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B. Marking scheme:
6. For each question in Section A(i), you will be awarded 3 marks if you darken only the bubble corresponding to
the correct answer and zero mark if no bubbles are darkened. In all other cases, minus one ( 1) mark will be
awarded.
7. For each question in Section A(ii), you will be awarded 3 marks if you darken only the bubble corresponding to
the correct answer and zero mark if no bubbles are darkened. No negative marks will be awarded in this Section.
8. For each question in Section A(iii), you will be awarded 3 marks if you darken only the bubble corresponding to
the correct answer and zero mark if no bubbles are darkened. In all other cases, minus one ( 1) mark will be
awarded.
9. For each question in Section C, you will be awarded 3 marks if you darken the bubble corresponding to the correct
answer and zero mark if no bubble is darkened. No negative marks will be awarded for in this Section
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-2
PART I
SECTION A
Single Correct Choice Type
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
ghR ghR
(A) (B)
4 2
(C) zero
3. A source and observer are approaching each other with same speed V. Velocity of sound in the
medium is Vs. Source emits sound of frequency f. Wavelength of sound pulse towards observer is
V Vs V Vs
(A) s (B)
f Vs V f
Vs V Vs V
(C) (D)
f f
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-3
6. Initially block is at rest and springs just relaxed. Now block is String Spring
displaced a little away and released. The time period of
k2 3k
oscillation of block is
m m m
(A) (B) 2 k1 k
k k
3 m 2 m Spring
(C) (D)
2 k 3 k
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-4
Y
9. There is a uniform horizontal magnetic field along ( k) and a uniform
gravitational field g( j) . A particle with charge q is projected from the B
origin along positive x-axis with speed V0, and is found to cross P (a, b) V0 X
O
after some time. Which of the following is true?
(A) The speed while crossing P is more than V0 g
(B) The speed while crossing P is less than V0 P
(C) Both magnetic field and gravitational field do work on particle
(D) Only gravitational field does work on particle.
10. A string is wrapped over a uniform cylinder, as shown in diagram (side view).
When cylinder is released, string unwraps without any slipping and cylinder
comes down. Which of the following is true?
(A) Work done by Tension force on the cylinder is zero
(B) Work done by the Tension is negative
1
(C) Ratio of rotational kinetic energy and translational kinetic energy is .
2
(D) Ratio of rotational kinetic energy to translational kinetic energy is 2.
11. Which of the following is true about ideal L C oscillatory circuit? Ignore any radiation.
(A) Total energy of the circuit dissipates with time.
(B) Total energy of the circuit remains conserved.
(C) Total charge on both plates of the capacitor (taken together) remains conserved.
(D) Total charge on both plates of the capacitor (taken together) oscillates simple harmonically.
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-5
Comprehension Type
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based
on the other paragraph 3 multiple choice questions have to be answered. Each of these questions has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Two identical blocks are placed on a smooth horizontal surface, View from above
connected by a light string of length 2 . String touches a fixed smooth l l
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-6
In a hypothetical atom, a negatively charged particle having a charge of magnitude 3e and mass 3m revolves
around a proton. Here, e is the electronic charge and m is the electronic mass.
Mass of proton may be assumed to be much larger than that of the negatively charged particle, thus the
proton is at rest.
h
mvr n
2
It is given that for the first Bohr orbit of hydrogen atom: radius of orbit is r0, speed of electron is v 0, and total
energy is E0.
14. Speed of the revolving particle is, in the first Bohr orbit.
(A) v0 (B) 9v0
v
(C) 3v0 (D) 0
9
16. The momentum of an emitted photon when it makes a transition from the second excited state to
ground state, is
8E0 E
(A) (B) 0
c c
81 E 0 27E0
(C) (D)
4 c c
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-7
SECTION C
Integer Answer Type
This section contains 7 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
8 3m
L1 L2
20cm
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-8
7. For P-V diagram shown for a diatomic ideal gas, heat given to 3
P (1unit 10 N/m)
2
2 B
the gas from A to B is(in kJ).
A
1
(1unit 1m3 )
V
1 2
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-9
PART II
SECTION A
Single Correct Choice Type
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. An evacuated glass vessel weighs 70.0 g when empty, 180 g when filled with a liquid of density 1.1 g
-1
mL , and 71 g when filled with an ideal gas at 760 mm of Hg at 300 K. Determine the molar mass of
the gas
-1 -1
(A) 46 g mol (B) 246 g mol
-1 -1
(C) 123 g mol (D) 141 g mol
2. The reaction of an alkene (X) with Br2/CCl4 gives on optically active compound. The alkene (X) on
ozonolysis in presence of Zn gives two compounds (Y) and (Z), both gives yellow ppt. with NaOH/I2.
Which of the following can be alkene (X)?
(A) (B)
(C) (D)
Br
O O CH
C
(C) R C O C R
(D)
Mg
ether
A Where R CH3
HBr excess H3 O
1 eq.
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-10
4. Which of the following statement is not a valid postulate of Valence bond theory?
(A) Overlaping orbitals have unpaired electron
(B) Greater is the extent of overlapping higher is the bond strength
(C) Greater is the orbital overlapping higher is the bond length
(D) Lateral overlapping of atomic orbitals results in formation of -bond
5. If a water tank of 10 K Ltr. contains 55.5 g of CaCl2, 47.5 g of MgCl2, 84 g of MgSO4 and 81.6 g of
CaSO4 then what will be the degree of hardness for 1 Ltr. of water from this tank? (Assuming density
of solution in tank = 1 g/ml)
(A) 26.86 ppm (B) 23 ppm
(C) 130 ppm (D) 286.6 ppm
o o
6. When 160 ml of water at 80 C is mixed with 90 ml of water at 30 C, what will be the final
temperature?(Assume that no heat is lost to surrounding; density of water is 1.00 g/ml).
o o
(A) 55 C (B) 26.24 C
o o
(C) 62 C (D) 48.4 C
7.
o
temeperature, but at 200 C it undergoes a first order break down with a half-life of 12.0 min. An
o
industrial flavor enhancing process requires that a biacetyl flavoured food be heated briefly at 200 C.
How long can the food be heated and retain 85% of its butter flavor? (log 1.176 = 0.0706)
(A) 2.81 sec (B) 169 sec
(C) 2 mins (D) 16.9 mins
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-11
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out which ONE OR MORE is/are correct.
8. Saccharine may be prepared from o-toluene sulphonyl chloride by its reaction with NH3 followed by
oxidation by neutral KMnO4. o-toluene sulphonyl chloride may be prepared by o-methylaniline as
following
NH2
CH3
i NaNO 2 /H2SO4 Cl2
ii SO 2 Cu
A NaOH
o toluenesulphonylchloride
CuCN H3 O Br2
A B FeBr3
C
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-12
10. In which of the following pairs of nucleophiles former is more nucleophilic in polar protic medium than
later?
(A) OH,H2 O (B) F , Cl
O
(C) O, (D) NH3 ,NH2
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-13
Comprehension Type
This section contains 2 paragraphs. Based upon the first paragraph 2 multiple choice questions and based
upon the second paragraph 3 multiple choice questions have to be answered. Each of these questions has
four choices A), B), C) and D) out of WHICH ONLY ONE CORRECT.
During the practice of isomerism in a class a student Paul was given an exercise by his teacher E.Smith as
following:
s among
carbon (C), hydrogen (H), deuterium (D) and oxygen (O). [MW of C(12), H(1), D(2), O(16)]
Condition 1: You cannot use more than three similar atoms in a molecule.
Condition 2: The molecule must be saturated.
12. If Paul has to draw the structure of an optically active molecule with lowest possible molecular weight
by following above conditions then what would be the molecular weight of that structure?
(A) 46 (B) 47
(C) 48 (D) 49
13. What will be the lowest possible molecular weight for the compound which is optically inactive
prepared with using above conditions by Paul.
(A) 15 (B) 16
(C) 17 (D) 18
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-14
librium
over the time:
A B C D E
14. If each particle represents 0.2 moles of particles then what will be the value of reaction quotient (Q)
for scene B?
(A) 0.36 (B) 0.18
(C) 4 (D) 5
15. -
each of [X] and [Y] in scene A the equilibrium stage can be represented by which of the picture?
(A) (B)
(C) (D)
16. in
terms of moles?
(A) A (B) B
(C) C (D) None the above
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-15
SECTION C
Integer Answer Type
This section contains 7 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
1. How many aldehydes with M.F. CnH2nO can give geometrical isomers on reaction with hydrazine
where n = 1 to 5 (including all).
2. How many of the following compounds contains ionic as well as covalent bond?
N2, NaN3, Li3N, Na2O2, HCl, KO2, CaC2, C2H2, KCN
3. The sum of the oxidation states of sulphur in the following compounds will be?
FeS2, K2S2O3, Na2S2O4, S2Cl2
4 moles 3
P, T, V 4 T, V
x moles
1 P, T,1/4V
2
If stopcocks A and B are removed then the number of moles remained in flask (1) is y and flask
(3) is z then value of y + z (nearest integer)? (Assuming volume of connecting tubes is negligible)
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-16
2+ 2+
5. The voltaic cell using Cu/Cu and Sn/Sn half cells is set up at standard conditions, and each
compartment has a volume of 240 mL. The cell delivers 0.15 A for 52.3 h then the concentration in
x
Cu chamber is so value of x is: [Given: Cu (M.W. = 63.5)]
10
6. What would be the atomic number of the missing species in the given transmutation
10
B ,n _____
7. How many of the following acids are relatively more acidic than acetic acid
COOH COOH COOH
CH3 OCH3
(A) (B) (C)
Cl
COOH OH
O2N NO2
NO2 NO2
COOH
OH
I
(G) HCOOH (H) (I)
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-17
PART III
SECTION A
Straight Objective Type
This section contains 7 multiple choice questions numbered 1 to 10. Each question has 4 choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.
2 2
1. A ray along the tangent drawn at point P(1, 1) on x + y = 2 gets reflected from line L at a distance of
2 units from point P. If reflected ray passes through the centre of circle then slope of line L can be
1 2 1 2 1 2 1
(A) tan , where is sin (B) tan , where is sin
4 2 3 2
1 2 1
(C) tan , where is sin (D) none of these
7 2
2
2. A variable chord PQ of the parabola y = 4x subtends a right angle at the vertex. Then the locus of
points of intersection of the tangents at P and Q is
2
(A) 4 y 1 16 x (B) y 4 0
(C) 4 y 4 4x2 (D) 4 y 1 0
3. A person writes a sequence of natural numbers randomly whose sum is 100. The probability that
there are exactly 45 terms in the sequence is
100 99
C45 C44
(A) 99
(B) 100
2 2
99 100
C44 C45
(C) 99
(D) 100
2 2
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-18
4. There are twenty points A1, A2, ..... A20 on a circle. The number of ways of selecting 4 points such that
there are atleast two points in between any two selected points is
11
C3
(A) 20 C1 11C3 (B) 20 C1
4
10
C3
(C) 20 C1 (D) none of these
4
5. The foot of perpendicular drawn from A( ) on the line passing through B( ) and perpendicular to OB
(where O is origin and , are complex numbers) is
(A) (B)
2 2
1 1
6. The value of 2
dx is equal to
x x6
1 1 x4 1 1 x4 x2 1 1 x4 1 x4 x2
(A) ln c (B) ln c
2 x2 2 1 x4 x2 2 x2 1 x4 x2
1 1 x2 1 1 x4 x2
(C) ln c (D) none of these
2 x2 2 1 x4 x2
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-19
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE or MORE are correct.
9. Let g(x) is twice differentiable function satisfying g(0) = 0, g(1) = 1. Then, which of following is/are
correct
(A) there exist distinct C1, C2 (0, 1) such that g' C1 g' C2 2
(B) there will be atleast one C such that g' C 1 for C (0, 1)
(C) there will be atleast one C (0, 1) such that g(C) = C for C (0, 1)
(D) if g( ) = for (0, 1) then there will exist atleast one C (0, 1) such that g" C 0
10. Family of curves which makes an angle of with the family of hyperbola xy = a, is
4
(a > 0, and a is a parameter)
2 2 2 2
(A) x 2xy y = A (B) y 2xy x = A
2 2 2 2
(C) x + 3xy y = A (D) y + 4xy x = A
11. If A and B are two square matrices of order 3 3 such that AB = A and BA = B, then which of
following is/are correct
4 4 10 10
(A) A + B = A + B (B) A + B = A + B
4 4 2 2
(C) A + B = A B (D) ABA BA + BAB AB = A + B
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-20
Comprehension Type
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based
on the other paragraph 3 multiple choice questions have to be answered. Each of these questions has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
x2 10x 8, x 2
2
Let continuous function f (x) = px qx r, 2 x 0 , where p
2
x 2x, x 0
y = f (x) at 3 points, then
14.
2 2 2 2
(A) x + y = 1 (B) x + y 2x 4y 9 = 0
2 2
(C) (y + 2) = 48 (x + 1) (D) (y + 2) = 13 (x + 1)
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Mock Test-4 Paper-1 (100390.1)-CMP-IITJEE-21
SECTION C
3 20 N
1. Let N tan 4 sin . The value of is equal to (where [.] is G.I.F.) __________.
11 111 3
2. At a point A (1, 1) on ellipse equation of tangent is y = x. If one of the foci of ellipse is (0, 2) and the
co ordinates of centre of ellipse are ( , ), then the value of + is __________. (Given length of
major axis of ellipse is 4 10 units)
3. If complex number z satisfies the condition |z 2 + i| 1, then maximum distance of origin from
A(4 + i(2 z)) is __________.
2x 3y 3x y x 2y
4. If x 3z 2x z 3x 2z (x y z) for all x, y, z R, then the value of is equal to
y 2z 2y 3z 3y z
__________.
6. nes x + y = 1, z = 0 and x y = 2, y+ z = 3.
x y z 1 3 n
and the value of cos is ,
1 2 3 14 8
then [n] is __________, where [.] denotes the greatest integer function.
3 2
7. Let f (x) = x + x + 2x 1. The minimum value of [x] if x satisfy f (f(x)) > f (2x + 1) is _________,
where [.] denotes the greatest integer function.
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