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(Course Notes)
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General
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We will study mine waste management in the following sequence:
• Reclamation
Reference texts:
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Mine Waste Streams
General
It is necessary to understand:
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⇒ Effects of water-deficiency, and the unsaturated land
surface condition can be used to advantage with careful
design and operating practices
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• Mines exist to make a profit, not to manage wastes:
Issues
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2. Volumes of waste streams:
⇒ Van Zyl et al. (2002) reported that the world’s iron, copper,
gold, lead and bauxite (aluminum) mines together
generated 35 thousand million tons of waste in 1995
alone.
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Figure 1.2 Typical Waste Balance for an Interior British Columbia Copper
Mine Relative to 1 Tonne of Copper Concentrate
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Figure 1.3 Typical Waste Balance for an Integrated Oil Sands Mining,
Extraction, and Upgrading Operation Relative to 1 m3 of Synthetic
Crude Oil
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Figure 1.4 Typical Waste Balance for a Western Canadian Rocky Mountain
Coking Coal Mine Relative to 1 Tonne of Clean Coal Product
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4. Storage:
5. Emissions:
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6. Reclamation:
• Coarse waste
⇒ How to reclaim to a productive or natural state
• Wet streams
⇒ How long until it can support weight of people and animals
on the surface of a tailings pond
7. Waste Utilization:
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Figure 4. A ware-house built into the slope of an abandoned gold tailing storage
( From reference [2] page 6)
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Figure 5. Dump of waste sand being re-mined to extract residual gold. (From
reference [2] page 4)
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Issues
1. Geometry:
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2. Stability:
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3. Drainage:
4. Contamination:
• Acid generation
5. Economics:
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• The relief
• Cost and type of mine waste haulage from source to dump site.
• Reclamation issues
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Table 2: Storage capacity and haulage distance of waste rock from the
source to the four disposal sites considered (Osanloo and Ataei, 2003)
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1. Valley in fill:
• Basic view by industry that thicker the placement lift the better:
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3. In pit disposal:
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Figure 3: Experimental setup from Wickland & Wilson (2005); column apparatus
and waste rock-tailings mixtures shown.
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Figure 4: Grain size distribution of 5:1 waste rock- tailings mixture (left) and
waste rock alone (right) and source materials (bottom) from Wickland & Wilson
(2005) experimentations.
Figure 5: Soil water characteristic curve of a 5:1 waste rock-tailings mixture and
CIP tailings from Wickland & Wilson (2005) tests.
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• e = Vv / Vs
• e r = (V a + V w + V t ) / V r
• e t = (V a + V w ) / V t
where: Vv, Vs, Va, Vw, Vt, and Vr are the volumes of voids,
solids, air, water, tailings solids, and rock solids
respectively as illustrated in figure:
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• e t = e + e r (ρ t / ρ r )
• e r = e + (ρ t / ρ r ) (1/R) (e+1)
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Figure 10: Typical cyclic response of paste rock (Wijewickreme et al. (2010)
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Figure 11: Cyclic resistance ratio of paste rock, waste rock only and tailings only
(Wijewickreme et al. (2010)
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4. Over-steepened crests:
⇒ The large particles roll down the hill, and the smaller
material stays at the top;
5. Foundation failure:
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6. Flow failure:
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• Evidence:
Flow failures usually occur after heavy rainfall events;
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Table 7: Relative effect of the increase in density on cohesion and friction angle
of waste rock dump material in Goa (Yellishetty and Darlington, 2010)
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Figure 12: Influence of the rise in pore water pressure on the computed factor of
safety as a result of monsoonal rainfall (Yellishetty and Darlington, 2010).
References:
Osanloo M. and Ataei (2003), “Factors affecting the selection of site for
arrangement of pit rock dumps”, Journal of Mining Science Vol 39 No2
pp49-54, April 2003.
Wickland B.E., Wilson G.W., Wijewickreme D., and Klein B. (2006) “Design
and evaluation of mixtures of mine waste rock and tailings”, Canadian
Geotechnical Journal, Vol. 43 Issue 9, p928-945, September 2006.
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(http://www.springerlink.com.login.ezproxy.library.ualberta.ca/content/b31q62767
n244162/)
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• Principles of failure:
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Sasitharan, S., Robertson, P.K., Sego, D.C., and Morgenstern, N.R. 1993.
Collapse behavior of sand. Canadian Geotechnical Journal, 30:
569 – 577.
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• Sand layers:
1) Affect free downward and lateral drainage during infiltration
into dump.
2) Affects the collapsible material by allowing it to maintain the
pore pressures that allow it to collapse.
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Bishop, A.W. 1973. The stability of tips and spoil heaps. Quaternary
Journal of Engineering Geology, 6: 335 – 376.
Blight, G.E. and Fourie, A.B. 2005. Catastrophe revisited – disastrous flow
failures of mine and municipal solid waste. Geotechnical and
Geological Engineering, 23: 219 – 248.
• October 21, 1966, a coal waste dump flowed downhill into the
village of Aberfan, Wales, killing 116 school children, age 7 –
10, and 28 adults.
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Morning of failure:
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Bulking effects:
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Bishop, A.W. 1973. The stability of tips and spoil heaps. Quaternary
Journal of Engineering Geology, 6: 335 – 376.
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Blight, G.E. 2008. Slope failures in municipal solid waste dumps and
landfills: a review. Waste Management & Research, 26: 448 – 463.
Blight, G.E and Fourie, A.B. 2005. Catastrophe revisited – disastrous flow
failures of mine and municipal solid waste. Geotechnical and
Geological Engineering, 23: 219 – 248.
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2) Undrained Loading
• Rapid construction – pore pressures develop during cyclic
straining and do not dissipate.
• Evaluation to determine if this can occur – Robertson and
Wride, 1998, Robertson, 2010.
Robertson, P.K and Wride, C.E. 1998. Evaluating cyclic liquefaction
potential using the cone penetration test. Canadian Geotechnical
Journal, 35: 442 – 459.
3) Drained Loading
• Slow trigger caused by slow foundation movements which
may cause material to strain
• Anisotropically loaded material passes peak resistance or
pore pressure increases slowly (water table rise), which
initiates collapse. Eckersley (1990)
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Reclamation criteria:
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We'll restrict the discussion here to waste dumps, and discuss the issue
again when we talk about tailings.
For waste dumps that have not been subject to ore processing there is the
potential for generation of acid by reaction of sulfide minerals contained in
waste rock with oxygen and water. This is referred to as acid rock
drainage (ARD).
Note: The term Acid Mine Drainage (AMD) was used in the past, but ARD
is the accepted terminology today since the phenomena does not occur
strictly in mines.
• This can occur naturally (eg. Rio Tinto, Sulpher Creek) or humans
can accelerate the weathering process through earth moving
operations (eg. mining, road cuts)
The Reaction
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Figure 2-11: Schematic Illustration of Factors that Affect Sulphide Oxidation and Modify
Mine Drainage during Transport
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oxidant. Note the resulting release of acidity (H+) and ferrous iron
(Fe2+).
Reaction (2) can remove some of the ferrous iron under slightly acidic
to alkaline conditions, producing relatively insoluble iron hydroxide
(Fe(OH) 3 ) but also releases much more acidity.
Reaction (3) occurs once the pH drops below 4.5 (more acidic). The
reaction consumes some acidity but oxidizes the ferrous iron into
ferric iron (Fe3+). Once the pH is 3.5 and lower, the bacteria
dominate the system. Also note, the bacteria that catalyze this
reaction require a nominal amount of oxygen. The presence of iron
oxidizing bacteria can speed up this reaction by 5-6 orders of
magnitude.
In Reaction (4), the ferric iron directly oxidizes pyrite, and occurs
under sufficiently acidic conditions (i.e. where dissolved ferric iron is
present – see Reaction 3). This reaction generates substantially
more acidity and the cycle continues.
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Figure 2-9: Schematic Illustration of Normalized Sulphide Oxidation Rates with and
without Bacterial Mediation (after Robertson and Broughton, 1992)
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Neutralizing Reactions
Other reactions can occur that consume acid and release alkalinity. Most
carbonate minerals are capable of dissolving rapidly, making them effective
acid consumers. An example of this reaction is below:
Characterization
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• What are the sources of ARD? How much ARD will be generated and
when?
• What are the significant pathways that transport contaminants to the
receiving environment?
• What are the anticipated environmental impacts of ARD release to
the environment?
• What can be done to prevent or mitigate/manage ARD?
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The most important sources are mine waste, ore, process waste, and the
disturbances from the extraction and processing operations. Water is the
primary environmental pathway for constituents released from these
sources. Thus, aquatic resources are usually the receptor of most interest.
See Figure 4-4 taken from the GARD Guide, below.
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Sources and Pathways for various mining operations are shown in Figure
4-6 to 4-9, below. (extracted from GARD Guide, Chapter 4)
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Figure 4-6: Sources and Pathways of ARD in a Pit during Operation and Closure
Figure 4-7: Sources and Pathways of ARD in Underground Workings during Operation
and Closure
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Figure 4-9: Sources and Pathways of ARD in a Subaqueous Tailings Storage Facility
(excerpt from GARD Guide, Chapter 4)
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Refer to Chapter 4 of the GARD Guide for detailed information on each site
characterization component.
Some general factors affecting mine waste ARD potential and rate:
• Percentage of sulphur and iron present in the mine waste
• Surface area (i.e. rock blocks vs. crushed rock vs. tailings)
• Overall mixture
High sulfide content rock (i.e. sulphide bearing minerals) are associated
with ore bodies containing base and precious metals (ex. copper, lead,
zinc, gold and silver)
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• Skarn deposits.
There is also a problem with some eastern North American coal deposits
that contain pyrite.
Important data relevant to the prediction of ARD can be gathered during the
core logging process:
For example: if the rock has 2% sulpher content, you will need
62.5 kg of carbonate per tonne of rock to neutralize the acid.
Figure 5-8: ARD Rock Type Classification Plot Based on ABA and NAG Test
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b) Column Tests
- No standards available for column testing
- Can simulate different degrees of saturation, including flooded and
oxygen-deficient conditions.
- Typically larger scale than humidity cell tests.
- In theory, column tests provide information on combined
weathering rates of primary and secondary minerals.
- May be more suited to evaluation of mitigation measures such as
covers and amended waste sites.
An example plot of kinetic testing results from the GARD Guide Chapter 5
is shown below. Note the relatively stable response for 2 years, and then a
sharp decline in pH (acid generation) and rapid increase of metals in
solution over a matter of weeks.
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3. Field Methods
• Range from rapid very small-scale tests to monitoring of full-
size mines for extended periods of time.
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b) Wall Washing
- Evaluation of runoff quality from an isolated section of in-situ
rock face after the application of a controlled amount of
irrigation.
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Prevention:
• Prevention is a proactive strategy
Mitigation:
• Mitigation is a reactive strategy.
Figure 6-2: Waste Rock Pile Structure and Processes (GARD Guide, Chapter 6)
- Must consider water and energy budgets coupled with the terrain,
landforms, surface topography, soils, stratigraphy and geology,
surface hydrology, hydrogeology, and flora.
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Figure 6-4 from the GARD Guide, Chapter 6 presents a schematic of the
methods and practice alternatives for the prevention and mitigation of ARD
through the lifecycle of a mine.
• Segregation:
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• Tailings Desulpherization:
• Blending:
• Co-Disposal:
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• Covers
- Refer to next chapter.
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In Summary
They involve:
• Preventing moisture or O 2 from coming into contact with the
sulfide rich minerals,
The first step is to determine where the sulfide rich rock is prone to ARD
and to test for ARD production
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(this solution can be affected by the acid generation kinetics…if the acid
is released slowly and the carbonates dissolve quickly, in the long-term
acid generation may result if the buffering capacity is too low)
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References
Price, W.A., and Kwong, Y.T.I., 1997. Guidelines for the prediction of acid rock drainage
and metal leaching for mines in British Columbia: Part III Waste Rock Weathering,
Sampling and Analysis, Some Lessons from the Provincial Database. In Proceedings of
the Fourth International Conference on Acid Rock Drainage, Vancouver, B.C. Canada,
May 31 – June 4, 1997, p. 31-45.
Price, W.A., Morin, K., and Hutt, N., 1997. Guidelines for the prediction of acid rock
drainage and metal leaching for mines in British Columbia: Part II. Recommended
procedures for static and kinetic testing. In Proceedings of the Fourth International
Conference on Acid Rock Drainage, Vancouver, B.C. Canada, May 31 – June 6, 1997.
p. 15-30.
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Covers
(refr: www.gardguide.com)
For selection and design of covers need to first determine the appropriate
level of control required (ie: how much oxygen ingress and/or net
percolation)
• Water balance:
• precipitation/infiltration
• Run-off
• evaporation
• evapotranspiration
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Figure 6.8: Covers and Climate Types (modified from Holdridge et al.,
1971 by Wickland and Wilson)
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Dry Covers
(refr: Section 6.6.7 Gard Guide)
• Typically earth, organic, or synthetic materials placed over mine
wastes
• Must interact with:
o Climate
o Hydrology
o Human activity
o Vegetation
o Animals
o Settlement of underlying
material
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• Store & Release covers are used in dry arid climates where:
1. Soil Covers
Soil covers generally involve granular materials placed over mine waste
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Performance of soil cover will differ for flat and sloping surfaces – The
ability of the soil cover to function as oxygen ingress and water
infilitration control will be different. The difference in performance
relates to:
o Site climate conditions,
o The slope length and angle
o The hydraulic properties of the cover materials
Note: Slopes must be stable for vegetation and erosion (typ < 1V:2H,
26°)
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Multi-Layer Systems
• multi layer soil covers for ARD control became popular in the 1990s
with the development of the science of unsaturated media that
enabled the predication of evaporation from soil cover systems
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Typical multi-layer dry soil covers may consist of the following components:
Surface Layer (Growth Medium)
• Prevents erosion
• Assists with revegetation
Protective layer
• Filter of either geotextile or sand
Biobarrier
• To prevent burrowing of animals
Bedding
• Possibly to prevent damage to drainage layer by
biobarrier
Drainage Layer
• Removes seepage
Seepage barrier
• Typical GCL
Infiltration barrier
• between seepage barrier and waste
• may contain capillary break (see below)
The topsoil thickness may be designed so all infiltration is held in this layer
and is evaporated or evapotranspired (by plants) hence no moisture will
reach underlying waste, mitigating ARD.
In wet climates the intent may be to have the cover capable of maintaining
a barrier to O 2 (i.e. saturated fine sand) at the base of the fine sand layer
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If the water balance is such that the fine sand remains saturated, ingress of
O 2 will be limited to diffusive transport, which will not be enough for ARD to
result.
Note: the smaller the diameter of capillary tube, the high the water will rise
(more capillary action)
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• When water table is lowered a meniscus will form in the pore space
between grains
• As the water table is further lowered the meniscus in the largest pore
will collapse first (it drains the fastest). The suction pressure that this
occurs at is termed the Air Entry Value (AEV)
• A soil water characteristic curve plots suction versus volumetric water
content (porosity) essentially a measurement of soils ability to
retain water under negative water pressures (suction)
• Once the AEV has been reached the curve decreases as smaller
pores progressively drain
o The slope of the line is a function of the grain size distribution
(well graded vs. poorly graded)
• The hydraulic conductivity of soil decreases once the AEV has been
reached (becomes desaturated)
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• Coarser grained material reach their AEV quickly (drain fast) - upon
which the permeability decreases rapidly
• The residual volumetric water is the water content at which all pores
have drained – only pockets of disconnected pores left
• By choosing a capillary material with a residual volumetric water
content less than the AEV of the fine cover material it will cause the
permeably of the capillary barrier to be much lower than the cover
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but
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Important consideration for use of soil covers are listed in Table 6.4
2. Alkaline Covers
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Want alkaline infiltration to react with sulphide bearing material and create
a surface coating:
• Forms a hardpan (chemical barrier) at contact between the alkaline
material and the mine waste
• Isolates underlying sulphide materials
Important considerations:
1) Climate
2) Availability of alkaline materials
3) Geometry & reactivity of alkaline materials
4) Time of consumption
Goal:
• Have infiltration through the cover transport with sufficient alkalinity to
neutralize the uppermost portion of the underlying waste
• This will in turn:
Increase the effective cover thickness
Slow the oxygen flux to reactive sulphides deeper in the profile
3. Organic Covers
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Limitations:
• Availability of organics materials
• Longevity – may become resistance to decomposition with time
• Climate – humid climates may be required to maintain anaerobic
conditions in the organic medium
Cover is made out of mine wastes that contain sulphides but have an
excess of neutralizing potential will cons ume O2 but not contribute to
ARD generation
5. Synthetic Covers
Synthetics Includse:
• Types of plastics (eg: high density polyethylene, HDPE)
• Polyvinyl chloride (PVC)
• Linear low-density polyethylene (LLDPE)
• Geosynthetic clay liners (GCL)
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Construction:
• Require a suitable bedding material (sand) – to prevent puncturing by
underlying rock
• Synthetic must be carefully covered with an overlying layer before adding
final growth substrate or rock mulch layer
• Slope stability analysis is recommended for multi-layer soil covers place
on steep slopes
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Vegetation
Establishment of vegetation often a criterion for closure
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Water Covers
(refr: Section 6.6.8 Gard Guide)
• Water covers are used in wet humid climates where:
Subaqueous Disposal
Limit the exposure of PAG materials to oxygen
Figure 6.13 shows various configuration for subaqueous tailings
disposal
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Hungarian Bauxite Tailings Dam Failure October 2010 (image taken from:
http://galeria.index.hu/belfold/2010/10/05/legifelvetelek_az_atszakadt_gatrol/?current_image_num=10&im
age_size=l)
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Wetland Covers
Involves placing wetlands over acid generating wastes
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Economics:
Cover systems for tailings and waste rock deposits are often costly
Soil covers cost can range from about $25,000 to $100,000 per
hectare (heavily dependent upon proximity to borrow source)
Application of synthetic and complex multi-layer covers can easily
double this cost – these methods are typically applied at smaller sites
Figure 6.16 is an example of relative costs of a few technologyies for
a particular site
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