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P22.1-18
PAPER-1 Academic Session: 2018-19 SET / CODE - 1

ALL INDIA OPEN TEST (AIOT)

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR


(JEE ADVANCED PATTERN)

Target : JEE (Main+Advanced) 2019


Date: 03-05-2019 | Duration : 3 Hours | Max. Marks: 240

COURSE: VIJETA(JP),VISHWAAS(JF),VIJAY(JR),VIVEK(JCC)

Please read the last page of this booklet for the instructions.
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MATHEMATICS
PART : I MATHEMATICS

MATHEMATICS
SECTION – 1 : (Maximum Marks : 60)
 This section contains FIFTEEN questions
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.

1. Number of different words can be formed using all the letters of the word 'INTEGRATION'
1
(A) The probability that each word starts with E and ends in N is
55

18
(B) The probability that each word either starts with  or ends in N is
55

1
(C) The probability that order of vowels remains same is
125

1
(D) The probability that the vowels and consonants alternate in the words is
462

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MATHEMATICS
3
2. All non-zero complex numbers satisfying z  z on the complex plane lie on the vertices of

MATHEMATICS
(A) a square (B) a rectangle

(C) an isosceles trapezium (D) a cyclic quadrilateral

2 
 1
  1

 2 cos1 x   1
 2 cos1 x  2
3. If the equation  a    a  0 has only one real solution then subsets of
   2  
   

values of 'a' are

(A) (–3, 1) (B) (–, –3]

(C) [1, ) (D) (2, )

4. f : R  R is one-one, onto and differentiable function and graph of y = f(x) is symmetric about the

point (4, 0) then :

(A) f–1(2010) + f–1(–2010) = 8


2018

(B)  f(x) dx = 0
–2010

(C) if f'(–100) > 0 then roots of x2 – f'(10)x – f'(10) = 0 may be non-real

(D) if f'(10) = 20, then f'(–2) = 20

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MATHEMATICS

5. If c is an arbitrary constant then solution of differential equation x dy – y dx – xy (x – y)dy = 0 is 2 2 2

MATHEMATICS
2 2
xy y x  y y
(A) n   c (B) n   c
x  y 2 xy 2

2 2
y y

(C) ( x  y )e 2
 cxy (D) ( x  y )e 2
 cxy

6. A rod of length 2 units whose one end is (1, 0, –1) and other end touches the plane x – 2y + 2z + 4 = 0,
is rotated on this plane, then
(A) the rod sweeps a solid structure whose volume is  cubic units
(B) the area of the region which the rod traces on the plane is 2

(C) the length of projection of the rod on the plane is 3 units


 2 2 5 
(D) the centre of the region which the rod traces on the plane is  , , 
3 3 3 

7. Let [.] and { . } be greatest integer function and fractional part function respectively. If A 1, A2 are

area of closed regions formed by curves y = {| x |} – 1 , 5y = | 2x2 – 7x + 5|, x = –1 and x = 1,

where A1 is area of the region on left to y-axis and A2 is area of the region on right to y-axis then -
7 19
(A) A1 + A2 = (B) |A1 – A2| =
5 15

(C) [15 A1A2] = 1 (D) [15 A1A2] = 0

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MATHEMATICS
8. Which of the following is/are CORRECT ? ([.] denotes greatest integer function)

MATHEMATICS
(A) If [sin–1x] > 0 then complete set of values of x is [a, b]. Then the value of [(cos –1b) + a] is 0
(B) If [sin–1x] > 0 then complete set of values of x is [a, b]. Then the value of [(cos –1b) + b] is 1
(C) Let A be a 2 × 3 matrix, B be a 3 × 2 matrix such that det(AB) = 4. Then the value of det (BA) is 0
(D) Let A be a 2 × 3 matrix, B be a 3 × 2 matrix such that det(AB) = 4. Then the value of det (BA) is 4

In a triangle ABC,   bc cos A 1   


2
9. ab   k cos A   cos A cos B  cos A cos B cos C

if k is equal to
(A) R (B) –R
(C) 2R (D) – 2R

10. Which of the following is/are CORRECT ?


(A) The coefficient of a8b4c9d9 in expansion of (abc + abd + acd + bcd)10 is 2520
10!
(B) The coefficient of a8b4c9d9 in expansion of (abc + abd + acd + bcd)10 is
8! 4! 9! 9!

(C) Suppose the probability for A to win a game against B is 0.4. If A has an option of playing
either a “best of 3 games “ or a “best of five games” match against B (No match in draw).
Then he should choose the option of best of 3 games so that the probability of his winning
the match is higher.
(D) Suppose the probability for A to win a game against B is 0.4. If A has an option of playing
either a “best of 3 games “ or a “best of five games” match against B (No match in draw).
Then he should choose the option of best of 5 games so that the probability of his winning
the match is higher.

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MATHEMATICS

11. A circle touches both the circle x2 + y2 = 25 and (x – 2)2 + y2 = 1. Then locus of its centre is

MATHEMATICS
(A) Ellipse with focus (2, 0) and (0, 10)

(B) Ellipse with length of major axes 6

(C) Ellipse with eccentricity 1/4

(D) Ellipse with auxillary circle x2 + y2 – 2x – 8 = 0

n
(1  c o s x )  5 n x
12. Consider the function f(x) = lim n
, then
n 
2  (1  c o s x )

(A) f(x) is continuous at positive odd multiples of 

(B) f(x) is discontinuous at positive even multiples of 


(C) f(x) is discontinuous at positive odd multiples of
2


(D) f(x) is continuous at positive even multiples of
2

n n
Cr
13. Let  = lim  r
, then
n 
r0
n .( r  3 )

(A)  > 1/2 (B)  < 1 (C)  < 2 (D)  > 3/2

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MATHEMATICS

ax
 xe ; x  0
14. Let f(x) =  where a is constant. In which of the following intervals f (x) is

MATHEMATICS
2 3
x  ax  x
 ; x  0

increasing

 a   2  a 
(A)  – ,  ,a<0 (B)  ,    , 
 3   a  3 

 2 a   2 
(C)  ,  ,a>0 (D) – , ,a<0
 a 3   a 

A B C
15. If ABC is a triangle and tan , tan , tan are in H.P., then
2 2 2

B
(A) the value of cot can be equal to 3
2

B
(B) the value of cot can be equal to 2
2

B
(C) the value of cot attains minimum if A = C
2

B
(D) the value of cot attains minimum if 2A = C
2

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MATHEMATICS

SECTION – 2 : (Maximum Marks : 20)

MATHEMATICS
 This section contains FIVE questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

16. The three distinct numbers a, b, c are in G.P. such that a + b + c = bx , then find the least positive
integral value of x.

17. The roots of the equation x5 – 40 x4 + Px3 + Qx2 + Rx + S = 0 are in G.P., if the sum of their
|s |
reciprocals is 10, then the value of can be equal to.
4

3 x 
18 While traveling at a speed of x km/hr a bus burns petrol    litres/km. If cost of petrol be
 x 300 

Rs 30/litre and other cost is also Rs30/h then speed for a journey of 75 km having minimum cost is

20  km/hr. Find the value of .

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MATHEMATICS

a  a  x
2 2
a
The segment of the tangent to the curve y   a  x
2 2

MATHEMATICS
19. n contained between
a  a  x
2 2
2

y-axis and the point of tangency is a, then the numerical quantity  is equal to

20. As shown in the figure, three circles which have the same radius r have centers at (0,0), (1,1) and
(2,1). If they have a common tangent line, as shown, then the value of 10 5r is ___.
y

r
r C2
C1

r
x
O 1 2
C

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PHYSICS
PART : II PHYSICS

PHYSICS
SECTION – 1 : (Maximum Marks : 60)
 This section contains FIFTEEN questions
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.

21. Largest and smallest distance of a satellite from center of planet are given by R max and Rmin.
respectively. At these two positions speeds are given v min and vmax respectively. The time period of
revolution of the satellite is T. If 'a' and 'b' are semi major and semi minor axis then
R max  R min
(A) a 
2

(B) b  R max . R min

T
(C) a  v max v min
2
T
(D) b  v max v min
2

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PHYSICS
22. Two identical blocks are resting on supports as shown. Two identical bullets travelling with the

PHYSICS
same speed hit the blocks & get embedded in them in very short time. The blocks leave the
contact immediately after bullet strikes them. In case (i) bullet's velocity is toward centre of mass
and in case (ii) bullet's velocity is off centre. The kinetic energies after collision are K 1 & K2 and
maximum height reached by the centre of mass are h1 & h2 respectively. then :

Case (i) Case (ii)


(A) K1 < K2 (B) K1 = K2 (C) h1 < h2 (D) h1 = h2

23. An object of mass m = 2 kg is thrown vertically up. In the presence of heavy air resistance the time
of ascent (t1) is no longer equal to the time of descent (t 2), Similarly the initial speed (u) with which
the body is thrown is not equal to the final speed (v) with which the object returns. Assuming that
the air resistance F = 10 N is constant.
t2 v t2 u t2 3 t2 3
(A)  (B)  (C)  (D) 
t1 u t1 v t1 1 t1 1

24. A radioactive nucleus A can decay in P or Q with decay constant 2 and  respectively. Another
radioactive nucleus B decays in Q with decay constant 3. Initially number of active nuclei of A and
that of B are equal (N0). Select correct relation for any later moment t.
N0
(A) NA = NB = N0e–3t (B) NP = NQ = (1– e–3t)
3
N0 4N 0
(C) NP = 2NQ = (1– e–3t) (D) 2NP = NQ = (1– e–3t)
3 3

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PHYSICS
25. In the circuit shown in figure capacitor was initially uncharged switch is closed at t = 0. Select

PHYSICS
correct alternatives.
1.2 M
S

+ 600 k 2.5 F


48V –

(A) The initial battery current immediately after switch S is closed is 40 A


80
(B) The battery current, long time after switch S is closed is A
3

(C) The time after which current through capacitor becomes half is n4 sec.
80
(D) The current through the 600k as a function of time is (1 – e–t) A.
3

26. If one of the slit of a standard YDSE apparatus is covered by a thin glass slab so that it allows only
one half of the light intensity of the other then
(A) Resultant intensity at centre of screen will decrease
(B) Resultant intensity at dark fringe will increase
(C) The fringe width will remain unchanged
(D) The fringe pattern will shift toward the covered slit.

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PHYSICS
27. Consider following circuit and select correct alternative(s)

PHYSICS
4
A B

6 3
2V
4 2V
C D

6 3
4
E F
1
(A) Current through each cell is A
6
1
(B) Current through each 6 resistance is A
6
1
(C) Current through each 3 resistance is A
3
1
(D) Current through each 4 resistance is A
2

28. When an impedance, consisting of an inductance L and a resistance R in series, is connected


across a 12V, 50 Hz supply, a current of 0.05 A flows which differs in phase from that of the
applied potential difference by 60º. If a capacitor of capacitance C connected in series in the above
circuit has the effect of bringing the current into phase with the applied potential difference. Select
correct alternative :
(A) R = 120 (B) L  0.66 H (C) C  15.37 F (D) C  25.37 F

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PHYSICS
29. A horizontal disk of radius r = 0.2 m is fixed onto a horizontal frictionless table. One end of a

PHYSICS
massless string of length L = 0.8 m is fixed to the perimeter of the disk, while the other end is

attached to an object of mass m = 0.6 kg, which stands on the table as shown. The object is then

given a velocity of magnitude v = 0.4 m/s in a direction perpendicular to the string.

r
O

v
m

(A) Object will hit disc after t = 4s.

(B) Angular momentum about O will remain constant.

(C) Angular momentum about O will decrease till particle hits the disc.

(D) Kinetic energy of particle will remain constant.

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PHYSICS
30. A point object is kept at a distance of O P  u . The radius of curvature of spherical surface APB is

PHYSICS
C P  R . The refractive index of the media are n 1 and n 2 which are as shown in the diagram, then
(consider only paraxial rays)

(A) If n1  n 2 image is virtual for all values of u


(B) If n 2  2 n1 image is virtual when R u

(C) The image is real for all values of u, n1 and n2

(D) If n 2  n1 then image will be always real

31. Wavelength and intensity of monocromatic light falling on a photoelectric cell as a function of time
is given by  = 10000 e–t/10 Å and  = 1000 (1 – e–t/10). The threshold wave length of metal used in
cell is 3700 Å.
(A) Work function of metal plate is equal to 3.35 eV
(B) At t = 0 sec photo current is zero.
(C) At t = 5 sec photo current is zero.
(D) At t = 20 sec photo current is zero.

32. Which among the following forces is conservative?


 
F  2 xy ˆi  x ˆj F  y ˆi  xy ˆj
2 3 2
(A) (B)
 
F  y ˆi  x ˆj F  2 xy ˆi  x y ˆj
2 2 2
(C) (D)

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PHYSICS
33. The circuit shown in the figure consists of two resistances R 1 & R2 connected to two ideal

PHYSICS
voltmeters V1 & V2. A time varying magnetic field B(t) exists in a circular region of radius a and it is

directed into the plane of the figure B(t) = B0t where B0 is a positive constant of proper dimensions

and t is the time

b b
v1 R1 R v2
2

B (t )

(A)The emf induced in the circuit is  a B 0 :


2

 a B 0 R1
2

(B)The reading of V1 is :
R1  R 2

 a B 0 R1
2

(C) The reading of V2 is :


R1  R 2

(D) V1 = V2

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PHYSICS
34. Consider a uniformly charged non conducting, uniform spherical shell of radius R. Net charge on

PHYSICS
the shell is Q. There is a small hole in the shell at 'A' shown in the figure. A point charge –q is
released at a distance 2R from the centre as shown in the figure. The shell and point charge have
same mass m. After release the point charge will move toward shell, passes through the hole and
hit the shell at 'B'.

× × ×
× ×
× ×
× A –q
B
×
m
× ×
R
× × R

× ×
× ×
Choose the correct option(s) :
5R
(A) The distance travelled by point charge till it hit the shell at B is
2

kQ q
(B) Speed of the point charge when it hit the shell is
2m R

3
8m R
(C) Time taken by the point charge to travel from A to B is
kQ q

(D) The distance travelled by the shell with constant velocity is R

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PHYSICS
35. A cylinder of mass M and radius R lies on a plank of mass M as shown. The surface between

PHYSICS
plank and ground is smooth, and between cylinder and plank is rough. Assuming no slipping

between cylinder and plank, and velocity amplitude of oscillation of plank V.

(M, R)

K
M

M
(A) Time period of oscillation of the set up when displaced from equilibrium is 4
3K

V MK
(B) Friction between plank and cylinder when acceleration is maximum is
2 3

M
(C) Time period of oscillation of the set up when displaced from equilibrium is 2
3K

V MK
(D) Friction between plank and cylinder when acceleration is maximum is
4 3

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PHYSICS

SECTION – 2 : (Maximum Marks : 20)

PHYSICS
 This section contains FIVE questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

36. In given arrangement both blocks are of same mass 2 kg. Initially spring is compressed by

compression 10 cm. Spring constant is 200 N/m. Find the ratio of magnitude of relative

acceleration of the two blocks and acceleration of centre of two blocks.

Smooth
A

30º

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PHYSICS
37. Consider the system as shown in figure. The body of mass M = 3kg leans against wall P placed at
the bottom of an inclined plane of an angle  = 30º and a length s = 10 m. This body is connected

PHYSICS
by an inelastic string passed over an ideal pulley mounted at the top of the plane to another body
of mass m = 1 kg as shown. What should be horizontal velocity (in m/sec) of m so that the other
the body (M) may detach from the wall.

P M 
 V
m
N  0 I( 2  1)
38. In the given circuit ABCD is a square of side 'a'. If magnetic induction at point O is
2a
find the value of N. Dotted line represents that wire goes upto infinity.

I I
2I B
C

I 2I
O

D
I A 2I
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PHYSICS
39. A fork and a string of length 100 cm give 4 beats/s. The string is made shorter, without any change

PHYSICS
of tension, until it is in unison with the fork. Its new length is 99 cm. The frequency of the fork is

80P Hz. Find the value of P.

40. A heater is designed to operate with a power of 1000 W in a 100 V line. It is connected in

combination with a resistance of 10 and a resistance R to a 100V mains as shown in Fig. What

should be the value of R so that the heater operates with a power of 62.5 W ?

10 

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CHEMISTRY

PART : III CHEMISTRY


Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,

CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,

Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION – 1 : (Maximum Marks : 60)


 This section contains FIFTEEN questions

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these

four option(s) is(are) correct

 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

 For each question, marks will be awarded in one of the following categories :

Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.

 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three

will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.

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CHEMISTRY
41. Select correct statement(s):
(A) The dissolution of CaCl2.6H2O in a large volume of water is endothermic to the extent of

CHEMISTRY
3.5 kcal/mol. If H = –23.2 kcal for the reaction, CaCl2(s) + 6H2O(l)  CaCl2.6H2O(s) then heat
of solution of CaCl2 (anhydrous) in a large volume of water is –19.7 kcal/mol
(B) If the equilibrium constant for the reaction A2 2A at 500 K and 700 K are 10–10 and 10–5
respectively, then reaction is exothermic
207
(C) In the nuclear reaction 92 U 
235
82 Pb , the total number of  and  particles emitted would be
11
(D) An aqueous solution of an alcohol (B.P. = 64.7ºC) in water (B.P. = 100ºC) has vapour pressure
more than that of water

d
42. For a gas, plot between v/s p, where (d= density of gas in g/L and p = pressure in atm) at
p
300 K temperature was obtained as :

d
 
P

P
Which of the following statement(s) is/are incorrect about the gas?
(A) The gas shows non ideal behaviour
(B) The curve should have positive slope for an ideal gas
(C) The curve should be parallel to pressure axis for an ideal gas
d
(D) The plot of   v/s temperature for an ideal gas should have a positive slope
p

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CHEMISTRY
43. Choose the correct statement(s) amongs the following:
(A) Radial distribution function (4r22dr) gives probability at a particular distance along one

CHEMISTRY
chosen direction
(B) 2(r) give probability density at a particular distance
(C) For s orbitals (r, ) is independent of  and 

(D) 2p orbital with quantum numbers n =2  =1, m = 0 also shows angular dependence

44. 20 ml of 0.05 M solution of the conjugate acid of an -amino acid methionine (H2A+) is taken. The
pKa of –COOH group in methionine is 2.8 and pKb of basic group is 4.8. Pick out the correct
statement(s) amongs the following [Use log 2 = 0.3, log 5 = 0.7] :
(A) pH of original amino acid solution was ~2.05
(B) pH of solution was ~2.8 when 10 ml 0.05 M NaOH solution is added to original solution
(C) pH of solution was ~ 6 when 20 ml 0.05 M NaOH solution is added to original solution
(D) pH of solution was 3.8 when 20 ml 0.05 M NaOH solution is added to original solution

45. Which of the following is/are correct for a non-ideal solution of liquids A and B, showing negative
deviation?
(A) Vmix = –ve, as interaction between molecule A and B is low
(B) Vmix = –ve, as interaction between molecule A and B is high
(C) Gmix = –ve, as mixing is spontaneous
(D)Ssurrounding = +ve, as Hmix is negative

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CHEMISTRY
46. During the production of iron and steel:
(A) The oxide ore is primarily reduced to iron by solid coke according to the reaction :

CHEMISTRY
2Fe2O3 + 3C  4Fe + 3CO2
(B) The oxide ore is reduced by the carbon monoxide according to the reaction.:

Fe2O3 + 3CO  2Fe + 3CO2


(C) Major silica impurities are removed as calcium silicate slag by addition of a fluxing agent lime
stone
(D) The slag containing phosphorus is used as a fertilizer

47. When an inorganic compound (X) having 3c-2e as well as 2c-2e bonds reacts with ammonia gas
at a certain temperature, gives a compound (Y) iso-structural with benzene. Compound (X) with
ammonia at a high temperature, produces a hard substance (Z). Then:
(A) (X) is B2H6 (B) (Z) is known as inorganic graphite
(C) (Z) having structure similar to graphite (D) (Z) having structure similar to (X)

48. Which of the following species(s) is/are having only one corner shared per tetrahedron?

(A) Si2O76 (B) Cr2O72 (C) S 2O72 (D) Si3O96

49. Correct statement(s) for [Co(EDTA)]– ion is/ are (EDTA4– is ethylenediaminetetraacetate ion):
(A) Total number of stereoisomers which are optically active is 2
(B) Number of [N — Co — O] bond angle in complex is 8
(C) Cobalt have oxidation number = +3 and co-ordination number = 6
(D) EDTA4– is a chelating ligand and is hexadentate

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CHEMISTRY
CONH2

CHEMISTRY
50.

Which statement is correct :


(A) Reduced product of P and Q will be metamers to each other.
(B) By dry distillation of hydrolysed products of P with Ca(OH) 2, gives benzophenone.

(C) Hydrolysed product of Q, reacts with NaNO2 + HCl followed by reaction with phenol, gives

orange red dye.


(D) Electrophile involved in the formation of Q is dichlorocarbene.

OH H H OH OH H
51.

Br H Cl H Br H Cl H Br H Cl H
(I) (II) (III)
Choose the correct option/s according to given compounds.
(A) Compound (I)st & (III)rd are Identical
(B) Compound (I)st & (II)nd are diastereomers
(C) Compound (II)nd & (III)rd are positional Isomers
(D) Compound (I)st & (III)rd are enantiomers

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CHEMISTRY
52. Observed the following reaction sequence and identify the correct options ?
O

CHEMISTRY
CH2–C Zn –Hg HCl
O  (A)  (B)  (C)
  (D)
 (E)
AlCl
3 Zn –Hg
5 3 PCl AlCl
+ HCl
CH2–C Pd–C/
O
(F)
(A) F reacts with KMnO4/H+ gives phthalic acid which upon heating gives phthalic anhydride.
(B) E upon monochlorination (Cl2/h) gives total four products.
(C) F upon complete catalytic hydrogenation gives saturated compound which show geometrical
isomerism.
(D) Compound (A) gives positive test with NaHCO3.

53. Which statements are correct in the following ?


(A) Cyclopentadiene reacts with NaNH2 and releases NH3 gas however cyclopropene does not.
(B) Cyclopropenone has a greater dipole moment than acetone
(C) Cyclobutadiene does not exist at room temperature but cyclobutene exists at room
temperature
(D) Cycloheptatrienyl bromide ionizes faster however cyclopentadienyl bromide does not

54. Optically active amines having molecular formula C5H13N on reaction with NaNO2 + HCl produces
tertiary optically inactive alcohol. Find out structures of amines.
NH2
NH2 N NH2
(A) (B) (C) (D)

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CHEMISTRY
55. Consider the structure of raffinose, a trisaccharide found in sugar beets and a number of higher

plants.

CHEMISTRY
HO
CH2OH O
H
HO OH
O
CH2 O
HO
H
HO OH
O
HOCH2
O
HO
CH2OH

OH

RAFFINOSE

Which is correct for raffinose :


(A) Raffinose is a non reducing sugar

(B) The glycoside linkages in raffinose are  (1, 6) glycoside linkage and  (1, 2) glycoside
linkage
(C) Raffinose is hydrolyzed into equal amounts of D-galactose, D-glucose and D-fructose
(D) Raffinose will show mutarotation

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CHEMISTRY

SECTION – 2 : (Maximum Marks : 20)

CHEMISTRY
 This section contains FIVE questions

 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

 For each question, darken the bubble corresponding to the correct integer in the ORS

 Marking scheme :

+4 If the bubble corresponding to the answer is darkened


0 If none of the bubbles is darkened
–1 In all other cases

56. Let z is the atomic number of the element with the maximum number of unpaired 4p electrons and

having spin multiplicity S. Let 'n' and 'p' are the group number and period number respectively in

zpSn
the modern periodic table for this element. Find .
8

57. The density of a pure substance 'A' whose atoms pack in cubic close pack arrangement is 1 g/cc.

If B atoms can occupy tetrahedral void and if all the tetrahedral voids are occupied by 'B' atoms.

What is the density of resulting solid in g/cc? [Atomic mass (A) = 20 g/mol & atomic mass

(B) = 40 g/mol]

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CHEMISTRY

58. How many of the following can liberate H2 gas when dissolved in water or heated with water?

CHEMISTRY
B2H6, C2H6, SiH4, CaH2,

B3N3H6, PH3, sodium amalgam, KO2,

XeF2, H2S, Cl2, SrC2,

59. Observe the following compounds.

OH NH2
.. ..
N
N
H N H N
(a) (d) (e) (f)

Write the number of those compound which is more basic than pyridine .
N

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CHEMISTRY
60. Consider the figure

CHEMISTRY
mixture separation
of amino of amino
acids acids

filter paper
Buffer solution
Buffer solution (pH = 5.0)
(pH = 5.0)

(Electrophoresis) (After Electrophoresis)

pKa Values
S.No. Amino acids
side chain

1. Arginine 2.17 9.04 12.48

2. Alanine 2.34 9.69 ------

3. Aspartic acid 2.09 9.82 3.86

4. Lysine 2.18 8.95 10.79

5 Glutamic acid 2.19 9.67 4.25

6. Valine 2.32 9.62 ------

Calculate :
Number of non essential amino acids move towards cathod = x
Number of essential amino acids move towards anode = y
Number of amino acids move towards cathod = z
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FIND x + y + z = ?

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P22.1-18
ALL INDIA OPEN TEST (AIOT) (JEE ADVANCED PATTERN)

PA PER - 1 COURSE : VIJETA(JP),VISHWAAS(JF),VIJAY(JR),VIVEK(JCC)


DATE : 03-05-2019
SET / CODE - 1
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the
back cover of this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
4. Blank spaces are provided within this booklet for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR


6. After the open booklet, verify that the booklet contains all the 60 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :
7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has two sections.
8. Each section as detailed in the following table :

Category-wise Marks for Each Question Maximum


Number of
Section Question Type Negative Marks
Questions Full Marks Partial Marks Zero Marks
Marks of the Section
+4 +1
0
If only the bubble(s) For darkening a bubble –2
One or More If none of the
1 15 corresponding to all the corresponding to each correct In all other 60
Correct Option(s) bubbles is
correct option(s) is(are) option, provided NO incorrect cases
darkened
darkened option is darkened
+4 0
–1
Single digit Integer If only the bubbles If none of the
2 5 – In all other 20
(0-9) corresponding to the correct bubbles is
cases
answer is darkened darkened

OPTICAL RESPONSE SHEET :


9. Darken the appropriate bubbles on the original by applying sufficient pressure.
10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
11. Do not tamper with or mutilate the ORS.
12. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.

DARKENING THE BUBBLES ON THE ORS :


13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
14. Darken the bubble COMPLETELY.
15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.
18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.

NAME OF THE CANDIDATE : ………………………………………………………………..………………………

ROLL NO. : ………………………..………………………

I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.

------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator

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