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Experiment 1: Thermoelectricity
A. Introduction
Thermoelectricity, i.e. direct conversion of electricity into heat or heat into electricity, is very
important in modern technique: Peltier-coolers are common parts in PC’s; thermocouples are
widely used for temperature measurements; and radioisotope thermoelectric generators are used
in space missions; for examples. In this problem a semiconductor thermoelectric cell is studied.
Initially the cell is used as a thermocouple, and the Seebeck-coefficient, the internal resistance of
the cell, as well as the efficiency of the thermoelectric generator are to be measured. Then it is
studied as a Peltier-cell and the Peltier-coefficient is measured. Finally the absolute temperature
can be determined from Seebeck- and Peltier-coefficient.
B. Theoretical background
The thermoelectric cell used in this measurement consists of several n-type and p-type semiconduc-
tors connected in series and attached between two aluminium plates using electrically insulating
glue that is a good thermal conductor at the same time (Fig. 1(a) and Fig. 1(b)). The cell can be
used as a thermoelectric generator or as a Peltier-cell. In the first case the temperature difference
between the plates generates an electromotive force (emf) between the terminals of the cell, in the
second case the current through the cell pumps heat from one plate to the other.
Figure 1: (a) Left: Schematic of Thermoelectic cell (b) Right: Thermoelectric cell
B.1
In these processes the following thermoelectric and purely thermal phenomena are performing
significant roles:
B.1.1 Seebeck-effect
Let us consider a simple set-up of n- and p-type semiconductors connected as shown in Fig. 2.
If we keep plates A and C at temperature T0 and plate B at temperature T = T0 + ∆T then a
voltage V = α · ∆T occurs between A and C. The constant α (called Seebeck-coefficient) depends
on the properties of the different materials (in this case n-type and p-type semiconductors) but
independent of the connecting materials.
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Problem Creator: Peter Vanko
Experiment 1: Thermoelectricity
Figure 2:
B.1.2 Peltier-effect
If we force an electric current I through the set-up on Fig. 2 then, at the connection of the two
different materials (B), heat is absorbed or emitted, depending on the direction of the current.
The heat absorbed or emitted per unit time is P = π · I , where π is the Peltier-coefficient. The
Peltier-coefficient π is not independent of the Seebeck-coefficient α:
π = α · T, (1)
B.1.3 Joule-heat
An electric current I flowing through a conductor releases heat. The heat released per unit time is
P = R · I 2 , where R is the (temperature-dependent) resistance of the conductor. The Joule-heat
released in the thermoelectric cell is equally distributed between the two sides of the cell.
Similarly Fig. 3(b) shows the thermal scheme of the cell used as a Peltier cooler. Using electric
power (PP , Peltier-power) the cell absorbs heat (P2 ) on the cooled side and emits the total heat
at the heated side (P1 ). Notice the opposite effect of the thermal conduction.
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Problem Creator: Peter Vanko
Experiment 1: Thermoelectricity
C. Apparatus
A. 1 × top part with heating resistor (big red-black connectors) and platinum thermometer
(small red-black connectors, RH = 10 Ω)
B. 1 × thermoelectric cell (red and black connectors) with heat conducting paste
C. 1 × bottom part with water cooling and platinum thermometer (small red-black connectors)
F. 4 × multimeters
H. 1 × stop watch
ATTENTION! Use the apparatus always as suggested in the tasks, otherwise you
can cause damages of the apparatus. Take care of the correct polarity of the cell, the
appropriate range of the multimeter, the maximum allowed values of voltage, current
and power.
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Problem Creator: Peter Vanko
Experiment 1: Thermoelectricity
Figure 4:
TASKS
Place the isolation cup carefully on the top part. Check whether the water cooling system works
properly.
The resistance of the heating resistor (big yellow connectors) is RH = 10.0 ohm which can be
taken independent of temperature in the range of your measurement. The heating power can be
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Problem Creator: Peter Vanko
Experiment 1: Thermoelectricity
Figure 5:
controlled by the output voltage of the power supply. At the next measurement start with a small
heating voltage (VH = 2.00V , e.g.) and later increase the voltage from time to time. Finally
increase the heating voltage up to VH = 10.0 V and after this measurement leave it switched on.
ATTENTION! Never use more then 10 V heating voltage in this task.
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Problem Creator: Peter Vanko
Experiment 1: Thermoelectricity
To obtain maximum external power from the cell, the resistance of the load should be equal to
the internal resistance of the cell. We can approach this maximum if the resistance of the load
and the internal resistance of the cell are in the same range. For the sake of this you can use an
ammeter (in range 200 mA) as a load.
If you connect the ammeter the launched current decreases the temperature difference between
the two sides of the cell (because of Peltier-effect) and thus it decreases the electromotive force,
too. After some time a new equilibrium can be approached with a constant voltage VE and a
constant current IE .
ATTENTION! If you are ready with this task, switch off the power supply connected
to the heating resistor.
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Problem Creator: Peter Vanko
Experiment 1: Thermoelectricity
ATTENTION! The red connector must be connected to the positive output of the
power supply. (Otherwise the top part will be heated instead of be cooled.)
ATTENTION! The Peltier current is bigger then 200 mA. Use the COM and 10
ADC inputs of the multimeter and the 10 A range; otherwise you can damage the
multimeter.
In this task you will cool down the top part by the cell used as a Peltier-cooler. During your
measurement you have to apply a constant Peltier-power PP = 1.00 W. But, because of the
changing electromotive force appearing on the cell, the Peltier-current IP is changing during the
measurement. So time to time you have to change the Peltier-voltage VP in order to keep the
Peltier-power PP constant. For easy and fast adjustment use the following table.
IP (A) VP (V) IP (A) VP (V) IP (A) VP (V) IP (A) VP (V) IP (A) VP (V)
0.40 2.50 0.50 2.00 0.60 1.67 0.70 1.43 0.80 1.25
0.41 2.44 0.51 1.96 0.61 1.64 0.71 1.41 0.81 1.23
0.42 2.38 0.52 1.92 0.62 1.61 0.72 1.39 0.82 1.22
0.43 2.33 0.53 1.89 0.63 1.59 0.73 1.37 0.83 1.20
0.44 2.27 0.54 1.85 0.64 1.56 0.74 1.35 0.84 1.19
0.45 2.22 0.55 1.82 0.65 1.54 0.75 1.33 0.85 1.18
0.46 2.17 0.56 1.79 0.66 1.52 0.76 1.32 0.86 1.16
0.47 2.13 0.57 1.75 0.67 1.49 0.77 1.30 0.87 1.15
0.48 2.08 0.58 1.72 0.68 1.47 0.78 1.28 0.88 1.14
0.49 2.04 0.59 1.69 0.69 1.45 0.79 1.27 0.89 1.12
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Problem Creator: Peter Vanko
Experiment 1: Thermoelectricity
In this task you will use the Peltier-cooler and the heating resistance in the same time. You have
to keep the Peltier-power at constant value PP = 1.00 W, as in the last task and you have to
apply heating powers PH1 = 5.00 W, PH2 = 11.00 W and PH3 = 18.00 W.
ATTENTION! If you are ready with this measurement, switch off both power
supplies.
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Problem Creator: Peter Vanko
Experiment 1: Thermoelectricity
If the temperature difference ∆TE = 0 , there is no thermal conduction and so the external heat
pumped by the Peltier-cell in unit time is equal with the heating power PH0 . The Peltier-cell can
pump more heat per unit time then the electric power consumed, therefore here the term
“coefficient of performance” is used instead of the term “efficiency” used for thermoelectric
generator. The cell’s coefficient of performance ε is the quotient of the external heat pumped per
unit time and the electric power consumed by the cell.
If the temperature difference ∆TE = 0, there is no electromotive force generated in the cell and
the Peltier-current IP can be simply calculated from the Peltier-power PP and the internal
resistance of the cell RC measured earlier.
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