Crude Assay - Al Shaheen Crude Oil 2018

Crude Assay Report
on
Crude sample marked
Al Shaheen Crude Oil 2018

LABORATORY REPORT NO. IDL 5579/2018
Date: December 21, 2018
Company details : NORTH OIL COMPANY
: Logistics Base within Gulf Warehousing Company

For the Attention of
Al Ghuwairiya Street
Street No. 512
West Side Support Service Area
Outside RLIC Khalifa Gate (Gate no. 2)
Ras Laffan - Qatar
Sample(s) received from : Qatar
Sample(s) submitted as : Al Shaheen Crude Oil 2018
Description(s) on Label(s) : Al Shaheen Crude Oil 2018
Seals on Sample(s) : Nil
Sample(s) received on : 21 November, 2018
The above sample(s) was/were examined and the following results obtained:
Please refer attached sheets for analysis report.
AUTHORIZED SIGNATURE
George Idicula
Laboratory Manager,O&P Laboratory
Bureau Veritas
Technopark – Plot 010407
Jebel Ali, Dubai, U.A.E
INDEX
Sl.No. Description Page No.
1 Front Cover 1
2 Title 2
3 Index 3
4 Main Assay Properties 4
5 True Boiling Point Distillation Data 5
6 True Boiling Point Distillation data - Graph 6
7 Summary of Product / Residue cut points & Yield 7
8 Summary of True Boiling Point Distillation Cuts - Graph 8
9 Whole Crude Analysis 9
10 Naphtha Cuts - Light Naphtha [IBP/C5/15-70°C] 10
11 Naphtha Cuts - Light Reformer Naphtha [70-165°C] 11
12 Naphtha Cuts - Reformer & Heavy Naphtha [165-195°C] 12
13 Kerosene Cut - Kerosene [195-235°C] 13
14 Vacuum Gas Oil Cuts - Light Gas Oil [235-325°C] 14
15 Vacuum Gas Oil Cuts - Gas Oil [325-370°C] 15
16 Vacuum Gas Oil Cuts - Gas Oil 1[370 - 540°C] 16
17 Vacuum Gas Oil Cuts - Heavy Vacuum Gas Oil [370 - 548°C] 17
18 Residue Cuts - Atmospheric Residue [+370°C] 18
19 Residue Cuts - Vacuum Residue [+548°C] 19
Page No: 3
Naphtha Cuts Vacuum Gas Oil Cuts Residue Cuts
Whole Crude
Kerosene Cut
TEST UNIT METHOD
Atmosph
Vacuum
Gas Oil 1
Naphtha
Naphtha
Naphtha
Reforme
Reforme
Vacuum
Kerosen
Residue
Residue
Gas Oil
Gas Oil
Gas Oil
Heavy
Heavy
Light
Light
Light
eric
r&
e
r
CUTS, YIELDS AND DISTILLATIONS 1 2 3 4 5 6 7 8 9 10
Initial BP °C IBP /C5/15 70 165 195 235 325 370 370 370 + 548 +
Final BP °C 70 165 195 235 325 370 540 548
ASTM D5236/
Yield % Wt. 3.27 9.58 5.10 5.52 17.65 7.51 22.71 24.79 49.50 24.65
ASTM D2892
ASTM D5236/
Yield % Vol. 4.43 11.35 5.63 5.92 18.14 7.41 21.57 23.55 44.77 21.23
ASTM D2892
ASTM D5002 / D4052 /
Density @ 15°C kg/L 0.6481 0.7415 0.7951 0.8190 0.8546 0.8909 0.9229 0.9251 0.9713 1.0199
D2598
Specific Gravity @ 60/60° F Conversion 0.8790 0.6482 0.7417 0.7954 0.8194 0.8551 0.8914 0.9234 0.9256 0.9718 1.0206
API Gravity @ 60° F ° API Calculated 29.5 86.8 59.3 46.4 41.2 34.0 27.2 21.7 21.4 14.1 7.2
Sulphur Content % Wt. IP 336 / ASTM D4294 2.31 0.0274 0.0897 0.1930 0.304 1.08 2.25 2.49 2.55 3.70 4.87
Mercaptan Sulphur ppm Wt. UOP 163 322 243 356 380 354 69 52
Hydrogen Sulphide ppm Wt. UOP 163 <1 <1 <1
Total Nitrogen ppm Wt. ASTM D4629 / D5762 900 0.3 0.4 0.6 0.9 36 220 639 680 1823 2800
Basic Nitrogen % Wt UOP 269 0.0225 0.0017 0.0063 0.0179 0.0186 0.0484 0.0728
Vapour Pressure psi ASTM D323 / D5191 6.20 14.67 1.81
PIONA Analysis
Total Paraffins 93.0 59.0 62.7
n-Paraffins 34.8 8.3 7.5
iso-Paraffins GC (ASTM D6839/ 58.2 50.7 55.2
% Vol
Total Olefins ASTM D6730) <0.1 <0.1 0.5
Total Napthenes 6.9 36.4 15.7
Total Aromatics <0.1 4.6 21.1
Unidentified <0.1 <0.1 <0.1
Research Octane Number (Clear) * ASTM D2699 70.0(2*) 55.0
Pour Point °C IP 15 / ASTM D97 <-18 <-36 <-36 <-36 +6 +30 +33 +24 +39
Cold Filter Plugging Point °C IP 309 <-51 -44 -16 +8
Cloud Point °C IP 219 / ASTM D2500 <-42 <-42 -14 +8
Freeze Point °C IP 16 /ASTM D2386 -81.5 -53.5
Cetane Index calc. IP 380 /ASTM D976 48.0 45.6
UOP K Factor calc. UOP 375 11.6 11.7 11.6 11.4
Kinematic Viscosity @ 15° C 31.88
IP 71 / D 445
Kinematic Viscosity @ 40° C cSt 10.88 0.9690 1.517 3.338 8.472 55.97 62.50 1212 266400*
Kinematic Viscosity @ 100° C 2.957 0.5520 0.7310 1.289 2.300 7.068 7.573 46.62 1131
Kinematic Viscosity @ 135° C ASTM D2170 3.575 3.754 15.90 188.1
Smoke Point mm IP 57 / ASTM D1322 26.0 25.0
Copper corrosion test @ 40° C, 3 hours IP 154 /ASTM D 130 2C 2C 3A 1A
Aniline Point °C IP 2 / ASTM D 611 53.6 59.0 68.2 71.4 83.6 81.0
Hydrocarbon types by FIA
FIA-Aromatic 20.3 23.8
% Vol. IP 156
FIA-Olefins 0.7 2.1
FIA-Saturates 79.0 74.1
Organic Chloride mg/kg ASTM D4929B 1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Conradson carbon residue % Wt. ASTM D189 4.84 <0.10 <0.10 0.25 0.40 9.30 19.5
Total Acid Number mgKOH/g IP 177 / ASTM D664 0.20 0.24 0.08 0.12 0.18 0.21 0.16 0.19 0.25
Refractive Index @ 70°C ASTM D1218 1.4557 1.4770 1.4945 1.4959
Naphthalene Content %Wt / %Vol ASTM D1840 0.18 1.95
Wax Content % Wt. UOP 46 <5(1.8) <5(1.9) <5(3.5) 19.2 20.1 5.4 2.2
Metals
Nickel 7 <1 <1 15 29
mg/kg IP 501
Vanadium 26 <1 <1 49 94
Sodium <1 <1 3 5
Softening Point ASTM D36 NA(1*) 35.2
Penetration @ 25°C ASTM D5 NA(1*) 248.0
Asphaltene % Wt. IP 143 1.7 3.9 7.6
Ash Content % Wt. IP 4 / ASTM D482 0.008 0.013 0.027
Salt Content mg/kg IP 265 / ASTM D3230 15
B.S. & Water % Vol. ASTM D4007 0.025
Water Content % Vol. IP 74 / ASTM D95 <0.05
Flash Point °C IP170 / ASTM D93 <40.0 <40.0 <40.0 <40.0 80.0 124.0 178.0
Distillation - - - - - - -
IBP °C 27.7 83.2 161.1 202.8 250.9 311.8
10% Evaporated/Recovered °C 37.6 99.3 170.5 210.8 264.3 334.3
60% Evaporated/Recovered °C ASTM D86 49.1 128.3 181.8 217.2 283.2 340.3
FBP °C 73.0 166.1 201.0 232.7 327.9 357.7
Residue % Vol. 0.9 0.7 0.7 1.2 1.0 0.8
Loss % Vol. 0.8 0.5 0.6 1.0 0.8 0.5
Composition (C1-C5) -
Methane % Wt. <0.01
Ethane % Wt. 0.02
IP344 / IP 601
Propane % Wt. 0.26
I-butane % Wt. 0.27
n-butane % Wt. 0.85
Remark(s): 1. Unable to test due to sample nature. 2. Results is calculated and only as indicative –
precision parameters are not applicable.
Page No: 4
TRUE BOILING POINT DISTILLATION DATA
(ASTM D 2892/D5236)
Sample Descriptions / Label : Al Shaheen Crude Oil 2018
Cumulative % Cumulative %
Sl. No. Vapour Temperature °C % Mass % Volume
Mass Volume
1 LPG 1.38 1.38 2.16 2.16
Light Naphtha
2 3.27 4.65 4.43 6.59
(C5-70C)
Light Reformer Naphtha

3 9.58 14.23 11.35 17.94
(70-165C)
Reformer & Heavy Naphtha

4 5.10 19.33 5.63 23.57
(165 - 195C)
Kerosene
5 5.52 24.85 5.92 29.49
(195- 235C)
Light Gas Oil
6 17.65 42.50 18.14 47.63
(235 - 325C)
Gas Oil
7 7.51 50.01 7.41 55.04
(325-370C)
Heavy Vacuum Gas Oil
9 24.79 74.80 23.55 78.59
(370-548C)
Vacuum Residue
10 24.65 99.45 21.23 99.82
(548+C)
Page No: 5
TRUE BOILING POINT DISTILLATION CURVE
(ASTM D 2892 & ASTM D 5236)
AL Shaheen Crude Assay Report 2018
560
548
540
520
500
480
460
440
420
400
380
370
360
340
320
325
Temperature °C
300
280
260
240
235
% Mass
220
% Volume
200
195
180
160
165
140
120
100
80
70
60
40
20
15
0
0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0 80.0
Recovery %
Page No: 6
SUMMARY OF PRODUCT / RESIDUE CUT POINTS AND YIELDS
Sample Descriptions / Label: Al Shaheen Crude Oil 2018
Yield %
Cut Points Al Shaheen Crude Oil 2018
(° C) % mass Volume %
0-15 1.38 2.16
15-70 3.27 4.43
70-165 9.58 11.35
165-195 5.10 5.63
195-235 5.52 5.92
235-325 17.65 18.14
325-370 7.51 7.41
370+ Res 49.50 44.70
370-540 22.71 21.57
370-548 24.79 23.55
548+ Res 24.65 21.23
Page No: 7
SUMMARY OF TRUE BOILING POINT DISTILLATION WIDE CUTS
Al Shaheen Crude Assay Report 2018
100.00
95.00
90.00
85.00
80.00
75.00
70.00
65.00
60.00
55.00
50.00
45.00
% Yield
40.00
35.00
30.00
25.00
20.00
15.00
10.00
5.00
0.00
0-15 15-70 70-165 165-195 195-235 235-325 325-370 370+ 370-540 370-548 548+
Fraction Range (° C)
% Volume % Mass
Page No: 8
WHOLE CRUDE PROPERTIES
TEST METHOD UNIT RESULT
Specific Gravity @ 60/60° F ASTM D5002 - 0.8790

API Gravity @ 60° F Calculated ° API 29.5
Sulphur Content ASTM D4294 % Wt. 2.31
Mercaptan Sulphur UOP 163 ppm Wt. 322
Hydrogen Sulphide UOP 163 ppm Wt. <1
Total Nitrogen ASTM D5762 ppm Wt. 900
Basic Nitrogen UOP 269 % Wt 0.0225
Vapour Pressure ASTM D323 psi 6.20
Pour Point ASTM D97 °C <-18
ASTM D445 cSt
Organic Chloride ASTM D4929B mg/kg 1.0
Conradson carbon residue ASTM D189 % Wt. 4.84
Total Acid Number ASTM D664 mgKOH/g 0.20
Wax Content UOP 46 % Wt. <5(1.8)
Nickel IP 501 mg/kg 7
Vanadium IP 501 mg/kg 26
Asphaltene IP 143 % Wt. 1.7
Ash Content ASTM D482 % Wt. 0.008
Salt Content ASTM D3230 mg/kg 15
B.S. & Water ASTM D4007 % Vol. 0.025
Water Content ASTM D95 % Vol. <0.05
Flash Point ASTM D93 °C <40.0
Composition (C1-C5) -
Methane <0.01
Ethane 0.02
IP 601 % Wt.
Propane 0.26
I-butane 0.27
n-butane 0.85
Page No: 9
Light Naphtha [IBP/C5 - 70° C]
Yield ASTM D2892 / D5236 % Wt. 3.27

Yield ASTM D2892 / D5236 % Vol. 4.43
Density @ 15°C ASTM D4052 kg/L 0.6481
Specific Gravity @ 60/60° F Conversion - 0.6482
Sulphur Content ASTM D 5453 % Wt. 0.0274
Total Nitrogen ASTM D4629 ppm Wt. 0.3
PIONA Analysis % Vol -
Total Paraffins % Vol 93.0
n-Paraffins % Vol 34.8
iso-Paraffins % Vol 58.2
ASTM D6839
Total Olefins % Vol <0.1
Total Napthenes % Vol 6.9
Total Aromatics % Vol <0.1
Unidentified % Vol <0.1
Research Octane Number (Clear) * ASTM D2699/ GC Cal 70.0(*)
Organic Chloride ASTM D4929 mg/kg <1.0
Distillation - -
IBP °C 27.7
10% Evaporated/Recovered °C 37.6
60% Evaporated/Recovered ASTM D86 °C 49.1
FBP °C 73.0
Residue % Vol. 0.9
Loss % Vol. 0.8
Page No: 10
Light Reformer Naphtha [70 - 165° C]
Yield ASTM D2892 / D5236 % Wt. 9.58

Yield ASTM D2892 / D5236 % Vol. 11.35
Total Paraffins % Vol 59
ASTM D6839
Total Olefins % Vol <0.1
Total Aromatics % Vol 4.6
Research Octane Number (Clear) ASTM D2699/ GC Cal - 55
Copper corrosion test @ 40° C, 3 hours ASTM D130 - 2C
Distillation °C -
IBP °C 83.2
FBP °C 166.1
Residue % Vol. 0.7
Loss % Vol. 0.5
Page No: 11
Reformer & Heavy Naphtha [165 - 195° C]

Yield ASTM D2892 / D5236 % Wt. 5.10
Yield ASTM D2892 / D5236 % Vol. 5.63
Total Paraffins % Vol 62.7
ASTM D6839
Total Olefins % Vol 0.5
Total Aromatics % Vol 21.1
Cold Filter Plugging Point IP 309 °C <-51
Cloud Point ASTM D2500 °C <-42
Freeze Point ASTM D2386 °C -81.5
Kinematic Viscosity @ 40° C ASTM D445 cSt 0.969
Smoke Point ASTM D1322 mm 26.0
Copper corrosion test @ 40° C, 3 hours ASTM D130 - 2C
Aniline Point ASTM D611 °C 53.6
Hydrocarbon types by FIA - -
FIA-Aromatic % Vol. 20.3
IP 156
FIA-Olefins % Vol. 0.7
FIA-Saturates % Vol. 79
Distillation °C -
IBP °C 161.1
FBP °C 201
Residue % Vol. 0.7
Loss % Vol. 0.6
Page No: 12
Kerosene [195 - 235° C]
Yield ASTM D 2892 / D5236 % Wt. 5.52

Yield ASTM D 2892 / D5236 % Vol. 5.92
Specific Gravity @ 60/60° F Conversion 0.8194
Cold Filter Plugging Point IP 309 °C -44
Cloud Point ASTM D2500 °C <-42
Freeze Point ASTM D2386 °C -53.5
Smoke Point IP 57 / ASTM D1322 mm 25.0
Copper corrosion test @ 40° C, 3 hours ASTM D130 3A
Aniline Point ASTM D611 (Proc. A) °C 59.0
Hydrocarbon types by FIA - -
FIA-Aromatic % Vol. 23.8
IP 156
FIA-Olefins % Vol. 2.1
FIA-Saturates % Vol. 74.1
Organic Chloride ASTM D4929B mg/kg <1.0
Naphthalene Content ASTM D1840 %Wt / %Vol 1.95
Flash Point ASTM D93 °C >70.0
Distillation - -
IBP °C 202.8
FBP °C 232.7
Residue % Vol. 1.2
Loss % Vol. 1.0
Page No: 13
Light Gas Oil [235 - 325° C]

Yield ASTM D2892 / D5236 % Wt. 17.65

Yield ASTM D2892 / D5236 % Vol. 18.14
Cold Filter Plugging Point IP 309 °C -16
Cloud Point ASTM D2500 °C -14
Cetane Index ASTM D976 calc. 48.0
Copper corrosion test @ 40° C, 3 hours ASTM D130 - 1A
Conradson carbon residue ASTM D189 % Wt. <0.10
Refractive Index @ 70°C ASTM D1218 1.4557
Flash Point ASTM D93 °C 124.0
Distillation - -
IBP °C 250.9
FBP °C 327.9
Residue % Vol. 1.0
Loss % Vol. 0.8
Page No: 14
Gas Oil [325 - 370° C]

Yield ASTM D2892 % Wt. 7.51

Yield ASTM D2892 % Vol. 7.41
Pour Point ASTM D97 °C +6
Cold Filter Plugging Point IP 309 °C +8
Cloud Point ASTM D2500 °C +8
Cetane Index ASTM D976 calc. 45.6
UOP K Factor UOP 375 calc. 11.6
Conradson carbon residue ASTM D189 % Wt. <0.10
Flash Point ASTM D93 °C 178.0
Distillation - -
IBP °C 311.8
FBP °C 357.7
Residue % Vol. 0.8
Loss % Vol. 0.5
Page No: 15
Vacuum Gas Oil 1 [370 - 540°C]
Yield ASTM D2892/ D5236 % Wt. 22.71

Yield ASTM D2892/ D5236 % Vol. 21.57
Total Nitrogen ASTM D 4629 ppm Wt. 639
Wax Content UOP 46 % Wt. 19.2
Metals - -
Nickel mg/kg <1
IP 501
Vanadium mg/kg <1
Sodium mg/kg <1
Page No: 16
Heavy Vacuum Gas Oil [370 - 548°C]
Yield ASTM D2892 / D5236 % Wt. 24.79

Yield ASTM D2892 / D5236 % Vol. 23.55
Metals - -
Nickel mg/kg <1
IP 501
Vanadium mg/kg <1
Sodium mg/kg <1
Page No: 17
Atmospheric Residue [370°C+]
Yield ASTM D2892 / D5236 % Wt. 49.50

Yield ASTM D2892 / D5236 % Vol. 44.77
Density @ 15°C IP 365 kg/L 0.9713
Kinematic Viscosity @ 40° C ASTM D445 cSt 1212
Metals - -
Nickel mg/kg 15
IP 501
Vanadium mg/kg 49
Sodium mg/kg 3
Page No: 18
Vacuum Residue [548°C+]
Yield ASTM D2892 / D5236 % Wt. 24.65

Yield ASTM D2892 / D5236 % Vol. 21.23
Kinematic Viscosity @ 40° C ASTM D445 cSt 266400*
Kinematic Viscosity @ 100° C ASTM D445 cSt 1131
Softening Point D 36 °C 35.2
Penetration @ 25°C ASTM D5 mm 248.0
Ash Content IP 4 / ASTM D482 % Wt. 0.027
Metals - -
Nickel mg/kg 29
IP 501
Vanadium mg/kg 94
Sodium mg/kg 5
Remark(s): Results is calculated and only as indicative – precision parameters are not applicable.
Page No: 19

Crude Assay - Al Shaheen Crude Oil 2018

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Crude Assay Report

Crude sample marked

Al Shaheen Crude Oil 2018

Date: December 21, 2018

Company details : NORTH OIL COMPANY

: Logistics Base within Gulf Warehousing Company

Sample(s) received from : Qatar

Sample(s) submitted as : Al Shaheen Crude Oil 2018

Description(s) on Label(s) : Al Shaheen Crude Oil 2018

Seals on Sample(s) : Nil

Sample(s) received on : 21 November, 2018

Please refer attached sheets for analysis report.

Al Shaheen Crude Oil 2018

Sl.No. Description Page No.

4 Main Assay Properties 4

5 True Boiling Point Distillation Data 5

6 True Boiling Point Distillation data - Graph 6

7 Summary of Product / Residue cut points & Yield 7

8 Summary of True Boiling Point Distillation Cuts - Graph 8

9 Whole Crude Analysis 9

10 Naphtha Cuts - Light Naphtha [IBP/C5/15-70°C] 10

11 Naphtha Cuts - Light Reformer Naphtha [70-165°C] 11

12 Naphtha Cuts - Reformer & Heavy Naphtha [165-195°C] 12

13 Kerosene Cut - Kerosene [195-235°C] 13

14 Vacuum Gas Oil Cuts - Light Gas Oil [235-325°C] 14

15 Vacuum Gas Oil Cuts - Gas Oil [325-370°C] 15

16 Vacuum Gas Oil Cuts - Gas Oil 1[370 - 540°C] 16

18 Residue Cuts - Atmospheric Residue [+370°C] 18

19 Residue Cuts - Vacuum Residue [+548°C] 19

Naphtha Cuts Vacuum Gas Oil Cuts Residue Cuts

TEST UNIT METHOD

1 LPG 1.38 1.38 2.16 2.16

Light Reformer Naphtha

Reformer & Heavy Naphtha

SUMMARY OF PRODUCT / RESIDUE CUT POINTS AND YIELDS

Sample Descriptions / Label: Al Shaheen Crude Oil 2018

Cut Points Al Shaheen Crude Oil 2018

0-15 1.38 2.16

15-70 3.27 4.43

70-165 9.58 11.35

165-195 5.10 5.63

195-235 5.52 5.92

235-325 17.65 18.14

325-370 7.51 7.41

370+ Res 49.50 44.70

370-540 22.71 21.57

370-548 24.79 23.55

548+ Res 24.65 21.23

TEST METHOD UNIT RESULT

Specific Gravity @ 60/60° F ASTM D5002 - 0.8790

Light Naphtha [IBP/C5 - 70° C]

Sample Descriptions / Label : Al Shaheen Crude Oil 2018

TEST METHOD UNIT RESULT

Yield ASTM D2892 / D5236 % Wt. 3.27

Light Reformer Naphtha [70 - 165° C]

Sample Descriptions / Label : Al Shaheen Crude Oil 2018

TEST METHOD UNIT RESULT

Yield ASTM D2892 / D5236 % Wt. 9.58

Sample Descriptions / Label : Al Shaheen Crude Oil 2018

TEST METHOD UNIT RESULT

Kerosene [195 - 235° C]

Sample Descriptions / Label : Al Shaheen Crude Oil 2018

TEST METHOD UNIT RESULT

Yield ASTM D 2892 / D5236 % Wt. 5.52