Resonance Advance (1-1) PDF

® Code
P16-18
0
CUMULATIVE TEST-1(CT-1)
(JEE ADVANCED PATTERN)
TARGET : JEE (MAIN + ADVANCED) 2019
PAPER-1 | CLASS XII/XIII | COURSE : ALL INDIA TEST SERIES (VIKALP)
Date : 29-07-2018 Time: 3 Hours Maximum Marks : 240
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the back cover of
this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
4. Blank spaces are provided within this booklet for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.
DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

6. After the open booklet, verify that the booklet contains all the 60 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :

7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has two sections.
8. Each section as detailed in the following table :
Category-wise Marks for Each Question Maximum
Number of
Section Question Type Marks of the
Questions Negative
Full Marks Partial Marks Zero Marks Section
Marks
+4 +1
0
If only the bubble(s) For darkening a bubble –2
One or More If none of
1 10 corresponding to all corresponding to each correct In all other 40
Correct Option(s) the bubbles
the correct option(s) option, provided NO incorrect cases
is darkened
is(are) darkened option is darkened
+4
0
Comprehension If only the bubble –2
If none of
2 (Single Correct 10 corresponding to the – In all other 40
the bubbles
Option) correct option is cases
is darkened
darkened
OPTICAL RESPONSE SHEET :
9. Darken the appropriate bubbles on the original by applying sufficient pressure.
10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
11. Do not tamper with or mutilate the ORS.
12. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this purpose on
the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each digit of your roll
number.
DARKENING THE BUBBLES ON THE ORS :
13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
14. Darken the bubble COMPLETELY.
15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.
18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles are
evaluated.
NAME OF THE CANDIDATE : ………………………………………………………………..………………………

ROLL NO. : ………………………..………………………
I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator
Resonance Eduventures Ltd.

CORPORATE / REG. OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : 07446607777, (0744) 3012100, 3012222, 6635555 | Toll Free : 1800 258 5555 | FAX No. : +91-022-39167222 | 80034 44888
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN: U80302RJ2007PLC024029
® Code
P16-18
0
CUMULATIVE TEST-1(CT-1)
(JEE ADVANCED PATTERN)
TARGET : JEE (MAIN + ADVANCED) 2019
PAPER-1 | CLASS XII/XIII | COURSE : ALL INDIA TEST SERIES (VIKALP)
fnukad : 29-07-2018 l e; : 3 ?k.Vs egÙke v ad : 240
Ñ i;k bu funsZ'kksad ks/;ku lsi<+saA v kid ks5 feuV fo'ks"k : i lsbl d ke d sfy , fn;sx;sgSaA
l kekU; %
1. ;g eksgjcU/k iqfLrd k vkid k iz'u i=k gSA bld h eqgj rc rd u rksM sat c rd bld k funsZ'k u fn;k t k;sA
2. iz'u&i=k d k d ksM (CODE) bl i`"B d sÅ ijh nk;sad ksuasij Nik gSA
3. iz'uksad k mÙkj nsusd sfy , vy x lsnh x;h vkWIVhd y fjLikal 'khV ¼vks- vkj- ,l-½ ( O RS ) d k mi;ksx d jsaA
4. d Ppsd k;Zd sfy , bl iqfLrd k esa[kky h LFkku fn;sx;sgSaA
5. bl i`"B ij uhpsfn, x, LFkku esaviuk uke rFkk jksy uEcj fy f[k,A
6. bl iqfLrd k d ks[kksy usd si'pkr~] d ì;k t k¡p y safd lHkh 60 iz'u vkSj mud smÙkj fod Yi Bhd lsi<sat k l d rsgSaA
iz'ui=k d k izk: i v kSj v ad u ;kst uk %

7. bl iz'u&i=k esarhu Hkkx gSa% xf.kr] HkkSfrd foK ku v kSj jl k;u foK kuA gj Hkkx esanks[kaM gSaA
8. çR;sd [kaM d k fooj.k fuEufy f[kr rkfy d k esafn;k x;k gS%
oxkZuql kj izR;sd iz'u d svad [kaM esa
[kaM iz'u d k izd kj iz'uksad h l a[;k
iw.kZvad vkaf'kd vad 'kwU; vad _ .k vad vf/kd re vad
+4 0
+1
;fn flQ Zlgh ;fn fd lh Hkh –2
,d y ;k ,d lsvf/kd iz
R;sd lgh fod Yi d svuq: i cqy cqy s
1 10 fod Yi@fod Yiks ad svuq: i cq
y cqy sd ks vU; lHkh 40
lgh fod Yi d ksd kyk d jusij] ;fn d ksbZxyr
cqy cqy s@ cqy cq
y ksad ksd kyk d ky k ugha ifjfLFkfr;ksaes
a
fod Yi d kyk ughafd ;k gS
fd ;k gS fd ;k gS
0
+4
;fn fd lh Hkh –2
vuqPNsn ;fn flQ Zlgh fod Yi d s
2 10 – cq
y cqy sd ks vU; lHkh 40
¼,d y lgh fod Yi½ vuq: i cqy cqy sd ksd kyk
d ky k ugha ifjfLFkfr;ksaes
a
fd ;k gS
fd ;k gS
v kWfIVd y fjLikal 'khV %
9. Å ijh ewy i`"B d svuq: i cqy cqy ksa(BUBBLES) d ksi;kZIr ncko Mky d j d ky k d jsaA
10. ewy i`"B e'khu&t k¡P; gSrFkk ;g ijh{kk d slekiu ij fujh{kd d s}kjk ,d =k d j fy ;k t k;sxkA
11. vks-vkj-,l- d ksgsj&Q sj@fod f̀r u d jsaA
12. viuk uke] jksy ua- vkSj ijh{kk d sanzd k uke ewy i`"B esafn, x, [kkuksaesad y e lsHkjsavkSj viusgLRkk{kj d jsaA buesalsd ksbZHkh t kud kjh
d ghavkSj u fy [ksaA jksy uEcj d sgj vad d suhpsvuq: i cqy cqy sd ksd ky k d jsaA
ORS ij cqy cqy ksad ksd ky k d jusd h fof/k %
13. Å ijh ewy i`"B d scqy cqy ksad ksd ky sckWy ikbUV d y e lsd ky k d jsaA
14. cqy cqy sd ksiw.kZ: i lsd ky k d jsaA
15. cqy cqy ksad ksrHkh d ky k d jsat c vkid k mÙkj fuf'pr gksA
16. cqy cqy ksad ksd ky k d jusd k mi;qDr rjhd k ;gk¡n'kkZ;k x;k gS%
17. d ky sfd ;sgq;scqy cqy sd ksfeVkusd k d ksbZrjhd k ughagSA
18. gj [k.M d siz kjEHk es
anh x;h va d u ;kst uk es
ad kysfd ;sx;srFkk d kysu fd ;sx;scqy cq
y ks
ad ksewY;ka
fd r d jusd k rjhd k fn;k x;k gSA
ijh{kkFkhZd k uke : ………………………………………………………………..………………………

jksy uEcj : ………………………..………………………
eSauslHkh funsZ'kksad k i<+fy ;k gSvkSj eSamud k eSusaijh{kkFkhZd k ifjp;] uke vkSj jksy uEcj
vo'; iky u d : ¡xk@d : ¡xhA d ksiwjh rjg t k¡p fy ;k gSA
------------------------- -------------------------
ijh{kkFkhZd sgLrk{kj ijh{kd d sgLrk{kj
Resonance Eduventures Ltd.

CORPORATE / REG. OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : 07446607777, (0744) 3012100, 3012222, 6635555 | Toll Free : 1800 258 5555 | FAX No. : +91-022-39167222 | 80034 44888
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN: U80302RJ2007PLC024029
PART : I MATHEMATICS
SECTION – 1 : (Maximum Marks : 40)
 This section contains TEN questions
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.
2
1. If  are the roots of quadratic equation ax + bx + c = 0, a  0 then
2
(A) roots of equation a(x  1)  b(x  1)  c  0 are   1 and   1
(B) roots of equation a(x  1)2  b(x  1)  c  0 are   1 and   1
 
(C) roots of equation ax 2  bx(x  1)  c(x  1)2  0 are and
1  1 
 
(D) roots of equation ax 2  bx(x  1)  c(x  1)2  0 are and
1  1 
2. For the equation x  1  x  3  2x  4  x which of the following is/are true
(A) for   1 above equation has two solutions (B) for   (0,1) equation has three solutions
(C) for   (0,2) equation has three solutions (D) for   0 equation has infinite solutions
Space for Rough Work
Corp. / Reg. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
P1JRCT1290718C0-1
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
2 2
3. If m, n  N such that 3m + m = 4n + n, then
2 2
(A) (m – n) (3m + 3n + 1) is divisible by m (B) (m – n) (3m + 3n + 1) is divisible by n
2 2
(C) (m – n) (4m + 4n + 1) is divisible by m (D) (m – n) (4m + 4n + 1) is divisible by n
4. Let ‘f’ is the greatest integer function & ‘g’ be the modulus function, then
 5
(A)  gof  fog     1 (B) (f + 2g) (- 1) = 1
 3
 5
(C)  gof  fog    0 (D) (f + 2g) (1) = 1
 3
2 3
5. If log|sinx| (x – 8x + 23) – > 0, then set of values of x contains
log2 | sin x |
(A) (, 5) (B) (3, )
 3   3 
(C)  ,  (D)  ,5
 2  2 
2 2 2 2 2 2
6. Let a,b,c be the three sides of a triangle and f(x) = b x + (b + c – a )x + c , then which of the
following is/are CORRECT?
(A) f(x) > 0  x  R (B) f(x)  0  x  R
(C) f(1) > 0 (D) f(a + b + c) = 0
P1JRCT1290718C0-2
sin2 x  4 sin x  5
7. If f(x) = , then
2 sin2 x  8 sin x  8
5 3
(A) minimum value of f(x) is (B) maximum value of f(x) is
9 4
4
(C) minimum value of f(x) is (D) maximum value of f(x) is 1
9
8. If a + b+ c+ ab + bc + ca + abc =2005 where a,b,c are distinct natural number such that a < b < c
then
(A) a = 1 (B) b = 15 (C) c = 58 (D) a + b + c = 75
 2  2 
9. The period of the function f(x) = sin   x {x}   , where {.} represents fractional part function
 3  3 
is
(A) 3 (B) 5 (C) 6 (D) 7
10. If  = 2log2 (cos x) and  = eloge (tan x) then  cannot be equal to
2 1 3
(A) – (B) 0.9 (C) (D)
3 0.9 5
P1JRCT1290718C0-3
 This section contains FIVE paragraphs
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct
 For each question, darken the bubble corresponding to the correct option in the ORS
 Marking scheme :
+4 If only the bubble corresponding to the correct option is darkened
0 If none of the bubbles is darkened
–2 In all other cases
Paragraph for Question Nos. 11 to 12

Every real number x can be expressed as x   x   x  where [.] represents GIF and {.} represent
fractional part of x
11. Number of solutions of equation 5x  20{x}  3[x]  7 are

(A) 12 (B) 10 (C) 9 (D) 13
12. If S1 is solution of inequality [3x]  [x]  2  3x and S 2 is the solution of [x]2  [x]  6  0 then
7 8 
(A) set of values of S 1  S2 is [–3, –2)  (2, 3) –  , 
3 3 
(B) set of values of S 1  S2 is [–3, –2)  (2, 3)
(C) set of values of S2 is [–3, –2)  (2, 3)
(D) set of values of S1 is [–3, –2)  [2,
3)
P1JRCT1290718C0-4
2 2
Let f(x) = x + xg'(1) + g"(2) and g(x) = f(1) x + xf'(x) + f"(x).
f x
13. The domain of function is
g x
2 
(A) (–, 1]  (2, 3] (B) (–2, 0]  (1, ) (C) (–, 0]   ,3  (D) (–, 2]  [3, )
3 
1
14. Let A be the solution set of in-equation f(x) > 0. The domain of the function h(x) =  f(x)  g( x ) is
2 2
(A) A (B) A –   (C) R –   (D) R
3  3 
Consider the bi-quadratic equation E : x 4  5x3  (  2)x 2  5x  1  0 then
15. The real values of '  ' so that equation E has four real solutions
 25   25   25 
(A)  6,  (B) (–,–14)  6,  (C) (6,7) (D)  5,   (7, )
 4   4   4 
16. Values of '  ' so that equation E has two real solutions
 25   25 
(A)  14,8    (B)  14,6     (C)  14,6  [ 7, ) (D)  2,  
4  4 
P1JRCT1290718C0-5
 2 – x , x  1
f : R R , f(x) =  2
, g(x) is inverse of f(x).
 2x – x , x  1
2
Number of roots of f(x) = g(x) is equal to 'a'. The expression h(x) = ax + bx + c , where a is as
above, f(b) = 0 and c is the greatest integer for which f(x) > 0.
17. Value of 'a' is

(A) 1 (B) 2 (C) 3 (D) 4
18. Minimum value of h(x) is

(A) 2/3 (B) 1/3 (C) 0 (D) 1

x 2 – 6x  5
Consider a function f(x) =
x 2  2x  1
2
19. If g(x) = (x + 1) f(x) then which of the following is CORRECT ?
1 1
(A) Least value of f(x) is . (B) Least value of f(x) is – .
3 4
(C) range of g(x) is [– 4, ) (D) range of g(x) is [– 4, ) – {12}
20. The function f(x) is/are

(A) one-one, onto (B) many-one, onto
(C) one-one, into (D) many-one, into
P1JRCT1290718C0-6
PART : II PHYSICS

darkened.
21. Two identical glass slabs of same thickness are joined to form an 'L' shape as shown. A ray is
incident on the combination as shown (in the plane of paper). For the final emergent ray, choose
incorrect option(s):
45°

A
(A) Will come out at point A in the same direction as that of origional ray.
(B) Will come out at point A but not in the same direction as that of origional ray.
(C) Does not come out at point A but is in the same direction as origional ray.
(D) Does not come out at point A and it is not in same direction as origional ray.
P1JRCT1290718C0-7
22. Which of the following can never be the separation between a point real object lying on the optical
axis of a converging lens of focal length 20 cm and its real image.
(A) 60 cm (B) 90 cm (C) 45 cm (D) 150 cm
23. For the system shown in figure, the tension in the string is T (inclined surfaces are frictionless).
m
mass is shifted from A to B or B to A as per given in options. Then :
2
(A) Tension in the string will increase when mass is shifted from A to B.
(B) Tension in the string will increase when mass is shifted from B to A.
(C) acceleration of blocks will increase when mass is shifted from A to B.
(D) acceleration of blocks will increase when mass is shifted from B to A.
24. There are three optical media 1,2 and 3 with their refractive index 1 , 2 and 3 such that 1 > 2 > 3.
Choose the correct options (TIR means total internal reflection)
(A) When a ray of light travels from medium 3 to 1 TIR can not take place.
(B) Critical angle between medium 1 and 2 is less then the critical angle between 1and 3 .
(C) Critical angle between medium 1 and 2 is more then the critical angle between 1and 3 .
(D) If C1, C2 and C3 are the speed of light in medium 1, 2 and 3 then C1 < C2 < C3.
P1JRCT1290718C0-8
25. At the same instant, two boys throw balls A and B from the window with speeds 0 and k0
respectively, where k is constant. They collide in air at time t. Which of the following options is/are
correct.
cos  2 sin 2
(A) k = (B) k =
cos 1 sin 1
h h
(C) t = (D) t =
(kv 0 sin 1  v 0 sin  2 ) (kv 0 cos 1  v 0 cos 2 )
2
26. For a body in motion position is given as a function of time as, x = at + bt + c, where a, b and c
are constants. The dimension of c are same as those of :
(A) x
(B) at
2
(C) bt
bc 2
(D) 2
a
P1JRCT1290718C0-9
R
27. The figure below shows an object O placed at a distance to the left of a concave spherical
4
mirror that has radius of curvature R. Point C is the center of curvature of the mirror. Size of the
object is much smaller than the radius of curvature of the mirror. The image formed by the mirror is
R
4
R R
(A) at a distance to the right of the mirror (B) at a distance to the left of the mirror
2 2
(C) larger in size and inverted (D) larger in size and upright

28. A boat crosses a river at a velocity v (relative to water) that is constant relative to water and

perpendicular to the banks. The magnitude of the velocity v is 0.3 m/s. Width of the river is
b = 63 m. Speed of the current varies according to the parabolic law.
2
4u0  b
u = u0 – x – 
b2  2
where x is distance from the banks and u0 is constant equal to 5m/s. Choose the correct options.
(A) Drift of the boat during the time it crosses the river is 1050m.
(B) Drift of the boat during the time it crosses the river is 700m
(C) Time taken by the boat to crosses the river is 210 sec.
(D) Time taken by the boat to crosses the river is 12.6 sec.
P1JRCT1290718C0-10
29. At an instant particle-A is at origin and moving with constant velocity (3iˆ  4ˆj) m / s and particle-B
is at (4,4)m and moving with constant velocity (4iˆ  3ˆj) m / s . Then at this instant which of the
following options are CORRECT :
(A) relative velocity of B w.r.t. A is ( ˆi  7ˆj) m / s
(B) approach velocity of A and B is 3 2 m/s

(C) relative velocity of B w.r.t. A remains constant
(D) approach velocity of A and B remains constant
30. A block is hanging with a light rope in a lift as shown in the figure (a). The lift is moving in upward
direction and its velocity time graph is plotted as shown in the figure (b) : (take g = 10 m/s2 ,
velocity is taken as positive in upward direction)
(A) Tension in the rope at t = 1 sec is 100 N

(B) Tension in the rope at t = 3 sec is 240 N
(C) Tension in the rope at t = 5 sec is 200 N
(D) Tension in the rope at t = 1 sec is 200 N
P1JRCT1290718C0-11
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct 

L is a equi convex thin lens, whose radius of curvature (of each side) is increasing with constant
dR
rate = 1 cm/s. At t = 0 radius of curvature of surfaces are 10 cm. A real object of size 1 cm is
dt
kept on the principal axis of lens at a distance 30 cm from optical centre of the lens as shown in
figure.
31. Choose the correct options regarding velocity of image

18
(A) velocity of the image formed at t= 0 is cm/sec, away from the lens.
25
9
(B) velocity of the image formed at t = 0 is cm/sec, towards the lens.
25
(C) velocity of image at t = 20 sec is 3 cm/s away from the lens
(D) velocity of image at t = 20 sec is 1 cm/s away from the lens
32. Choose the incorrect option regarding position and nature of image
(A) at t = 0, image is real and at distance, 6 cm from lens
(B) at t = 20 sec size of object and image is same
(C) at t = 70 sec image is virtual
(D) at t = 20 sec image is virtual
P1JRCT1290718C0-12
Paragraph for Questions 33 and 34
A ball is projected with initial velocity u = 20 m/sec at an angle  = 30º (from horizontal) from point
A which is at a height H = 20m above horizontal. P is the highest point for complete motion of
particle, whereas M is the point at which particle strikes ground. (g = 10 m/s2)
33. Velocity (along vertical direction) of the particle at point P is :
(A) 0 m/sec (B) 10 3 m/sec (C) 5 3 m/sec (D) 4 3 m/sec
34. Total time of flight (from A to M) of the projectile is :
(A) 2 sec (B) ( 5  1) sec (C) ( 5 – 1) (D) (2  5 ) sec
P1JRCT1290718C0-13
Paragraph for Questions 35 and 36
Raindrops are falling with a velocity 10 2 m/s making an angle of 450 with the vertical. The drops
appear to be falling vertically to a man running with constant velocity. The velocity of rain drops
change such that the rain drops now appear to be falling vertically with 3 times the velocity it
appeared earlier to the same person running with same velocity.
35. After the velocity of rain drops change, the magnitude of velocity of raindrops with respect to
ground is
(A) 20 m/s (B) 20 3 m/s (C) 10 m/s (D) 10 3 m/s
36. The angle (in degrees) between the initial and the final velocity vectors of the raindrops with
respect to the ground is
(A) 8 (B) 15 (C) 22.5 (D) 37
P1JRCT1290718C0-14
Two concave refracting surfaces S1 and S2 each with radius of curvature R = 35 cm and refractive
indices 1 and 2 respectively, are placed facing each other in air as shown in figure. A point object
'O' is placed at a distance R/2 from one of the surface as shown. Answer the following : (Consider
image formation only by paraxial rays)
Air
S1 S2
37. Distance of image after refraction from 1st surface (1 = 1.5) is equal to :
(A) 45 cm towards left of P1
(B) 45 cm towards right of P1
(C) 30 cm towards left of P1
(D) 30 cm towards right of P1
38. Separation between the images of 'O' formed by each refracting surface is equal to : (2 = 1.5)
(A) 8 cm
(B) 4 cm
(C) 2 cm
(D) cannot be determined
P1JRCT1290718C0-15
Consider the given system shown in figure. At certain instant velocity of lift (w.r.t. ground), velocity
of A (relative to lift) is shown. Velocity of lift is constant.
39. Choose the correct options.

(A) Velocity of A relative to ground is 6 m/s upward
(B) Velocity of B relative to ground is 2 m/s upward
(C) Velocity of B relative to ground is 4 m/s downward
(D) Velocity of A relative to ground is 4 m/s upward
40. If mA = mB = m, choose the correct options.

g g
(A) acceleration of A is downward (B) acceleration of A is upward
3 5
6mg g
(C) force on the ceiling of lift by string is (D) acceleration of B is downward
5 5
P1JRCT1290718C0-16
PART : III CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

darkened.
41. Which of the following will be same for Glucose and Acetic acid ?
(A) Molar mass (B) Empirical formula mass
(C) % of carbon by mass (D) Empirical formula
P1JRCT1290718C0-17
42. Which of the following compound does not obey octet rule?
(A) CO2 (B) SF6 (C) PCl5 (D) O2
43. Which of the following statement(s) about critical constants of gases is/are correct?
Tc
(A) Larger the P value of a gas, larger would be the excluded volume.
c
(B) Critical temperature  Tc  of gas is greater than it's Boyle's temperature (TB)
 P 
(C) At the critical point in the vander Waals gas isotherm   0
 Vm Tc
(D) Vc  3a
44. Select the correct option(s) :
(A) rF   rH (B) rBr   rCl–
(C) r (rCl  – rF – ) > r (rBr  – rCl – ) (D) r (rBr  – rCl – ) > r (rCl  – rF – )
P1JRCT1290718C0-18
E
Z z>1
45.
Z=1
D
A C
B dz
dz >0 z<1
<0 dz dp
dp =0
dp
P
The correct statement(s) regarding the above Z v/s P plot for a real gas :
(A) At points A & C repulsion tendencies are present but attractive tendencies are dominant.
(B) The maximum attractive tendency is at point B.
(C) The point corresponding to the Boyle's temperature (TB) in low pressure region has attraction
tendencies = Repulsion tendencies.
(D) At point E, the gas is difficult to liquefy.
46. Select the INCORRECT statement(s) :

d
(A) y-intercept of the graph of (g/atm-L) v/s P (atm) at 360 K for a real gas is 2. [Given : Molar
P
1 atm  L
mass of gas = 60 g/mol, R = ]
12 mol  K
(B) Under conditions when a real gas is less compressible w.r.t ideal gas, upon increasing
pressure keeping temperature constant, gas will respond by increasing its volume.
(C) A sample of real gas having temperature 273 K has Z  1.1 and gas is less compressible w.r.t
ideal gas, if same amount (moles) of an ideal gas is having temperature 300 K at same P & V.
(D) At critical conditions, volume occupied by one mole of a van der Waal gas is "4x" times the
volume of 1 mole gaseous molecules.
Space forThen x is 3.
Rough Work
P1JRCT1290718C0-19
47. Which of the following group(s) shows – effect stronger than –F group ?
(A) (B) –CN
(C) –NO2 (D) –OH
48. Which of the following statements is/are correct?
(A) The reductive ozonolysis of m–xylene and p-xylene give the same products.
(B) The reductive ozonolysis of o-xylene gives glyoxal + methyl glyoxal + dimethyl glyoxal.
(C) The reductive ozonolysis of benzene gives only one product.
(D) But-2-ene gives two different products on reductive ozonolysis.
P1JRCT1290718C0-20
49. In which of the following II is more stable than I :
(A) (B)
(C) (D)
50. Select the correct statements about the following reaction
(Y) Monochloro structural products
(A) The IUPAC name of compound (X) is 4-Methylpent-1-ene.
(B) Compound Y has three positional isomers.
(C) Four monochloro products are fomed which are all positional isomers.
(D) Two alkynes can give Y on hydrogenation.
P1JRCT1290718C0-21

 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct 
A sample of iron (II) sulphate crystals, FeSO4.7H2O has been left open to the air and some of the
iron (II) ions has been converted to iron (III). 4.2 g of the impure crystals were dissolved in a total
3
of 250 cm water and dilute sulphuric acid. This solution was treated with a solution of potassium
-3
dichromate. The concentration of dichromate ions in this solution was 0.1 mol dm . Volume of
3
K2Cr2O7 used was 23.5 cm .
+2 2- + +3 +3
(Unbalanced reaction is Fe + Cr2O7 + H  Cr + Fe + H2O)
2+
51. How many moles of Fe ions would there have been in the solution?
-4 -4 -2
(A) 7.05 x 10 mol (B) 2.35 x 10 mol (C) 1.41 x 10 mol (D) None of these
52. The approximate percentage purity of the crystal is :

(A) 69% (B) 72%Space for Rough
(C) 93%
Work (D) None of these
P1JRCT1290718C0-22
Schrodinger Wave Mechanical model
Ervin Schrodinger developed a model which is based on the particle and wave nature of the
electron, known as Wave Mechanical Model of atom. The equation determines the behaviour of
the wave function that describes the wave like properties of subatomic system. It is solved to find
the different energy levels of the system.
53. Match the nature of this graph with appropriate x & y axes ?
x y
(A) r 200(r)
(B) r Radial probability density of 2s
(C) r Radial probability of 311
(D) r Radial wave function of n=2, =1, m=0
P1JRCT1290718C0-23
54. For similar nature of below radial probability graph where n  5 , select incorrect statement :
4r R (r)
2
2
r
(A) Angular node present in orbital may be 1
(B) Angular nodes present in orbital may be 2
(C) For possible orbitals magnetic quantum number may be 2
(D) For possible orbital value of total nodes must be less than 4
Overlapping of Atomic Orbitals

When two atoms come close to each other there is overlapping of atomic orbitals. This overlap
may be positive, negative or zero depending upon the properties of overlapping of atomic orbitals.
55. Which of the following is correct for the formation of  bond ?

(I) overlapping of px-px (Z internuclear axis)
(II) overlapping of pz-pz orbitals (Z internuclear axis)
(III) overlapping of py-py orbitals (Z internuclear axis)
(IV) overlapping of s-pz orbitals (Z internuclear axis)
(A) I & II (B) II & III
Space for Rough (C) IWork
& III (D) II & IV
P1JRCT1290718C0-24
56. Which of the following overlapping can form two types of bonds either () or (,) or (,) ?
(I) dz2 + dz2 (II) s + s (III) dxy + dxy (IV) px + px
(A) I & III (B) III & IV (C) II & IV (D) I & II

The analgesic drug ibuprofen (P) exist in two isomeric form. One isomer is Physiologically active,
while the other is inactive. The structure of ibuprofen is given below :
Me COOH
(P)
57. The IUPAC name of (P) is

(A) 3-(4-Isobutylphenyl) propanoic acid (B) 2-(4-Isobutylphenyl) propanoic acid
(C) 3-(4-sec-Butylphenyl) propanoic acid (D) 2-(4-sec-Butylphenyl) propanoic acid
3
58. The number of sp hybridised carbon atom in (P) is :
(A) 3 (B) 4 (C) 6 (D) 5
P1JRCT1290718C0-25
Delocalisation of electrons take place in conjugated system involving carbon atoms. Delocalisation
may also occur in a conjugated system involving carbon atoms and atoms other than the carbon.
There are examples in which orbital and p orbital (vacant or half- filled or filled) overlap. Thus
delocalisation are of the following types :
(i) delocalisation by  overlap.
(ii) delocalisation by p overlap.
Delocalisation makes system stable. more is the number of resonating structures more is the
stability of the system .
59. In which of the following compounds delocalisation of electrons not possible :
(A) 1, 4-pentadiene (B) 1,3-butadiene
(C) 1,3,5-hexatriene (D) benzene
60. How many resonating structures of are possible (including given structure ) :
(A) 4 (B) 5 (C) 6 (D) 7
P1JRCT1290718C0-26

Resonance Advance (1-1) PDF

Загружено:

Сведения о документе

Оригинальное название

Авторское право

Доступные форматы

Поделиться этим документом

Поделиться или встроить документ

Параметры публикации

Этот документ был вам полезен?

Это неприемлемый материал?

Авторское право:

Доступные форматы

Resonance Advance (1-1) PDF

Загружено:

Авторское право:

Доступные форматы

® Code

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

QUESTION PAPER FORMAT AND MARKING SCHEME :

NAME OF THE CANDIDATE : ………………………………………………………………..………………………

Resonance Eduventures Ltd.

iz'ui=k d k izk: i v kSj v ad u ;kst uk %

ijh{kkFkhZd k uke : ………………………………………………………………..………………………

Resonance Eduventures Ltd.

2. For the equation x  1  x  3  2x  4  x which of the following is/are true

Space for Rough Work

(A) (, 5) (B) (3, )

(A) f(x) > 0  x  R (B) f(x)  0  x  R

(C) f(1) > 0 (D) f(a + b + c) = 0

Space for Rough Work

10. If  = 2log2 (cos x) and  = eloge (tan x) then  cannot be equal to

Space for Rough Work

Paragraph for Question Nos. 11 to 12

11. Number of solutions of equation 5x  20{x}  3[x]  7 are

Space for Rough Work

Paragraph for Question Nos. 15 to 16

Consider the bi-quadratic equation E : x 4  5x3  (  2)x 2  5x  1  0 then

Space for Rough Work

17. Value of 'a' is

18. Minimum value of h(x) is

Paragraph for Question Nos. 19 to 20

20. The function f(x) is/are

Space for Rough Work

SECTION – 1 : (Maximum Marks : 40)

Space for Rough Work

Space for Rough Work

Space for Rough Work

Space for Rough Work

Space for Rough Work

(B) approach velocity of A and B is 3 2 m/s

(A) Tension in the rope at t = 1 sec is 100 N

Space for Rough Work

Paragraph for Question Nos. 31 to 32

31. Choose the correct options regarding velocity of image

Space for Rough Work

particle, whereas M is the point at which particle strikes ground. (g = 10 m/s2)

33. Velocity (along vertical direction) of the particle at point P is :

(A) 0 m/sec (B) 10 3 m/sec (C) 5 3 m/sec (D) 4 3 m/sec

34. Total time of flight (from A to M) of the projectile is :

(A) 2 sec (B) ( 5  1) sec (C) ( 5 – 1) (D) (2  5 ) sec

Space for Rough Work

appeared earlier to the same person running with same velocity.

(A) 20 m/s (B) 20 3 m/s (C) 10 m/s (D) 10 3 m/s

respect to the ground is

(A) 8 (B) 15 (C) 22.5 (D) 37

Space for Rough Work

Space for Rough Work

Space for Rough Work

39. Choose the correct options.

40. If mA = mB = m, choose the correct options.

Space for Rough Work

SECTION – 1 : (Maximum Marks : 40)

(A) CO2 (B) SF6 (C) PCl5 (D) O2

44. Select the correct option(s) :

(A) rF   rH (B) rBr   rCl–

Space for Rough Work

46. Select the INCORRECT statement(s) :

(A) (B) –CN

(C) –NO2 (D) –OH