CHE 3161: Chemistry & Chemical Thermodynamics Test 3 Date: 09/04/2009 Total Marks: 30 The exam is open book and notes. 1) Consider a liquid for which the molar volume is a function of temperature and pressure, ie, V=V(Z,P), and @ and « are constant. (a) Show that, Inge = ATT) — HPP) @ where, pa i (& dna (& » = 4 (ar), “~V\OP)_ (b) If the liquid undergoes a reversible isothermal expansion from (Vj, Pi) to (V2, P2), use the expression, d3= ort —pVaP (2) and eqn.(1}, to show that the change in the entropy of the liquid, due to the change of state, is given by the expression, as=2y-w @) (10 marks) (0) Since VeV(T)P), We com wnle, ave War a NV By debriben, Be LOL) amd ee bi, T hp As a rumlk, AV. (Bv)AaT - (kv) dP tn o . pat - K AP ; Laeger) ‘ me )_ deo sted V wd 6 * Ort, P) aD (VT, P -0)(D We are gven, AL. & AT ~pv 4P Me umstouk hanpenatare trae, As. -pvdP from eqn, p _ Pek p(t ~ mH] Me towtoud leunpenalive, 7 on, -ev{-L Av \_ podV ds - ev RA) # Tnleyvokes frown V, 1oV,, for conttamk: Band Ke, » L(y-v - As. EB (Y w) ( 2) Propane gas undergoes a change from 105°C and 5 bar (state 1) to 190°C and 25 bar (state 2). Determine the enthalpy change (A/) and the entropy change (AS) for this change of state, using the generalized second-virial-coefficient correlation to find the residual enthalpies (H®) and residual entropies ($%). ‘The ideal heat capacity for propane gas is known to depend on temperature through the relation, Cp a T+CT* eT AtBTHO where, T is in degrees Kelvin. The coefficients A,B and C, and the critical parameters for propane are given in the Table below. (20 marks) A B c 1213 _[ 28.785 x 10-* | —8.824 x 10-* | T.(K)|__ FP. (bar) w 369.8 25 O152Dekeorwinn AK $e AS* Stake A! los*a ) & boar Stake 2! 190°C , 2e bar Calelakionnl ‘Patic Rea ar ft Goes Ct) PD one fe -5% Ss cr ,R,> yD Ldeab Tdeal Woke property Onainge, AH = —H,* + Ane + as i R As. 3% 4ASn8 45, T= 29Rk 1 Pee 2s har, 20152 = T, foo} 2TZAS ®0 A, = Ps 023 269° Pa - S Lone 42S B® . o0e3 — 2422 © 0 324 THe a B34 -ONI> _ _oolT The “ em = ~0°324 + (0152) (0-017) =- 0327