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JEE
JEE (Advanced)
(ADVANCED) 2016
2019

22-05-2016
DATE: 27-05-2019

Memory Based Questions & Solutions


PAPER ¼isij½- 1 | SUBJECT : CHEMISTRY
PAPER-1 : INSTRUCTIONS TO CANDIDATES
 Question Paper-1 has three (03) parts: Physics, Chemistry and Mathematics.
 Each part has a total eighteen (18) questions divided into three (03) sections (Section-1, Section-2 and Section-3)
 Total number of questions in Question Paper-1 are Fifty Four (54) and Maximum Marks are One Hundred Eighty Six (186)

Type of Questions and Marking Schemes


SECTION-1 (Maximum Marks : 12)

 This section contains FOUR (04) questions.

 Each question has FOUR options ONLY ONE of these four options is the correct answer.

 For each question, choose the correct option corresponding to the correct answer.

 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.

SECTION-2 (Maximum Marks : 32)

 This section contains EIGHT (08) questions.

 Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).

 For each question, choose the option(s) corresponding to (all) the correct answer(s).

 Answer to each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of which are correct.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.

Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.

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SECTION-3 (Maximum Marks : 18)

 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.

 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer. If the numerical value has more than two decimal places truncate/round-off the value to
TWO decimal placed.

 Answer to each question will be evaluated according to the following marking scheme :

Full Marks : +3 If ONLY the correct numerical value is entered.

Zero Marks : 0 In all other cases.

Answering Questions :

 To select the option(s), use the mouse to click on the corresponding button(s) of the option(s).

 To deselect the chosen option for the questions of SECTION-1, click on the button of the chosen option again or click on the Clear
Response button to clear the chosen option.

 To deselect the chosen option(s) for the questions of SECTION-2, click on the button(s) of the chosen option(s) again or click on the
Clear Response button to clear all the chosen options.

 To change the option(s) of a previously answered question of SECTION-1 and SECTION-2 first deselect as given above and then
select the new option(s).

 To answer questions of SECTION-3, use the mouse to click on numbers (and/or symbols) on the on–screen virtual numeric keypad
to enter the numerical value in the space provided for answer.

 To change the answer of a question of SECTION-3, first click on the Clear Response button to clear the entered answer and then
enter the new numerical value.

 To mark a question ONLY for review (i.e. without answering it), click on the Mark for Review & Next button.

 To mark a question for review (after answering it), click on Mark for Review & Next button – the answered question which is also
marked for review will be evaluated.

 To save the answer, click on the Save & Next button – the answered question will be evaluated.

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PART-I : CHEMISTRY
SECTION-1 (Maximum Marks : 12)
 This section contains FOUR (04) questions.
 Each question has FOUR options ONLY ONE of these four options is the correct answer.
 For each question, choose the correct option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.

1. Which of the following set represent correct formula for Malachite, Magnetite, Calamine & Cryolite ?
fuEu esa ls dkSulk leqPp; esysdkbV, eSXusVkbV, dsykekbu rFkk Øk;ksykbV ds fy, lgh lw=k iznf'kZr djrk gSA
(A) CuCO3, Fe2O3, ZnO, Al2O3
(B) CuCO3.Cu(OH)2, Fe3O4 , ZnCO3, Na3AlF6
(C) CuCO3, Fe3O4, ZnCO3, Al2O3
(D) CuCO3.Cu(OH)2, Fe2O3 , ZnCO3, Na3AlF6
Ans. (B)
Sol. Malachite, CuCO3.Cu(OH)2
Magnetite, Fe3O4
Calamine, ZnCO3
Cryolite, Na3AlF6
Sol. esysdkbV, CuCO3.Cu(OH)2
eSXusVkbV, Fe3O4
dsykekbu, ZnCO3
Øk;ksykbV, Na3AlF6

2. Find the correct acidic strength order :


fuEu dk lgh vEyh; lkeF;Zrk dk Øe gS%
(i) HCC–COOH (ii) H2C=CH–COOH

(iii) MeO COOH (iv) CH3–CH2–COOH

(A) (i) > (ii) > (iv) > (iii) (B) (i) > (ii) > (iii) > (iv)
(C) (iii) > (ii) > (i) > (iv) (D) (iii) > (i) > (iv) > (ii)
Ans. (B)
Sol. pKa
(i) HC  C–COOH 1.89
(ii) H2C = CH–COOH 4.3

(iii) MeO COOH 4.5

(iv) CH3–CH2–COOH 4.87

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3. Sodium stearate is a strong electrolyte. Which of the following plot is correct regarding its conductance :
lksfM;e LVhjsV izcy oS|qr vi?kV~;’ gSA fuEu esa ls dkSulk vkjs[k bldh pkydrk ds lanHkZ esa lgh gS&

CMC CMC
(A) m (B) m

C C

(C) m (D) m
CMC
CMC

C C
Ans. (B)

4. Which green coloured compound of chromium is formed in borax bead test ?


cksjsDl eudk ijh{k.k esa Øksfe;e dk dkSulk gjk jaxhu ;kSfxd curk gS \
(A) Cr(BO2)3 (B) Cr2O3 (C) CrB (D) CrBO3
Ans. (A)
 
Sol. Na2B4O7.10H2O  Na2B4O7  NaBO2 + B2O3

Cr2O3 + B2O3  Cr (BO2 )3
Green

SECTION-2 (Maximum Marks : 32)


 This section contains EIGHT (08) questions.
 Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of which are correct.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.

5. Choose the reaction, for which the standard enthalpy of reaction is equal to the standard enthalpy of
formation :
,slh vfHkfØ;k’vksa dk p;u dhft, ftuds fy, vfHkfØ;k dh ekud ,UFkSYih] lEHkou dh ekud ,UFkSYih ds cjkcj
gksrh gS&
3
(A) 2C(g) + 3H2(g)  C2H6 (g) (B) O2(g)  O3(g)
2
1
(C) S8(s) + O2(g)  SO2(g) (D) 2H2(g) + O2(g) 2H2O()
8
Ans. (BC)
Sol. Standard enthalpy of formation : “The standard enthalpy of formation of a compound is the change in
the standard enthalpy when one mole of the compound is formed starting from the requisite amounts of
elements in their stable state of aggregation”.

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lEHkou dh ekud ,UFkSYih % inkFkZ ;k ;kSfxd dh ekud laHkou m"ek] ekud m"ek esa ifjorZu tc ,d eksy ;kSfxd]
vius izkjfEHkd rRoksa dh vko';d ek=kk ls bldh LFkk;h laxq.khr voLFkk esa curk gSA

6. A Tin-chloride 'P' gives following reaction (unbalanced reaction)


P + Cl–  X [Monoanion pyramidal geometry]
P + Me3N  Y
P + CuCl2  Z + CuCl
Then which of the following is/are correct.
(A) Y contains co-ordinate bond. (B) X is sp3 hybridised.
(C) Oxidation state of Sn in X is +1. (D) X contain lone pair on central atom.
,d fVu DyksjkbM 'P' fuEu vfHkfØ;k nsrk gS (vlarqfyr vfHkfØ;k)
P + Cl–  X [,dy _.kk;u fijkfeMh; T;kfefr]
P + Me3N  Y
P + CuCl2  Z + CuCl
rc fuEu esa ls dkSulk@dkSuls lgh gS@gSa \
(A) Y esa milgla;kstd cU/k mifLFkr gSA
(B) X, sp3 ladfjr gSA
(C) X esa Sn dh vkWDlhdj.k voLFkk +1 gSA
(D) X esa dsUnzh; ijek.kq ij ,dkdh ;qXe mifLFkr gSA
Ans. (ABD)
Sol. SnCl2 + Cl–  SnCl3
P  X 
SnCl2 + Me3N  SnCl2 [N(CH3 )3 ]
P  Y 
SnCl2 + 2CuCl2  SnCl4 + CuCl
P  Z 

x1 234 x2 234 x3 234 x 230


92 U 90 Th 91 Pa  Z 

238
7. 90 Th
4

x1, x2, x3, x4, are either particles or radiation. Then


(A) x1 is deflected toward negatively charged plate.
(B) x2 is - particle.
(C) x3 is -radiation.
(D) z is isotope of 238 U
x1 234 x2 234 x3 234 x 230
92 U 90 Th 91 Pa  Z 

238
90 Th
4

x1, x2, x3, x4, ;k rks d.k gS ;k fofdj.k gSaA rc


(A) x1 _.kkosf'kr IysV dh vksj fopfyr gksrs gSA
(B) x2 -d.k gSA
(C) x3 -fofdj.k gSA
(D) z 238 U dk leLFkkfud gSA
Ans. (ABD)
Sol. x1 = 
X2 = 
 X3 = 
X4 = 

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8. Fusion of MnO2 along with KOH and O2 forms X. Electrolytic oxidation of X yields Y. X undergoes
disproportionation reaction in acidic medium to MnO2 and Y. The Manganese in X and Y is in the form
W & Z respectively, then
(A) W & Z are coloured
(B) W is diamagnetic and Z is paramagnetic
(C) Both W & Z are tetrahedral in shape
(D) Both W & Z involve p–d bonding for  bond
KOH rFkk O2 dh mifLFkfr esa MnO2 laxyu }kjk X cukrk gSA X dk oS|qr vi?kVuh; vkWDlhdj.k ls Y izkIr gksrk
gSA X vEyh; ek/;e esa fo"kekuqikrhdj.k vfHkfØ;k }kjk MnO2 rFkk Y nsrk gSA X rFkk Y esa eSaXuht Øe'k% W rFkk Z
ds :i esa gS rc&
(A) W rFkk Z jaxhu gSaA
(B) W izfrpqEcdh; gS rFkk Z vuqpqEcdh; gSA
(C) nksuksa W rFkk Z prq"Qydh; vkd`fr esa gSA
(D) nksuksa W rFkk Z esa cU/k ds fy, p–dcU/ku mifLFkr gSA
Ans. (ACD)
KOH electrolytic
Sol. MnO2 MnO24 MnO4
O2 (W) Oxidation (Z)

acidic
medium

MnO2 + MnO4
KOH oS|qr vi?kVuh;
Sol. MnO2 MnO24 MnO4
O2 (W) vkWDlhdj.k (Z)

vEyh;
ek/;e
MnO2 + MnO4

(1)CH MgBr Conc.HCl


9. C6H10O 
3
 Q 
 S
(2)H2O (Major) (Major)
20%H PO (1)H / Ni
Q 
3 4
 R 
2
 T
(Major) 360K (Major) (2)Br2 / h (Major)
HBr/
(R) (U)
Ph–C–O–O–C–Ph
(Major) (Major)
O O
CH3 CH3 CH3 CH3
Cl Br Br Cl
(A) S = ,T= (B) U = ,S=

CH3 CH3 CH3 CH3


Br Br Cl Br
(C) U = ,T = (D) S = ,U=

Ans. (CD)

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CH3 CH3
O OH Cl
(1)CH MgBr Conc.HCl
Sol. 
3
 

(2)H2O

(Q) (S)
CH3 CH3
CH3
Br
OH
20%H PO (1)H / Ni

3 4
 
2

360K (2)Br2 / h
(R) (T)
(Q)
CH3 CH3
Br
HBr/
Ph–C–O–O–C–Ph
(R) (U)
O O

10. Which of the following are true .


(A) Monosaccharides can not be hydrolysed to give polyhydroxy aldehydes and ketones.
(B) Hydrolysis of sucrose gives dextrorotatory glucose and laevorotatory fructose
(C) Oxidation of glucose with bromine water gives glutamic acid.
(D) The two six membered hemiacetal form of D (+) glucose are anomers.
fuEu esa ls dkSulk dFku lR; gSA
(A) eksukslsdSjkbM ty vi?kVu ij ikWyhgkbMªksDlh ,fYMgkbM ,oa dhVksu ugha nsrs gSA
(B) lqØksl tyvi?kVu ij nf{k.kkorhZ ?kzq.kZd Xyqdksl rFkk ckekorhZ ?kzq.kZd ÝDVksl nsrk gSA
(C) Xyqdksl dk vkWDlhdj.k czksehu ty ds lkFk djkus ij XyqVkfed vEy izkIr gksrk gSA
(D) D (+) Xyqdksl dk N% lnL;h gseh,slhVsy :i ,suksej gksrk gSA
Ans. (ABD)

H,H O
Sol. Sucrose   D( ) Glucos e  D(  ) Fructose
2

Hydrolysis Dextrorotatory  Laevorotatory 

& rFkk an anomers of each other. (,d nwljs ds ,uksej gS)

-D-Xyqdksik;jsuksl -D-Xyqdksik;jsuksl

11. Identify the option where all four molecules possess permanent dipole moment at room temperature.
og fodYi igpkfu, tgk¡ lHkh pkjksa v.kq dejs ds rki ij LFkk;h f}/kqzo vk?kw.kZ j[krs gaSA
(A) BF3, O3, SF6, XeF6 (B) BeCl2, CO2, BCl3, CHCl3
(C) SO2, C6H5Cl, H2Se, BrF5 (D) NO2, NH3, POCl3, CH3Cl
Ans. (CD)

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Cl
S
Sol. (C) SO2 sp2 (2 + 1) ; O O C6H5Cl ; H2Se ; H–Se

H
O Cl
N P C
N H H Cl Cl H H
(D) O O H Cl H

12. Which of the following is/are correct regarding root mean square speed (Urms) & average translation
K.E.(Eav) of molecule in a gas at equilibrium.
(A) Eav is doubled when its temperature is increased 4 times
(B) Urms is inversely proportional to the square root of its molecular mass
(C) Eav at a given temperature doesn't depend on its molecular mass
(D) urms is doubled when its temperature is increased 4 times
lkE; ij xSl ds v.kq ds oxZ ek/; ewy osx (Urms) rFkk vkSlr LFkkukUrj.k ÅtkZ K.E.(Eav) ds lanHkZ esa fuEu esa ls
dkSulk@dkSuls dFku lgh gS@gSa\
(A) Eav nqxuh gks tkrh gS tc blds rkieku easa 4 xquk o`f) dh tkrh gSA
(B) Urms blds vkf.od nzO;eku ds oxZewy ds O;qRØekuqikrh gksrk gS
(C) fn;s x;s rkieku ij Eav blds vkf.od nzO;eku ij fuHkZj ugha djrh gSA
(D) urms nqxuh gks tkrh gS tc blds rkieku easa 4 xquk o`f) dh tkrh gSA
Ans. (BCD)
3 3RT 1
Sol. Eav = RT Urms= & Urms 
2 M M
 EAV doesn't depend on its molecular mass
 EAV blds vkf.od nzO;eku ij fuHkZj ugha djrh gSA

SECTION-3 (Maximum Marks : 18)


 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer. If the numerical value has more than two decimal places truncate/round-off the value to
TWO decimal placed.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +3 If ONLY the correct numerical value is entered.
Zero Marks : 0 In all other cases.

13. XeF4 + O2F2  product. The total number of lone pairs on the xenon containing product is : (I)
XeF4 + O2F2  mRikn thukWu ;qDr mRikn ij dqy ,dkdh ;qXeksa dh la[;k gS&
Ans. (19)

Sol. XeF4 + O2F2  XeF6 + O2

(3 lp on each F and 1 lp on Xe)

(izR;sd F ij 3 lp rFkk Xe ij 1 lp)

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14. For the following reaction, equilibrium constant Kc at 298 K is 1.6 × 1017
 2–
Fe(2aq )  S(aq ) FeS(s)

When equal volume of 0.06 M Fe+2 and 0.2 M S–2 solution are mixed, then equilibrium concentration of
Fe+2 is found to be Y × 10–17 M . Y is :
fuEu vfHkfØ;k ds fy, 298 K ij lkE; fu;rkad Kc 1.6 × 1017 gSA
 2–
Fe(2aq )  S(aq ) FeS(s)

tc 0.06 M Fe+2 rFkk 0.2 M S–2 ds leku vk;ruksa dks feyk;k tkrk gS rc lkE; ij Fe+2 dh lkE; lkanzrk Y ×
10–17 M ik;h tkrh gS rc Y gS&
Ans. (8.92 & 8.93)
 –
Sol. Fe(2aq ) + S(2aq ) FeS(s) KC = 1.6 × 1017

0.06 M 0.2 M
After mixing 0.03 M 0.1 M
? 0.07 M
1
1.6 × 1017 =
Fe  0.07
2

1017 1015 100


or [Fe2+] =  =  1017 = 8.928 ×10–17 = Y × 10–17
1.6  0.07 11.2 11.2
Answer after rounding of is = 8.93
Answer after truncation of is = 8.92

NH2
(1) aq. Br2
15. (Q)
(2) NaNO2/HCl
(3) CuCN/KCN
(4) H2O/H
(5) SOCl2

(1) Oleum
(R)
(2) NaOH/H2O
(3) Br2/CS2

(1) NaOH
( 2) Q
R 
 T
Number of atoms of Br in compound 'T'
;kSfxd T esa Br ijek.kqvksa dh dqy la[;k gSA
Ans. (4)

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NH2 NH2 N2Cl CN


Br Br Br Br Br Br
Aq. Br2 NaNO2 CuCN
Sol. 
  

HCl KCN

Br Br Br

COOH C–Cl
Br Br Br Br
H2O / H SOCl 2
 


Br Br
(Q)

SO3H OH OH

Oleum Fused Br
    
2
 'R'
1 NaOH CS 2
( 2 ) H
Br

O Br O Br
Br O Cl—C Br  Br O—C Br

Br 'T' Br

16. Which of the following compounds contain bond between same type of atoms.

N2O4, B3N3H6, H2S2O3, N2O, H2S2O8, B2H6

fuEu esa ls dkSuls ;kSfxdks esa leku ijek.kqvksa ds e/; ca/k ik;s tkrs gS

N2O4, B3N3H6, H2S2O3, N2O, H2S2O8, B2H6

Ans. (4)

Sol. N2O4, H2S2O3, N2O, H2S2O8

S S S
O O, , ,
N—N S NN O S S
O O O OH OH O—O OH
OH O O

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17. A+B+C  Product


Ex. No [A] [B] [C] Rate of reaction
1. 0.2 0.1 0.1 6 × 10–5
2. 0.2 0.2 0.1 6 × 10–5
3. 0.2 0.1 0.2 1.2 × 10–4
4. 0.3 0.1 0.1 9 × 10–5
When [A] = 0.15
[B] = 0.25
[C] = 0.15
Rate of reaction is Y x 10–5 M/s Find Y.

A+B+C  mRikn
iz;ksx la[;k [A] [B] [C] vfHkfØ;k dh nj
1. 0.2 0.1 0.1 6 × 10–5
2. 0.2 0.2 0.1 6 × 10–5
3. 0.2 0.1 0.2 1.2 × 10–4
4. 0.3 0.1 0.1 9 × 10–5
tc [A] = 0.15
[B] = 0.25
[C] = 0.15
vfHkfØ;k dh nj Y x 10–5 M/s gS rc Y Kkr dhft,A
Ans. (6.75)
Sol. r = k [A]a [B]b [C]c
by experiment no. 1&2 b=0
by experiment no. 1&3 c=1
by experiment no. 1&4 a=1
r = K [A]1 [B]0 [C]1
From Ex. no.1 6 × 10–5 = k (0.2) (0.1)
k = 3 × 10–3
Given [A] = 0.15 [B] = 0.25 [C] = 0.15
r = k [A]1 [B]0 [C]1
= 3 x 10–3 × 0.15 × 1 × 0.15
= 3 × 0.025 × 10–3
= 6.75 × 10–5 mol L–1 sec–1
Y = 6.75

Sol. r = k [A]a [B]b [C]c


iz;ksx la[;k 1 rFkk 2 ls b=0
iz;ksx la[;k 1 rFkk 3 ls c=1
iz;ksx la[;k 1 rFkk 4 ls a=1
r = K [A]1 [B]0 [C]1
iz;ksx la[;k 1 ls 6 × 10–5 = k (0.2) (0.1)
k = 3 × 10–3
fn;k gS [A] = 0.15 [B] = 0.25 [C] = 0.15
r=k [A]1 [B]0 [C]1
= 3 × 10–3 × 0.15 × 1 × 0.15
= 3 × 0.025 × 10–3
= 6.75 × 10–5 mol L–1 sec–1
Y = 6.75

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18. On dissolving 0.5 g of non–volatile, non–ionic solute to 39 g of benzene, its vapour pressure decreases

from 650 mm of Hg to 640 mm of Hg. The depression of freezing point of benzene (in K) upon addition

of the solute is _________.

[Given data : Molar mass & molar freezing point depression of benzene is 78 g mol–1 & 5.12 K Kg mol–1]

csUthu ds 39 xzke esa vok"i'khy] vu~&vk;fur foys; inkFkZ ds 0.5 xzke foy; djus ij] bldk ok"i nkc 650 mm

Hg ls 640 mm Hg rd ?kVrk gSA foys; inkFkZ feykus ij csUthu ds fgekad fcUnq esa voueu (K esa) ________ gSA

[fn;s x;s vk¡dMs csUthu dk eksyj nzO;eku rFkk eksyy fgekad fcUnq voueu Øe'k% 78 g mol–1 rFkk 5.12 K Kg

mol–1 gSA]

Ans. (1.02)

P 0 – Ps n 
Sol.  i  solute 
Ps  n solvent 

650  640 0.5  78


=1× Msolute = 64 gm
640 M  39

0.5  1000
Tf = Kf × m = 5.12 × 
64  39

Tf = 1.02

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