JEE Advanced 2019 Paper-2 Chemistry

®
JEE
JEE (Advanced)
(ADVANCED) 2016
2019
22-05-2016
DATE: 27-05-2019
Memory Based Questions & Solutions

PAPER ¼isij½- 2 | SUBJECT : CHEMISTRY
PAPER-2 : INSTRUCTIONS TO CANDIDATES

 Question paper-2 has three (03) parts : Physics, Chemistry and Mathematics.
 Each part has a total of eighteen (18) questions divided into three (03) sections (Section-1, Section-2 and Section-3).
 Total number of questions in Question Paper-2 are : Fifty Four (54) and Maximum Marks are One Hundred Eighty Six (186).
Type of Questions and Marking Schemes
SECTION 1 (Maximum Marks : 32)
 This section contains EIGHT (08) questions.
 Each question has FOUR options ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of which are correct.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.
 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to
TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +3 If ONLY the correct numerical value is entered.
Zero Marks : 0 In all other cases.
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 This section contains TWO (02) List-Match sets.
 Each List-Match set has TWO (02) Multiple Choice Questions.
 Each List-Match set has two lists : List-I and List-II.
 List-I has Four entries (I),(II), (III) and (IV) List-II has Six entries (P),(Q), (R ), (S), (T) and (U).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies
the condition asked in the Multiple Choice Question.
Full Marks : +3 If ONLY the option corresponding to the correct combination is chosen.
Answering Questions :
 To select the option(s), use the mouse to click on the corresponding button(s) of the option(s).
 To deselect the chosen option(s) for the questions of SECTION-1 click on the button(s) of the chosen option(s) again or click on the
Clear Response button to clear all the chosen options.
 To deselect the chosen option for the questions of SECTION-3, click on the button of the chosen option again or click on the Clear
Response button to clear the chosen option.
 To change the option(s) of a previously answered question of SECTION-1 and SECTION-3 first deselect as given above and then
select the new option(s)
 To answer questions of SECTION-2 use the mouse to click on numbers (and/or symbols) on the on-screen virtual numeric keypad to
enter the numerical value in the space provided for answer.
 To change the answer of a question of SECTION-2 first click on the Clear Response button to clear the correct answer and then
enter the new numerical value.
 To mark a question ONLY for review (i.e. without answering it). Click on the Mark for Review & next button.
 To mark is question for review (after answering it), click on Mark for Review & Next button - the answered question which is also
marked for review will be evaluated.
 To save the answer click on the Save & Next button, the answered question will be evaluated.

This solution was download from Resonance JEE (ADVANCED) 2019 Solution portal
| JEE (ADVANCED) 2019 | DATE : 27-05-2019 | PAPER-2 | MEMORY BASED | CHEMISTRY
PART-I : CHEMISTRY
 This section contains EIGHT (08) questions.
 Each question has FOUR options ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of which are correct.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
1. With reference to aqua regia, choose the correct option(s) :

(A) Aqua regia is prepared by mixing conc. HCl and conc. HNO 3 in 3 : 1 molar ratio.
(B) Reaction of gold with aqua regia produces an anion having Au in +3 oxidation state.
(C) Reaction of gold with aquaregia produces NO2 in the absence of air
(D) The yellow colour of aqua regia is due to the presence of NOCl & Cl2.
,Dok jsft;k ¼vEy&jkt½ ds lanHkZ esa lgh fodYi@fodYiksa dk p;u dhft, :
(A) ,Dok jsft;k dks 3 : 1 eksyj vuqikr esa lkanz HCl rFkk lkUnz HNO3 dks feykdj cuk;k tkrk gSA
(B) ,Dok jsft;k ds lkFk xksYM dh vfHkfØ;k] +3 vkWDlhdj.k voLFkk esa Au j[kus okyk _.kk;u mRikfnr djrh gSA
(C) ,Dok jsft;k ds lkFk xksYM dh vfHkfØ;k] ok;q dh vuqifLFkfr esa] NO2 mRikfnr djrh gSA
(D) ,Dok jsft;k dk ihyk jax NOCl rFkk Cl2 dh mifLFkfr ds dkj.k gksrk gSA
Ans. (ABD)
Sol. Au + 4H+ + NO 3 + 4Cl–  [AuCl4] + NO + 2H2O
(A) Fact.
(B) [AuCl4]– gets formed; Au(+3).
(C) NOCl/NO is formed.
(D) Fact.
Sol. Au + 4H+ + NO 3 + 4Cl–  [AuCl4] + NO + 2H2O
(A) rF;
(B) [AuCl4]– curk gS; Au(+3).
(C) NOCl/NO curk gSA
(D) rF;

This solution was download from Resonance JEE (ADVANCED) 2019 Solution portal PAGE # 1
2. Choose the correct option that gives aromatic compound as major product :
CH3
(i) Alc.KOH, NaNH2
Br (ii) Red hot iron tube 873 K
NaOEt
(A)   (B)
Br
Br
NaOEt UV
(C)   (D) + Cl2 500

K
fuEu esa ls dkSulh vfHkfØ;k eq[; mRikn ds :i esa ,sjkseSfVd ;kSfxd nsrh gSA
CH3
(i) Alc.KOH, NaNH2
Br
NaOEt (ii) jDr rIr ykSg ufydk 873 K
(A)   (B)
Br
Br
NaOEt UV
(C)   (D) + Cl2 500

K
Ans. (AB)
NaOEt
Sol. (A)  
CH3
(B) (i) Alc.KOH, NaNH2 red hot iron tube
  
Br
Br
Aromatic
3. Which of the following reaction produce propane as major product ?
fuEu esa ls fdl vfHkfØ;k esa eq[; mRikn izksisu izkIr gksrk gS\
(A) CH3 Electrolysis oS| qr vi?kVu
  

COONa
Br
Zn
Br 
(B) 
H3C
(C) Cl 
Zn, dilHCl

Zn, ruq HCl
 
H3C
(D) CH3 NaOH,CaO,

  
COONa
Ans. (CD)
Sol. Cl 
Zn, dilHCl

Zn, ruq HCl
 
H3C
CH3 NaOH,CaO,
  
COONa

4. Which of the following is / are Correct

(A) Teflon is formed by polymerization of tetrafluoroethene.
(B) Natural rubber is the trans from of polyisoprene.
(C) Cellulose contains only -D-glucose linkage
(D) Nylon-6 contains amide linkage.
fuEu esa ls dkSulk@dkSuls dFku lgh gS&
(A) Vs¶ykWu dk fuEkkZ.k VsVªk¶yksjks,sfFku ds cgqyhdj.k ij gksrk gSA
(B) izkd`frd jcj] iksyhvkblksizhu dk foi{k :i gksrk gSA
(C) lSY;wyksl esa dsoy -D-Xyqdksl caèk ik;k tkrk gSA
(D) uk;ykWu-6 esa ,ekbM caèk ik;k tkrk gSA
Ans. (AD)
CC–CH2–CH=O
(1) HgSO / dil.H SO (1) SOCl / Py ZnHg/HCl

5. 
4 2 4
 'Q' 
2
 R  S
(2) AgNO3 / NH4OH (2) AlCl3
(3)ZnHg / HCl
OMe
OH
(A) Q = ,R=
O MeO
MeO
O
(B) R = , S=
MeO MeO
O
(C) R = , S=
MeO MeO
O
OH
OH
(D) Q = ,S=
O MeO
MeO
Ans. (AB)

Sol.
O O OH
CC–CH2–CH=O C–CH2–CH2–CH=O C–CH2–CH2–C=O
HgSO / dil.H SO AgNO / NH OH


4 2 4
 
3 4

OMe OMe OMe

OH Cl
ZnHg SOCl / Py

 O 
2
 O
HCl MeO MeO
(Q)
AlCl ZnHg

3
 MeO 

HCl MeO
O (S)
(R)
6. Consider the following reaction (unbalanced)

Zn + Hot conc. H2SO4  G + R + X
Zn + conc. NaOH  T + Q
G + H2S + NH3(aq)  Z(precipitate) + X + Y
Choose the correct option (s)
(A) R is a V-shaped molecule
(B) Z is dirty white in colour
(C) Bond order of Q is 1 in its ground state
(D) The oxidation state of Zn in T is +1.
fuEu vfHkfØ;k (vlarqfyr) dk voyksdu dhft,&
Zn + xeZ lkUnz H2SO4  G + R + X
Zn + lkUnz NaOH  T + Q
G + H2S + NH3(aq)  Z(vo{ksi) + X + Y
lgh fodYi@fodYiksa dk p;u dhft,&
(A) R, V- vkd`fruqek v.kq gSA
(B) Z xanys lQsn (dirty white) jax dk gksrk gSA
(C) Q dk cU/k Øe bldh vk| voLFkk esa 1 gSA
(D) T esa Zn dh vkWDlhdj.k voLFkk +1 gSA
Ans. (ABC)
Sol. Zn + H2SO4  ZnSO4 + SO2 + H2O
(Hot & conc .) ( G) (R ) ( X)
Zn + conc. NaOH  Na 2 ZnO2 + H2

(T) (Q )
ZnSO4 + H2S + NH3(aq)  ZnS  + (NH4 )2 SO4 + H2O

( G) ( Z) (Y) ( X)

7. In the Mac. Arthur process of extraction

NaCNQ extracted
 R 
Au   Z
with Y
 2–
(A) R is [Au(CN4)] (B) Z is [Zn(CN)4]
(C) Q is O2 (D) Y is Zn
fu"d"kZ.k ds esd vkWFkZj izØe esa
NaCNQ Y ds lkFk fu" df" kZr
Au   R  Z
 2–
(A) R, [Au(CN4)] gSA (B) Z, [Zn(CN)4] gSA
(C) Q, O2 gSA (D) Y, Zn gSA
Ans. (BCD)
NaCN O  Zn 2–
Sol. Au 
2
 [Au(CN4)] 
 [Zn(CN)4] + Au
8. For He+ the electron is in orbit with energy equal to 3.4eV. The azimuthal quantum number for that orbit
is 2 and magnetic quantum number is 0. Then which of the following is/ are correct.
(A) The subshell is 4d.
(B) The number of angular nodes in it is 2.
(C) The numbers of radial nodes in it is 3.
(D) The nuclear charge experienced in n = 4 is 2e less than that in n = 1, where e is electronic charge.
He+ ds fy, 3.4eV ds cjkcj ÅtkZ;qDr d{k esa bysDVªkWu gSA ml d{k ds fy, f}xa'kh DokUVe la[;k 2 gS rFkk
pqEcdh; DokUVe la[;k 0 gS rc fuEu esa dkSulk@dkSuls lgh gS@gSa&
(A) midks'k 4d gSA
(B) blesa dks.kh; uksMks dh la[;k 2 gSA
(C) blesa f=kT;h; uksMks dh la[;k 3 gSA
(D) n = 4 esa vuqHko fd;k x;k ukfHkdh; vkos'k n = 1 dh rqyuk esa 2e de gS tgk¡ e bysDVªkWfud vkos'k gSA
Ans. (AB)
( 2) 2 –13.6
Sol. E  = –13.6 × 2 = –3.4 =
He
n 4
n2 = 16 so n=4
quantum number are
n = 4,  = 2, m = 0
so subshell is = d.
angular node =  = 2
Radial node = [n––1] = 4 – 2 – 1 = 1
( 2) 2 –13.6
Sol. E  = –13.6 × 2 = –3.4 =
He
n 4
n2 = 16 so n=4
DokUVe la[;k,a gS%
n = 4,  = 2, m = 0
blfy, midks'k = d gSA
dks.kh; uksM =  = 2
f=kT;h; uksM = [n––1] = 4 – 2 – 1 = 1

 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to
TWO decimal places.
Full Marks : +3 If ONLY the correct numerical value is entered.
Zero Marks : 0 In all other cases.
9. Calculate the total number of cyclic ether (including stereo) having formula C 4H8O
C4H8O v.kqlw=k ds dqy pØh; bZFkj ¼f=kfoe lfgr½ dh x.kuk dhft,A
Ans. (10)
O
O O O
O O
Sol.
(R+S) (R+S)
(R,R), (S, S)
(R,S)  (S, R)
= 10
10. 1 mole of Rhombic sulphur is treated with conc. HNO3. Find the mass of H2O formed.
1 eksy jksgfEcd lYQj dks lkUnz HNO3 ds lkFk mipkfjr fd;k tkrk gS rc fufeZr H2O dk nzO;eku Kkr dhft,\
Ans. (288)
32H2O  S 8  8H2SO4  48H  48e 
[e   H  HNO 3  NO 2  H2O]  48
Sol.
S 8  48HNO 3  8H2SO4  48NO 2  16H2O
1 mol 16mol
 mass of H2O formed = (16) (18)g = 288 g
 fufeZr H2O dk nzO;eku = (16) (18)g = 288 g
11. Mole fraction of urea in 900 gram water is 0.05. Density of solution is 1.2 g/cm 3. Find molarity of
solution.
900 g ty esa ;wfj;k dk eksy izHkkt 0.05 gSA foy;u dk ?kuRo 1.2 g/cm3 gSA foy;u dh eksyjrk Kkr dhft,\
Ans. (2.98 OR 2.99)
900
Sol. wt H2O = 900 g  nH2O = = 50
18
Let moles of urea ekuk dh ;wfj;k ds eksy = y
y
 xurea  = 0.05
y  50
50
y=
19

 50  3000
 Wturea =    60 =
 19  19
3000 (201)
 Wtsolution = + 900 = × 100
19 19
solution = 1.2 g/cm3
wt  201 100
 Vsolution = =  
  19  1.2
 50 
   1000
 Murea =
nurea 19
 1000 =   =
500(1.2) = 600 ~_ 2.985
Vml  201 100 201 201
 
 19  1.2
Answer after rounding off = 2.98
Answer after truncation = 2.98
H /Pd BaSO dil.KMnO

12. 
2 4
 'X' 
4
 'Y'
273 K
Number of hydroxyl group in compound 'Y' is :

;kSfxd 'Y' esa dqy fdrus gkbMªkfDly lewg mifLFkr gSA
Ans. (06)
H /Pd BaSO
Sol. 
2 4

H H
dil.KMnO

4
 HO OH
273 K
HO OH
OH OH
13. In following reaction the value of K is 5 × 10–4 S–1.


2N2O5  2N2O4 + O2
Initial pressure was 1 atm, while the final pressure was 1.45 atm at time y × 103 sec calculate 'y'.
fuEu vfHkfØ;k esa K dk eku 5 × 10–4 S–1 gS]


2N2O5  2N2O4 + O2
izkjfEHkd nkc 1 atm Fkk] tcfd le; y × 103 sec ij vfUre nkc 1.45 atm ik;k x;k rc 'y' dh x.kuk djks&
Ans. (2.30)
Sol. From unit of K reaction is first order
K dh bdkbZ ls vfHkfØ;k izFke dksfV dh gS


2N2O5  2N2O4 + O2

t=0 1atm 0 0
P
t=t (1–P) P
2
t=  0 1 atm 0.5 atm
P0 = 1 atm, Pt = 1.45 atm P = 1.5 atm
1  P  P0 
t= ln 
2 K  P  Pt 
2.303  1.5 – 1 
t= 4
log  
2  5  10  1.5 – 1.45 
t = 2.303 × 103 = y × 103

so y = 2.303
Answer after rounding off & truncation = 2.30.
14. Number of N–Mn–Cl bonds [N–Mn bonds is cis to Mn–Cl bond] in cis [Mn(en)2Cl2] are …………… .
lei{k&[Mn(en)2Cl2] esa N–Mn–Cl cU/kksa dh la[;k gS& [N–Mn cU/k] Mn–Cl cU/k ds lei{k fLFkfr esa gS]
Ans. (6)
Cl Cl
Cl N Cl
Sol. en Mn Mn
N N
en
N
 This section contains TWO (02) List-Match sets.
 Each List-Match set has TWO (02) Multiple Choice Questions.
 Each List-Match set has two lists : List-I and List-II.
 List-I has Four entries (I),(II), (III) and (IV) List-II has Six entries (P),(Q), (R ), (S), (T) and (U).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies
the condition asked in the Multiple Choice Question.
Full Marks : +3 If ONLY the option corresponding to the correct combination is chosen.

Match The Column :

List 1 List 2
I Radius P   n–1
II Angular momentum Q   n–2
III Kinetic energy R   n–0
IV Potential energy S V  n1
T V  n2
U IV  n3
LrEHk lqesfyr dhft,&

lwph 1 lwph 2
I f=kT;k P   n–1
II dks.kh; laosx Q   n–2
III xfrt ÅtkZ R   n–0
IV fLFkfrt ÅtkZ S V  n1
T V  n2
U IV  n3
15. Which of the following is correct

fuEu esa ls dkSulk lgh gS&
(A) P V (B) P  (C) T  (D) T 
Ans. (C)
16. Which of following is correct

fuEu esa ls dkSulk lgh gS&
(A) S V (B) R  (C) Q  (D) U 
Ans. (C)
 n2 
Sol. rn = 0.529   Å  rn  n2
 Z 
 
dks.kh; laosx () =      n1

nh
Angular momentum
 2 
2
1 1  Z
K.E. = mv 2 = m 2.18  106 
2 2  n
Z2
 K.E.  K.E.  n–2
2
n
Z2
P.E. = – 2K.E.  P.E.    
n2
 P.E.  n–2

Answer the Question No. 17 & 18 on the basis of information given in Column-I & Column-II.
Match the reactant in column-I with the possible intermediates and products of column-II.
LrEHk-I rFkk LrEHk-II esa nh x;h lwpukvksa ds vkèkkj ij iz-la- 17 rFkk 18 ds mÙkj crkb;sA LrEH-I esa fn;s x;s
vfHkdkjdks dks LrEHk-II esa fn;s x;s mRikn ,oa laHkkfor eè;orhZ ds lkFk lqesfyr dhft,A
Column-I (LrEHk-I) Column-II (LrEHk-II)
(i) DIBALH O
CN (ii) dil.HCl
(P)    (I)
O (iii) NaBH4
(iv) Conc.H2 SO4 COOH
O
(i) O 3 OH
(ii) Zn / H O
(Q)   2 (II)
COOH (iii) NaBH4 OH
(iv) Conc.H2 SO4
(i ) KCN
Cl (ii) H O / 
(R)  2  (III)
(iii) LiAIH4 O
CO2CH3 (iv) Conc.H2 SO4
CO2Me OH
(i) LiAlH4
(S) 
 (IV)
CO2Me (ii) Conc.H2 SO4
COOH
COOH
(V )
COOH
(VI)
O
17. Which of the following is correct?

fuEu esa ls dkSulk lgh gS\
(A) P-II, III; S- II, III (B) P-II, IV; S- II, III
(C) P-III, VI; S- II, III (D) P-II, III; S- IV, V
Ans. (A)
18. Which of the following is correct?

fuEu esa ls dkSulk lgh gS\
(A) Q-I, IV, VI; R- II, III, V (B) Q-I, III, VI; R- II, IV, V
(C) Q-I, II, VI; R- II, III, VI (D) Q-I, IV, V; R- III, I, V
Ans. (A)

CN (i) DIBALH CHO dil..HCl CHO 

NaBH4
Sol. (I)     
O O
CHO
O O
OH
Conc.H SO

2

4

OH O
O CHO NaBH CH2OH

(II) 
3
 
4

Zn / H2 O
COOH COOH COOH
Conc.H SO

2

4

O
Cl KCN CN H O COOH LiAlH

(III)  3 
 
4

CO2CH3 CO2CH3 COOH
OH
Conc.H SO

2

4

OH O
CO2Me OH
LiAlH Conc.H SO
(IV) 
4
 
2

4

CO2Me OH O


JEE Advanced 2019 Paper-2 Chemistry

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Memory Based Questions & Solutions

PAPER-2 : INSTRUCTIONS TO CANDIDATES

SECTION 1 (Maximum Marks : 32)

 This section contains EIGHT (08) questions.

SECTION 2 (Maximum Marks : 18)

Full Marks : +3 If ONLY the correct numerical value is entered.

Zero Marks : 0 In all other cases.

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 This section contains TWO (02) List-Match sets.

 Each List-Match set has TWO (02) Multiple Choice Questions.

 Each List-Match set has two lists : List-I and List-II.

Negative Marks : –1 In all other cases.

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SECTION 1 (Maximum Marks : 32)

 This section contains EIGHT (08) questions.

1. With reference to aqua regia, choose the correct option(s) :

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(D) CH3 NaOH,CaO,

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4. Which of the following is / are Correct

(1) HgSO / dil.H SO (1) SOCl / Py ZnHg/HCl

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HgSO / dil.H SO AgNO / NH OH

OMe OMe OMe

6. Consider the following reaction (unbalanced)

Zn + conc. NaOH  Na 2 ZnO2 + H2

ZnSO4 + H2S + NH3(aq)  ZnS  + (NH4 )2 SO4 + H2O

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7. In the Mac. Arthur process of extraction

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SECTION 2 (Maximum Marks : 18)

Full Marks : +3 If ONLY the correct numerical value is entered.

Zero Marks : 0 In all other cases.

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H /Pd BaSO dil.KMnO

Number of hydroxyl group in compound 'Y' is :

13. In following reaction the value of K is 5 × 10–4 S–1.

fuEu vfHkfØ;k esa K dk eku 5 × 10–4 S–1 gS]

K dh bdkbZ ls vfHkfØ;k izFke dksfV dh gS

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P0 = 1 atm, Pt = 1.45 atm P = 1.5 atm

t = 2.303 × 103 = y × 103

SECTION 3 (Maximum Marks : 12)

 This section contains TWO (02) List-Match sets.

 Each List-Match set has TWO (02) Multiple Choice Questions.

 Each List-Match set has two lists : List-I and List-II.

Negative Marks : –1 In all other cases.

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Match The Column :

LrEHk lqesfyr dhft,&

15. Which of the following is correct

16. Which of following is correct

dks.kh; laosx () =      n1

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17. Which of the following is correct?

18. Which of the following is correct?

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CN (i) DIBALH CHO dil..HCl CHO 

O CHO NaBH CH2OH

Cl KCN CN H O COOH LiAlH

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