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5/15/2019 CN106243462A - Calcium/zinc stabilizer and preparation method thereof - Google Patents

 Patents

Calcium/zinc stabilizer and preparation method thereof

Abstract
CN106243462A
The invention discloses a calcium/zinc stabilizer and a preparation method thereof. The
China
calcium/zinc stabilizer is prepared from the following raw materials in percentage by weight: 10-12%
of calcium stearate, 4-5% of zinc stearate, 8-10% of beta-diketone, 4-30% of phosphite ester, 12-15%
of an antioxidant, 9-16% of hydrotalcite, 13-19% of PE wax, 4-10% of epoxy axseed oil and 1-3% of Download PDF Find Prior Art Similar
an auxiliary stabilizer. The calcium/zinc stabilizer disclosed by the invention is a non-toxic harmless
product, conforms to environmental protection requirements of China, and can effectively restrain Other languages: Chinese
PVC materials from physical effects of heating, friction, shearing and the like during shaping and
Inventor: 王京胜, 周腊芳, 严德道, 王京胜, 周腊芳, 严德道
processing, and degradation caused by external conditions of light reception, heat oxidation and the
like in the use process, and the problems that PVC product surfaces are crude and have bubbles are
solved. Worldwide applications

2016 CN
Classi cations

Application CN201610756484.1A events


C08L23/06 Polyethene
2016-08-30 Application led by 江苏联盟化学有限公司, 江苏
View 9 more classi cations 联盟化学有限公司

2016-08-30 Priority to CN201610756484.1A

2016-12-21 Publication of CN106243462A

Info: Patent citations (3), Non-patent citations (4), Legal events,


Similar documents, Priority and Related Applications

External links: Espacenet, Global Dossier, Discuss

Claims (5) Hide Dependent


translated from Chinese

A Ca-Zn stabilizer, characterized in that the percentage by mass of the raw material composition is as follows: calcium stearate 10% -12% zinc stearate 4% -5%, β- 8% -10
diketone %, 4% -30% phosphite antioxidant 12% -15%, hydrotalcite 9% -16%, ΡΕ 13-19% wax, 4-10% epoxidized linseed oil, co-stabilizer I .

2. Ca-Zn stabilizer according to claim 1, wherein the antioxidant is four [β_ (3,5- di-t-butyl-4-hydroxyphenyl) propionate] or β- (3,5-di-t-butyl-4-hydroxyphenyl) propionic acid
esters of n-octadecanol.

Ca-Zn stabilizer according to claim 1, wherein the hydrotalcite or an organic magnesium aluminum hydrotalcite Hydrotalcite.

Calcium zinc stabilizer as claimed in claim 1, characterized in that the secondary stabilizer is pentaerythritol or di-pentaerythritol or polyvinyl alcohol or dipentaerythritol.

5. A method for preparing a Ca-Zn stabilizer, characterized by comprising the following steps: First, the 10% calcium stearate _12% zinc stearate 4% -5%, β- diketone 8% - 10%,
4% -30% phosphite antioxidant 12% -15%, hydrotalcite 9% -16%, ΡΕ 13-19% wax, 4-10% epoxidized linseed oil, co-stabilizer I% -3% in the mixing tank are mixed to form a mixture;
step two, the mixture was stirred in a mixer; step three, the stirred mixture was heated in a reaction vessel, a heating time of ten minutes to three Ten minutes later, after cooling
to obtain a product of the invention.

Description translated from Chinese

Calcium zinc stabilizer and preparation method

FIELD

[0001] The present invention relates to a stabilizer and its preparation method, particularly to a mother zinc stabilizer and a preparation method.

Background technique

[0002] With the enhancement of environmental awareness around the world, the gradual improvement of environmental regulations, particularly pharmaceuticals, food
processing, daily necessities, plastic toys and other plastic products to improve the health requirements, lead, cadmium salt stabilizer will eventually be fully non-toxic
PVC stabilizer substituted agent. Plastic Auxiliaries production will increasingly large-scale customization, environmental protection has been taken seriously, and more
e cient energy development, research and development of new environmentally friendly non-toxic PVC stabilizer has become an inevitable trend. Toxic PVC heat
stabilizers direction focused on two aspects of the organotin compound and a calcium zinc heat stabilizer, and have made considerable progress. Its success mainly
organic tin heat stabilizer study in the United States as the representative of large-scale use and to promote the use of Europe as the representative of a non-toxic
calcium Zn heat stabilizers, organotin but the price is too expensive. Calcium zinc composite stabilizer will eventually build the future of non-toxic PVC stabilizer systems
around the world. While China is still a one-component powdered lead salts and metal soaps mainstream, compared with foreign countries, variety and performance falls
far short of market requirements, liquid composite stabilizer production although some growth, but the proportion of small, Therefore, the research and development of
environment-friendly new variety has not been a major breakthrough.

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5/15/2019 CN106243462A - Calcium/zinc stabilizer and preparation method thereof - Google Patents
[0003] calcium zinc heat stabilizer is currently divided into two categories: solid calcium zinc heat stabilizer, a liquid Ca-Zn composite stabilizer. The solid calcium zinc
heat stabilizer is calcium zinc heat stabilizer initial composite agents products, but also far from the development point of full maturity. Liquid Ca-Zn composite stabilizer
is a non-toxic, transparent, low cost new heat stabilizer in PVC processing is applied, but zinc burn easily occurs with time.

[0004] lead-series products are currently the most widely used organic tin series. But the high price limits its larger increase in number. Ca-Zn composite stabilizer
advantage since non-toxic, often proposed to replace lead salt, but only for the production of soft PVC articles.

[0005] polyvinylchloride (PVC) is one of ve general-purpose synthetic resins, because of their excellent properties, are widely used in industrial buildings, agriculture,
daily necessities, utilities, after the current production of polyethylene (PE ), ranking No. 2 in the plastic. Since the difference in thermal stability of PVC processing, when
it must be added to the hot molding processing stabilizers, heat stabilizers typically mainly lead salt, metal soaps, organic tin, rare earth, and Ca / Zn-based stabilizer and
the like. Since the 1990s, the world, especially Western countries, calls for ban cadmium and other heavy metals lead in the rising heat stabilizers. In 2003 I on May 27,
the EU has o cially announced the "Waste Electrical and Electronic Equipment Directive" (WEEE) and "on the Prohibition of the Use of Certain Hazardous Substances in
Electrical and Electronic Equipment" (RoHs) ο directive from July 2006 I the date is prohibited in the EU market contain lead, mercury, cadmium, hexavalent chromium,
polybrominated biphenyls and polybrominated diphenyl ethers six kinds of hazardous substances in electrical and electronic equipment; in May 2006, ESPA and EUPC
shared commitment to the EU in 2015 a total ban on the use of lead stabilizers for PVC, and the EU in late 2006 Vinyl2010 also banned the use of cadmium stabilizers.
Therefore, at present in the world, non-toxic, non-polluting, e cient complex and has become the development trend of PVC heat stabilizers irreversible. And non-toxic Ca
/ Zn heat stabilizer is now recognized as the world's non-toxic, environmentally friendly heat stabilizers, and has a low price, good lubricity, etc., it has a very broad space
for development.

[0006] In the processing of polyvinyl chloride and vinyl chloride copolymer, a thermal stabilizer must be used, which prevents the PVC during processing due to
degradation caused by heat and mechanical shear, to prevent the article during use heat, light, damaging effects of oxygen. Heat stabilizers composed mainly of lead
salt, an organic metal soaps, organic tin, complex stabilizers, organic heat stabilizers and the like. Wherein, lead, cadmium, barium soaps heat stabilizer due to high
performance and low cost, the heat developed yield about 60% ~ 70% of a stabilizer; ratio of greater, about 80% ~ 90% . For a long time, lead, cadmium stabilizers have
dominated the consumer market in the world PVC heat stabilizers. However, due to the large lead salts and barium cadmium soap heat stabilizers toxicity, there is a
serious threat to human health. Since the 1970s, the world's developed countries, particularly in Europe and other countries have been fully aware of the environmental
problems of lead, cadmium, etc., causing increasingly serious, to be very strict restrictions on lead, cadmium salt, especially food packaging, medical and health
equipment and other security issues cause people attach great importance to research and development of countries around the world lead, cadmium alternatives. China
has a heat stabilizer more than 90 manufacturers, heat stabilizers yield about 50,000 t, the product structure is very uneven, lead, cadmium products accounted for the
vast majority, and non-toxic varieties yield less than 15%. After joining the WTO, to further enhance the people's awareness of environmental protection, research and
development of new environmentally friendly non-toxic PVC stabilizer has become an inevitable trend.

SUMMARY

[0007] The present invention solves the technical problem is to provide a calcium-zinc stabilizer and a preparation method, which is a non-toxic products, in line with the
state environmental requirements, PVC material can effectively inhibit the heat during molding, friction, physical effects and use of the shear degradation by light, heat,
oxidation, etc. caused by external conditions, PVC products avoid rough surface, there is a problem of bubbles.

[0008] The present invention is to solve the above problems by the following technical solutions: A Ca-Zn stabilizer, characterized in that the percentage by mass of the
raw material composition is as follows: calcium stearate 10% -12%, stearic zinc 4% ~ 5%, β- diketone 8% -10%, 4% -30% phosphite antioxidant 12% -15%, hydrotalcite 9%
-16%, ΡΕ wax 13% -19 %, epoxidized linseed oil 4% -1 O%, auxiliary stabilizer I% -3%.

[0009] Preferably, the antioxidant is four [β- (3,5- di-t-butyl-4-hydroxyphenyl) propionate], or [beta] (3,5-di-t-butyl-4 - hydroxyphenyl) propionic acid esters of n-octadecanol.

[0010] Preferably, the hydrotalcite is an organic or magnesium aluminum hydrotalcite Hydrotalcite.

[0011] Preferably, the auxiliary stabilizer is a polyvinyl alcohol or pentaerythritol or dipentaerythritol or dipentaerythritol.

[0012] The present invention also provides a method for preparing a Ca-Zn stabilizer, characterized by comprising the steps of:

[0013] Step a, the calcium stearate 10% -12% zinc stearate 4% _5%, β_ -dione 8% -10%, 4% -30% phosphite antioxidant 12% -15%, hydrotalcite 9% -16%, ΡΕ 13-19% wax, 4-
10% epoxidized linseed oil, an auxiliary I% -3% stabilizer were mixed to form a mixed material in a mixing tank;

[0014] Step two, the mixture was stirred in a mixer;

[0015] Step three, the mixture was stirred in a reaction vessel is heated, a heating time of ten to thirty minutes, and cooled to obtain the product of the present invention.

[0016] The positive effect of the present invention is characterized in progress: Ca-Zn stabilizer of the invention is a non-toxic products, in line with the state
environmental requirements, can effectively inhibit the action of physical PVC material during molding of the heat, friction, shear, and the use of during degradation by
light, heat, oxidation, etc. caused by external conditions, yet provide a stabilizer e ciency and thermal stability, surface roughness PVC products avoid sugar, has
problems of air bubbles, low cost, simple to manufacture and convenient.

BRIEF DESCRIPTION

[0017] FIG. 1 is a owchart of a method for preparing calcium zinc stabilizer of the present invention.

Detailed ways

[0018] The following drawings are given preferred embodiments of the present invention, to be described in detail in conjunction with the technical solutions of the
present invention.

[0019] Ca-Zn stabilizer of this invention by the following mass percentage of raw material composition: 10% calcium stearate _12% zinc stearate 4% -5%, β- diketone 8%
-10%, phosphites 4 % -30%, 12% -15%, antioxidants, hydrotalcite 9% -16%, PE wax 13% -19%, 4-10% epoxidized linseed oil, auxiliary stabilizer I% -3%.

[0020] The antioxidant is four [β- (3,5_ di-t-butyl-4-hydroxyphenyl) propionate] or β- (3,5_ di-t-butyl-4-hydroxyphenyl) n-octadecanol acid esters, such low cost, good
antioxidant effect.

[0021] Hydrotalcite is an organic or magnesium aluminum hydrotalcite Hydrotalcite, such a low cost.

[0022] The auxiliary stabilizer is a polyvinyl alcohol or pentaerythritol or dipentaerythritol or dipentaerythritol, such a low cost, to increase stability.

[0023] As illustrated, the production method of the present invention Ca-Zn stabilizer 1 comprising the steps of:

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5/15/2019 CN106243462A - Calcium/zinc stabilizer and preparation method thereof - Google Patents
[0024] Step a, to 10% calcium stearate _12% zinc stearate 4% _5%, β_ -dione 8% -10%, 4% -30% phosphite antioxidant 12% - 15%, hydrotalcite 9% -16%, ΡΕ 13-19% wax, 4-
10% epoxidized linseed oil, an auxiliary I% -3% stabilizer were mixed to form a mixed material in a mixing tank;

[0025] Step two, the mixture was stirred in a mixer;

[0026] Step three, the mixture was stirred in a reaction vessel is heated, a heating time of ten to thirty minutes, and cooled to obtain the product of the present invention.

[0027] Example 1

[0028] The 12% calcium stearate, zinc stearate 5%, β_ diketone 8%, 4% phosphite antioxidant 15%, hydrotalcite 16%, ΡΕ 19% wax, epoxy linseed 10% oil, 1% of co-stabilizer
mixture formed by mixing in a mixing tank; the mixture was stirred in a mixer; the stirred mixture is heated in a reaction kettle, heating time is ten minutes, cooled to give
product of the invention.

[0029] Example 2

[0030] The 10% calcium stearate, zinc stearate 4%, β_ dione 10%, 24% phosphite antioxidant 12%, hydrotalcite 11%, ΡΕ 18% wax, epoxy linseed after stirring the mixture
was heated in a reaction vessel, heating time of thirty minutes, cooled; 9% oil, 2% of co-stabilizer mixture formed by mixing in a mixing tank; the mixture was stirred in a
mixer to give the product of the present invention.

[0031] Example 3

[0032] The 11% calcium stearate, zinc stearate 4.5%, β_ dione 9.5%, phosphites 30%, 13% antioxidants, hydrotalcite 13%, ΡΕ 13% wax, epoxidized linseed oil 4%, 3%
auxiliary stabilizer in a mixing tank mixed to form a mixture; mixture was stirred in a mixer; the stirred mixture is heated in a reaction kettle, heating time is twenty
minutes, cooled to give product of the invention.

[0033] Ca-Zn stabilizer of this invention is a non-toxic products, in line with the state environmental requirements, can effectively inhibit the PVC material is heated during
molding, the physical effect of friction, shearing and use light, thermal oxidation and other external conditions that cause degradation of PVC products avoid rough
surface, there is a problem of bubbles, low cost, simple to manufacture and convenient, stabilizers to improve thermal stability and e ciency, greatly promoted the
development of molded PVC processing industry, to produce a more high-quality PVC products, PVC has a leading role in the development of the industry. An auxiliary
heat stable e ciency stabilizer has a synergistic effect can be improved Ca-Zn stabilizer, i.e., to develop e cient auxiliary stabilizer, thereby improving the initial color of
PVC and improved long-term thermal stability of PVC.

[0034] The foregoing speci c embodiments, the technical problem, technical solutions, and bene cial effects of the solution according to the present invention has been
described in further detail, should be understood that the above descriptions are merely embodiments of the present invention only, and not intended to limit the present
invention, all within the spirit and principle of the present invention, any changes made, equivalent substitutions and improvements should be included within the scope of
the present invention.

Patent Citations (3)

Publication number Priority date Publication date Assignee Title

CN101429289A * 2008-11-28 2009-05-13 杭州油脂化工有限公 Environment-friendly calcium-zinc compound stabilizer


CN101942110A * 2010-09-06 2011-01-12 芜湖海螺型材科技股 Zn-Ca compound stabilizer


份有限公司

CN105542356A * 2016-03-04 2016-05-04 隋东阳 Ca-Zn composite stabilizer for PVC (polyvinyl chloride) cables and preparation
method of Ca-Zn composite stabilizer

Family To Family Citations

* Cited by examiner, † Cited by third party

Non-Patent Citations (4)

Title

《合成材料助剂手册》编写组 编: "《合成材料助剂手册》", 30 April 1977 *

郑德 等主编: "《塑料助剂系列丛书 稳定剂》", 30 June 2011 *

《合成材料助剂手册》编写组 编: "《合成材料助剂手册》", 30 April 1977 *

郑德 等主编: "《塑料助剂系列丛书 稳定剂》", 30 June 2011 *

* Cited by examiner, † Cited by third party

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Priority And Related Applications

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Application Filing date Title

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Legal Events

Date Code Title Description

2016-12-21 C06 Publication

2017-01-18 C10 Entry into substantive examination

2016-12-21 C06 Publication

2017-01-18 C10 Entry into substantive examination

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