DATOS

LOGK FORMULA K
1 Pb(OH)2 -17.12 Pb2+ = 2H+ + Pb(OH)2 7.5857757503E-18
2 Pb(OH)3- -28.06 Pb2+ = 3H+ + Pb(OH)3- 8.7096358996E-29
3 Pb(OH)4 2- -39.7 Pb2+ = 4H+ + Pb(OH)4 2- 1.995262315E-40
4 PbOH+ -7.71 Pb2+ = H+ + PbOH+ 1.9498445998E-08
5 H2O -14 H+ + OH- = H2O 1E-14
6 Pb(OH)2(s) -8.15 Pb2+ = 2H+ +Pb(OH)2 (s) 7.0794578438E-09

7 CO2(g) 18.149 2H+ + CO3- =CO2(g) 1.409288798E+18

8 H2CO3 16.681 2H+ + CO3 2- = H2CO3 4.797334486E+16
9 HCO3 - 10.329 H+ + CO3 2- = HCO3- 21330449131.466
10 Pb(CO3)2 2- 10.64 Pb2+ + 2CO3 2-=Pb(CO3)2 2- 43651583224.017
11 PbCO3 7.24 Pb2+ + CO3 2- = PbCO3 17378008.287494
12 PbHCO3+ 13.229 Pb2+ + H+ + CO3 2- =PbHCO3+ 16943378004473
13 PbCO3(s) 13.13 Pb2+ + CO3 2- =PbCO3(s) 13489628825917

ECUACIONES

13-7 Pb2+ Pb2+ + CO2(g)+ H2O = 2H+ + PbCO3(s)

13-12 PbHCO3+ PbHCO3+ = PbCO3(s)+ H+
13-11 PbCO3 PbCO3=PbCO3(s)
13-10+7 Pb(CO3)2 2- Pb(CO3)2 2- +2H+ = PbCO3(s) + CO2(g) +H2O
13-2-7 Pb(OH)3- Pb(OH)3- + CO2(g) + H+ = PbCO3(s) + 2H2O
13-3-7 Pb(OH)4 2- Pb(OH)4 2- + 2H+ CO2(g) = PbCO3(s) +4H2O
13-1-7 Pb(OH)2 CO2(g) + Pb(OH)2=PbCO3(s) + H2O
13-4-7 PbOH+ PbOH+ + CO2(g) = PbCO3(s) + H+

pH [H+] [Pb2+] [PbHCO3+] PbCO3 [Pb(CO3)2 2-]

0 1 522360.10961 1.2560299637 1.28824955E-06 2.2961486481E-24
0.5 0.31622777 52236.010961 0.3971915495 1.28824955E-06 2.2961486481E-23
1 0.1 5223.6010961 0.1256029964 1.28824955E-06 2.2961486481E-22
1.5 0.03162278 522.36010961 0.0397191549 1.28824955E-06 2.2961486481E-21
2 0.01 52.236010961 0.0125602996 1.28824955E-06 2.2961486481E-20
2.5 0.00316228 5.2236010961 0.0039719155 1.28824955E-06 2.2961486481E-19
3 0.001 0.5223601096 0.00125603 1.28824955E-06 2.2961486481E-18
3.5 0.00031623 0.052236011 0.0003971915 1.28824955E-06 2.2961486481E-17
4 0.0001 0.0052236011 0.000125603 1.28824955E-06 2.2961486481E-16
4.5 3.1623E-05 0.0005223601 3.9719154947E-05 1.28824955E-06 2.2961486481E-15
5 0.00001 0.000052236 1.2560299637E-05 1.28824955E-06 2.2961486481E-14
5.5 3.1623E-06 5.2236011E-06 3.9719154947E-06 1.28824955E-06 2.2961486481E-13
6 0.000001 5.2236011E-07 0.000001256 1.28824955E-06 2.2961486481E-12
 6.5 3.1623E-07 5.2236011E-08 3.9719154947E-07 1.28824955E-06 2.2961486481E-11
7 0.0000001 5.2236011E-09 1.2560299637E-07 1.28824955E-06 2.2961486481E-10
7.5 3.1623E-08 5.2236011E-10 3.9719154947E-08 1.28824955E-06 2.2961486481E-09
8 0.00000001 5.2236011E-11 1.2560299637E-08 1.28824955E-06 0.000000023
8.5 3.1623E-09 5.2236011E-12 0.000000004 1.28824955E-06 2.2961486481E-07
9 1E-09 5.2236011E-13 1.2560299637E-09 1.28824955E-06 2.2961486481E-06
9.5 3.1623E-10 5.2236011E-14 3.9719154947E-10 1.28824955E-06 2.2961486481E-05
10 1E-10 5.2236011E-15 1.2560299637E-10 1.28824955E-06 0.0002296149
10.5 3.1623E-11 5.2236011E-16 3.9719154947E-11 1.28824955E-06 0.0022961486
11 1E-11 5.2236011E-17 1.2560299637E-11 1.28824955E-06 0.0229614865
11.5 3.1623E-12 5.2236011E-18 3.9719154947E-12 1.28824955E-06 0.2296148648
12 1E-12 5.2236011E-19 1.2560299637E-12 1.28824955E-06 2.2961486481
12.5 3.1623E-13 5.2236011E-20 3.9719154947E-13 1.28824955E-06 22.9614864811
13 1E-13 5.2236011E-21 1.2560299637E-13 1.28824955E-06 229.6148648112
13.5 3.1623E-14 5.2236011E-22 3.9719154947E-14 1.28824955E-06 2296.1486481124
14 1E-14 5.2236011E-23 1.2560299637E-14 1.28824955E-06 22961.486481124
14.5 3.1623E-15 5.2236011E-24 3.9719154947E-15 1.28824955E-06 229614.86481124
15 1E-15 5.2236011E-25 1.2560299637E-15 1.28824955E-06 2296148.6481124
15.5 3.1623E-16 5.2236011E-26 3.9719154947E-16 1.28824955E-06 22961486.481124
16 1E-16 5.2236011E-27 1.2560299637E-16 1.28824955E-06 229614864.81124
16.5 3.1623E-17 5.2236011E-28 3.9719154947E-17 1.28824955E-06 2296148648.1124
17 1E-17 5.2236011E-29 1.2560299637E-17 1.28824955E-06 22961486481.124
17.5 3.1623E-18 5.2236011E-30 3.9719154947E-18 1.28824955E-06 229614864811.24
18 1E-18 5.2236011E-31 1.2560299637E-18 1.28824955E-06 2296148648112.4
18.5 3.1623E-19 5.2236011E-32 3.9719154947E-19 1.28824955E-06 22961486481124
19 1E-19 5.2236011E-33 1.2560299637E-19 1.28824955E-06 229614864811235
19.5 3.1623E-20 5.2236011E-34 3.9719154947E-20 1.28824955E-06 2.296148648E+15
20 1E-20 5.2236011E-35 1.2560299637E-20 1.28824955E-06 2.296148648E+16

RECTAS VERTICALES

pH Pb+2/PbHCO3+ pH PbHCO3+/PbCO3
5.65 0 6 0
5.65 -5 6 -5
5.65 -10 6 -10

0
0 5

-2
 0
0 5

-2

-4

-6

-8

-10

-12
 LOG K K
-5.019 9.571941E-06
-0.099 0.7961593504
5.89 776247.11663
20.639 4.355119E+20
23.041 1.099006E+23
52.83 6.76083E+52
12.101 1.261828E+12
2.691 490.90787615

[Pb(OH)3-] [Pb(OH)4 2-] ∑[Pb2+]t pH

9.099133E-16 1.479108E-51 522361.3656417 0
2.877398E-15 1.479108E-49 52236.40815388 0.5
9.099133E-15 1.479108E-47 5223.726700389 1
2.877398E-14 1.479108E-45 522.3998300536 1.5
9.099133E-14 1.479108E-43 52.2485725489 2
2.877398E-13 1.479108E-41 5.2275742998 2.5
9.099133E-13 1.479108E-39 0.5236174278 3
2.877398E-12 1.479108E-37 0.0526344908 3.5
9.099133E-12 1.479108E-35 0.0053504924 4
2.877398E-11 1.479108E-33 0.0005633675 4.5
9.099133E-11 1.479108E-31 6.60846512E-05 5
2.877398E-10 1.479108E-29 1.04840541E-05 5.5
9.099133E-10 1.479108E-27 3.06755183E-06 6
2.877398E-09 1.479108E-25 1.74057747E-06 6.5
9.099133E-09 1.479108E-23 1.4284049E-06 7
2.877398E-08 1.479108E-21 1.3595612E-06 7.5
0.000000091 1.479108E-19 1.4148149E-06 8
2.877398E-07 1.479108E-17 1.8095814E-06 8.5
9.099133E-07 1.479108E-15 4.49556803E-06 9
2.877398E-06 1.479108E-13 2.71275318E-05 9.5
9.099133E-06 1.479108E-11 0.0002400024 10
0.000028774 1.479108E-09 0.0023262124 10.5
9.099133E-05 1.479108E-07 0.023053914 11
0.00028774 1.479108E-05 0.229918684 11.5
0.000909913 0.0014791084 2.298538958 12
0.002877398 0.1479108388 23.1122760066 12.5
0.009099133 14.791083882 244.4150491139 13
0.028773984 1479.1083882 3775.285811553 13.5
0.090991327 147910.83882 170872.4162906 14
0.287739841 14791083.882 15020699.03423 14.5
0.909913273 1479108388 1481404537.726 15
2.877398415 147910838817 147933800306 15.5
9.099132726 1.479108E+13 14791313496556 16
28.77398415 1.479108E+15 1.47911068E+15 16.5
90.99132726 1.479108E+17 1.47910862E+17 17
287.7398415 1.479108E+19 1.47910841E+19 17.5
909.9132726 1.479108E+21 1.47910839E+21 18
2877.398415 1.479108E+23 1.47910839E+23 18.5
9099.132726 1.479108E+25 1.47910839E+25 19
28773.98415 1.479108E+27 1.47910839E+27 19.5
90991.32726 1.479108E+29 1.47910839E+29 20

pH PbCO3/Pb(CO3)2 2- pH Pb(CO3)2 2-/Pb(OH)3 - pH

9.2 0 11.6 0 12
9.2 -5 11.6 -5 12
9.2 -10 11.6 -10 12
pH A1 pH A3
0 -2 0 -1.3010299957
10 -2 10 -1.3010299957
20 -2 20 -1.3010299957

pH de los cambios de es especies diferentes especies

0
0 5 10 15 20 25

-2
Pb+2/PbHCO3+
 pH de los cambios de es especies diferentes especies
0
0 5 10 15 20 25

-2
Pb+2/PbHCO3+
PbHCO3+/PbCO3
-4 PbCO3/Pb(CO3)2 2-
Pb(CO3)2 2-/Pb(OH)3 -
Pb(OH)3 - /Pb(OH)4 2-
H2CO3/HCO3-
-6
HCO3-/CO3=
A1
A3
-8

-10

-12
 LOGATIRMOS

[H+] [Pb2+] [PbHCO3+] PbCO3 [Pb(CO3)2 2-]

1 5.71797 0.099 -5.89 -23.639
0.316227766 4.71797 -0.401 -5.89 -22.639
0.1 3.71797 -0.901 -5.89 -21.639
0.0316227766 2.71797 -1.401 -5.89 -20.639
0.01 1.71797 -1.901 -5.89 -19.639
0.0031622777 0.71797 -2.401 -5.89 -18.639
0.001 -0.28203 -2.901 -5.89 -17.639
0.0003162278 -1.28203 -3.401 -5.89 -16.639
0.0001 -2.28203 -3.901 -5.89 -15.639
3.1622776601684E-05 -3.28203 -4.401 -5.89 -14.639
0.00001 -4.28203 -4.901 -5.89 -13.639
3.1622776601684E-06 -5.28203 -5.401 -5.89 -12.639
0.000001 -6.28203 -5.901 -5.89 -11.639
 3.1622776601684E-07 -7.28203 -6.401 -5.89 -10.639
0.0000001 -8.28203 -6.901 -5.89 -9.639
3.1622776601684E-08 -9.28203 -7.401 -5.89 -8.639
0.00000001 -10.28203 -7.901 -5.89 -7.639
3.1622776601684E-09 -11.28203 -8.401 -5.89 -6.639
0.000000001 -12.28203 -8.901 -5.89 -5.639
3.1622776601684E-10 -13.28203 -9.401 -5.89 -4.639
1E-10 -14.28203 -9.901 -5.89 -3.639
3.1622776601684E-11 -15.28203 -10.401 -5.89 -2.639
1E-11 -16.28203 -10.901 -5.89 -1.639
3.1622776601684E-12 -17.28203 -11.401 -5.89 -0.639
1E-12 -18.28203 -11.901 -5.89 0.361
3.1622776601684E-13 -19.28203 -12.401 -5.89 1.361
1E-13 -20.28203 -12.901 -5.89 2.361
3.1622776601684E-14 -21.28203 -13.401 -5.89 3.361
1E-14 -22.28203 -13.901 -5.89 4.361
3.1622776601684E-15 -23.28203 -14.401 -5.89 5.361
1E-15 -24.28203 -14.901 -5.89 6.361
3.1622776601684E-16 -25.28203 -15.401 -5.89 7.361
1E-16 -26.28203 -15.901 -5.89 8.361
3.1622776601684E-17 -27.28203 -16.401 -5.89 9.361
1E-17 -28.28203 -16.901 -5.89 10.361
3.1622776601684E-18 -29.28203 -17.401 -5.89 11.361
1E-18 -30.28203 -17.901 -5.89 12.361
3.1622776601684E-19 -31.28203 -18.401 -5.89 13.361
1E-19 -32.28203 -18.901 -5.89 14.361
3.1622776601684E-20 -33.28203 -19.401 -5.89 15.361
1E-20 -34.28203 -19.901 -5.89 16.361

Pb(OH)3 - /Pb(OH)4 2- pH H2CO3/HCO3- pH HCO3-/CO3=

0 6.352 0 10.329 0
-5 6.352 -5 10.329 -5
-10 6.352 -10 10.329 -10

s especies
25

Pb+2/PbHCO3+
s especies
25

Pb+2/PbHCO3+
PbHCO3+/PbCO3
PbCO3/Pb(CO3)2 2-
Pb(CO3)2 2-/Pb(OH)3 -
Pb(OH)3 - /Pb(OH)4 2-
H2CO3/HCO3-
HCO3-/CO3=
A1
A3
 G

DIAGRA
[Pb(OH)3-] [Pb(OH)4 2-] ∑[Pb2+]t 0
-15.041 -50.83 5.7179710486
-14.541 -48.83 4.7179733066 -1
-14.041 -46.83 3.7179804471
-13.541 -44.83 2.718003027 -2
-13.041
-12.541
-42.83
-40.83
1.7180744299
0.7183002142 -3 PbCO3(s)
-12.041 -38.83 -0.280985907
-4

〖��
-11.541 -36.83 -1.2787295745
-11.041 -34.83 -2.2716062525
-5
-10.541 -32.83 -3.2492081775
-10.041
-9.541
-30.83
-28.83
-4.1798993981
-4.9794707462
-6
〗 ^(
+2)
-9.041 -26.83 -5.51320809 -7
(
〖〖 ��

-8 PbCO3
-9
 -6
〗 ^(
+2)
-7

(
〖〖 ��
-8.541 -24.83 -5.7593066418
-8.041 -22.83 -5.8451486697 -8 PbCO3
-7.541 -20.83 -5.8666012382
-9
-7.041 -18.83 -5.8493003748
-6.541 -16.83 -5.742421877
-10
-6.041 -14.83 -5.3472154263 0 1 2 3 4 5 6 7 8 9 10
-5.541 -12.83 -4.5665897181
-5.041 -10.83 -3.619784438
-4.541 -8.83 -2.6333506335
-4.041 -6.83 -1.6372553316
-3.541 -4.83 -0.638425735
-3.041 -2.83 0.361451869
-2.541 -0.83 1.3638427152
-2.041 1.17 2.3881279428
-1.541 3.17 3.5769498359
-1.041 5.17 5.2326719608
-0.541 7.17 7.1766901444
-0.041 9.17 9.1706736706
0.459 11.17 11.1700674141
0.959 13.17 13.1700067419
1.459 15.17 15.1700006742
1.959 17.17 17.1700000674
2.459 19.17 19.1700000067
2.959 21.17 21.1700000007
3.459 23.17 23.1700000001
3.959 25.17 25.17
4.459 27.17 27.17
4.959 29.17 29.17
 GRÁFICA

DIAGRAMA DE PREDOMINANCIA Y ECAS

A3
A1 [Pb2+]
[PbHCO3+]

PbCO3(s) PbCO3
[Pb(CO3)2 2-]
[Pb(OH)3-]
[Pb(OH)4 2-]

� 〖〖�� (��)
A1
A3
∑[Pb2+]t
Pb+2/PbHCO3+
〗 _4 〗 ^(+2 PbHCO3+/PbCO3
3
−2) ^(
( � �_

) PbCO3/Pb(CO3)2 2-
_2 〗

Pb(CO3)2 2-/Pb(OH)3 -
〖〖 ��

Pb(OH)3 - /Pb(OH)4 2-
PbCO3
)〗
 〖〖�� (��) ∑[Pb2+]t
Pb+2/PbHCO3+
〗 _4 〗 ^(+2 PbHCO3+/PbCO3

3
−2) ^(
( � �_
) PbCO3/Pb(CO3)2 2-

_2 〗
Pb(CO3)2 2-/Pb(OH)3 -

〖〖 ��
Pb(OH)3 - /Pb(OH)4 2-
PbCO3

)〗
5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21
 DATOS

LOGK FORMULA
1 Pb(OH)2 -17.12 Pb2+ = 2H+ + Pb(OH)2
2 Pb(OH)3- -28.06 Pb2+ = 3H+ + Pb(OH)3-
3 Pb(OH)4 2- -39.7 Pb2+ = 4H+ + Pb(OH)4 2-
4 PbOH+ -7.71 Pb2+ = H+ + PbOH+
5 H2O -14 H+ + OH- = H2O
6 Pb(OH)2(s) -8.15 Pb2+ = 2H+ +Pb(OH)2 (s)

7 CO2(g) 18.149 2H+ + CO3- =CO2(g)

8 H2CO3 16.681 2H+ + CO3 2- = H2CO3
9 HCO3 - 10.329 H+ + CO3 2- = HCO3-
10 Pb(CO3)2 2- 10.64 Pb2+ + 2CO3 2-=Pb(CO3)2 2-
11 PbCO3 7.24 Pb2+ + CO3 2- = PbCO3
12 PbHCO3+ 13.229 Pb2+ + H+ + CO3 2- =PbHCO3+
13 PbCO3(s) 13.13 Pb2+ + CO3 2- =PbCO3(s)

ECUACIONES

13-7 Pb2+ Pb2+ + CO2(g)+ H2O = 2H+ + PbCO3(s)

13-12 PbHCO3+ PbHCO3+ = PbCO3(s)+ H+
13-11 PbCO3 PbCO3=PbCO3(s)
13-10+7 Pb(CO3)2 2- Pb(CO3)2 2- +2H+ = PbCO3(s) + CO2(g) +H2O
13-2-7 Pb(OH)3- Pb(OH)3- + CO2(g) + H+ = PbCO3(s) + 2H2O
13-3-7 Pb(OH)4 2- Pb(OH)4 2- + 2H+ CO2(g) = PbCO3(s) +4H2O
13-1-7 Pb(OH)2 CO2(g) + Pb(OH)2=PbCO3(s) + H2O
13-4-7 PbOH+ PbOH+ + CO2(g) = PbCO3(s) + H+

∑[Pb2+]t 0.001 M ∑[CO3 2-]t

pH [H+] [Pb2+] [PbHCO3+] PbCO3
0 1 1044720219 12560.2996369487 0.0128824955
0.5 0.31622777 104472021.92 3971.9154946944 0.0128824955
1 0.1 10447202.192 1256.0299636949 0.0128824955
1.5 0.03162278 1044720.2192 397.1915494694 0.0128824955
2 0.01 104472.02192 125.6029963695 0.0128824955
2.5 0.00316228 10447.202192 39.7191549469 0.0128824955
3 0.001 1044.7202192 12.5602996369 0.0128824955
3.5 0.00031623 104.47202192 3.9719154947 0.0128824955
4 0.0001 10.447202192 1.2560299637 0.0128824955
4.5 3.1623E-05 1.0447202192 0.3971915495 0.0128824955
5 0.00001 0.1044720219 0.1256029964 0.0128824955
5.5 3.1623E-06 0.0104472022 0.0397191549 0.0128824955
6 0.000001 0.0010447202 0.0125602996 0.0128824955
 6.5 3.1623E-07 0.000104472 0.0039719155 0.0128824955
7 0.0000001 1.04472E-05 0.00125603 0.0128824955
7.5 3.1623E-08 1.04472E-06 0.0003971915 0.0128824955
8 0.00000001 1.04472E-07 0.000125603 0.0128824955
8.5 3.1623E-09 1.04472E-08 3.97191549469439E-05 0.0128824955
9 1E-09 0.000000001 1.25602996369487E-05 0.0128824955
9.5 3.1623E-10 1.04472E-10 3.97191549469439E-06 0.0128824955
10 1E-10 1.04472E-11 0.000001256 0.0128824955
10.5 3.1623E-11 1.04472E-12 3.97191549469439E-07 0.0128824955
11 1E-11 1.04472E-13 1.25602996369487E-07 0.0128824955
11.5 3.1623E-12 1.04472E-14 3.97191549469439E-08 0.0128824955
12 1E-12 1.04472E-15 1.25602996369487E-08 0.0128824955
12.5 3.1623E-13 1.04472E-16 0.000000004 0.0128824955
13 1E-13 1.04472E-17 1.25602996369487E-09 0.0128824955
13.5 3.1623E-14 1.04472E-18 3.97191549469439E-10 0.0128824955
14 1E-14 1.04472E-19 1.25602996369487E-10 0.0128824955
14.5 3.1623E-15 1.04472E-20 3.97191549469439E-11 0.0128824955
15 1E-15 1.04472E-21 1.25602996369487E-11 0.0128824955
15.5 3.1623E-16 1.04472E-22 3.97191549469439E-12 0.0128824955
16 1E-16 1.04472E-23 1.25602996369487E-12 0.0128824955
16.5 3.1623E-17 1.04472E-24 3.97191549469439E-13 0.0128824955
17 1E-17 1.04472E-25 1.25602996369487E-13 0.0128824955
17.5 3.1623E-18 1.04472E-26 3.97191549469439E-14 0.0128824955
18 1E-18 1.04472E-27 1.25602996369487E-14 0.0128824955
18.5 3.1623E-19 1.04472E-28 3.97191549469439E-15 0.0128824955
19 1E-19 1.04472E-29 1.25602996369487E-15 0.0128824955
19.5 3.1623E-20 1.04472E-30 3.97191549469439E-16 0.0128824955
20 1E-20 1.04472E-31 1.25602996369487E-16 0.0128824955

Pb+2 FRA
1 PbCO3
Pb(C
0.9

0.8

0.7
Pb+2

0.6
0.8

0.7
Pb+2

0.6

0.5

0.4

0.3

0.2

0.1

0
0 2.5 5 7.5
 K
7.58577575E-18
8.7096359E-29
1.995262315E-40
1.9498446E-08
1E-14
7.079457844E-09

1.4092888E+18
4.79733449E+16
21330449131.47
43651583224.02
17378008.28749
16943378004473
13489628825917

LOG K K
-5.019 9.571941E-06
-0.099 0.7961593504
5.89 776247.11663
20.639 4.355119E+20
23.041 1.099006E+23
52.83 6.76083E+52
12.101 1.261828E+12
2.691 490.90787615

0.01 M
[Pb(CO3)2 2-] [Pb(OH)3-] [Pb(OH)4 2-] [Pb(OH)2] ∑[Pb2+]t
1.148074324E-22 9.09913272632254E-11 1.479108E-45 7.9250133E-13 1044732780
1.148074324E-21 5.75479682947138E-11 1.479108E-43 7.9250133E-13 104475993.85
1.148074324E-20 1.81982654526452E-10 1.479108E-41 7.9250133E-13 10448458.235
1.148074324E-19 5.75479682947138E-10 1.479108E-39 7.9250133E-13 1045117.4237
1.148074324E-18 1.81982654526452E-09 1.479108E-37 7.9250133E-13 104597.6378
1.148074324E-17 5.75479682947138E-09 1.479108E-35 7.9250133E-13 10486.93423
1.148074324E-16 1.81982654526452E-08 1.479108E-33 7.9250133E-13 1057.2934014
1.148074324E-15 5.75479682947138E-08 1.479108E-31 7.9250133E-13 108.45681997
1.148074324E-14 0.000000182 1.479108E-29 7.9250133E-13 11.716114833
1.148074324E-13 5.75479682947138E-07 1.479108E-27 7.9250133E-13 1.4547948397
1.148074324E-12 1.81982654526452E-06 1.479108E-25 7.9250133E-13 0.2429593336
1.148074324E-11 5.75479682947138E-06 1.479108E-23 7.9250133E-13 0.0630546075
1.148074324E-10 1.81982654526452E-05 1.479108E-21 7.9250133E-13 0.0265057138
 1.148074324E-09 0.000057548 1.479108E-19 7.9250133E-13 0.0170164322
1.148074324E-08 0.0001819827 1.479108E-17 7.9250133E-13 0.0143309668
1.148074324E-07 0.0005754797 1.479108E-15 7.9250133E-13 0.0138563263
1.148074324E-06 0.0018198265 1.479108E-13 7.9250133E-13 0.0148291776
1.148074324E-05 0.0057547968 1.479108E-11 7.9250133E-13 0.0186885027
0.0001148074 0.0181982655 1.479108E-09 7.9250133E-13 0.0312081312
0.0011480743 0.0575479683 1.479108E-07 7.9250133E-13 0.0715826581
0.0114807432 0.1819826545 1.479108E-05 7.9250133E-13 0.2063619404
0.1148074324 0.5754796829 0.0014791084 7.9250133E-13 0.7046491165
1.1480743241 1.8198265453 0.1479108388 7.9250133E-13 3.1286943293
11.4807432406 5.7547968295 14.791083882 7.9250133E-13 32.039506487
114.8074324056 18.1982654526 1479.1083882 7.9250133E-13 1612.1269685
1148.074324056 57.5479682947 147910.83882 7.9250133E-13 149116.47399
11480.74324056 181.9826545265 14791083.882 7.9250133E-13 14802746.62
114807.4324056 575.4796829471 1479108388 7.9250133E-13 1479223771
1148074.324056 1819.8265452645 147910838817 7.9250133E-13 147911988711
11480743.24056 5754.7968294714 1.479108E+13 7.9250133E-13 1.47911E+13
114807432.4056 18198.2654526452 1.479108E+15 7.9250133E-13 1.479109E+15
1148074324.056 57547.9682947138 1.479108E+17 7.9250133E-13 1.479108E+17
11480743240.56 181982.654526452 1.479108E+19 7.9250133E-13 1.479108E+19
114807432405.6 575479.682947138 1.479108E+21 7.9250133E-13 1.479108E+21
1148074324056 1819826.54526452 1.479108E+23 7.9250133E-13 1.479108E+23
11480743240562 5754796.82947138 1.479108E+25 7.9250133E-13 1.479108E+25
1.14807432E+14 18198265.4526452 1.479108E+27 7.9250133E-13 1.479108E+27
1.14807432E+15 57547968.2947138 1.479108E+29 7.9250133E-13 1.479108E+29
1.14807432E+16 181982654.526452 1.479108E+31 7.9250133E-13 1.479108E+31
1.14807432E+17 575479682.947138 1.479108E+33 7.9250133E-13 1.479108E+33
1.14807432E+18 1819826545.26452 1.479108E+35 7.9250133E-13 1.479108E+35

GRÁFICA

b+2 FRACCIÓN
Pb(OH)4 -2
PbCO3
Pb(CO3)2 -2

Pb+2
 Pb+2

Pb(OH)3-

2.5 5 7.5 10 12.5 15 17.5 20

 PORCENTAJES

pH [H+] [Pb2+] [PbHCO3+] PbCO3

0 1 0.99998798 1.20224998037865E-05 1.23309000821108E-11
0.5 0.31622777 0.99996198 3.80174942425494E-05 1.23305795352096E-10
1 0.1 0.99987979 0.000120212 1.23295659772186E-09
1.5 0.03162278 0.99961994 0.0003800449 1.23263618282298E-08
2 0.01 0.99879906 0.0012008206 1.23162394369242E-07
2.5 0.00316228 0.99621128 0.0037874897 1.2284329466376E-06
3 0.001 0.98810814 0.0118796728 1.21844092663596E-05
3.5 0.00031623 0.96325913 0.0366220907 0.0001187799
4 0.0001 0.8916951 0.1072053306 0.0010995535
4.5 3.1623E-05 0.71812203 0.2730223799 0.0088551974
5 0.00001 0.42999798 0.5169712745 0.0530232584
5.5 3.1623E-06 0.16568499 0.6299167744 0.2043069656
6 0.000001 0.03941491 0.4738713982 0.4860271124
 6.5 3.1623E-07 0.00613948 0.2334164682 0.7570620799
7 0.0000001 0.00072899 0.0876444681 0.898927175
7.5 3.1623E-08 7.5397E-05 0.0286649969 0.9297194118
8 0.00000001 7.045E-06 0.0084699907 0.8687262274
8.5 3.1623E-09 5.5902E-07 0.0021253257 0.6893273217
9 1E-09 3.3476E-08 0.0004024688 0.4127929168
9.5 3.1623E-10 1.4595E-09 5.54871193936406E-05 0.1799667107
10 1E-10 5.0626E-11 6.08653883175015E-06 0.0624267028
10.5 3.1623E-11 1.4826E-12 5.63672812746545E-07 0.0182821424
11 1E-11 3.3392E-14 4.01454994164488E-08 0.0041175309
11.5 3.1623E-12 3.2607E-16 1.23969309462116E-09 0.0004020816
12 1E-12 6.4804E-19 7.79113548876766E-12 0.000007991
12.5 3.1623E-13 7.0061E-22 2.66363292288974E-14 8.6392168296919E-08
13 1E-13 7.0576E-25 8.48511425547791E-17 8.70277378059422E-10
13.5 3.1623E-14 7.0626E-28 2.68513498249095E-19 8.70895652752467E-12
14 1E-14 7.0631E-31 8.49173873355961E-22 8.70956818929913E-14
14.5 3.1623E-15 7.0632E-34 2.68534236026846E-24 8.70962913581473E-16
15 1E-15 7.0632E-37 8.49180409113049E-27 8.70963522341759E-18
15.5 3.1623E-16 7.0632E-40 2.68534442481404E-29 8.70963583195396E-20
16 1E-16 7.0632E-43 8.4918047437719E-32 8.70963589280051E-22
16.5 3.1623E-17 7.0632E-46 2.68534444545012E-34 8.70963589888494E-24
17 1E-17 7.0632E-49 8.49180475029737E-37 8.70963589949338E-26
17.5 3.1623E-18 7.0632E-52 2.68534444565647E-39 8.70963589955422E-28
18 1E-18 7.0632E-55 8.49180475036263E-42 8.70963589956031E-30
18.5 3.1623E-19 7.0632E-58 2.68534444565853E-44 8.70963589956091E-32
19 1E-19 7.0632E-61 8.49180475036328E-47 8.70963589956097E-34
19.5 3.1623E-20 7.0632E-64 2.68534444565855E-49 8.70963589956098E-36
20 1E-20 7.0632E-67 8.49180475036328E-52 8.70963589956098E-38

A
CENTAJES

[Pb(CO3)2 2-] [Pb(OH)3-] [Pb(OH)4 2-] [Pb(OH)2]

1.0989167244939E-31 8.7095E-20 1.4157767586E-54 7.58568455E-22
1.09888815769437E-29 5.5082E-19 1.4157399549E-51 7.585487357E-21
1.09879783048223E-27 1.7417E-17 1.4156235828E-48 7.58486384E-20
1.09851228012596E-25 5.5064E-16 1.4152556973E-45 7.582892721E-19
1.09761018335902E-23 1.7398E-14 1.4140934913E-42 7.57666566E-18
1.09476640066027E-21 5.4876E-13 1.4104297364E-39 7.557035384E-17
1.08586161851285E-19 1.7212E-11 1.3989573625E-36 7.495566788E-16
1.05855429319745E-17 5.3061E-10 1.3637762831E-33 7.307067741E-15
9.79910439920709E-16 1.5533E-08 1.2624563767E-30 6.764199069E-14
7.89165793509813E-14 3.9557E-07 1.0167126991E-27 5.447512659E-13
4.72537649354751E-12 7.4903E-06 6.0878846103E-25 3.261868226E-12
1.82076198744089E-10 9.1267E-05 2.3457578243E-22 1.256849202E-11
4.33142202735918E-09 0.00068658 5.580337892E-20 2.98992639E-11
6.74685688449865E-08 0.00338191 8.6922356876E-18 4.657270828E-11
8.01114355064741E-07 0.01269856 1.0321064914E-15 5.529992083E-11
8.28556069653257E-06 0.04153191 1.0674607097E-13 5.719418803E-11
0.00007742 0.12271932 9.9743116408E-12 5.344202838E-11
0.0006143212 0.30793247 7.9145366075E-10 4.24058226E-11
0.0036787667 0.58312577 4.7394968236E-08 2.539406556E-11
0.0160384422 0.80393729 2.0662943066E-06 1.107113583E-11
0.0556340148 0.88186152 7.1675444863E-05 3.840346378E-12
0.1629285125 0.81668971 0.0020990708 1.124675121E-12
0.3669499808 0.58165687 0.0472755799 2.53300977E-13
0.358330839 0.17961565 0.4616514267 2.473512914E-14
0.0712148824 0.01128836 0.9174887692 4.915874158E-16
0.0076991783 0.00038593 0.991914809 5.314646392E-18
0.000775582 1.2294E-05 0.9992121233 5.353745158E-20
7.76132960064417E-05 3.8904E-07 0.9999219977 5.357548641E-22
7.76187470712399E-06 1.2303E-08 0.9999922258 5.357924921E-24
7.76192902201168E-07 3.8907E-10 0.9999992234 5.357962414E-26
7.76193444721871E-08 1.2304E-11 0.9999999224 5.357966159E-28
7.76193498953987E-09 3.8907E-13 0.9999999922 5.357966534E-30
7.76193504376566E-10 1.2304E-14 0.9999999992 5.357966571E-32
7.76193504918804E-11 3.8907E-16 0.9999999999 5.357966575E-34
7.76193504973028E-12 1.2304E-17 1 5.357966575E-36
7.7619350497845E-13 3.8907E-19 1 5.357966575E-38
7.76193504978992E-14 1.2304E-20 1 5.357966575E-40
7.76193504979046E-15 3.8907E-22 1 5.357966575E-42
7.76193504979052E-16 1.2304E-23 1 5.357966575E-44
7.76193504979052E-17 3.8907E-25 1 5.357966575E-46
7.76193504979052E-18 1.2304E-26 1 5.357966575E-48
 DATOS

LOGK FORMULA
1 Pb(OH)2 -17.12 Pb2+ = 2H+ + Pb(OH)2
2 Pb(OH)3- -28.06 Pb2+ = 3H+ + Pb(OH)3-
3 Pb(OH)4 2- -39.7 Pb2+ = 4H+ + Pb(OH)4 2-
4 PbOH+ -7.71 Pb2+ = H+ + PbOH+
5 H2O -14 H+ + OH- = H2O
6 Pb(OH)2(s) -8.15 Pb2+ = 2H+ +Pb(OH)2 (s)

7 CO2(g) 18.149 2H+ + CO3- =CO2(g)

8 H2CO3 16.681 2H+ + CO3 2- = H2CO3
9 HCO3 - 10.329 H+ + CO3 2- = HCO3-
10 Pb(CO3)2 2- 10.64 Pb2+ + 2CO3 2-=Pb(CO3)2 2-
11 PbCO3 7.24 Pb2+ + CO3 2- = PbCO3
12 PbHCO3+ 13.229 Pb2+ + H+ + CO3 2- =PbHCO3+
13 PbCO3(s) 13.13 Pb2+ + CO3 2- =PbCO3(s)

ECUACIONES

13-7 Pb2+ Pb2+ + CO2(g)+ H2O = 2H+ + PbCO3(s)

13-12 PbHCO3+ PbHCO3+ = PbCO3(s)+ H+
13-11 PbCO3 PbCO3=PbCO3(s)
13-10+7 Pb(CO3)2 2- Pb(CO3)2 2- +2H+ = PbCO3(s) + CO2(g) +H2O
13-2-7 Pb(OH)3- Pb(OH)3- + CO2(g) + H+ = PbCO3(s) + 2H2O
13-3-7 Pb(OH)4 2- Pb(OH)4 2- + 2H+ CO2(g) = PbCO3(s) +4H2O
13-1-7 Pb(OH)2 CO2(g) + Pb(OH)2=PbCO3(s) + H2O
13-4-7 PbOH+ PbOH+ + CO2(g) = PbCO3(s) + H+

pH [H+] [Pb2+] [PbHCO3+] PbCO3

0 1 10447202192.2 12560.2996369487 0.0128824955
0.5 0.31622777 1044720219.22 3971.9154946944 0.0128824955
1 0.1 104472021.922 1256.0299636949 0.0128824955
1.5 0.03162278 10447202.1922 397.1915494694 0.0128824955
2 0.01 1044720.21922 125.6029963695 0.0128824955
2.5 0.00316228 104472.021922 39.7191549469 0.0128824955
3 0.001 10447.2021922 12.5602996369 0.0128824955
3.5 0.00031623 1044.72021922 3.9719154947 0.0128824955
4 0.0001 104.472021922 1.2560299637 0.0128824955
4.5 3.1623E-05 10.4472021922 0.3971915495 0.0128824955
5 0.00001 1.0447202192 0.1256029964 0.0128824955
5.5 3.1623E-06 0.1044720219 0.0397191549 0.0128824955
6 0.000001 0.0104472022 0.0125602996 0.0128824955
 6.5 3.1623E-07 0.0010447202 0.0039719155 0.0128824955
7 0.0000001 0.000104472 0.00125603 0.0128824955
7.5 3.1623E-08 1.04472022E-05 0.0003971915 0.0128824955
8 0.00000001 1.04472022E-06 0.000125603 0.0128824955
8.5 3.1623E-09 1.04472022E-07 3.97191549469439E-05 0.0128824955
9 1E-09 1.04472022E-08 1.25602996369487E-05 0.0128824955
9.5 3.1623E-10 0.000000001 3.97191549469439E-06 0.0128824955
10 1E-10 1.04472022E-10 0.000001256 0.0128824955
10.5 3.1623E-11 1.04472022E-11 3.97191549469439E-07 0.0128824955
11 1E-11 1.04472022E-12 1.25602996369487E-07 0.0128824955
11.5 3.1623E-12 1.04472022E-13 3.97191549469439E-08 0.0128824955
12 1E-12 1.04472022E-14 1.25602996369487E-08 0.0128824955
12.5 3.1623E-13 1.04472022E-15 0.000000004 0.0128824955
13 1E-13 1.04472022E-16 1.25602996369487E-09 0.0128824955
13.5 3.1623E-14 1.04472022E-17 3.97191549469439E-10 0.0128824955
14 1E-14 1.04472022E-18 1.25602996369487E-10 0.0128824955
14.5 3.1623E-15 1.04472022E-19 3.97191549469439E-11 0.0128824955
15 1E-15 1.04472022E-20 1.25602996369487E-11 0.0128824955
15.5 3.1623E-16 1.04472022E-21 3.97191549469439E-12 0.0128824955
16 1E-16 1.04472022E-22 1.25602996369487E-12 0.0128824955
16.5 3.1623E-17 1.04472022E-23 3.97191549469439E-13 0.0128824955
17 1E-17 1.04472022E-24 1.25602996369487E-13 0.0128824955
17.5 3.1623E-18 1.04472022E-25 3.97191549469439E-14 0.0128824955
18 1E-18 1.04472022E-26 1.25602996369487E-14 0.0128824955
18.5 3.1623E-19 1.04472022E-27 3.97191549469439E-15 0.0128824955
19 1E-19 1.04472022E-28 1.25602996369487E-15 0.0128824955
19.5 3.1623E-20 1.04472022E-29 3.97191549469439E-16 0.0128824955
20 1E-20 1.04472022E-30 1.25602996369487E-16 0.0128824955

REACCIONES CO3 -2

13-8-6 H2CO3 4.599 Pb(OH)2(s) + H2CO3 = PbCO3(s)+2H2O

13-9-6 HCO3- 10.951 HCO3- + H+ + Pb(OH)2(s) =PbCO3(s) + 2H2O
13-6 CO3 2- 21.28 2H+ + CO3 2- + Pb(OH)2(s) = PbCO3(s) + 2H2O
13-11 PbCO3 5.89 PbCO3=PbCO3(s)

pH [H+] [H2CO3] [HCO3-] [CO3 2-]

0 1 2.5176769278 1.11943788346715E-06 5.2480746024977E-17
0.5 0.31622777 2.5176769278 0.00000354 5.2480746024977E-16
1 0.1 2.5176769278 1.11943788346715E-05 5.2480746024977E-15
1.5 0.03162278 2.5176769278 3.53997341083434E-05 5.2480746024977E-14
2 0.01 2.5176769278 0.0001119438 5.2480746024977E-13
2.5 0.00316228 2.5176769278 0.0003539973 5.2480746024977E-12
 3 0.001 2.5176769278 0.0011194379 5.2480746024977E-11
3.5 0.00031623 2.5176769278 0.0035399734 5.2480746024977E-10
4 0.0001 2.5176769278 0.0111943788 5.2480746024977E-09
4.5 3.1623E-05 2.5176769278 0.0353997341 5.2480746024977E-08
5 0.00001 2.5176769278 0.1119437883 5.2480746024977E-07
5.5 3.1623E-06 2.5176769278 0.3539973411 5.2480746024977E-06
6 0.000001 2.5176769278 1.1194378835 5.2480746024977E-05
6.5 3.1623E-07 2.5176769278 3.5399734108 0.0005248075
7 0.0000001 2.5176769278 11.1943788347 0.0052480746
7.5 3.1623E-08 2.5176769278 35.3997341083 0.052480746
8 0.00000001 2.5176769278 111.9437883467 0.5248074602
8.5 3.1623E-09 2.5176769278 353.9973410834 5.2480746025
9 1E-09 2.5176769278 1119.4378834672 52.480746025
9.5 3.1623E-10 2.5176769278 3539.9734108343 524.8074602498
10 1E-10 2.5176769278 11194.3788346715 5248.0746024977
10.5 3.1623E-11 2.5176769278 35399.7341083434 52480.7460249767
11 1E-11 2.5176769278 111943.788346715 524807.460249767
11.5 3.1623E-12 2.5176769278 353997.341083434 5248074.60249767
12 1E-12 2.5176769278 1119437.88346715 52480746.0249768
12.5 3.1623E-13 2.5176769278 3539973.41083434 524807460.249767
13 1E-13 2.5176769278 11194378.8346715 5248074602.49767
13.5 3.1623E-14 2.5176769278 35399734.1083434 52480746024.9767
14 1E-14 2.5176769278 111943788.346715 524807460249.767
14.5 3.1623E-15 2.5176769278 353997341.083434 5248074602497.67
15 1E-15 2.5176769278 1119437883.46715 52480746024976.7
15.5 3.1623E-16 2.5176769278 3539973410.83434 524807460249767
16 1E-16 2.5176769278 11194378834.6715 5248074602497674
16.5 3.1623E-17 2.5176769278 35399734108.3434 5.2480746024977E+16
17 1E-17 2.5176769278 111943788346.715 5.2480746024977E+17
17.5 3.1623E-18 2.5176769278 353997341083.434 5.2480746024977E+18
18 1E-18 2.5176769278 1119437883467.15 5.2480746024977E+19
18.5 3.1623E-19 2.5176769278 3539973410834.34 5.2480746024977E+20
19 1E-19 2.5176769278 11194378834671.5 5.2480746024977E+21
19.5 3.1623E-20 2.5176769278 35399734108343.4 5.2480746024977E+22
20 1E-20 2.5176769278 111943788346715 5.2480746024977E+23
 K
7.58577575E-18
8.7096359E-29
1.995262315E-40
1.9498446E-08
1E-14
7.079457844E-09

1.4092888E+18
4.79733449E+16
21330449131.47
43651583224.02
17378008.28749
16943378004473
13489628825917

LOG K K
-5.019 9.571941E-06
-0.099 0.7961593504
5.89 776247.11663
20.639 4.355119E+20
23.041 1.099006E+23
52.83 6.76083E+52
12.101 1.261828E+12
2.691 490.90787615

[Pb(CO3)2 2-] [Pb(OH)3-] [Pb(OH)4 2-] [Pb(OH)2] [Pb(OH)+] ∑[Pb2+]t

2.296148648E-21 9.09913272632254E-13 1.479108E-48 7.9250133E-09 203.70420777 10447214956.225
2.296148648E-20 2.87739841473569E-12 1.479108E-46 7.9250133E-09 64.416926552 1044724255.5661
2.296148648E-19 9.09913272632258E-12 1.479108E-44 7.9250133E-09 20.370420777 104473298.33535
2.296148648E-18 2.87739841473569E-11 1.479108E-42 7.9250133E-09 6.4416926552 10447605.838333
2.296148648E-17 9.09913272632258E-11 1.479108E-40 7.9250133E-09 2.0370420777 1044847.8721418
2.296148648E-16 2.87739841473569E-10 1.479108E-38 7.9250133E-09 0.6441692655 104512.3981288
2.296148648E-15 9.09913272632258E-10 1.479108E-36 7.9250133E-09 0.2037042078 10459.979078557
2.296148648E-14 2.87739841473569E-09 1.479108E-34 7.9250133E-09 0.0644169266 1048.7694341484
2.296148648E-13 9.09913272632258E-09 1.479108E-32 7.9250133E-09 0.0203704208 105.7613048191
2.296148648E-12 2.87739841473569E-08 1.479108E-30 7.9250133E-09 0.0064416927 10.8637179666
2.296148648E-11 0.000000091 1.479108E-28 7.9250133E-09 0.0020370421 1.1852428521
2.296148648E-10 2.87739841473569E-07 1.479108E-26 7.9250133E-09 0.0006441693 0.1577181375
2.296148648E-09 9.09913272632258E-07 1.479108E-24 7.9250133E-09 0.0002037042 0.0360946217
 0.000000023 2.87739841473569E-06 1.479108E-22 7.9250133E-09 6.441693E-05 0.0179664564
2.296148648E-07 9.09913272632258E-06 1.479108E-20 7.9250133E-09 2.037042E-05 0.0142727046
2.296148648E-06 0.000028774 1.479108E-18 7.9250133E-09 6.441693E-06 0.013327654
2.296148648E-05 9.09913272632258E-05 1.479108E-16 7.9250133E-09 0.000002037 0.013125141
0.0002296149 0.0002877398 1.479108E-14 7.9250133E-09 6.441693E-07 0.0134403259
0.0022961486 0.0009099133 1.479108E-12 7.9250133E-09 2.037042E-07 0.0161013398
0.0229614865 0.0028773984 1.479108E-10 7.9250133E-09 6.441693E-08 0.0387254259
0.2296148648 0.0090991327 1.479108E-08 7.9250133E-09 2.037042E-08 0.2515977923
2.2961486481 0.0287739841 1.479108E-06 7.9250133E-09 6.441693E-09 2.3378070185
22.9614864811 0.0909913273 0.0001479108 7.9250133E-09 0.000000002 23.0655083503
229.6148648112 0.2877398415 0.0147910839 7.9250133E-09 6.441693E-10 229.9302782804
2296.148648112 0.9099132726 1.4791083882 7.9250133E-09 2.037042E-10 2298.5505522894
22961.48648112 2.8773984147 147.91083882 7.9250133E-09 6.441693E-11 23112.287600863
229614.8648112 9.0991327263 14791.083882 7.9250133E-09 2.037042E-11 244415.06070815
2296148.648112 28.7739841474 1479108.3882 7.9250133E-09 6.441693E-12 3775285.8231472
22961486.48112 90.9913272632 147910838.82 7.9250133E-09 2.037042E-12 170872416.30215
229614864.8112 287.7398414736 14791083882 7.9250133E-09 6.441693E-13 15020699034.246
2296148648.112 909.9132726323 1.479108E+12 7.9250133E-09 2.037042E-13 1481404537726.2
22961486481.12 2877.3984147357 1.479108E+14 7.9250133E-09 6.441693E-14 147933800306176
229614864811.2 9099.1327263226 1.479108E+16 7.9250133E-09 2.037042E-14 1.47913135E+16
2296148648112 28773.9841473569 1.479108E+18 7.9250133E-09 6.441693E-15 1.479110684E+18
22961486481124 90991.3272632258 1.479108E+20 7.9250133E-09 2.037042E-15 1.479108618E+20
2.29614865E+14 287739.841473569 1.479108E+22 7.9250133E-09 6.441693E-16 1.479108411E+22
2.29614865E+15 909913.272632258 1.479108E+24 7.9250133E-09 2.037042E-16 1.47910839E+24
2.29614865E+16 2877398.41473569 1.479108E+26 7.9250133E-09 6.441693E-17 1.479108388E+26
2.29614865E+17 9099132.72632258 1.479108E+28 7.9250133E-09 2.037042E-17 1.479108388E+28
2.29614865E+18 28773984.1473569 1.479108E+30 7.9250133E-09 6.441693E-18 1.479108388E+30
2.29614865E+19 90991327.2632258 1.479108E+32 7.9250133E-09 2.037042E-18 1.479108388E+32

39719.15494694
89330548373.33
1.90546072E+21
776247.1166287

∑[Pb2+]t
2.5176780472
2.5176804677
2.5176881221
2.5177123275
2.5177888715
2.5180309251
 2.5187963657
2.5212169017
2.5288713118
2.5530767143
2.6296212409
2.8716795169
3.637167292
6.0581751461
13.717303837
37.9698917821
114.9862727347
361.7630926137
1174.43630642
4067.298548012
16444.9711141
87882.99781025
636753.7662734
5602074.461258
53600186.42612
528347436.1783
5259268983.85
52516145761.6
524919404040.6
5248428599841
52481865462863
5.24811E+14
5.2480858E+15
5.24807814E+16
5.24807572E+17
5.24807496E+18
5.24807471E+19
5.24807464E+20
5.24807461E+21
5.24807461E+22
5.2480746E+23
 LOGATIRMOS

pH [H+] [Pb2+] [PbHCO3+]

0 1 0.9999987782 1.20226296573566E-06
0.5 0.31622777 0.9999961364 3.80187927439488E-06
1 0.1 0.9999877824 1.20224974582803E-05
1.5 0.03162278 0.9999613647 3.80174707598682E-05
2 0.01 0.9998778263 0.0001202118
2.5 0.00316228 0.9996136707 0.0003800425
3 0.001 0.9987784979 0.0012007959
3.5 0.00031623 0.99613908 0.0037872152
4 0.0001 0.9878095027 0.0118760823
4.5 3.1623E-05 0.9616599238 0.0365612906
5 0.00001 0.8814397972 0.1059723719
5.5 3.1623E-06 0.6623970049 0.2518363174
6 0.000001 0.2894393043 0.3479825816
 6.5 3.1623E-07 0.0581483735 0.2210739501
7 0.0000001 0.0073197074 0.0880022392
7.5 3.1623E-08 0.0007838741 0.0298020604
8 0.00000001 7.95968758033262E-05 0.0095696493
8.5 3.1623E-09 0.000007773 0.0029552226
9 1E-09 6.48840550668692E-07 0.0007800779
9.5 3.1623E-10 0.000000027 0.0001025661
10 1E-10 4.1523425534556E-10 4.9922137723681E-06
10.5 3.1623E-11 4.46880435799102E-12 1.69899203113929E-07
11 1E-11 4.52936134488805E-14 5.44549005648978E-09
11.5 3.1623E-12 4.54363917198754E-16 1.72744343389639E-10
12 1E-12 4.54512613690511E-18 5.46444350525102E-12
12.5 3.1623E-13 4.52019392135729E-20 1.71852979821269E-13
13 1E-13 4.27436924792571E-22 5.13892212720344E-15
13.5 3.1623E-14 2.76726125692358E-24 1.05208338673105E-16
14 1E-14 6.11403667033911E-27 7.35068884069535E-19
14.5 3.1623E-15 6.95520372812837E-30 2.64429470668363E-21
15 1E-15 7.05222775153859E-33 8.47864261049674E-24
15.5 3.1623E-16 7.0620792344857E-36 2.68492764092708E-26
16 1E-16 7.06306589650794E-39 8.49167292673062E-29
16.5 3.1623E-17 7.0631645778647E-42 2.68534027697114E-31
17 1E-17 7.06317444615174E-45 8.49180343210675E-34
17.5 3.1623E-18 7.06317543298196E-48 2.68534440397162E-36
18 1E-18 7.06317553166499E-51 8.49180473718072E-39
18.5 3.1623E-19 7.06317554153329E-54 2.68534444524168E-41
19 1E-19 7.06317554252012E-57 8.49180475023146E-44
19.5 3.1623E-20 7.0631755426188E-60 2.68534444565438E-46
20 1E-20 7.06317554262867E-63 8.49180475036197E-49

Bjer
0

-1

-2

-3
 0

-1

-2

-3

-4

-5

-6

-7

-8

-9

-10
0 2.5 5 7.5 10
 PbCO3 [Pb(CO3)2 2-] [Pb(OH)3-] [Pb(OH)4 2-] [Pb(OH)2] [Pb(OH)+]
1.23310332666751E-12 2.197857188E-31 8.7096252585E-23 1.4158E-58 7.585766482E-19 1.949842E-08
1.23310006906566E-11 2.197851381E-29 2.7542180622E-21 1.4158E-55 7.585746442E-18 6.165926E-08
1.23308976764379E-10 2.19783302E-27 8.7095294887E-20 1.4158E-52 7.58568307E-17 0.000000195
1.23305719188458E-09 2.197774958E-25 2.754122293E-18 1.4157E-49 7.585482672E-16 6.165712E-07
1.23295418026019E-08 2.197591352E-23 8.7085718112E-17 1.4156E-46 7.584848968E-15 1.949606E-06
1.23262844864162E-07 2.197010775E-21 2.753164664E-15 1.4152E-43 7.582845142E-14 6.163568E-06
1.23159859309283E-06 2.195175182E-19 8.6989970611E-14 1.4141E-40 7.576509709E-13 1.947463E-05
1.22834391406461E-05 2.189374112E-17 2.7435948465E-12 1.4103E-37 7.556487677E-12 6.142144E-05
0.0001218073 2.171066868E-15 8.603461107E-11 1.3985E-34 7.493301372E-11 0.000192608
0.0011858275 2.113593758E-13 2.6486313651E-09 1.3615E-31 7.29493653E-10 0.000592955
0.0108690767 1.937281161E-11 7.6770197011E-08 1.2479E-28 6.686404639E-09 0.001718671
0.0816804948 1.455855797E-09 1.8243928438E-06 9.3782E-26 5.024795137E-08 0.004084307
0.3569090051 6.361470326E-08 2.5209109559E-05 4.0979E-23 2.195621656E-07 0.005643617
 0.7170304038 0.000001278 0.0001601539 8.2326E-21 4.411005214E-07 0.0035854
0.9025966614 1.608769125E-05 0.0006375199 1.0363E-18 5.552565915E-07 0.001427229
0.9665988852 0.0001722845 0.0021589684 1.1098E-16 5.946292794E-07 0.000483333
0.9815129226 0.0017494278 0.0069325981 1.1269E-14 6.038040503E-07 0.000155202
0.9584957664 0.017084025 0.0214086952 1.1005E-12 5.896444281E-07 4.79281E-05
0.800088419 0.142606061 0.0565116495 9.1862E-11 4.921958915E-07 1.265138E-05
0.3326624622 0.5929305093 0.0743025635 3.8195E-09 2.046462532E-07 1.663427E-06
0.0512027367 0.9126267076 0.0361653918 5.8789E-08 3.149873945E-08 0.000000081
0.0055105043 0.9821805778 0.0123081092 6.3269E-07 3.389934773E-09 2.755442E-09
0.0005585177 0.9954901549 0.0039449088 6.4126E-06 3.435871945E-10 8.831551E-11
5.60278342342603E-05 0.9986282213 0.0012514221 6.4329E-05 3.446702785E-11 2.801585E-12
5.60461700705272E-06 0.9989550353 0.0003958639 0.0006435 3.447830763E-12 8.86229E-14
5.5738729715576E-07 0.9934752837 0.0001244965 0.00639966 3.428917744E-13 2.787129E-15
5.2707453786222E-08 0.9394464651 3.722819985E-05 0.06051625 3.242440659E-14 8.334356E-17
3.41232323071956E-09 0.6082052474 7.6216703835E-06 0.39178713 2.099182334E-15 1.706279E-18
7.53924816873393E-11 0.1343779586 5.3251033275E-07 0.86562151 4.637971111E-17 1.192142E-20
8.57649533324681E-13 0.0152865632 1.9156221746E-08 0.98471342 5.276061578E-19 4.288544E-23
8.69613612545326E-15 0.0015499808 6.1422335997E-10 0.99845002 5.349661826E-21 1.375075E-25
8.70828403668981E-17 0.0001552146 1.9450581333E-11 0.99984479 5.35713494E-23 4.354443E-28
8.70950069439821E-19 1.552362911E-05 6.1516732293E-13 0.99998448 5.3578834E-25 1.377188E-30
8.70962237885617E-21 1.5523846E-06 1.9453570617E-14 0.99999845 5.357958258E-27 4.355112E-33
8.70963454748862E-23 1.552386769E-07 6.1517677721E-16 0.99999984 5.357965743E-29 1.377209E-35
8.70963576435373E-25 1.552386986E-08 1.9453600514E-17 0.99999998 5.357966492E-31 4.355119E-38
8.70963588604026E-27 1.552387008E-09 6.1517687175E-19 1 5.357966567E-33 1.377209E-40
8.70963589820891E-29 1.55238701E-10 1.9453600813E-20 1 5.357966574E-35 4.355119E-43
8.70963589942577E-31 1.55238701E-11 6.151768727E-22 1 5.357966575E-37 1.377209E-45
8.70963589954746E-33 1.55238701E-12 1.9453600816E-23 1 5.357966575E-39 4.355119E-48
8.70963589955963E-35 1.55238701E-13 6.1517687271E-25 1 5.357966575E-41 1.377209E-50

GRAF
Bjerrum

[Pb2+]
[PbHCO3+]
 [Pb2+]
[PbHCO3+]
PbCO3
[Pb(CO3)2 2-]
[Pb(OH)3-]
[Pb(OH)4 2-]
[Pb(OH)2]
[Pb(OH)+]
[H2CO3]
[HCO3-]
[CO3 2-]
[H+]
[OH+]

7.5 10 12.5 15 17.5 20

pH [H+] [Pb2+] [PbHCO3+] PbCO3
0 1 -3.0000005306 -8.9200005306 -14.9090005306
0.5 0.31622777 -3.0000016779 -8.4200016779 -13.9090016779
1 0.1 -3.0000053061 -7.9200053061 -12.9090053061
1.5 0.03162278 -3.0000167794 -7.4200167794 -11.9090167794
2 0.01 -3.0000530626 -6.9200530626 -10.9090530626
2.5 0.00316228 -3.0001678131 -6.4201678131 -9.9091678131
3 0.001 -3.0005308159 -5.9205308159 -8.9095308159
3.5 0.00031623 -3.0016800216 -5.4216800216 -7.9106800216
4 0.0001 -3.0053268002 -4.9253268002 -6.9143268002
4.5 3.1623E-05 -3.0169784823 -4.4369784823 -5.9259784823
5 0.00001 -3.0548073449 -3.9748073449 -4.9638073449
5.5 3.1623E-06 -3.17888164 -3.59888164 -4.08788164
6 0.000001 -3.5384424943 -3.4584424943 -3.4474424943
 6.5 3.1623E-07 -4.2354624288 -3.6554624288 -3.1444624288
7 0.0000001 -5.1355062772 -4.0555062772 -3.0445062772
7.5 3.1623E-08 -6.1057537101 -4.5257537101 -3.0147537101
8 0.00000001 -7.0991039781 -5.0191039781 -3.0081039781
8.5 3.1623E-09 -8.109409801 -5.529409801 -3.018409801
9 1E-09 -9.1878620158 -6.1078620158 -3.0968620158
9.5 3.1623E-10 -10.5689962024 -6.9889962024 -3.4779962024
10 1E-10 -12.3817068259 -8.3017068259 -4.2907068259
10.5 3.1623E-11 -14.3498086581 -9.7698086581 -5.2588086581
11 1E-11 -16.3439630306 -11.263963031 -6.2529630306
11.5 3.1623E-12 -18.3425961649 -12.762596165 -7.2515961649
12 1E-12 -20.3424540597 -14.26245406 -8.2514540597
12.5 3.1623E-13 -22.3448429331 -15.764842933 -9.2538429331
13 1E-13 -24.3691279634 -17.289127963 -10.2781279634
13.5 3.1623E-14 -26.5579498372 -18.977949837 -11.4669498372
14 1E-14 -29.2136719608 -21.133671961 -13.1226719608
14.5 3.1623E-15 -32.1576901444 -23.577690144 -15.0666901444
15 1E-15 -35.1516736706 -26.071673671 -17.0606736706
15.5 3.1623E-16 -38.1510674141 -28.571067414 -19.0600674141
16 1E-16 -41.1510067419 -31.071006742 -21.0600067419
16.5 3.1623E-17 -44.1510006742 -33.571000674 -23.0600006742
17 1E-17 -47.1510000674 -36.071000067 -25.0600000674
17.5 3.1623E-18 -50.1510000067 -38.571000007 -27.0600000067
18 1E-18 -53.1510000007 -41.071000001 -29.0600000007
18.5 3.1623E-19 -56.1510000001 -43.571 -31.0600000001
19 1E-19 -59.151 -46.071 -33.06
19.5 3.1623E-20 -62.151 -48.571 -35.06
20 1E-20 -65.151 -51.071 -37.06

GRAFICA
 [Pb(CO3)2 2-] [Pb(OH)3-] [Pb(OH)4 2-] [Pb(OH)2] [Pb(OH)+] [H2CO3]
-33.6580005306 -25.0600005306 -60.8490005306 -21.1200005306 -10.7100005306 -2.0000002
-31.6580016779 -23.5600016779 -57.8490016779 -20.1200016779 -10.2100016779 -2.0000006
-29.6580053061 -22.0600053061 -54.8490053061 -19.1200053061 -9.7100053061 -2.0000019
-27.6580167794 -20.5600167794 -51.8490167794 -18.1200167794 -9.2100167794 -2.0000061
-25.6580530626 -19.0600530626 -48.8490530626 -17.1200530626 -8.7100530626 -2.0000193
-23.6581678131 -17.5601678131 -45.8491678131 -16.1201678131 -8.2101678131 -2.0000611
-21.6585308159 -16.0605308159 -42.8495308159 -15.1205308159 -7.7105308159 -2.0001931
-19.6596800216 -14.5616800216 -39.8506800216 -14.1216800216 -7.2116800216 -2.0006102
-17.6633268002 -13.0653268002 -36.8543268002 -13.1253268002 -6.7153268002 -2.0019267
-15.6749784823 -11.5769784823 -33.8659784823 -12.1369784823 -6.2269784823 -2.0060639
-13.7128073449 -10.1148073449 -30.9038073449 -11.1748073449 -5.7648073449 -2.0188932
-11.83688164 -8.73888164 -28.02788164 -10.29888164 -5.38888164 -2.057136
-10.1964424943 -7.5984424943 -25.3874424943 -9.6584424943 -5.2484424943 -2.1597633
 -8.8934624288 -6.7954624288 -23.0844624288 -9.3554624288 -5.4454624288 -2.3813418
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