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K. V Sharma
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ABSTRACT
In the present study, the properties of nanofluids from various sources available in
the literature are correlated with reasonable accuracy considering nanofluid as a
homogenous medium. These correlations are subsequently employed in the evaluation of
momentum and convective heat transfer coefficients for turbulent flow in a tube.
Regression techniques are used to establish correlations, to predict friction and heat
transfer coefficients for a wide range of nanofluids containing Cu, CuO, TiO2, SiC, ZrO2
and Al2O3 nanoparticles of different sizes, concentration and temperatures dispersed in
water. A theoretical model proposed, predicts nanofluid heat transfer coefficients in the
turbulent range closely. The reason for the deviation of experimental data with theory is
due to different values of properties employed.
NOMENCLATURE
C specific heat, (J/kg K)
C1 constant in equation (5)
C2 constant in equation (6)
Corresponding author email: kvsharmajntu@gmail.com; Tel./Fax +6-09-4246231/+6-09-4246222
2 K. V. Sharma, P. K. Sarma, W. H. Azmi et al.
Greek symbols
Subscripts
b bulk
max maximum
min minimum
nf nanofluid
p particle
r ratio
v laminar sublayer
w water
1. INTRODUCTION
To achieve compactness and miniaturization of electronic equipment passive and active
methods of augmentation have been suggested in heat transfer literature [1, 2]. The initial
studies relevant to the augmentation of heat transfer are mostly related to use of micro sized
solid particles of various sizes in the base fluid. However, these techniques became
impracticable and obsolete due severe practical problems arising due to clogging, erosion of
pipe lines and high pumping power requirements, in spite of the fact that a certain degree of
heat transfer augmentation is achieved. Further, agglomeration and resettlement of particles
posed severe maintenance problem. In contrast, recent studies with the reduction of particle
size to nano level proved significantly more effective in achieving better heat transfer
augmentation without any substantial increase in pumping power requirement. Results from
several investigations have been coming to light from different sources and typical reviews of
such literature can be cited.
Experiments are mostly conducted for the determination of viscosity and thermal
conductivity of nanofluids. Choi [3] conducted experiments with Carbon Nano Tubes in
motor oil at 1.0% volume concentration. The thermal conductivity enhancement obtained is
160% higher than that of the base liquid. Various investigators [4-17] determined the
properties of nanofluids dispersed with Cu and metal oxides such as Al 2O3, TiO2, CuO, SiO2,
etc in different base fluids, concentrations and temperatures. Based on the investigations, it
can be stated that the pertinent parameters influencing nanofluid properties are concentration,
temperature, particle size, pH and the material properties. All the investigators observed
thermal conductivity and viscosity of nanofluid to increase with concentration. The thermal
conductivity of nanofluid increases while viscosity decreases with temperature.
4 K. V. Sharma, P. K. Sarma, W. H. Azmi et al.
The thermal conductivity increases rapidly for particles less than 50nm approximately
and decreases rather slowly thereafter. The viscosity increases with a decrease of particle size
due to larger surface area. Besides, the techniques employed for particle dispersion with
surfactant and the pH, affect the values of thermal conductivity and thermal stability of the
nanofluid. It is observed that fluids dispersed with high thermal conducting materials, predict
greater values of nanofluid thermal conductivity. The experimental values of thermal
conductivity obtained by these investigators deviated from the values predicted by the
theoretical models of Maxwell [18] and Hamilton and Crosser [19].
Experiments to determine heat transfer coefficients and pressure drop are undertaken for
water based nanofluids in a tube under turbulent flow conditions by various investigators.
Certain authors determined nanofluid properties while others used the values in the literature
to evaluate heat transfer coefficients. The authors observed the heat transfer coefficients to
increase with nanofluid concentration and influenced by particle size and operating
temperatures. Hence particle size can play an important role influencing the properties and
hence heat transfer coefficients. Salient results obtained by various investigators from
experiments are presented as Table 1.
The present objective is to develop generalized correlations for thermal conductivity and
absolute viscosity of water based metal and metal oxide nanofluids. A model is to be
developed for the estimation of heat transfer coefficients under turbulent flow. The values
from the model are to be validated with the nanofluid experimental data of various
investigators, employing the eddy diffusivity relations of Sarma et al. [20]. The property
relations will be used in the process of estimating the heat transfer coefficients.
2.1. Density, nf
Applying the principle of mass conservation of the two species in a finite control volume
of the nano fluid, the nanofluid density can be obtained from the relation
nf
nf p 1 (1)
100 100 w
The thermal conservation of energy of the two species in a finite control volume will
yield the overall specific heat Cnf of the nano fluid as
6 K. V. Sharma, P. K. Sarma, W. H. Azmi et al.
C p 1 C w
100 100
C nf (2)
nf
k nf
F 1 , 2 , 3 , 4 (3)
kw
Tnf dp p
where 1 :2 : 3 , 4
T *
nf d *
p w
Tnf* and d *p are the upper limits of the experimental data related to temperature and
nanoparticle diameter chosen as reference values employed in the regression.
k nf Tnf
1.37 0.2777
dp
0.0336
p
0.01737
kr 0.8938 1 1 1 (4)
kw
100 70 150 w
Tw 4.02
w 1000 1.0 [47]
119000 1365 Tw 4 Tw 2
w 0.00169 4.25263e 5 Tw 4.9255e 7 Tw 2 2.0993504e 9 Tw 3
k w 0.56112 0.00193 Tw 2.60152749e 6 Tw 6.08803e 8 Tw
2 3
temperature of water in oC. The values of density, specific heat and thermal conductivity of
nano materials used in the regression equation (4) are shown as Table 3. The correlation
equation is validated with the data shown in the legend of Figure 1 with a maximum deviation
of less than 11% for a few points.
Thermal
Density, Specific heat,
Nanoparticle Conductivity, Reference
kg/m3 J/ kg K
W/m K
Al2O3 36 3880 773 Pak and Cho [21]
Kothandaraman and
Cu 383 8954 386
Subramanyam [48]
CuO 69 6350 535 Fotukian and Nasr Esfahany [17]
Manahan [49]
Fe3O4 6 5180 670 wikipedia [50]
engineeringtoolbox [51]
Kothandaraman and
SiC 490 3160 675
Subramanyam [48]
SiO2 1.4 2220 745 Vajjha et al. [52]
TiO2 8.4 4175 692 Pak and Cho [21]
Vajjha and Das [53]
ZnO 29 5600 514
Hong et al. [28]
Kothandaraman and
ZrO2 1.7 5500 502
Subramanyam [48]
Nguyen et al. [29] conducted experiments for the determination of viscosity of Al 2O3 and
CuO nanofluids in water at different concentrations and particle sizes under ambient
conditions. The authors have stated that the viscosity of Al2O3 nanofluid with particle size of
36 and 47nm and CuO of 29nm size predicted close values for volume concentration less than
4% and deviated at higher concentrations. Hence the experimental data of viscosity obtained
by Nguyen et al. [29], Hwang et al. [30], Wang et al. [31], Zeinali Heris et al. [32], Nguyen et
al. [33], Lee et al. [34], Pak and Cho [21], He et al. [35], Duangthongsuk and Wongwises [36]
and Lee et al. [37] having volume concentration less than 4%, consisting of 233 data points
are subjected to regression and the following correlation obtained.
0.038 0.061
nf
11 .3 T d
r C1 1 1 nf 1 p (5)
w 100 70 170
Correlation equation (5) is validated with the experimental data, shown as Figure 2 with
C1 1 .4 for SiC and C1 1 .0 for other water based nanofluids. The data could be correlated
with an average deviation of 3.18%, standard deviation of 3.8% and a maximum deviation of
13%. Thus, having established correlations (1), (2), (4) and (5) for the estimation of nanofluid
properties, the application of these relations in evaluating friction and heat transfer
coefficients for turbulent flow will be undertaken.
For conditions of dynamic similarity for flow of the two media viz., nanofluid and base
liquid water in tubes, the ratio of friction coefficients can be written as follows:
fn f C Re mB
fr 2 (6)
fB C 3 Re nf
p
fn f nf nf
fr F , (7)
fB w w
The data from experimental investigations of Williams et al. [13], Fotukian and Esfahany
[17], Yu et al. [12], Xuan and Li [16], Sundar and Sharma [38], Sharma et al. [39] are
employed to obtain the exact relationship between the non-dimensional terms of Eq. (7). The
equation reduces to Blasius form when 0 .
fn f nf
0.514
nf
0.1248
fr 1.078 (8)
fB w w
h D Prnf
Nu
Colburn
Colburn 0.0003729 Re
k
0.7571
Pr
1/ 3
w
f /8
r
2.311
1
100
0.5558
(9)
nf
10 K. V. Sharma, P. K. Sarma, W. H. Azmi et al.
with an average deviation of 6.1% and standard deviation of 7.5% with the exception of a few
data points deviating from the correlation by a maximum of 19.0%. Equations (1), (2), (4), (5)
and (8) are used in the development of Eq. (9) for the estimation of Nusselt number. Equation
(9) is validated with the nanofluid experimental data and water as shown in Figure 4.
1/ 3
3
micro p
h gd p p w
d
Nu 0.10 Pr (10)
micro k 2 w w
w w
The turbulent forced convective heat transfer coefficient is estimated with equation (9).
The combined influence of micro and forced convection heat transfer are combined with the
procedure suggested by Churchill [41] given as
hnf hmicro n h Colburn n 1 / n (11)
For n=8, the experimental data is in close agreement with Eq. (11) as shown in Figure 5
shown as
hnf hmicro 8 h Colburn 8 1 / 8 (12)
h D 0.012
nf 0 .8 0 .4
Nu 0.023 Re Pr 1 Pr 1 0.23 (13)
nf k w nf
nf
with an average deviation of 6.13% and standard deviation of 7.5% with the exception of a
few data points deviating from the correlation by 20%. In the absence of nanoparticles, 0 ,
Pr 0 , Eq. (12) simplifies to the conventional form applicable for base liquid water
nf
obtained as
h D 0 .8 0 .4
Nu w 0 .023 Re Pr (14)
k w
w
The modified Dittus-Boelter equation (13) is applicable for both water and nanofluids.
The values obtained using Eq. (13) is compared with the experimental values as shown in
Figure 6.
12 K. V. Sharma, P. K. Sarma, W. H. Azmi et al.
Figure 5. Comparison of experimental heat transfer coefficients with the Eq. (11).
f
8
Re 1000 Pr
b b
Nu (15)
b
1
f
v 8
Pr
v
2/3
1
The operating temperatures not disclosed, Prandtl number thus determined with equation
(15) are estimated to vary between 2.0 and 4.7 with the assumption that Prv Prb . The heat
transfer coefficients in the volume concentration range of experimental data shown in Figure
8 encompass between 2.1 and 6.8 for Prandtl number. Experimental data of Yu et al. [12]
with SiC dispersed in water at 3.7% volume concentration undertaken in the range
3300 Re 13000 is shown along with theoretical values in Figure 9.
14 K. V. Sharma, P. K. Sarma, W. H. Azmi et al.
Figure 10. Comparison of data with theory for TiO 2 nanofluids of [21].
16 K. V. Sharma, P. K. Sarma, W. H. Azmi et al.
Figure 11. Comparison of data with theory for Al2O3 nanofluids of [21].
Figure 12. Comparison of data with theory for ZrO 2 nanofluids of [13].
Correlations to Predict Friction and Forced Convection Heat Transfer Coefficients … 17
Figure 13. Comparison of data with theory for Al2O3 nanofluids of [13].
Figure 14. Comparison of data with theory for TiO 2 nanofluid of [36].
The authors have stated the experimental range as 34 to 57 oC for temperature and Prandtl
number between 4.6 and 7.1. It is to be noted that the viscosity of SiC are consistently higher
18 K. V. Sharma, P. K. Sarma, W. H. Azmi et al.
by about 40% than those predicted by the Eq. (5). Hence using a coefficient of 1.4 in viscosity
equation (5), the theoretical values enclose the experimental data for the temperatures stated
by the author. Pak and Cho [21] conducted experiments with TiO2 and Al2O3 nanofluids at
25oC approximately.
The experimental data are compared with the theory for the minimum and maximum
concentration in Figures 10 and 11. The theoretical values are in good agreement with the
experimental data for TiO2 shown in Figure 10. The Al2O3 nanofluid experimental data are
presented along with values from theory in Figure 11.
The values of Prandtl number estimated with Eqs. (4) and (5) is shown as dashed line and
for the values given by the author as solid lines in the Figure 11. The theory predicts better
with the values of the author. This is due to very high values of viscosity obtained by them
compared to values obtained by all other investigators.
The variation of heat transfer coefficient with Reynolds number for ZrO 2 and Al2O3
nanofluids at different concentrations obtained by Williams et al. [13] is shown in Figures 12
and 13 respectively.
The authors have reported the experimental range of 21–76oC for temperature. However,
the theoretical values of heat transfer coefficients are shown between 20 – 70oC, as the
property relations developed are valid in this range. It can be observed that most of the
theoretical values are in good agreement with the experimental data. The deviations between
them are primarily due to inadequate information regarding nanofluid temperatures and the
Prandtl number evaluated by them.
Figure 15. Variation of property enhancement ratio with temperature for TiO2 of [36].
Correlations to Predict Friction and Forced Convection Heat Transfer Coefficients … 19
Figure 16. Variation of property enhancement ratio with temperature for SiC of [12].
Figure 17. Variation of property enhancement ratio with temperature for Al 2O3 of [21].
20 K. V. Sharma, P. K. Sarma, W. H. Azmi et al.
Figure 18. Variation of property enhancement ratio with temperature for ZrO2 of [13].
Correlations to Predict Friction and Forced Convection Heat Transfer Coefficients … 21
Figure 19. Variation of property enhancement ratio with temperature for Al 2O3 of [13].
The heat transfer data of Duangthongsuk and Wongwises [36] is shown along with the
values from theory for TiO2 nanofluid at a temperature of 25oC. The authors have observed a
decrease in heat transfer coefficients with increasing concentration as can be observed from
Figure 14. A significant deviation between the present theory and the experimental data can
be observed. The property equations (4) and (5) are used to determine the enhancements in
viscosity to thermal conductivity ratio. Figure 15 is drawn between the ratio and nanofluid
temperature valid for the experimental conditions undertaken by Duangthongsuk and
Wongwises [36].
According to Prasher et al. [44], heat transfer enhancements are possible if the viscosity
to thermal conductivity enhancement ratio is less than 4.0 shown as a thick horizontal line in
Figure 15. Since the experiments are undertaken at 25 oC at all flow rates, the enhancement
ratio is less than 4.0 for 1.0% concentration and greater for 2.0%. Hence, there is a decrease
in heat transfer coefficients when the concentration is increased from 1.0% to 2.0% as
observed by the investigators. Similar observations can be made for the data of ZrO 2, Al2O3
(Williams et al. [36]), SiC (Yu et al. [12]) and Al2O3 (Pak and Cho [21]). The reasons for the
reduction in heat transfer coefficients can be observed through Figures 16 -19 for the
conditions undertaken by the authors.
CONCLUSION
The following conclusions are made from the analysis undertaken with Cu, CuO, TiO 2,
SiC, ZrO2 and Al2O3 nanofluids with water as the base fluid
ACKNOWLEDGMENT
The financial support to the first author by University Malaysia Pahang is gratefully
acknowledged. Prof. P.K.Sarma acknowledges the support received from GITAM University,
Visakhapatnam, India.
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