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and Optimization
N. LIEBERMAN, Vacuum Improvement
Consulting Engineering, Metairie, Louisiana; and
R. CARDOSO, Phillips 66, Westlake, Louisiana
The first-stage ejectors are close-coupled to the vacuum Steam Steam Steam point
tower and work in parallel. They are directly connected to the J = 10, 11, 12
tower discharging to the three respective first-stage condensers. “C train”
E = 10, 11, 12
Each first-stage ejector/condenser was designed for one third
of the total design load. There are three trains, each compris-
ing second, third and fourth stages. The vapors from the three To seal drum
first-stage condensers combine in a common header before go-
FIG. 1. Vacuum tower overhead system.
ing to the second-stage ejectors (one in each train). Condensed
Hydrocarbon Processing | FEBRUARY 201659
Process Engineering and Optimization
these were not in a 4:1 ratio (even accounting for the CO2 for- sequently generated in the ejector suction chamber pulls the
mation). The samples were taken in stainless steel cylinders, process load and the resulting mixture, still at supersonic veloc-
which could cause the hydrogen sulfide (H2S) to mask the ity, enters the diffuser. In its converging section, velocity is con-
presence of O2 in the offgas, as shown in Eq. 1: verted to pressure as the cross-sectional area decreases. Past the
throat, as vapor flows from sonic to subsonic, pressure is hugely
H2S + O2 → H2O + S0(s) (1)
increased and velocity drops to a subsonic level.1 This transition
Whenever exposure to H2S can take place (e.g., while per- from critical flow to subcritical flow is called the “sonic boost.”
forming a pressure survey or collecting samples), appropriate The ejector is designed to work in this critical mode of opera-
personal protection equipment is required. tion. In the diffuser-diverging section, velocity continues to be
The operator collected new offgas samples, using a plastic converted into pressure as the cross-sectional area increases,
syringe. Gas chromatography analyses did not indicate any even if the sonic boost is lost. This is called “velocity boost.”
considerable air leakage that could contribute to the high off- The steam nozzle throat is an orifice designed for critical
gas flowrate. Most of the detected N2 was calculated to come flow; therefore, steam pressure and temperature define the
from instrument purges. flowrate through the nozzle. The throat is designed to pass a
A common source of seal drum offgas is residual propane specific steam mass flow. Wet steam can limit the required steam
and butane, either from crude leaking into a vacuum tower flow through the nozzle, and accelerated droplets can erode the
pumparound stream, or from poor stripping of vacuum tower nozzle and/or the diffuser, leading to poor performance.
feed. However, the amount of olefins in the seal drum offgas The manufacturer will provide the performance curve that
indicated that the vapor load to the ejectors was almost exclu- indicates ejector inlet pressure as a function of ejector suction
sively due to thermal cracking (high furnace coil temperature gas mass load (as water equivalent in lb/hr). The same curve
and residence time in the bottom of the tower). also indicates the design motive steam conditions (temperature
While collecting the samples, another important fact was and pressure), cooling water supply temperature and the ejec-
noticed. Four feet of stainless steel tubing was used to connect tor’s maximum discharge pressure (MDP).
the syringe to the process pipe (FIG. 1 indicates sample point lo- Ejector suction pressure will follow the operating curve
cation). Between samples, offgas cooled in the stagnant tubing. (i.e., if gas load increases, then so does the suction pressure),
When the second sample was collected, steam condensate was and it should be, but is not always, independent of discharge
drawn into the syringe, which indicated that part of the high off- pressure until the MDP is reached. The ejector cannot oper-
gas rate was due to problems with the fourth-stage condensers ate properly above its MDP. The ejector will typically make a
not being able to efficiently condense ejector motive steam. surging sound. The ejector manufacturers term this improper
operation “being forced out of critical flow.” The steam and gas
The steam ejector, demystified. An ejector is really a com- flowing through the ejector is no longer dropping from sonic
pressor. It converts the enthalpy of motive steam to supersonic to subsonic velocity in the appropriate portion of the ejector’s
velocity through an adiabatic expansion. The low pressure con- diffuser. The compression ratio of the ejector will drop (for ex-
ample, from six-to-one to two-to-one). Performance will break,
TABLE 1. Gas chromatography analyses of offgas samples and the ejector suction pressure will increase sharply and may
Stainless steel Plastic syringe
be unstable. In general, all upstream ejector stages will subse-
Components cylinder analysis, %mol analysis, %mol quently break performance.
Methane 21 28.6
The system in this study was designed for cooling water at
88°F and process gas outlet at 96°F (8°F approach). These con-
Ethane/ethylene 9.5/1.3 14.8/1.8 ditions allow for a low design maximum discharge pressure of
Propane/propylene 6.7/2.9 10.5/4.5 67 mm Hg. However, as the bundle fouls and/or cooling wa-
Butanes/butenes 0.5/2.5 5.5/4.1 ter flowrate drops, the approach increases, and this results in a
much higher process gas outlet temperature of 108°F to 113°F.
Pentanes and heavier 3.3 2.9
When that happens, the vapor pressure of water becomes a ma-
N2 13.7 2.2 jor contributor to the operating pressure of the system, which
O2 1.3 0.5 will eventually lead to jet breakage in the first stage, as it exceeds
H 2S 31.5 21.3 its MDP of 67 mm Hg.
TABLE 2 shows the relationship between process gas out-
H2, CO and CO2 5.8 3.3
let temperature and the pressure contribution of water alone.
Note that, as the temperature increases, the margin to the MDP
TABLE 2. Outlet temperature vs. water saturation temperature shrinks, and any additional process load will throw the ejec-
Gas outlet temperature, °F Water partial pressure, mm Hg1 tors out of their stable operation curve. Typically, 5 mm Hg to
8 mm Hg is added to the condenser gas outlet pressure to es-
96 (design) 43.5
timate the ejector discharge pressure, which accounts for the
101 50.6 pressure drop across the tube bundle. This explains why the
106 58.7 condensers, even when in reasonable condition, would cause the
111 67.92 vacuum to break during the hot months of the year.
1
From steam table
The previously mentioned MDP is low for an ejector on the
2
Higher than MDP US Gulf Coast (USGC), where the temperature of cooling water
60FEBRUARY 2016 | HydrocarbonProcessing.com
Process Engineering and Optimization
in the summer can exceed 90°F. Performance break is, therefore, plugged. A new bundle was installed, and the system then per-
not an exception, but is almost unavoidable during hot, humid formed far better.
days at a USGC refinery.
Details for vacuum system condensers. Proprietary de-
Ejectors and condensers are interactive. When evaluating signs attempt to minimize shell-side pressure drop, eliminate
a vacuum system, condensers and ejectors are highly interdepen- the potential for tubes blanketing by noncondensable gases,
dent and should be analyzed altogether to pinpoint the source achieve proper separation from condensate and offgases, and
of the malfunction. Ejector surging can be caused by excessive provide extra cooling for noncondensable load to the next stage.
discharge pressure—for example, by deteriorated performance An interesting feature present in some condenser designs is
of a downstream condenser, or by an extra-system noncondens- the air baffle. The air or vapor baffle extends along the length
able load. Therefore, it is important to keep in mind some of the of the shell and fits snugly against it. Leaf seals (FIG. 3 in red)
most common factors that can impact condenser performance: are used to prevent leakage around the air baffle. That way, the
• Cooling water supply temperature and flowrate upstream ejector discharge stream goes through the bundle be-
• Noncondensable load
• Condensable load 35 1,000
• Fouling Fourth-stage discharge pressure Fourth-stage C-train
Offgas flowrate out of service
• Drain leg (insufficient height or plugged). 850
The progressive loss of vacuum system overhead capac- 30
ity largely appears to be a function of fouling, especially in the
700
first-stage condenser. Measured shell side ∆P was 6 mm Hg to
fore leaving the condenser vapor outlet nozzle. Without the air The barometric leg (drain from condenser to seal drum) is
baffle, the inlet stream would short-cut the condenser, going another common problem. Height must be sufficient to avoid
directly to the condenser vapor outlet nozzle and overloading flooding by taking into consideration the differential pressure
the downstream ejector. between the seal drum, the condenser and the liquid to be
The air baffle is located directly above the gas outlet nozzle drained (density and tendency to foam). The design requires a
(FIG. 3 and FIG. 4). A temperature survey of the entire length of minimum change in direction and absolutely no horizontal runs
the shell side directly below the air baffle location revealed that (which creates “air pockets”).
at least five out of 12 condensers had problems related to the The pipe configuration may have several 45° elbows due to
mechanical integrity of the leaf seals. Seal problems can be gen- plant layout and/or available space. These elbows increase the
erated by poor installation of the bundle into the shell (bend- risk of deposits, such as salts from amines injected to neutral-
ing the air baffle), corrosion due to wrong metallurgy of the ize hydrogen chloride, wax formation and corrosion product
air baffle, leaf seals being too narrow, and not providing proper accumulation. Sludge that accumulates in the seal drum due to
sealing against the exchanger shell.2 biological corrosion is also a common source of poor seal leg
The leak around the air baffle increases the load to be han- drainage. Good engineering practice is to construct the entire
dled by the downstream ejector, and it can eventually compro- seal leg out of 316 SS and not carbon steel (CS). It is also a good
mise the performance of the entire vacuum system: practice to tape up all flanges.
• Hot gas leakage can occur, indirectly increasing the The A-train second-stage condenser (E-4 in FIG. 1) was found
saturated condensable loading to be operating partially flooded on its shell side. FIG. 5 presents
• The overall higher gas rate exiting the condenser may an infrared scan of the condenser shell side showing that con-
be higher than the downstream ejector capacity at the densate level was approximately 50%. The resulting reduction
condenser original design pressure in the tube area available to condense the discharge of the up-
• Condenser pressure will increase, and this can be higher stream ejector increased the gas load to the downstream ejector.
than the MDP of the upstream ejector. The additional load was, especially during summer, above the
For the case described here, although the leak by itself was handling capacity, and the condenser pressure increased. The
not responsible for performance issues, it was a contributing resulting pressure would exceed the upstream ejector maximum
factor. Observing the leaf seal deficiency helps to develop the discharge pressure, and the ejector would “break performance.”
scope for the next outage. The leaf seal should be a flexible Forced out of critical flow, the second-stage ejector subsequent-
grade of 316 stainless steel (SS)—never brass or bronze. ly cascaded the effect back to the first-stage system.
A partially plugged barometric leg could be the source of the
problem. To test this hypothesis, a hose was connected to the
2-in. block valve (with a blind flange), as shown in FIG. 6, to help
drain the condenser to the seal drum.
Water was used to fill the hose and push air pockets in the
hose all the way to the condenser. After the line was filled with
water, the condenser started draining. Flooding disappeared
and first-stage ejectors stopped surging.
Another common cause of poor seal leg drainage and con-
densate backup are holes in the seal leg. Air draw through such
holes slows the drainage of water and oil from the condenser.
FIG. 4. Temperature readings indicating leak around air baffle. Leaks on the seal legs are indicated by cool spots on the legs
themselves. Air entering the vacuum inside the legs expands
and cools. In the US state of Louisiana, the humid air will con-
dense and visibly drip off the seal legs, indicating the exact lo-
cation of a leak. If a leak is inside the seal drum, then raising
the seal drum level will result in the restoration of drainage and
improved condenser performance.
The same steam header serves all 12 ejectors (FIG. 1), and the The first-stage condensers (E-1, E-2 and E-3) were designed
steam header conditions are controlled with a pressure-reduc- for 10,000 gpm of cooling water. This cooling water cascades
ing valve and a temperature controller to inject steam conden- to the next stages, as depicted in FIG. 7. As fouling and scaling
sate and control the superheat degree. take place, the first-stage ejector will be the first to be impacted.
Knowing that some condensers were fouled and that cooling As the cooling water flowrate drops, condenser process outlet
water flowrate was below the design flowrate, the pressure con- temperature will increase. Due to the low maximum design dis-
troller setpoint was stepped down from the design value and the charge pressure, jet performance may break.
system was observed. Reducing steam flow to the ejectors un- In an attempt to recover performance in the first-stage ejector,
loads the cooling requirements of the condensers. Steam pres- the cooling water bypass valve would be partially opened (FIG. 7).
sure was reduced by 3% stepwise. Steam pressure was optimized Opening the bypass valve restored cooling water rates to the
at 6% lower than the design pressure. No major improvement in first-stage condenser, but starved the subsequent stages. Low
operating conditions was observed, but unloading the condens- cooling water velocities in the tube side further promoted scaling
ers also led to approximately 3,500 lb/hr in steam savings. and tube plugging, as observed in the fourth-stage condensers.
Motive steam supply lines for the system were not properly Design cooling water rates for first-stage condensers could be
insulated, which led to condensate formation upstream of the achieved by using the cooling water bypass valve, but, even at
ejector nozzles. Steam condensate not only reduces ejector that rate, performance of the first stage would not be restored.
compression capacity, but it can also cause erosion of the steam Cold-side “temperature approach” (process vapor outlet minus
nozzle and diffuser throat, which ultimately will cause the ejec- cooling water inlet temperatures) would be an excessive 20°F.
tor to not perform as expected. Steam headers should be insu- This was a clear indication that the condensers were severely im-
lated all the way to the ejector. pacted by poor heat transfer coefficients due to the fouling layer.
As suggested in the literature,3 regardless of what tempera- To slow the rate of fouling in the condensers, N2 should be
ture and pressure readings indicate in a steam header, it is always blown through the tubes twice per week, and the condensers
advisable to check steam quality as closely as possible to each should be back-flushed once per week.
ejector. By opening a bleeder valve and observing the jet, the
following can indicate steam quality:
• Superheated steam—jet is invisible for some distance
beyond the bleed
• Steam close to saturation or with slugs of water—jet
becomes visible a short distance beyond the bleed, and
periodic puffs of white are visible.
When connections are available, a test can be executed to de-
termine if the nozzle is damaged. It is recommended to install a
pressure gauge on the inlet to the downstream condenser, on the
inlet of motive steam, and on the ejector inlet nozzle. The steam
valve can then be closed, reducing the pressure to approximately
70% of design. If the pressure in the inlet of the ejector decreases,
then the motive steam nozzle will need replacement. However, if
the pressure downstream of the ejector decreases, then it means
that the condenser was unloaded, indicating a fouled condenser.
As mentioned previously, the steam nozzle throat is an ori-
FIG. 6. Valve used to install a drain hose parallel to the partially
fice designed for critical flow. Observing the reduction in steam plugged barometric leg.
usage when removing the ejector from service gives an excellent
indication as to whether the ejector is consuming more or less
than the design amount.
The total motive steam consumption for the entire vacuum E = 4, 5, 6
E = 1, 2, 3
system (12 ejectors) was approximately 10% above the design “A train”
Cooling water
value, an indication that threads on the nozzle or the extension Cooling water bypass valve
in the steam chest may be damaged and/or the nozzle itself has
Cooling water return header
supply
eroded due to wet steam. Problems with the nozzle threaded
connection can cause a considerable amount of steam to leak
and bypass the nozzle. This leaking steam does not provide any E = 7, 8, 9
“B train”
compression work and, indeed, it will add to the ejector suction First stage
load, deteriorating the system performance. Second stage
Third stage
Fourth stage
Cooling water system fouling. The cooling water supplied E = 10, 11, 12
“C train”
to the surface condensers comes at the end of the plantwide
distribution header, where minimum differential pressure exists
(low supply and high return pressures) impacting the cooling
FIG. 7. Schematic of the cooling water sides of the surface condensers.
water flows. Thus, fouling deposits are likely.
Hydrocarbon Processing | FEBRUARY 201663
Process Engineering and Optimization
64FEBRUARY 2016 | HydrocarbonProcessing.com