Rate of Adsorption Related terms: Carbon Atom, Surfactant, Dye, Molecule, Diffusion, ‘Adsorption, Sorption, Isotherm, Adsorbent View all Topics > 4 A ® Characterization of Porous Solids VII F. Benaliouche, ... Y. Boucheffa, in Studies in Surface Science and Catalysis, 2007 Conclusion According to the results presenting the initial rate of adsorption andjor the initial diffusion coefficient versus the calcium exchange degrees, it appears that the propane molecule seems be a very interesting model of adsorbat in highlighting the effect of calcium exchanging in A adsorbents. Actually, the parameters mentioned above, are affected identically and their behavior versus calcium exchange were similar to the evolution of nitrogen capacity adsorption. Moreover, the concordance of experimental and theoretical curves allows us to consider the propane molecule as an excellent probe molecule. The idle period preceding the effective diffusion, using the approximate model ensuing from the second Fick's law, was evidently affected by the calcium exchange. This result excludes the hypothesis of the existence of the intererystalline resistance as the unique phenomena during the diffusion. Metallurgical Slag as an Efficient and Economical Adsorbent of Arsenic B.M. Mercado-Borrayo, ... R.M. Ramirez-Zamora, in Water Reclamation and Sustainability, 2014 1.2.3.2 Adsorption Kinetics Kinetic models can be used to determine the adsorption rate of contaminants and the time needed for the process to reach equilibrium. The study of adsorption kinetics permits an estimation of the type of adsorption of contaminants occurring on the surface of the adsorbent:** Table 7 shows the equation and description of the models of adsorption kinetics (pseudo-first order, pseudo-second order, and Elovich)*#; these models are the most cited in scientific articles or published works related to adsorption models of heavy metals because they are best able to fit the data.*#" The ‘equations are given in their linear form. ‘The Lagergren (pseudo-first order) model describes the adsorption rate and depends on the available sites in the adsorbent for physisorption process; Ho (pseudo-second order model) describes the adsorption reaction rate with dependent energetically heterogeneous sites on the adsorbent; itis considered a chemisorptions model. The Elovich‘equation assumes that the actual solid surfaces are energetically heterogeneous and that neither desorption nor interactions between the adsorbed species could substantially affect the kinetics of adsorption at low surface coverage. This model describes chemisorption kinetics. Based on the information discussed in the introduction, the objective of this study was to show that metallurgical slags are an efficient and economic adsorbent for arsenic present at high initial concentrations, on the basis of comparison with the removal efficiencies and treatment costs of water utilizing zero-valent iron nanoparticles (nZVI). The efficiency was determined using isotherm and kinetic models Adsorption and its Applications in Industry and Environmental Protection M.S. Ray, in Studies in Surface Science and Catalysis, 1999 1976 Chihara, K.; Suzuki, M., and Kawazoe, K., Effect of heat generation on measurement of adsorption rate by gravimetric method, Chem. Eng. Sci., 31 (6). 505-507 (1976). England, R., and Thomas, W,., The significance and measurement of surface diffusion coefficients in catalysis. Trans. ICheme, 54, T115-T118 (1976), Ferrell, j.K.; Rousseau, RW., and Branscome, M.R., Development and testing of mathematical model for complex adsorption beds, Ind. Eng. Chem. Process Des. Dev., 15(1), 114-122 (1976). Gidaspow, D., Dharia, D., and Leung, L., Gas purification by porous solids with structural changes, Chem. Eng. Sci., 31 (6), 337-344(1976). Hsu, C.C.; Rudzinski, W., and Wojciechowski, B.W., Three-dimensional mobile adsorption: Evaluation of density distribution in adsorbed phases, Chem. Eng. Sci., 31(12), 1123-1130 (1976). Nagy, L.G., Study of porous adsorbents by isotopic molecular exchange method. Period. Polytech. Chem. Eng., 20, 25-36 (1976). Ruthven, .M., Sorption and diffusion in molecular sieve zeolites, Sep. Purif Methods. 5(2), 189-246 (1976). Szirmay, L., Relative diffusivities from breakthrough curves through exchange adsorption. Sep. Sci., 11(2), 159-170(1976). Tien, C., Hsieh, J.C, and Turian, RM., Application of h-transformation for solution of multicomponent adsorption in fixed bed, AIChE J., 22(3), 498-505 (1976). Waksmundzki,A., et al. Application of gas-adsorption chromatography data to investigation of adsorptive properties of adsorbents, Sep. Sci., 11(1), 29-38, 11(4), 411-416(1976) Heterogeneous Catalysis of Mixed Oxides Makoto Misono, in Studies in Surface Science and Catalysis, 2013 1.2.2 Adsorption on Solid Surface; Rate and Isotherm Ifthe surface is uniform and adsorbed molecules do not interact with each other forming monolayer of less, the rate of adsorption may be expressed by r, = k,p (1 ~ 6) and the rate of desorption by rs = 8, where pis the pressure of the molecule or its concentration). 8s its coverage on the surface and k, and ky rate constants of adsorption and desorption. At equilibrium, r,= ry. Then, (1.10) where K = ky/ky. This is well-known Langmuir isotherm, which is quantitatively valid only for very weak adsorption at a Int nouarnna taming But thie ientharm ranenduinae nivalitatival the widely aheaniad trand that tha adenrntinn ineraneaeom cunciege rogienss wu sine rus prune quliiiauiycny sie miiy UUSLI reas Ghia Sa Sie awe ie rapidly with pressure (or concentration) in a low-pressure region and then tends to saturate in a high-pressure region, From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference F. Aurelian, in Studies in Surface Science and Catalysis, 2007 3. Experimental ‘The paper presents a study of uranium adsorption on zeolite from synthetic solution in order to = identify the diffusion mechanism, which determines the adsorption rate of the uranium recovery from wastewaters; - determine the zeolite loading capacity; ~ determine the mass transfer coefficient. The kinetic curve was obtained. In all cases, the work parameters were maintained in the same conditions: solid-liquid contact = fixed bed; liquid flow rate = 25 ml/h = 5 bed equivalent volume (BEV); zeolite volume = 5 ml; 1 BEV = 5 ml zeolite. The anion, which is “hanging” on the zeolite bead, was uranyl-tri-carbonate (UTC). The uranium's initial concentration in solution was 0.017 meq UTC/(1 mgU/!). Methodology of Adsorption at the Gas-Solid Interface Frangoise Rouquerol, .. Kenneth Sing, in Adsorption by Powders and Porous Solids, 1999 Continuous sonic nozzle procedure The continuous calorimetric sonic nozzle experiment, as described in Section 2.7.2, involves the use of the following equation: (3.2) The ‘rate of adsorption’ f is determined with the help of Equation (2.80) from the experimental rate of introduction, f, of the adsorptive, the dead volumes V. and Ve and their temperatures T. and Te, and the slope dp/dt. The only extra information needed is a continuous recording of the heat-flow @ from the beginning to the end of the experiment. To obtain these data, a convenient procedure is described in the following steps. Steps 1-5 as for the discontinuous experiment. Dead space volume determination (Step 4) also possible by the discontinuous sonic nozzle procedure (Section 3.3.2). 6. Adsorbent bulb and calibrated volumes evacuated. Adsorbent bulb isolated. 7. Gas flow rate calibrated (cf. Step 3 of continuous sonic nozzle procedure). 8. Calibrated volume evacuated, while adsorptive still introduced at constant rate. 9. Evacuation valve closed (starting time of experiment). 10. Adsorption bulb opened and heat-flow @ = (dQ/dt), and quasi-equilibrium pressure p recorded, 11. Adsorbent bulb evacuated when final pressure reached, The results can be presented in the form of a continuous curve of differential enthalpies of adsorption versus n?, as shown in Figure 3.16b, with a resolution which is much higher than that obtained by the discontinuous procedure (Figure 3.162). Ifthe adsorption calorimeter cannot be easily connected to a well-calibrated and well-temperature- controlled adsorption sonic nozzle set-up, or when the adsorption isotherm is difficult to determine (eg. if very small amounts are adsorbed), there remains the possibility of determining, separately, the adsorption isotherm by any of the discontinuous or continuous procedures described in Sections 3.3.1 or 3.3.2. A simple procedure can be applied which