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Abstract
Significant reductions in the heating energy demand of buildings are achievable through minimization of the thermal transmittance of
glazing. This paper reviews all the heat transport processes occurring in gas-filled and evacuated insulating glazing. The heat transfer
mechanisms in gas-filled glazing cavities include radiative exchange between the glass sheet surfaces, convection and gaseous conduction.
The application of two low-emissivity coatings (0.04) lowers the thermal conductance due to radiation between the glass pane surfaces to
roughly 0.1 W m2 K1. At the same time, even where fill gases such as krypton and xenon are used, thermal conductance due to
convection and conduction cannot be reduced to much below 1 W m2 K1. Heat transfer by convection and gaseous conduction only
becomes negligible where the cavity is evacuated to approximately 102 Pa. Heat transfer is then determined by radiation and, even more
importantly, conduction in support pillars required to bear the atmospheric load on the external glass sheet surfaces. The fact that the
average centre-of-glazing heat transfer rates achievable by evacuation of the cavity are some two to five times lower than those of gas-
filled cavities increases the significance of heat transfer in the glazing edge regions. Consequently, in addition to the heat transfer in the
cavity, the impact on glazing thermal transmittance of the edge seal and different frame constructions was also quantified. The
possibilities and limitations of reducing total heat transfer in evacuated glazing are discussed on the basis of analytical and numerical
methods. The results suggest that this concept offers significant advantages over current glazing technology in terms of overall thermal
transmittance.
r 2007 Elsevier Ltd. All rights reserved.
Keywords: Insulating glazing; Fill gas; Vacuum; Heat transfer processes; Edge effects; Total thermal transmittance
0960-1481/$ - see front matter r 2007 Elsevier Ltd. All rights reserved.
doi:10.1016/j.renene.2007.01.007
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120 H. Manz / Renewable Energy 33 (2008) 119–128
often filled with inert gas—mainly argon or krypton, but scratching of the glass [33]. A patent was also granted for a
sometimes xenon—instead of air. triple vacuum glazing unit incorporating thin wires in the
However, negligible gaseous conduction (and convec- cavities to support the glass sheets [34]. Using a numerical
tion) is only achievable by evacuation of the glazing cavity. method, Manz et al. [35] discuss the impact of geometrical
Zoller [9] first described this concept in the patent and thermophysical parameters on the thermal transmit-
literature. Numerous patent applications were then filed tance of evacuated triple glazing.
in the following decades. A laser welding technique for Weinlaeder et al. [36] analyze heat transfer in evacuated
producing evacuated glazing was investigated at the US glazing including edge effects and conclude that thermal
Solar Energy Research Institute [10–12]. The deflection of transmittances of 0.4 W m2 K1 are possible for double
the glazing due to atmospheric pressure was reduced by vacuum glazing of 1 m2 area. The edge sealing solutions
spherical glass spacers with radii of roughly 0.25–1.5 mm, investigated in this study are glass–glass joints, soldering
periodically arrayed between the glass sheets. Problems metal foils and high barrier adhesives. The preliminary
with the sealing technique prevented the manufacture of conclusions drawn by the authors point to high barrier
complete glazing units. Collins and his group at the adhesives as the most promising option.
University of Sydney [13–20] were the first to successfully In order to remove gases from the internal surfaces,
fabricate a double vacuum glazing unit. A 0.1–0.2 mm high Collins and Simko [14] suggested baking the glazing at
cavity was evacuated to a pressure below 101 Pa. temperatures between 100 and 250 1C during the evacua-
Radiative transfer was lowered by means of a low- tion process. More recent work [37–40] has shown that
emissivity coating on the glass surfaces. Metal support photodesorption can occur when the glazing is exposed to
pillars with radii of 0.1–0.2 mm were used—hardly visible sunlight. It was found by means of mass spectroscopic
to the naked eye—and the glazing edges were sealed with analysis that the gases evolved are mainly carbon
solder glass. During the edge sealing process, the whole monoxide and carbon dioxide, rather than water vapor,
assembly was heated up to temperatures of around 500 1C, which was observed to outgas at elevated temperatures. It
imposing limitations on the use of low-emissivity coatings. was concluded that temperatures of 350–400 1C are needed
In collaboration with the University of Sydney, a Japanese during manufacturing to prevent a pressure increase in the
company developed a commercial double vacuum glazing glazing cavity during service life. Benson et al. proposed
unit with a thermal transmittance of roughly the use of getters to maintain the vacuum inside the sealed
1.5 W m2 K1 [21]. space [10]. Collins filed a patent for an evacuated panel
In order to overcome the restrictions imposed by a high- incorporating a getter [41].
temperature manufacturing process, mainly with regard to This study sets out to review the heat transfer mechan-
coating techniques, a low-temperature method for sealing isms in gas-filled and evacuated architectural glazing and to
the edges of vacuum glazing units was investigated at the quantify heat transfer rates as a function of thermophysi-
Universities of Ulster and Patras [22]. An edge seal cal, mechanical and geometrical parameters. Given the
employing indium wires and epoxy resin was developed increased significance of heat conduction through the
that enabled fabrication at temperatures below 200 1C. A glazing edges due to the higher thermal resistance of
highly insulating frame for vacuum glazing was developed evacuated cavities, edge effects will also be discussed.
at the University of Ulster [23].
Working in collaboration with Baechli [25–27], the 2. Radiative heat transfer between glass pane surfaces
Fraunhofer Institute for Solar Energy Systems [24]
developed a hermetic glazing edge seal for vacuum glazing As the distance between the glass panes in an insulating
based on metallized glass surfaces and a soldering glazing unit is very small compared with the height and
technique. Unlike the previously described approaches, width of the glazing, flat and parallel plates with infinite
Baechli’s method is based on a flexible edge seal using steel extension, each being isothermal though at different
foil. A key advantage of this system is that it accommo- temperatures, may be assumed for modelling the radiative
dates the temperature-induced expansion of the glass heat transfer in a glazing cavity. Application of the laws of
panes, i.e. temperature differences between the glazing Kirchhoff and Stefan–Boltzmann and using a lineariza-
surfaces do not cause any deflection of the structure. In this tion—valid only if temperature differences are not too
type of construction, the glass sheet must slide over the great—produces the following commonly used thermal
support pillars. The author is unaware of any complete conductance for radiative transfer in glazing cavities:
glazing prototypes successfully manufactured using this
approach. 1
Several other patent applications have been filed in Lrad ¼ 4sT 3 . (1)
1=1 þ 1=2 1
recent years related to vacuum glazing. These cover, for
example, various manufacturing or processing methods In Eq. (1), s is the Stefan–Boltzmann constant,
[28–32] and a support pillar design featuring a hard core T denotes the mean surface temperature in the cavity,
with high compressive strength and a soft metallic or and e1 and e2 are the emissivities of the glass pane surfaces.
carbon contact layer that serves to reduce cracking or Fig. 1 illustrates Eq. (1) and shows, by way of example,
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H. Manz / Renewable Energy 33 (2008) 119–128 121
Nulgas
0.1 Lgas ¼ , (5)
Both panes coated L
(ε1 = ε2 = ε)
0
where lgas denotes the thermal conductivity of gas. The
0 0.02 0.04 0.06 0.08 0.1 thermophysical properties of air, argon, krypton and
Emissivity (-) xenon are given in the appendix (Table A1). Fig. 3 shows
that at a certain distance between the panes heat flow is
Fig. 1. Radiative heat transport between glass surfaces as a function of
minimum. The location of this minimum position depends
emissivity at a mean surface temperature of 10 1C ( ¼ 283.15 K).
Emissivity of non-coated glass surface was assumed to be 0.84 [44]. on the thermophysical properties of the gas. At the
minimum positions, when xenon is employed as a fill gas,
2.5 Ar
where lgas stands for the thermal conductivity of the fill
Kr
gas, L the width of the gas layer, qm the average non- Xe
radiative heat flow across the gas layer and DT the 2
heat transfer by gaseous conduction and convection is temperature is roughly 0.06 mm. The ratio between the
nearly half that recorded for an air-filled cavity. mean free path, lgas, and a representative physical length,
here given by the cavity width, L, is known as the Knudsen
3.2. Total heat transfer in a cavity number, Kn ¼ lgas/L. The thermal conductivity of a gas,
lgas, falls with increasing Knudsen number (Kaganer, 1969,
Superposition of heat flows due to gaseous conduc- as cited in Ref. [47]). In other words, if the mean free path
tion, convection and radiation in the glazing cavity is much longer than the distance between the warm and the
results in [44] cold pane, molecular heat conduction is virtually impos-
sible. Fig. 5 shows the gaseous conductivity as a function of
Ltot ¼ Lgas þ Lrad . (6) pressure and cavity width L. Assuming a cavity width of
If advanced low-emissivity coatings are employed, heat 0.1 mm and a pressure below 101 Pa, thermal conductivity
transfer in gas-filled glazing cavities is dominated by is reduced by a factor of roughly 103 compared with its
gaseous conduction and convection (Figs. 1 and 3). original value at standard atmospheric pressure. The mean
free path at 101 Pa is roughly 6 cm. To allow comparison
of the heat transfer in a glazing cavity by gaseous
4. Evacuated cavity
conduction with other heat transport mechanisms, the
thermal conductance, L ¼ lgas/L, was calculated (Fig. 6).
Heat transfer by convection and gaseous conduction
Given the dependencies described above, thermal conduc-
may be eliminated through evacuation of the cavity.
tance ceases to be a function of cavity width. Assuming
Support pillars are then needed to prevent the glazing
again a pressure less than 101 Pa, thermal conductance is
from collapsing due to the atmospheric load on either pane
below 0.1 W m2 K1.
and to avoid contact between the glass pane surfaces.
Additional thermal losses result from conduction in these
support pillars. Radiative heat transfer between the glazing
surfaces is basically not affected by evacuation of the
cavity. (Note: Support pillars used in evacuated glazing
have an impact on surface temperature distribution. It was
found that Eq. (1), assuming isothermal surface tempera-
tures, still provides accurate results.)
100
N2
H2
10-1 O2
Mean free path (m)
He
Ar
10-2
Kr
Xe
10-3 H2O
CO
CO2
10-4
10-2 10-1 100 101 102
Pressure p (Pa)
Fig. 4. Mean free path at 10 1C for different gases as a function of Fig. 6. Thermal conductance due to gaseous conduction as a function of
pressure (Sutherland 1893, as cited in Ref. [47]). pressure and distance between panes.
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H. Manz / Renewable Energy 33 (2008) 119–128 123
Pillar separation s:
Fig. 7. Thermal conductance due to heat conduction through pillars, for Fig. 8. Thermal conductance due to heat conduction through pillars, for
cylindrical pillars with a thermal conductivity much higher than that of cylindrical pillars with thermal conductivity equal to that of glass
glass (lpilb1 W m1 K1). Dashed curves indicate lines of constant (lpil ¼ 1 W m1 K1). Dashed curves indicate lines of constant compres-
compressive stress in pillars. sive stress in pillars.
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124 H. Manz / Renewable Energy 33 (2008) 119–128
Table 1
Contribution of different heat transport processes to total thermal
conductance in glazing cavity
Thermal conductance
(W m2 K1)
Cold surface
Fig. 10. Linear thermal transmittance of edge seal for two different
Pillar thermal conductances of cavity and as a function of edge seal width (no
frame; thermal conductivity of seal material 100 W m1 K1).
(roughly 101 m) is much higher than the cavity width cavity concept offers significant thermal advantages over
(roughly 104 m), and conductive heat transfer in the fill current glazing technology based on fill gases such as air,
gas is virtually impossible. If advanced low-emissivity argon, krypton and xenon. The thermal superiority of
coatings are employed in such glazing, heat conduction evacuated glazing remains significant even where edge
through support pillars becomes a key heat transfer effects—more pronounced for evacuated glazing—are
mechanism in the cavity. This necessitates a very careful taken into account. Evacuated double glazing can
design of the support pillars, including selection of achieve similar or even lower thermal transmittances than
material(s) and optimization of geometry, with due current advanced triple glazing, while at the same time
consideration for mechanical as well as thermal aspects offering higher solar energy transmittance and lower
discussed by Collins and Simko [14] and Manz et al. [35]. overall thickness and weight. Higher solar energy trans-
As the total cavity thermal resistance for evacuated mittance is advantageous in terms of passive solar energy
glazing is much higher than for gas-filled glazing, heat use for the reduction of the building heating demand and
conduction through the glazing edges has an even greater transmission of visible solar radiation for daylighting
impact on total thermal transmittance. The much smaller purposes.
cavity width (e.g. 0.2 mm) in evacuated glazing is, of However, much more work is needed to overcome the
course, not advantageous in terms of reducing heat remaining technological challenges, which are mainly (i) to
conduction through the edge seal. Given these very low develop a glazing concept suitable for cost-effective large-
seal thicknesses, the thermal conductivity of the seal scale manufacturing, taking into account aspects such as
material has almost no impact over a wide range of low-emissivity coatings, low-conducting support pillars
numerical values. For instance, a glass seal offers only with high compressive yield strength, suitable outgassing
marginal thermal advantages over a highly conducting and evacuation procedures, and hermetic edge sealing, (ii)
metal seal. More crucial to thermal transmittance is the to enable long-term thermal stability, i.e. a service life of
width of the edge seal, with small widths naturally being more than 20 years, particularly to prevent a pressure
preferable. Baechli [26] suggests a flexible edge seal based increase in glazing exposed to sunlight and temperature
on metallic foil soldered to the glass sheet surfaces. Such a fluctuations due to photodesorption and/or temperature-
construction might therefore be advantageous from a induced outgassing [37–40], by means of an appropriate
thermal point of view. However, if insulating frames are manufacturing process and possibly also the use of getters
applied, the thermal advantage of this approach is [10,41], and (iii) to show that the mechanical strength of the
significantly reduced and mechanical and tightness-related glass panes, support pillars and edge seal is sufficient to
factors also require consideration in the development of a withstand loads due to atmospheric pressure, temperature
suitable edge seal design. differences and wind occurring during the service life of the
The results of the described thermal modelling underline glazing.
the importance of developing advanced highly insulating
frames for evacuated glazing, as already undertaken by
Fang et al. [23]. Even if advanced frames are applied, the
edge region is still likely to exhibit a lower thermal Acknowledgments
resistance than the central region of the glazing and
account therefore needs to be taken of the impact of the The author gratefully acknowledges valuable discussions
glazing geometry on thermal performance. Hence, in terms with Nikolai Artmann, Vinzenz Bissig, Nick Bosco,
of thermal performance, roughly square, large-area glazing Samuel Brunner, Paolo Chiggiato, Hans Josef Hug,
units are particularly advantageous. Jolanta Janczak, Peter Loutzenhiser, Venkatesh Sivasu-
bramaniam and Dirk Thomschke.
Table A1
Thermophysical properties of fill gases at 10 1C [44,50]
Thermal conductivity (W m1 K1) 2.496 102 1.684 102 0.900 102 0.533 102
Thermal diffusivity (m2 s1) 2.010 105 1.910 105 1.032 105 0.575 105
Kinematic viscosity (m2 s1) 1.429 105 1.274 105 0.674 105 0.377 105
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H. Manz / Renewable Energy 33 (2008) 119–128 127
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