 6.6 2.5119E-07 3.98107E-08 1.7966E-05 9 0.28474181 1.1336E-06 7
1.3338421 0.6661294 0.33385557 0.9999983
5 26.676843 6.7 1.9953E-07 5.01187E-08 1.3291E-05 6 9 1.6732E-06 3
1.3868513 27.737027 0.6131293 0.38685847 0.9999975
6 3 6.8 1.5849E-07 6.30957E-08 9.7174E-06 7 6 2.4409E-06 6
1.4426825 28.853651 0.5573057 0.44268370 0.9999964
9 7 6.9 1.2589E-07 7.94328E-08 7.0161E-06 6 4 3.5164E-06 8
1.5 30 7 1E-07 1E-07 5E-06 0.499995 0.499995 5E-06 0.999995
1.5573174 31.146349 0.55730576 0.9999929
7 4 7.1 7.9433E-08 1.25893E-07 3.5164E-06 0.4426837 4 7.0161E-06 8
1.6131488 0.3868584 0.61312936 0.9999902
5 32.262977 7.2 6.3096E-08 1.58489E-07 2.4409E-06 8 5 9.7174E-06 8
1.6661583 0.3338555 0.66612945 0.9999867
5 33.323167 7.3 5.0119E-08 1.99526E-07 1.6732E-06 8 6 1.3291E-05 1
1.7152796 34.305592 0.2847418 0.9999820
3 6 7.4 3.9811E-08 2.51189E-07 1.1336E-06 1 0.71523909 1.7966E-05 3
1.7597832 35.195664 0.2402471 0.75972809 0.9999759
4 8 7.5 3.1623E-08 3.16228E-07 7.5973E-07 2 7 2.4025E-05 8
1.7992877 35.985754 0.2007535 0.79921415 0.9999681
3 6 7.6 2.5119E-08 3.98107E-07 5.0427E-07 2 8 3.1817E-05 8
1.8337242 36.674484 0.1663305 0.83362736 0.9999582
3 5 7.7 1.9953E-08 5.01187E-07 3.3187E-07 3 2 4.178E-05 2
1.8632722 37.265444 0.1367994 0.86314591 0.9999455
3 6 7.8 1.5849E-08 6.30957E-07 2.1681E-07 1 4 5.4461E-05 4
1.8882849 37.765699 0.1118078 0.88812144 0.9999294
8 5 7.9 1.2589E-08 7.94328E-07 1.4076E-07 7 7 7.0546E-05 5
0.0909008 0.90900818
1.9092187 38.184374 8 1E-08 1E-06 9.0901E-08 2 9 9.0901E-05 0.9999091
1.9265741 38.531482 0.0735789 0.92630435 0.0001166 0.9998833
4 8 8.1 7.9433E-09 1.25893E-06 5.8446E-08 7 6 1 9
1.9408533 38.817066 0.0593420 0.94050880 0.0001490 0.9998509
2 3 8.2 6.3096E-09 1.58489E-06 3.7442E-08 9 8 6 4
1.9525310 39.050620 0.0477176 0.95209235 0.0001899 0.9998100
3 6 8.3 5.0119E-09 1.99526E-06 2.3915E-08 5 5 7 3
1.9620385 39.240770 0.0382772 0.96148121 0.0002415 0.9997584
1 2 8.4 3.9811E-09 2.51189E-06 1.5238E-08 6 5 1 9
39.395124 0.0306440 0.96904951 0.0003064 0.9996935
1.9697562 1 8.5 3.1623E-09 3.16228E-06 9.6905E-09 4 4 4 6
1.9760127 39.520254 0.0244938 0.97511793
4 7 8.6 2.5119E-09 3.98107E-06 6.1526E-09 6 7 0.0003882 0.9996118
1.9810877 39.621755 0.97995615 0.0004911 0.9995088
9 7 8.7 1.9953E-09 5.01187E-06 3.9013E-09 0.0195527 9 4 6
1.9852170 0.0155919 0.98378729 0.0006207 0.9993792
5 39.704341 8.8 1.5849E-09 6.30957E-06 2.4712E-09 8 2 3 7
0.0124229 0.98679317 0.0007838 0.9992161
1.9885982 39.771964 8.9 1.2589E-09 7.94328E-06 1.564E-09 9 1 4 6
1.9913970 39.827940 0.98911968 0.0009891 0.9990108
3 6 9 1E-09 1E-05 9.8912E-10 0.0098912 3 2 8
1.9937534 39.875069 0.0078708 0.0012474 0.9987525
6 2 9.1 7.9433E-10 1.25893E-05 6.252E-10 5 0.9908817 5 5
1.9957871 39.915742 0.0062601 0.99216736 0.0015724 0.9984275
1 1 9.2 6.3096E-10 1.58489E-05 3.9499E-10 5 7 8 2
1.9976024 39.952049 0.99304162 0.0019813 0.9980186
7 3 9.3 5.0119E-10 1.99526E-05 2.4944E-10 0.004977 3 8 2
1.9992936 39.985873 0.0039553 0.99354892 0.0024956 0.9975043
7 4 9.4 3.9811E-10 2.51189E-05 1.5747E-10 9 8 8 2
2.0009489 40.018979 0.99371519
7 5 9.5 3.1623E-10 3.16228E-05 9.9372E-11 0.0031424 3 0.0031424 0.9968576
2.0026550 40.053101 0.0024956 0.99354892 0.0039553 0.9960446
8 6 9.6 2.5119E-10 3.98107E-05 6.2689E-11 8 8 9 1
2.0045014 40.090028 0.0019813 0.99304162
3 6 9.7 1.9953E-10 5.01187E-05 3.9534E-11 8 4 0.004977 0.995023
40.131693 0.0015724 0.99216736 0.0062601 0.9937398
2.0065847 9 9.8 1.5849E-10 6.30957E-05 2.4922E-11 8 8 5 5
2.0090135 0.0012474 0.99088170 0.0078708 0.9921291
5 40.180271 9.9 1.2589E-10 7.94328E-05 1.5704E-11 5 1 5 5
2.0119139 40.238279 0.0009891 0.98911968
9 8 10 1E-10 1E-04 9.8912E-12 2 3 0.0098912 0.9901088
2.0154353 40.308707 10. 0.00012589 0.0007838 0.98679317 0.0124229 0.9875770
6 2 1 7.9433E-11 3 6.2262E-12 4 2 9 1
2.0197572 40.395144 10. 0.00015848 0.0006207 0.98378729 0.0155919 0.9844080
4 8 2 6.3096E-11 9 3.9165E-12 3 4 8 2
2.0250974 40.501948 10. 0.00019952 0.0004911 0.97995616
2 3 3 5.0119E-11 6 2.4615E-12 4 2 0.0195527 0.9804473
2.0317209 40.634419 10. 0.00025118 0.97511794 0.0244938 0.9755061
9 8 4 3.9811E-11 9 1.5455E-12 0.0003882 3 6 4
2.0399507 40.799015 10. 0.00031622 0.0003064 0.96904952 0.0306440 0.9693559
6 3 5 3.1623E-11 8 9.6905E-13 4 3 4 6
2.0501787 41.003574 10. 0.00039810 0.0002415 0.0382772 0.9617227
2 5 6 2.5119E-11 7 6.0665E-13 1 0.96148123 6 4
2.0628784 41.257568 10. 0.00050118 0.0001899 0.95209237 0.0477176 0.9522823
4 8 7 1.9953E-11 7 3.7903E-13 7 8 5 5
10. 0.00063095 0.0001490 0.94050884
2.0786178 41.572356 8 1.5849E-11 7 2.3625E-13 6 3 0.0593421 0.9406579
2.0980712 41.961424 10. 0.00079432 0.0001166 0.0735789 0.9264210
1 3 9 1.2589E-11 8 1.4681E-13 1 0.92630441 7 3
2.1220302 42.440604 0.90900827 0.0909008 0.9090991
3 6 11 1E-11 0.001 9.0901E-14 9.0901E-05 2 3 7
2.1514112 11. 0.00125892 0.88812157 0.1118078 0.8881921
5 43.028225 1 7.9433E-12 5 5.6037E-14 7.0546E-05 2 8 2
2.1872596 43.745192 11. 0.00158489 0.86314610 0.1367994 0.8632005
4 8 2 6.3096E-12 3 3.4362E-14 5.4461E-05 1 4 6
2.2307507 44.615015 11. 0.00199526 0.83362763 0.1663305 0.8336694
5 1 3 5.0119E-12 2 2.094E-14 4.178E-05 8 8 2
2.2831918 45.663837 11. 0.00251188 0.79921456 0.2007536 0.7992463
5 1 4 3.9811E-12 6 1.2667E-14 3.1817E-05 1 2 8
2.3460341 46.920683 11. 0.00316227 0.75972867
7 3 5 3.1623E-12 8 7.5973E-15 2.4025E-05 4 0.2402473 0.7597527
2.4209131 48.418263 11. 0.00398107 0.71523990 0.2847421 0.7152578
7 5 6 2.5119E-12 2 4.5129E-15 1.7966E-05 1 3 7
2.5097468 50.194937 11. 0.00501187 0.66613057 0.3338561 0.6661438
8 6 7 1.9953E-12 2 2.6519E-15 1.3291E-05 1 4 6
52.298735 11. 0.00630957 0.61313086 0.3868594 0.6131405
2.6149368 9 8 1.5849E-12 3 1.5401E-15 9.7175E-06 2 2 8

Ácido Triprótico 1
14

12

10

0
-10 0 10 20 30 40 50 60
 HOJA DE CALCULO DE LA VALORACION DE UN ACIDO TRIPROTICO CON UN BASE FUERTE
Valoración de una solución de un ácido triprótico, C 0 (M)
Con una solución de una base fuerte, C T (M)
pKW pKA1 pKA2 pKA3 C0 CT V0 V1erPE V2oPE V3oPE
14 1 3 6.2 0.1 0.1 20 20 40 60
KW KA1 KA2 KA3
1E-14 0.1 0.001 6.3096E-07

6 7 1 2 3 4 5 6 suma
 V pH  
 
   

-
- 0.0548520 0.0630957 1.58489E- 0.3831399 0.6072359 0.00962404
0.0027426 4 1.2 3 13 6 1 1 9.624E-08 0.9999999
0.1215362 2.4307251 0.0501187 1.99526E- 0.3294813 0.6574016 0.01311688 1.6513E- 0.9999998
6 1 1.3 2 13 1 4 7 07 3
0.2430579 4.8611585 0.0398107 2.51189E- 0.7026288 2.7972E- 0.9999997
3 5 1.4 2 13 0.2797216 8 0.01764924 07 2
7.1814099 0.0316227 3.16228E- 0.2346162 0.7419216 0.02346162 4.6812E- 0.9999995
0.3590705 7 1.5 8 13 3 7 3 07 3
0.4676201 9.3524029 0.0251188 3.98107E- 0.7745931 0.03083710 7.7459E- 0.9999992
5 6 1.6 6 13 0.194569 2 8 07 3
0.5676545 11.353090 0.0199526 5.01187E- 0.1596661 0.8002262 0.04010631 1.2683E- 0.9999987
2 5 1.7 2 13 3 8 9 06 3
0.6589831 13.179663 0.0158489 6.30957E- 0.1297404 0.8186068 0.05165060 2.0562E- 0.9999979
6 1 1.8 3 13 5 9 3 06 4
0.7421390 14.842780 0.0125892 7.94328E- 0.1044465 0.8296487 0.06590134 3.3029E-
5 9 1.9 5 13 9 6 4 06 0.9999967
0.8181913 16.363827 0.8333289 0.08333289 0.9999947
8 6 2 0.01 1E-12 0.0833329 5 5 5.258E-06 4
0.8885488 17.770977 0.0079432 1.25893E- 0.0659010 0.8296446 0.10444606 8.2964E-
8 6 2.1 8 12 1 2 9 06 0.9999917
0.9547768 19.095537 0.0063095 1.58489E- 0.0516500 0.8185979 0.12973903 1.2974E- 0.9999870
6 2 2.2 7 12 4 5 3 05 3
1.0184363 20.368726 0.0050118 1.99526E- 0.0401055 0.8002112 0.15966312
1 2 2.3 7 12 6 1 7 2.01E-05 0.9999799
1.0809447 21.618894 0.0039810 2.51189E- 0.0308361 0.7745698 0.19456314 3.0836E- 0.9999691
4 7 2.4 7 12 8 4 6 05 6
0.0031622 3.16228E- 0.0234605 0.7418872 0.23460536 0.9999531
1.1434564 22.869128 2.5 8 12 4 9 1 4.681E-05 9
1.2067631 0.0025118 3.98107E- 0.7025797 0.27970202 7.0258E- 0.9999297
5 24.135263 2.6 9 12 0.017648 2 2 05 4
1.2712230 25.424460 0.0019952 5.01187E- 0.0131155 0.6573332 0.32944703 0.0001041 0.9998958
2 4 2.7 6 12 2 6 8 8 2
1.3367293 26.734586 0.0015848 6.30957E- 0.0096225 0.6071433 0.38308156 0.0001525 0.9998474
4 8 2.8 9 12 7 6 1 1 9
1.4027334 28.054668 0.0012589 7.94328E- 0.0069657 0.0002202 0.9997797
2 4 2.9 3 12 2 0.5533068 0.43950721 8 2
0.0049735 0.4973563 0.49735631 0.0003138 0.9996861
1.4683271 29.366542 3 0.001 1E-11 6 1 3 1 9
1.5323778 0.0007943 1.25893E- 0.0035025 0.4409426 0.0004409 0.9995590
5 30.647557 3.1 3 11 3 4 0.55511389 4 6
1.5936938 31.873877 0.0006309 1.58489E- 0.0024335 0.3856852 0.61126995 0.0006112 0.9993887
8 7 3.2 6 11 1 7 4 7 3
33.023738 0.0005011 1.99526E- 0.0016690 0.3330240 0.66447035 0.0008365 0.9991634
1.6511869 1 3.3 9 11 7 6 1 2 8
1.7040010 34.080020 0.0003981 2.51189E- 0.0011310 0.2841031 0.71363479 0.0011310 0.9988689
1 3 3.4 1 11 3 3 9 3 7
1.7515875 35.031750 0.0003162 3.16228E- 0.0007580 0.2397075 0.75802194 0.0015124 0.9984875
4 8 3.5 3 11 2 8 1 5 5
1.7937220 35.874440 0.0002511 3.98107E- 0.0005030 0.2002569 0.79723742 0.0020025 0.9979974
3 5 3.6 9 11 2 9 1 7 3
1.8304738 0.0001995 5.01187E- 0.1658452 0.83119534 0.0026284 0.9973715
5 36.609477 3.7 3 11 0.0003309 8 9 7 3
1.8621467 37.242934 0.0001584 6.30957E- 0.0002160 0.1363089 0.86005112 0.0034239 0.9965760
4 9 3.8 9 11 4 2 3 3 7
1.8892089 37.784178 0.0001258 7.94328E- 0.0001401 0.1113046 0.88412412 0.0044311 0.9955688
4 8 3.9 9 11 2 3 6 2 8
1.9122273 38.244546 9.0382E- 0.0903824 0.90382442 0.0057027 0.9942972
1 3 4 1E-04 1E-10 05 4 8 5 5
1.9318139 7.9433E- 1.25893E- 5.8022E- 0.0730457 0.91959164 0.0073045 0.9926954
5 38.636279 4.1 05 10 05 6 1 8 2
1.9485881 38.971763 6.3096E- 1.58489E- 3.7098E- 0.0587956 0.93184873 0.0093184 0.9906815
8 7 4.2 05 10 05 8 5 9 1
1.9631535 39.263070 5.0119E- 1.99526E- 2.3636E- 0.0471602 0.94097003 0.0118461 0.9881538
3 7 4.3 05 10 05 2 6 1 9
1.9760871 39.521742 3.9811E- 2.51189E- 1.5013E- 0.0377111 0.94726078 0.0150130 0.9849869
2 4 4.4 05 10 05 3 4 7 3
1.9879384 39.758768 3.1623E- 3.16228E- 9.5095E- 0.0300715 0.95094511 0.0189738 0.9810261
5 9 4.5 05 10 06 2 6 5 5
1.9992346 39.984692 2.5119E- 3.98107E- 6.0077E- 0.0239171 0.95215965 0.0239171 0.9760828
2 5 4.6 05 10 06 7 4 7 3
2.0104895 40.209790 1.9953E- 5.01187E- 3.7858E- 0.0189739 0.95095055
1 2 4.7 05 10 06 6 9 0.0300717 0.9699283
2.0222146 40.444292 1.5849E- 6.30957E- 2.3794E- 0.0150132 0.94727275 0.0377116 0.9622883
2 4 4.8 05 10 06 6 2 1 9
2.0349298 40.698597 1.2589E- 7.94328E- 1.4914E- 0.0118463 0.94099087 0.0471612 0.9528387
5 1 4.9 05 10 06 7 4 6 4
2.0491722 40.983444 9.3188E- 0.0093188 0.93188243 0.0587978 0.9412021
3 6 5 0.00001 1E-09 07 2 7 1 9
2.0655003 41.310006 7.9433E- 1.25893E- 5.8026E- 0.91964446 0.0730499 0.9269500
4 8 5.1 06 09 07 0.007305 7 6 4
2.0844920 41.689840 6.3096E- 1.58489E- 3.5985E- 0.0057032 0.0903905 0.9096094
3 6 5.2 06 09 07 6 0.9039058 8 2
2.1067323 42.134647 5.0119E- 1.99526E- 2.2211E- 0.0044317 0.88424783 0.1113202 0.8886797
8 6 5.3 06 09 07 4 4 1 9
2.1327887 42.655775 3.9811E- 2.51189E- 1.3634E- 0.0034246 0.86023684 0.1363383 0.8636616
8 5 5.4 06 09 07 6 7 5 5
2.1631707 43.263414 3.1623E- 3.16228E- 8.3147E- 0.0026293 0.83147041 0.1659001 0.8340998
2 5 5.5 06 09 08 4 8 6 4
2.1982738 43.965477 2.5119E- 3.98107E- 5.0328E- 0.0020035 0.79763861 0.2003577 0.7996422
7 5 5.6 06 09 08 8 2 6 4
2.2383113 44.766226 1.9953E- 5.01187E- 0.75859695 0.2398894 0.7601105
1 2 5.7 06 09 3.02E-08 0.0015136 1 2 8
2.2832406 45.664812 1.5849E- 6.30957E- 1.7946E- 0.0011323 0.71444284 0.2844248 0.7155751
4 8 5.8 06 09 08 2 6 2 8
2.3327011 46.654023 1.2589E- 7.94328E- 1.0549E- 0.0008379 0.66558124 0.3335808 0.6664191
9 9 5.9 06 09 08 2 8 2 8
2.3859798 47.719596 6.1276E- 0.0006127 0.3866261 0.6133738
3 6 6 1E-06 1E-08 09 6 0.61276111 2 8
2.4420230 48.840461 7.9433E- 1.25893E- 3.5148E- 0.0004424 0.55706502 0.4424924 0.5575075
7 4 6.1 07 08 09 9 6 8 2
6.3096E- 1.58489E- 1.9899E- 0.0003153 0.49984230 0.4998423 0.5001576
2.4995054 49.990108 6.2 07 08 09 8 9 1 9
2.5569490 51.138981 5.0119E- 1.99526E- 1.1117E- 0.0002218 0.44259016 0.5571880 0.4428119
7 4 6.3 07 08 09 2 8 1 9
2.6128749 52.257498 3.9811E- 2.51189E- 6.1304E- 0.0001539 0.38680360
4 7 6.4 07 08 10 9 7 0.6130424 0.3869576
53.319062 3.1623E- 3.16228E- 3.3383E- 0.0001055 0.33382533
2.6659531 1 6.5 07 08 10 6 1 0.6660691 0.3339309
2.7151222 54.302444 2.5119E- 3.98107E- 1.7965E- 0.28472688
2 4 6.6 07 08 10 7.152E-05 4 0.7152016 0.2847984
2.7596569 55.193139 1.9953E- 5.01187E- 9.5642E- 4.7934E- 0.24024155 0.7597105 0.2402894
6 1 6.7 07 08 11 05 7 1 9
2.7991791 55.983582 1.5849E- 6.30957E- 5.0427E- 3.1817E- 0.20075362 0.7992145 0.2007854
2 4 6.8 07 08 11 05 1 6 4
2.8336222 56.672445 1.2589E- 7.94328E- 2.6362E- 0.16633404 0.8336450 0.1663549
9 8 6.9 07 08 11 2.094E-05 8 1 9
2.8631676 57.263352 1.3681E- 1.3681E- 0.13680501
2 4 7 1E-07 1E-07 11 05 7 0.8631813 0.1368187
2.8881692 57.763385 7.9433E- 1.25893E- 8.8818E- 0.11181477 0.8881763 0.1118236
7 3 7.1 08 07 7.055E-12 06 7 4 6
2.9090836 58.181673 6.3096E- 1.58489E- 3.6191E- 5.7359E- 0.09090856 0.9090856 0.0909143
9 8 7.2 08 07 12 06 9 9 1
2.9264112 58.528224 5.0119E- 1.99526E- 1.8484E- 3.6881E- 0.07358728 0.9264090 0.0735909
1 1 7.3 08 07 12 06 5 3 7
3.9811E- 2.51189E- 9.4065E- 2.3628E- 0.05935080 0.9406468 0.0593531
2.9406528 58.813056 7.4 08 07 13 06 3 3 7
2.9522815 59.045631 3.1623E- 3.16228E- 4.7727E- 1.5092E- 0.04772664 0.9522718 0.0477281
8 6 7.5 08 07 13 06 9 4 6
2.9617263 59.234527 2.5119E- 3.98107E- 2.4157E- 9.6171E- 0.03828646 0.9617125 0.0382874
9 7 7.6 08 07 13 07 7 7 3
2.9693644 59.387289 1.9953E- 5.01187E- 1.2203E- 6.1162E- 0.03065341 0.9693459 0.0306540
7 3 7.7 08 07 13 07 1 8 2
2.9755203 59.510406 1.5849E- 6.30957E- 3.8835E- 0.02450335 0.9754962 0.0245037
2 4 7.8 08 07 6.155E-14 07 8 5 5
2.9804683 59.609366 1.2589E- 7.94328E- 3.1004E- 2.4627E- 0.01956229 0.9804374 0.0195625
3 5 7.9 08 07 14 07 9 5 5
2.9844374 59.688749 1.5602E- 1.5602E- 0.9843981 0.0156018
7 5 8 1E-08 1E-06 14 07 0.01560166 8 2
2.9876169 59.752339 7.9433E- 1.25893E- 7.8445E- 9.8757E- 0.01243273 0.9875671 0.0124328
5 1 8.1 09 06 15 08 4 7 3
2.9901618 59.803237 6.3096E- 1.58489E- 3.9417E- 6.2471E- 0.00990098 0.9900989 0.0099010
7 5 8.2 09 06 15 08 9 5 5
2.9921986 59.843973 5.0119E- 1.99526E- 1.9795E- 3.9497E- 0.00788068 0.9921192 0.0078807
9 8 8.3 09 06 15 08 4 8 2
3.9811E- 2.51189E- 9.9373E- 2.4961E- 0.00627001 0.9937299 0.0062700
2.9938301 59.876602 8.4 09 06 16 08 2 6 4
3.1623E- 3.16228E- 4.9869E- 0.00498687 0.9950131 0.0049868
2.9951393 59.902786 8.5 09 06 16 1.577E-08 9 1 9
2.9961936 59.923873 2.5119E- 3.98107E- 2.5019E- 9.9603E- 0.00396528
9 7 8.6 09 06 16 09 6 0.9960347 0.0039653
2.9970479 59.940958 1.9953E- 5.01187E- 6.2897E- 0.00315230 0.9968476 0.0031523
3 5 8.7 09 06 1.255E-16 09 9 8 2
2.9977465 59.954931 1.5849E- 6.30957E- 6.2938E- 3.9711E- 0.00250559
8 5 8.8 09 06 17 09 3 0.9974944 0.0025056
2.9983262 59.966525 1.2589E- 7.94328E- 2.5069E- 0.00199128 0.9980087 0.0019912
5 1 8.9 09 06 3.156E-17 09 9 1 9
2.9988174 59.976349 1.5824E- 1.5824E- 0.00158238 0.9984176 0.0015823
5 1 9 1E-09 1E-05 17 09 5 1 9
7.9433E- 1.25893E- 7.9333E- 9.9874E- 0.00125734 0.9987426 0.0012573
2.9992461 59.984922 9.1 10 05 18 10 3 6 4
2.9996348 59.992697 6.3096E- 1.58489E- 3.9771E- 6.3033E- 0.00099900
7 4 9.2 10 05 18 10 1 0.999001 0.000999
3.0000043 60.000087 5.0119E- 1.99526E- 1.9937E- 3.9779E- 0.00079369
9 7 9.3 10 05 18 10 8 0.9992063 0.0007937
3.0003742 60.007485 3.9811E- 2.51189E- 9.9937E- 2.5103E- 0.00063055 0.9993694 0.0006305
7 5 9.4 10 05 19 10 9 4 6
60.015284 3.1623E- 3.16228E- 5.0094E- 1.5841E- 0.00050093 0.9994990 0.0005009
3.0007642 1 9.5 10 05 19 10 6 6 4
3.0011949 60.023898 2.5119E- 3.98107E- 2.5109E- 0.00039794 0.9996020 0.0003979
5 9 9.6 10 05 19 9.996E-11 9 5 5
3.0016894 60.033789 1.9953E- 5.01187E- 1.2585E- 6.3076E- 0.00031612 0.9996838 0.0003161
6 2 9.7 10 05 19 11 8 7 3
3.0022741 60.045482 1.5849E- 6.30957E- 3.9801E- 0.00025112 0.9997488 0.0002511
3 6 9.8 10 05 6.308E-20 11 6 7 3
3.0029801 60.059603 1.2589E- 7.94328E- 3.1616E- 2.5114E- 0.00019948 0.9998005 0.0001994
9 8 9.9 10 05 20 11 6 1 9
3.0038453 60.076907 1.5846E- 1.5846E- 0.00015846 0.9998415 0.0001584
8 5 10 1E-10 1E-04 20 11 4 4 6
3.0049160 60.098320 10. 7.9433E- 0.00012589 7.9423E- 9.9987E- 0.00012587 0.9998741 0.0001258
1 2 1 11 3 21 12 7 2 8
3.0062494 60.124989 10. 6.3096E- 0.00015848 3.9807E- 6.3089E- 0.9999000
8 7 2 11 9 21 12 9.999E-05 1 9.999E-05
3.0079174 60.158348 10. 5.0119E- 0.00019952 1.9951E- 3.9808E- 7.94265E- 0.9999205 7.9427E-
2 4 3 11 6 21 12 05 7 05
 60.200191 10. 3.9811E- 0.00025118 9.9994E- 2.5117E- 6.30918E- 0.9999369 6.3092E-
3.0100096 9 4 11 9 22 12 05 1 05
3.0126389 60.252779 10. 3.1623E- 0.00031622 5.0116E- 1.5848E- 5.01162E- 0.9999498 5.0116E-
6 2 5 11 8 22 12 05 8 05
3.0159479 60.318959 10. 2.5119E- 0.00039810 2.5118E- 9.9996E- 3.98091E- 0.9999601 3.9809E-
7 3 6 11 7 22 13 05 9 05
3.0201166 60.402333 10. 1.9953E- 0.00050118 1.2589E- 6.3094E- 3.16218E- 0.9999683 3.1622E-
9 8 7 11 7 22 13 05 8 05
3.0253732 60.507465 10. 1.5849E- 0.00063095 6.3094E- 2.51182E- 0.9999748 2.5118E-
7 4 8 11 7 23 3.981E-13 05 8 05
3.0320074 60.640148 10. 1.2589E- 0.00079432 3.1622E- 2.5118E- 1.99522E- 0.9999800 1.9952E-
2 4 9 11 8 23 13 05 5 05
3.0403880 60.807760 1.5849E- 1.5849E- 1.58487E- 0.9999841 1.5849E-
3 6 11 1E-11 0.001 23 13 05 5 05
3.0509863 61.019726 11. 7.9433E- 0.00125892 7.9432E- 9.9999E- 1.25891E- 0.9999874 1.2589E-
1 1 1 12 5 24 14 05 1 05
11. 6.3096E- 0.00158489 6.3095E- 9.9999E-
3.0644065 61.28813 2 12 3 3.981E-24 14 9.9999E-06 0.99999 06
3.0814272 61.628544 11. 5.0119E- 0.00199526 1.9952E- 7.94322E- 0.9999920 7.9432E-
4 7 3 12 2 24 3.981E-14 06 6 06
3.1030578 62.061156 11. 3.9811E- 0.00251188 9.9999E- 2.5119E- 6.30953E- 0.9999936 6.3095E-
4 9 4 12 6 25 14 06 9 06
3.1306165 11. 3.1623E- 0.00316227 5.0118E- 1.5849E- 5.01185E- 0.9999949 5.0118E-
5 62.612331 5 12 8 25 14 06 9 06
3.1658411 63.316822 11. 2.5119E- 0.00398107 2.5119E- 3.98106E- 0.9999960 3.9811E-
4 8 6 12 2 25 1E-14 06 2 06
3.2110492 11. 1.9953E- 0.00501187 1.2589E- 6.3096E- 3.16227E- 0.9999968 3.1623E-
5 64.220985 7 12 2 25 15 06 4 06
3.2693769 65.387539 11. 1.5849E- 0.00630957 6.3096E- 3.9811E- 2.51188E- 0.9999974 2.5119E-
6 3 8 12 3 26 15 06 9 06
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