Brenntag Polska Sp.z o.

o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
(48/77) 4721500, (48/77) 4721600

diacetone alcohol
Version: V Date of compilation: 01.11.2002
Revision date: 26.01.2017

Safety Data Sheet

legal basis:
Comission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council
on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)

SECTION 1:Identification of the substance/mixture and of the company/undertaking

1.1.Product identifier
Trade name: diacetone alcohol
Identifier: 603-016-00-1
Product code: 150021
REACH registration number 01-2119473975-21-XXXX
Composition for label/Other name(s) Diacetone alcohol, 4-hydroxy-4-methyl-2-pentanone.,

1.2.Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Industrial uses:
substance distribution, formulation and repackaging, use in coatings, use in cleaning agents, lubricants, use in agrochemicals, use in functional fluids,
Laboratory chemicals, water treatment chemicals
Professional uses:
use in coatings, use in cleaning agents, Laboratory chemicals
Consumer uses:
use in coatings, use in cleaning agents, use in agrochemicals
Uses advised against:
other than named above
1.3.Details of the supplier of the safety data sheet
Name and address: Brenntag Polska Sp.z o.o
ul. Bema 21, 47-224 Kędzierzyn-Kożle
Poland
Phone number: (48/77) 4721500
Fax number: (48/77) 4721600
e-mail address for a competent person kch@brenntag.pl
responsible for the safety data sheet:

1.4.Emergency telephone number

998 or 112, or contact with the nearest local Fire Departmen

SECTION 2:Hazards identification

2.1.Classification of the substance or mixture
General hazards
This product is classified as hazardous according to current regulations
Health hazards
Eye Irrit. 2 Eye irritation, Category 2 H319 Causes serious eye irritation
STOT SE 3 Specific target organ toxicity — single exposure, Category H335 May cause respiratory irritation
3

Physical hazards
not applicable
Environmental hazards
not applicable
2.2.Label elements
Hazard pictograms:

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diacetone alcohol
Signal Word:
Warning
Hazard statements:
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/ spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501a Dispose of contents/container to licensed waste disposal plant
2.3.Other hazards
This substance does not fullfill the PBT or vPvB criteria accorging to Annex XIII to REACH Regulation (EC) 1907/2006
Heating may produce combustible vapour which can form explosive mixture with air.

SECTION 3:Composition/information on ingredients

3.1.Substances
Concentration Substance CAS WE Index number REACH registration number Hazard class
value
>= 99 % Diacetone alcohol 123-42-2 204-626-7 603-016-00-1 01-2119473975-21-XXXX Eye Irrit. 2, H319, STOT SE 3, H335

See Section 16 for the full text of the H statements

SECTION 4:First aid measures

4.1.Description of first aid measures
Inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products. Consult a physician.
Skin contact
Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water. Consult a physician.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a specialist.
Ingestion
Do NOT induce vomiting. Do not give anything to drink. Ensure doctor's assistance.
4.2.Most important symptoms and effects, both acute and delayed
Symptoms and effects:
Symptoms and effects
eye irritation, Respiratory irritation. gastrointestinal discomfort, dizziness, Headache, nausea
4.3.Indication of any immediate medical attention and special treatment needed
Show this safety data sheet to the doctor in attendance.

SECTION 5:Firefighting measures

5.1.Extinguishing media
Suitable extinguishing media
foam, dry powder, carbon dioxide (CO2)
Unsuitable extinguishing media
high volume water jet
5.2.Special hazards arising from the substance or mixture
Vapors form explosive mixtures with air. Closed containers exposed to fire or high temperatures may explode due to increase of the internal pressure .
5.3.Advice for firefighters
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Keep containers and surroundings cool with
water spray. Wear self-contained breathing apparatus and full protective clothing.

SECTION 6:Accidental release measures

6.1.Personal precautions, protective equipment and emergency procedures
Prevent unauthorised persons entering the danger zone. Handling accident effects should be done by trained employees equipped with suitable protective
equippment. Avoid skin and eyes contamination. Do not breathe in vapors. Do not smoke. Remove all sources of ignition. Do not use sparking tools.
6.2.Environmental precautions
Prevent from entering the sewerage system, watercourses and soil. In case of environment contamination, inform appropriate services.
6.3.Methods and material for containment and cleaning up
Stop the spillage. Soak up with inert absorbent material. Pick up and transfer to properly labelled containers. Transfer for disposal. Do not use sparking
tools. Clean contaminated surface thoroughly. Washings should be collected and disposed of as a waste.
6.4.Reference to other sections
More information about suitable personal protective equipment is given in section 8 .
Dispose of in accordance with the recommendations given in Section 13.

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diacetone alcohol
SECTION 7:Handling and storage
7.1.Precautions for safe handling
Avoid to accumulation of electrostatic charges. No smoking. Do not use sparking tools. Use proper bonding and/or ground procedures. Ensure suitable
ventilation. Electrical installations / working materials must comply with the technological safety standards. Handle in accordance with good industrial
hygiene and safety practice. Avoid inhalation, ingestion and contact with skin and eyes. Use personal protective equipment, Smoking, eating and drinking
should be prohibited in the application area. Wash hands before every break and after work. Ensure the emergency shower and eye bath in the workplace.
7.2.Conditions for safe storage, including any incompatibilities
Store in original packagings. Protect from frost, heat and sunlight. Recommended storage temperature: <, 43°C, Keep away from heat, flame sparks and
other ignition sources. Store away from strong oxidizing agents. Store away from strong bases. Storage under nitrogen atmosphere is recommended.
Storage containers should be earthed and bonded. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Suitable
packages: Stainless steel. Carbon steel. Unsuitable packages: Plastics.
7.3.Specific end use(s)
no data available.

SECTION 8:Exposure controls/personal protection

8.1.Control parameters
DNEL value
Diacetone alcohol DNEL value for workers by inhalation acute exposure Local effects 240 mg/m³
DNEL value for workers through skin Long-term Systemic effects 9,4 mg/kg
contact exposure bw/day
DNEL value for workers by inhalation Long-term Systemic effects 66,4 mg/m³
exposure
DNEL value for workers by inhalation Long-term Local effects 66,4 mg/m³
exposure
DNEL value for general by inhalation acute exposure Local effects 120 mg/m³
population
DNEL value for general through skin Long-term Systemic effects 3,4 mg/kg
population contact exposure bw/day
DNEL value for general by inhalation Long-term Systemic effects 11,8 mg/m³
population exposure
DNEL value for general after ingestion Long-term Systemic effects 3,4 mg/kg
population exposure bw/day
DNEL value for general by inhalation Long-term Local effects 11,8 mg/m³
population exposure

PNEC value
Diacetone alcohol PNEC value Fresh water 2 mg/l
PNEC value Intermittent releases 1 mg/l
PNEC value Marine water 0,2 mg/l
PNEC value Sediment (Fresh water) 9,06 mg/l
PNEC value Sediment (Marine water) 0,91 mg/l
PNEC value Soil 0,63 mg/l
PNEC value Sewage treatment plant (STP) 82 mg/l

Occupational exposure limits

Diacetone alcohol NDS 240 mg/m³

Comments
Poland. OELs - Regulation of the Minister of Labour and Social Policy, of 6 June 2014; Journal of Laws 2014, item 817
Biological limit values comments
not available
Recommended monitoring procedures
Regulation of the Minister of Health on tests and measurements applicable for hazardous substances and other adverse factors which are present in the
workplace, of 2 February 2011 (Journal of Laws No33, item 166).
8.2.Exposure controls
Appropriate engineering controls
Provide adequate ventilation.
Ensure that eyewash stations and safety showers are close to the workstation location.
Individual protection measures
Respiratory protection
Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures Breathing
apparatus with filter.
Eye /face protection
Tightly fitting safety goggles
Skin and hand protection

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diacetone alcohol
Protective gloves complying with EN 374. Gloves must be inspected prior to use.
Other protection equipment
Protective clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Reference to regulations
Individual protection measures should satisfy the requirements specified in the Regulation of the Minister of Economy on basic requirements for personal
protection controls, of 21 December 2005 (Journal of Laws No 259, item 2173).
General advice
Do not eat, drink or smoke when using this product. Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Environ. exposure controls
Prevent entry into drains, waterways, sewers and soil.

SECTION 9:Physical and chemical properties

9.1.Information on basic physical and chemical properties
Physical state Colour
Appearance: liquid colorless

Odour: pleasant

Odour threshold: no data available

pH: no data available

Melting point/freezing point: -44 °C

Initial boiling point and boiling range: 167,9 °C

Flash point: 62,7 °C

Evaporation rate: no data available

Flammability (solid, gas): Not applicable.

Upper flammability or explosive limits: 6,90 % vol

Lower flammability or explosive limits: 1,80 % vol

Vapour pressure: 1,29 hPa 20 °C

Vapour density: 1,005

Relative density: 0,94 20/20 °C

Solubility: Water. miscible

Alcohol. miscible
Ether. miscible
Aromatic hydrocarbons. miscible
organic solvents miscible

Partition coefficient: n-octanol/water: -0,09

Auto-ignition temperature: 643 °C at 1013 hPa

Decomposition temperature: no data available

Viscosity: Dynamic viscosity. 2,798 mPa.s 25 °C

Explosive properties: Not explosive.

Oxidising properties: No data available.

9.2.Other information
Minimum ignition energy: no data available

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diacetone alcohol
Conductivity: no data available

Surface tension: no data available

Density: 92 kg/dm³ 20 °C

Additional information Molecular weight 116,16 g/mol

SECTION 10:Stability and reactivity

10.1.Reactivity
No data available.
10.2.Chemical stability
Stable at normal ambient temperature and pressure.
10.3.Possibility of hazardous reactions
No data available.
10.4.Conditions to avoid
Heat, flames and sparks. Avoid static discharge.
10.5.Incompatible materials
Strong oxidizing agents. Strong bases.
10.6.Hazardous decomposition products
Burning of the material can produce: Carbon monoxide. Carbon dioxide.

SECTION 11:Toxicological information

11.1.Information on toxicological effects
Acute oral toxicity
Diacetone alcohol LD50 3 002 mg/kg Rat male and female OECD Test Guideline
401

Acute dermal toxicity

Diacetone alcohol LD0 > 1 875 mg/kg Rat male and female OECD Test Base on available
Guideline 402 data product is
not classificated

Acute inhalation toxicity

Diacetone alcohol LC0 >= 7,6 mg/l 4h Rat male and OECD Test vapour Base
female Guideline 403 on available
data product
is not
classificated

Acute toxicity - other exposure routes

No data available.
Skin corrosion/irritation
Diacetone alcohol Not irritating Rabbit OECD Test Guideline 404

Serious eye damage/irritation

Diacetone alcohol Eye irritation Rabbit OECD Test Guideline 405

Respiratory sensitisation
No data available.
Skin sensitisation
Diacetone alcohol Maximisation Test (GPMT) not sensitizing Guinea pig OECD Test Guideline 406

Germ cell mutagenicity

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diacetone alcohol
Diacetone alcohol Ames test OECD Test Guideline 471 with and without
metabolic activation
nagative
Bacterial Reverse Escherichia coli OECD Test Guideline 471 with and without
Mutation Test metabolic activation
nagative
In vitro Mammalian Cell Mouse OECD Test Guideline 476 with and without
Gene Mutation Test metabolic activation
nagative
In vitro Mammalian OECD Test Guideline 473 with and without
Chromosomal Aberration metabolic activation
Test nagative
Genotoxicity in vivo nagative

Summary
Carcinogenicity

Summary
No carcinogenic effects.
The prodcut was not tested.
Data are based on products of similar structure or composition.
Reproductive toxicity
Diacetone alcohol Screening for 300 mg/kg Rat male and female OECD Test oral
reproductive/de Guideline 422
velopmental
toxicity NOAEL
Parent
Screening for 300 mg/kg Rat male and female OECD Test oral
reproductive/de Guideline 422
velopmental
toxicity NOAEL
F1 generation
Teratogenicity No foetal effects.

Summary
STOT-single exposure

Summary
May cause respiratory irritation
STOT-repeated exposure
Diacetone alcohol NOAEL 100 mg/kg 44 days Rat male and orally OECD Test
bw/day female Guideline 422
NOAEC 4 685 mg/m³ 6 weeks Rat male and OECD Test
female Guideline 412

Summary
Based on the available data, there was no risk of toxicity for target organs after a repeated exposure.
Aspiration hazard
No data available.
Information on likely routes of exposure
Eye contact.
Inhalation.
Ingestion.
Symptoms related to the physical, chemical and toxicological characteristics
central nervous system depression
gastrointestinal discomfort
Headache
dizziness
nausea
Delayed and immediate effects as well as chronic effects from short and long-term exposure
in high concentrations
vapors may cause:
eye irritation
Respiratory irritation.

SECTION 12:Ecological information

12.1.Toxicity

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diacetone alcohol
Diacetone alcohol Acute toxicity LC50 > 100 mg/l 96 h Oryzias latipes OECD Test semi-static
to fish Guideline 203 test
Acute toxicity EC50 1 000 mg/l 48 h Daphnia OECD Test Immobilizatio
to aquatic magna (Water Guideline 202 n semi-static
invertebrates flea) test
Toxicity to NOEC 1 000 mg/l 72 h Pseudokirchne OECD Test Growth
aquatic plants riella Guideline 201 inhibition
subcapitata static test
(green algae)
Toxicity to ErC10 > 429 mg/l 72 h Pseudokirchne OECD Test Growth
aquatic plants riella Guideline 201 inhibition
subcapitata static test
(green algae)
Toxicity to ErC50 > 1 000 mg/l 72 h Pseudokirchne OECD Test Growth
aquatic plants riella Guideline 201 inhibition
subcapitata static test
(green algae)
Toxicity to EC50 825 mg/l 16 h Pseudomonas OECD Test Respiration
microorganis putida Guideline 201 inhibition
ms static test
Chronic NOEC 100 mg/l 21 days Daphnia OECD Test reproduction
toxicity to magna (Water Guideline 211 rate semi-
aquatic flea) static test
invertebrates

12.2.Persistence and degradability

Diacetone alcohol Biodegradability 98,5 % 28 days OECD Test Guideline 301A

Summary
Readily biodegradable
12.3.Bioaccumulative potential

Summary
Does not bioaccumulate.
12.4.Mobility in soil

Summary
Not expected to adsorb on soil.
12.5.Results of PBT and vPvB assessment
This substance does not fullfill the PBT or vPvB criteria accorging to Annex XIII to REACH Regulation (EC) 1907/2006
12.6.Other adverse effects
no data available

SECTION 13:Disposal considerations

13.1.Waste treatment methods
Comply with below named regulations:
Waste Disposal Law, of 14 December 2012 (Journal of Laws 2013, item 21), with further amendments.
Law on packages and spent packages, of 13 June 2013 (Journal of Laws 2013, item 888).
The generation of waste should be avoided or minimised wherever possible. Do not dispose of together with household Waste. Do not discharge to
sewage systems, to soil or to water reservoirs. Send to a licensed Waste management company. Dispose of by burning in special appliances compliant with
current legislation concerning Waste disposal. Do not reuse empty containers. Dispose of in accordance with local regulations.
Waste code: 07 01 04* Other organic solvents, washing liquids and mother liquors.
Regulation of the Minister of Environment on Wastes catalogue, of 9 December 2014 (Journal of Laws 2014, item 1923).

SECTION 14:Transport information

14.1.UN number
Transport type UN Number
ADR N/A
RID N/A
ADN N/A
IMDG N/A
ICAO N/A

14.2.UN proper shipping name

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diacetone alcohol
Transport type UN proper shipping name
ADR not subject to transport regulations
RID not subject to transport regulations
ADN not subject to transport regulations
IMDG not subject to transport regulations
ICAO not subject to transport regulations

14.3.Transport hazard class(es)

Transport type Transport hazard class: Classification code: Hazard identification Tunnel restriction code: Labels numbers:
number:
ADR not relevant not relevant not relevant - not relevant
RID not relevant not relevant not relevant - not relevant
ADN not relevant not relevant not relevant - not relevant
IMDG not relevant not relevant not relevant - not relevant
ICAO not relevant not relevant not relevant - not relevant

14.4.Packing group
Transport type Packing group:
ADR not relevant
RID not relevant
ADN not relevant
IMDG not relevant
ICAO not relevant

14.5.Environmental hazards
The product does not pose a hazard to the environment in accordance with the criteria of the UN Model Regulations.
14.6.Special precautions for user
not available
14.7.Transport in bulk according to Annex II of Marpol and the IBC Code
not available

SECTION 15:Regulatory information

15.1.Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation
and Restriction of Chemicals (REACH),
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances
and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (OJ L 353, 31.12.2008, p. 1).
Law on chemical substances and mixtures thereof, of 25 February 2011 (Journal of Laws № 63, item 322), with further amendments
15.2.Chemical safety assessment
A Chemical Safety Assessment has been carried out for this substance.

SECTION 16:Other information

Changes of previous version
General revision
Key or legend to abbreviations and acronyms used in the safety data sheet
Asp. Tox. - Aspiration hazard
Aquatic Acute - Hazardous to the aquatic environment - Acute
Aquatic Chronic - Hazardous to the aquatic environment - Chronic
Ozone - Hazardous for the ozone layer
Lact. - Effects on or via lactation
NDS - Maximum permissible exposure level/concentration
NDSCH - Maximum short-term exposure level/concentration
NDSP - Maximum permissible ceiling exposure level/concentration
vPvB (Substance) very persistent and very bioaccumulating
PBT (Substance) persistent, bioaccumulating and toxic
PNEC – Predicted No Effect Concentration
DNEL – Derived No Effect Level
LD50 - Lethal dose 50; dose/amount of a substance which kills 50 % of the test population
LC50 - Lethal concentration; concentration of a substance which kills 50 % of the test population
LOEC - Lowest Observed Effect Concentration
NOEL No Observed Effect Level
NOEC - No Observed Effect Concentration
ECX - Effective concentration; concentration of a substance which produces X % effect response
ADR – Agreement Concerning the International Carriage of Dangerous Goods by Road
ADN – Agreement Concerning the International Carriage of Dangerous Goods by Inland Waters
RID – Regulations Concerning the International Carriage of Dangerous Goods by Rail
IMDG – International Maritime Dangerous Goods Code

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diacetone alcohol
ICAO/IATA – International Civil Aviation Organization/International Air Transport Association
UVCB - Substances of Unknown or Variable composition, Complex reaction products or Biological materials
STOT RE - Specific target organ toxicity — repeated exposure
Expl. - Explosive
Flam. Gas - Flammable gas
Flam. Aerosol - Flammable aerosol
Ox. Gas - Oxidising gas
Press. Gas - Gases under pressure
Flam. Liq. - Flammable liquid
Flam. Sol. - Flammable solid
Self-react. - Self-reactive substance or mixture
Pyr. Liq. - Pyrophoric liquid
Pyr. Sol. - Pyrophoric solid
Self-heat. - Self-heating substance or mixture
Water-react. - Substance or mixture which in contact with water emits flammable gas
Ox. Liq. - Oxidising liquid
Ox. Sol. - Oxidising solid
Org. Perox. - Organic peroxide
Met. Corr. - Substance or mixture corrosive to metals
Acute Tox. - Acute toxicity
Skin Corr. - Skin corrosion
Skin Irrit. - Skin irritation
Resp. Sens. - Respiratory sensitization
Skin Sens. - Skin sensitization
Muta. - Germ cell mutagenicity
Carc. - Carcinogenicity
Repr. - Reproductive toxicity, Category 1A
STOT SE - Specific target organ toxicity — single exposure
Key literature references and sources for data
This safety data sheet has been prepared based on the MSDS provided by the manufacturer or / and internet databases and current regulations.
Advice on any training appropriate for workers to ensure protection of human health and the environment
People involved in the handling of the product should be trained in the handling, safety and hygiene
List of relevant hazard statements and/or precautionary statements
H319 Causes serious eye irritation
H335 May cause respiratory irritation
not applicable
P261 Avoid breathing dust/fume/gas/mist/vapours/ spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P337+P313 If eye irritation persists: Get medical advice/ attention.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501a Dispose of contents/container to licensed waste disposal plant
Other Information
This safety data sheet is prepared to provide downstream users information about product.
The information contained in this safety data sheet refer to the product in the form in which it is delivered
The data contained in this safety data sheet are based on our current knowledge and experience and describe the product in terms ofsafety requirements.
These data can not be considered in any case describe the product (as product specification).

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