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TO GEOCHEMISTRY
Elements
White P6 PERIODENSYSTEM
Here the e-configuration for the elements – in some periods special shells are filled before other sub-ordinated shells will
be completed. The K-shell contains a 1s configuration f.e. and He fills the places with two e. The L-shell contains two
Why
sub-shells (2s and 2p) and can hold 8 e. etc. The 4. Period: N-shell has several sub-shells, but instead of filling the 4p
shell, elements completing the 3d (energetic more convenient), then follows the 4p shell and these are then special
that
elements: the first transition metals. etc. -or elements like Rare earth elements including Lanthanides and Actinides.
diagram?
E of each e is individual and characteristic - it the e gets ‘exited’ (E adding) or
if it goes back on its place (E release)
BONDING
Ionic Bonds
• When an atom loses or Sodium atom (Na) Chlorine atom (Cl)
gains electrons, it
becomes electrically
charged
Complete
outer shells
• Ionic bonds are formed
between oppositely
charged ions
Ionic Pairs
Covalent
Pairs
Metallic Bonding
• atomic nuclei and inner filled electron shells in a sea of electrons made
up of unbound valence electrons or not equally shared
IONIC POTENTIAL= charge : radius and is a measure of solubility: the higher the IP, the lower S.
Different groups of elements can be distinguished:
Incompatibility and compatibility:
compatible: are mostly these elements which are retained in the residual solids during Partial
Melting and extracted in the crystallizing solids during Fractional Crystallisation;
incompatible vice versa
6. First series transition metals: Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn
More complex chemistry than other elements: 2-x+ valences; higher EN partly covalent bonds with S
f.e.; geometry of the d-orbital which favors a specific orientation of coordinating anions; solubility
depends on existing anions in the solution; behavior in magma is variable:
highly incompatible: Ti (upper mantle), Cu, Zn to very compatible: Sc, Cr, Ni, Co, Ti (in subduction
zones) as a function of composition
everything else
Ir 0.6-5 ppm
It is assumed that meteorites reflect the EARTH composition at 4.5-4.6 Ga.
Mineralogy and chemistry of chondrites and “primitive” mantle rocks.
Typical chemical compositions of the most important rock types
• Abundance
• fractionation