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The prevailing description for dissipative quantum dynamics is given by the Lindblad form of a Markovian
master equation, used under the assumption that memory effects are negligible. However, in certain physical
situations, the master equation is essentially of a non-Markovian nature. In this paper we examine master
equations that possess a memory kernel, leading to a replacement of white noise by colored noise. The
conditions under which this leads to a completely positive, trace-preserving map are discussed for an expo-
nential memory kernel.
˙ = KL , 共3兲 1
˜共s兲 = 兺i Tr兵Li共0兲其 Ri . 共7兲
where K is an integral operator that depends on time of the s − K̃共s兲i
form K = 兰t0k共t − t⬘兲共t⬘兲dt⬘. The kernel function k共t − t⬘兲 is a We now illustrate how a master equation of the form of
well-behaved, continuous function that determines the type Eq. (3) arises. Consider the time-dependent Hamiltonian,
of memory in the physical problem. The solution to the mas- 3
ter equation can be found by taking the Laplace transform
H共t兲 = ប 兺
i=1
⌫i共t兲i , 共8兲
s˜共s兲 − 共0兲 = K̃共s兲L˜共s兲, 共4兲
where ⌫i共t兲 are independent random variables and i are the
determining the poles, and inverting the equation in the stan- Pauli operators. Each random variable obeys the statistics of
dard way. The solution to Eq. (3) defines a linear map a random telegraph signal, which is defined by ⌫i共t兲
⌽t : → t that describes the evolution of a system coupled to =ai共−1兲ni共t兲. The random variable ni共t兲 has a Poisson distri-
an environment provided that ⌽t satisfies properties 2共i兲 , 共ii兲, bution with a mean equal to t / 2i, while ai is an independent
and 共iii兲. Because the master equation is no longer of the coin-flip random variable. By the abuse of notation, the ran-
Lindblad form, the semigroup property is lost. However, this dom variable ai takes the values ±ai. The random telegraph
property is not necessary to describe a physically acceptable signal is a wide sense stationary stochastic process 关10兴 with
state evolution. All that is required is that the linear map be a zero mean. This model is applicable to any two-level quan-
completely positive, trace-preserving map. tum system that interacts with an environment possessing
The evolution of quantum systems is described by unitary random telegraph signal noise. For example, this could de-
operators. Therefore, ⌽t should describe an evolution of the scribe a two-level atom subjected to a fluctuating laser field
system that arises from an overall unitary evolution of the that has jump-type random phase noise 关11兴. In the language
system and environment of nuclear magnetic resonance, this model describes a spin-
1 / 2 particle in the presence of three orthogonal magnetic
⌽t共兲 = Tr⌫兵U共 丢 兩␥0典具␥0兩兲U†其, 共5兲 fields. Each field has a constant magnitude ai and inverts
randomly in time with a distribution given by ni. The
where ⌫ denotes the environment degrees of freedom and ␥0 strength of the coupling of the system to the external influ-
is some initial state of the environment. It is assumed that the ence is given by the parameters ai. The flipping or fluctua-
state is prepared at some time t = 0 and so is initially un- tion rate is inversely given by i.
correlated with the external system. The state and the envi- The equation of motion for the density operator is given
ronment evolve unitarily for some time and they become by the von Neumann equation =−共i/ប兲关H, 兴
correlated. One may think of the environment as extracting =−i兺k⌫k共t兲关k, 兴, which has the solution
冕兺
information from the system as it will typically map pure
t
states into mixed states. This noise process is described by a
共t兲 = 共0兲 − i ⌫k共s兲关k, 共s兲兴ds. 共9兲
linear map involving only operators on the system of interest 0 k
so that it has a Kraus decomposition,
Upon the substitution of Eq. (9) back into the von Neumann
⌽ t共 兲 = 兺k A†k Ak , 共6兲 equation and performing a stochastic average, one obtains
0 k
e−共t−t⬘兲/ka2k †k,关k, 共t⬘兲兴‡dt⬘ , 共10兲
served for all time [1]. A map has a Kraus decomposition if
and only if it is completely positive. Physically, complete where the correlation functions of the random telegraph sig-
positivity ensures that the system evolution is compatible nal 具⌫ j共t兲⌫k共t⬘兲典 = a2k e−兩t−t⬘兩/k␦ jk have been employed, as well
with a unitary evolution on the system-environment Hilbert as the decorrelation of the state from the random variables
space. [11]. Equation (10) is an equation of motion for the average
In solving Eq. (3) it is advantageous, in practice, to find a density operator using an incoherent sum approximation.
damping basis [9] for the superoperator L that diagonalizes That is, it is the sum of three exact equations of motion, one
the master equation. Solving the eigenvalue equation L for each component k = 1 , 2 , 3. After averaging over the res-
= produces a complete, orthogonal basis with which to ervoir variables, we are left with a homogeneous Volterra
expand the density operator at any time. This results in a set equation for the system density operator that has an expo-
of eigenvalues 兵i其 and right and left eigenoperators, nential memory kernel. The state of the system at time t
兵Ri其 , 兵Li其, that satisfy the duality relation Tr兵LiR j其 = ␦ij. Once depends on its past history. The power spectrum of the envi-
the initial state is known 共0兲 = 兺iTr兵Li共0兲其Ri, the state of ronment is given by a Fourier transform of the exponential
the system at any later time can be found through 共t兲 correlation function, which is an unnormalized Lorentzian
= 兺iTr兵Li共0兲其⌳i共t兲Ri = 兺iTr兵Ri共0兲其⌳i共t兲Li. The ⌳i共t兲 are with a maximum of 2a2 and a full width at half maximum
general functions that determine the time evolution. The equal to 1 / 共兲. In the case of white noise, the delta-function
damping basis allows for the replacement of L by the eigen- correlation in time leads to a flat power spectrum for the
values i so that Eq. (4) may be written as environment with a strength given by a diffusion constant.
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The system is equally coupled to all frequencies of the ex- of entropy between the two. The entropy of the average sys-
ternal system. In the case of colored noise, the system prefers tem state can oscillate in time with an overall decay.
certain frequencies. Thus, a is the coupling strength of the The solution to the master equation (12) defines a linear
system with the external system while determines which map ⌽t : → t on M2 that is a generalization of the depo-
frequencies the system prefers most. Increasing both a and larizing channel to the case of colored noise. This map has a
1 / corresponds to a more noisy environment. Therefore, the Kraus decomposition ⌽t共兲 = 兺kA†k Ak with Kraus operators
dimensionless product a is the fundamental quantity that given by A1 = 冑1共兲1, A2 = 冑2共兲2, A3 = 冑3共兲3, and
determines the amount of fluctuation. A4 = 冑4共兲I, provided the following linear combinations are
Having derived a master equation of the form of Eq. (3) non-negative:
with an exponential kernel function, we now determine the
damping basis and solve the master equation. We assume 41共兲 = 1 + ⌳1 − ⌳2 − ⌳3 艌 0,
that the fluctuation rates i are equal so that they obey the
same Poisson statistics. This leads to a single kernel operator 42共兲 = 1 − ⌳1 + ⌳2 − ⌳3 艌 0,
acting on the Lindblad superoperator, rather than a linear
superposition of such operations: ˙ = K1L1 + K2L2 + K3L3. 43共兲 = 1 − ⌳1 − ⌳2 + ⌳3 艌 0,
The damping basis for Eq. (10) is found to be the following
set of eigenvalues and eigenoperators: 兵0 , 1 , 2 , 3其 = 兵0 , 44共兲 = 1 + ⌳1 + ⌳2 + ⌳3 艌 0. 共13兲
−4共a22 + a23兲 , −4共a21 + a23兲 , −4共a21 + a22兲其 and 兵R0 , R1 , R2 , R3其
= 兵L0 , L1 , L2 , L3其 = 兵0 / 冑2 , 1 / 冑2 , 2 / 冑2 , 3 / 冑2其 which are We now show which properties (2) hold. Clearly, this map-
self-dual. Using the damping basis, the Laplace transform of ping is trace-preserving and property 共2兲共i兲 is satisfied. Prop-
Eq. (10) becomes erty 共2兲共iii兲 is satisfied because limt↓0⌳i共t兲 = 1. The system
evolves continuously in time and the evolution is described
s + 1/
˜共s兲 = 兺i Tr兵Li共0兲其 s共s + 1/兲 − i Ri , 共11兲 by the identity map at the initial time. The semigroup prop-
erty 共2兲共iv兲 is lost as ⌳i共t兲⌳i共s兲 ⫽ ⌳i共t + s兲.
The map is completely positive if ⌽t 丢 In 艌 0 ∀ n 苸 Z+. It
with 0 = I. This can be inverted to give the solution is sufficient to show that the composite operation on a maxi-
共t兲 = 兺 Tr兵Li共0兲其⌳i共t兲Ri . 共12兲 mally entangled state is positive [8]. For a linear map from
i M2 to M2, we need only show that the composite map ⌽t
丢 I共兩00典具00兩兲 on M4 is positive semidefinite, where 兩00典
In terms of the dimensionless time = t / 2, the functions = 共1 / 冑2兲共兩00典 + 兩11典兲 is the maximally entangled Bell state.
⌳i共兲 = e−关cos共i兲 + sin共i兲 / i兴 are damped harmonic os- Hence the map is completely positive if and only if the ei-
cillators having frequencies i = 冑共4ii兲2 − 1 with 2i = a2j genvalues of the composite map are non-negative. The ei-
+ a2k for i ⫽ j ⫽ k. This differs from the Markovian case, genvalues 兵 j其 are exactly those given by Eqs. (13). There-
where the functions are purely exponential functions in time fore, property 2共ii兲 is satisfied for all ai and every if and
with parameters defining the characteristic lifetimes. A only if
power series expansion gives ⌳共兲 = 1 − 21 共2 + 1兲2 + O共3兲,
which shows that the linear term in is missing. Thus, the inf j共兲 艌 0, j = 1,2,3,4. 共14兲
共ai兲
standard white noise diffusion term vanishes. This is a gen-
eral property of the memory kernel and a fundamental dif- This follows from the fact that the existence of a Kraus de-
ference between white noise and colored noise. composition and the composite operation on the maximally
The function ⌳共兲 has two regimes—pure damping and entangled state are both necessary and sufficient to show
damped oscillations. The fluctuation parameter, given by the complete positivity.
product , determines the behavior of the solution. When Condition (14) is not satisfied for all values of the param-
0 艋 ⬍ 1 / 4 the solution is described by damping. The fre- eters. A case where it is satisfied occurs when two or more of
quency is imaginary with magnitude less than unity. When the ai are zero. For example, if two of the ai are zero and one
= 1 / 4 the function ⌳共兲 = e−共1 − 兲 is unity at the initial is nonzero then ⌽t defines a dephasing channel with colored
time and approaches zero as time approaches infinity. In ad- noise. Suppose a3 = a , a1 = a2 = 0. In this case, ⌳1共兲 = ⌳2共兲
dition to pure damping, damped harmonic oscillations in the = ⌳共兲 and ⌳3共兲 = 1. This map has Kraus operators given by
interval 关−1 , + 1兴 exist in the regime ⬎ 1 / 4. A1 = 冑关1 + ⌳共兲兴 / 2I and A2 = 冑关1 − ⌳共兲兴 / 23. This map is a
The functions ⌳i共兲 determine the evolution of each com- completely positive, trace-preserving map for all values of
ponent of the Bloch vector. The bound 兩⌳共兲兩 艋 1 ensures the fluctuation parameter a because 兩⌳共兲兩 艋 1 for all times
that the density operator evolves only to states on or inside . This is due to the fact that the master equation for this case
the Bloch sphere so that ⌽t always maps positive operators is exact, making no use of any approximation. The Hamil-
to positive operators. For Markovian master equations, the tonian H = ប⌫33 implies that the z component of the spin-
dissipation results in a contraction of each component, which 1/2 particle is a constant of the motion so that the two states
is a consequence of the semigroup property. This property is 兩 ± 典z are fixed points and do not evolve. As a physical model,
absent for colored noise, so that the dissipation results in a constant magnitude magnetic field is applied in the z direc-
contractions with oscillations. The information exchange be- tion which inverts randomly in time. If the field is unob-
tween the system and the environment leads to an exchange served, the average trajectory for the density operator of the
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spin-1 / 2 system is dissipative. As time approaches infinity, noise in this singular limit and Eq. (10) becomes ˙ 共t兲 =
there is maximum uncertainty in the x and y components of −兰t0␦共t − t⬘兲兺k2a2k [k , 关k , 共t⬘兲兴]dt⬘. This master equation is
the spin system. A steady state ⌽t共兲ss = 21 共 + 33兲 is local in time, leading to ⌳i共t兲 = exp共−␥it兲 in Eq. (12) with
reached; the entire Bloch sphere evolves to a line connecting inverse lifetimes ␥i = 42i . We point out that, even in the case
the north and south poles. of white noise, there are examples of maps that are positive
We find that if two or more of the ai are nonzero then
but not completely positive [6,12,13]. For Markovian dy-
there are regimes for the fluctuation parameters where com-
plete positivity is lost. This is due to the incoherent sum namics, the relations (13) are satisfied if and only if ␥i 艋 ␥ j
approximation. Assume the frequencies i are equal. Then + ␥k for all permutations of the indices.
only the last eigenvalue in (13) need be considered. Setting By construction of our example, complete positivity holds
the time equal to = / we find that if the frequencies are in the white noise limit. We conclude that the loss of com-
less than or equal to / ln共3兲 the map defined by Eq. (12) is plete positivity, when the memory kernel is present, is a fea-
completely positive for all time. The case of three equal fre- ture of the colored noise. The validity of Eq. (3) has been
quencies sets an upper bound. We have the following suffi- questioned [14]. In this paper we show conditions under
cient condition for (14) to be satisfied: If * which an exponential memory kernel, applied to a two-level
= max兵1 , 2 , 3其 艋 / ln共3兲 then the map is completely posi- system, leads to a CPM and shows that such conditions can
tive for all time. Complete positivity is lost as the frequencies be achieved. We have presented an example of a completely
become large. This reflects the fact that the approximate so- positive, trace-preserving map that results from a system-
lution deviates from the exact solution (which will always be environment coupling that is essentially non-Markovian and
completely positive) as the fluctuation parameters become defines a depolarizing channel with colored noise. The re-
large. The exact master equation may be obtained by iterat- sults reveal that interesting features arise from the colored
ing the steps leading to Eq. (10) with the exception of aver- noise of the environment, which are not present in the limit
aging after a series is generated. The exact master equation of white noise. White noise is an idealization of real noises
will not have the form of Eq. (3); the incoherent sum ap- and under certain conditions cannot be used. Thus, more
proximation produces this form. When the map is completely work needs to be done in the study of more general noises
positive, it defines a depolarizing channel with colored noise, that include memory effects.
which arises from a non-Markovian master equation.
We recover the Markovian master equation by letting This work was partially supported by a KBN grant No.
→ 0 and a → ⬁ in such a way that 2a2 becomes a constant. 2PO3B 02123 and the European Commission through the
The random telegraph signal reduces to a Gaussian white Research Training Network QUEST.
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