13.

- 𝑃𝑣 𝜑 = 𝑘
12
𝑃 = 𝑘𝑣 𝜑
10
8
Ln p=ln k +ln v- φ

6 Ln P =ln K – φ ln V
4
Ln P= - φln V + ln V
2
Y=mx + b
0
0 1 2 3 4 m= - φ
10
ln( )𝑏𝑎𝑟
3.78
𝜑= 3.3 =3.5
ln( )𝑙
2.5

M= -3.5

14.- Datos : Cp=7/2 R

N=l mol x2(g) CP=5/2 R

r=1.4

FORMULA :
𝑃𝐵 𝑃𝐶
𝑇𝐵
= 𝑇𝐶

𝑇𝐵𝑃𝐶
𝑇𝑐 = 𝑃𝐵

150B exp(-)

∆u=nCv∆

Q=∆H=nCP∆V

SUSTUTUCION
300.7 𝐾∗1𝑏𝑎𝑟
𝑇𝐶 = 10𝑏𝑎𝑟

TC=30.07K

∆u=1mol *5/2 + 8.314 J/Kmol*(300.7-58.06)

∆u=5043.27J

Q=∆H=1mol *7/2*8.314J/Kmol *(300.7-58,06)k

Q=∆H=-7060.58J
 10𝑏𝑎𝑟 101.325𝐽
𝑊= (0.4827𝐿) ∗
1.013 1𝐴𝑇𝑀𝐿

W=-482.62J

FORMULASA: SUSTITULOCION
𝑝1 1
𝑙𝑛 𝑙𝑛
𝑝2 10
ᶲ=r= 𝑣1 𝑉2 = 𝑒 + 𝑙𝑛2.5
𝑙𝑛 1.4
𝑣2

𝑝1
𝑙𝑛 +𝑙𝑛𝑉2
𝑝2
𝑉2 = 𝑒 𝑟
𝑉2 = 0.4827

10𝑏𝑎𝑟∗0.4827𝐿
Pv=nRt 𝑇2 = 𝑏𝑎𝑟−𝐿
1𝑚𝑙∗8.314∗10−2
𝐾∗𝑚𝑜𝑙

TA=TAVA/Nr TA=58.06K
58.06𝐾∗2.5𝐿
Va/Ta=VB/TB 𝑇𝐵 = 0.4827𝐿

TB=TAVB/VA 𝑇𝐵 = 300.7

FORMULAS: sutitucion

150°C CBmpp(+) Q=∆=-1mol*5/2*8.314*(30.07-300.7)K

Q=∆u=w=nCr∆T Q=∆u=-5625.046J

∆H=nCp∆T ∆H=-1mol*7/2*8.314L/K*mol *(58.06K – 30.07K)

W=0 ∆H=-7875.06J

ADIAB EXP(-)REV Q=∆=-1mol*5/2*8.314*(30.07-300.7)K

Q=∆u=w=nCr∆T Q=∆u=+5625.046J

∆H=nCp∆T ∆H=-1mol*7/2*8.314L/K*mol *(58.06K – 30.07K)

Q=0 ∆H=7875.06J

∆uciclo=0 ∆uciclo= -5043.27J + 5625.046J – 581.776J=0

∆Hciclo=0 ∆Hciclo=-7060.58J + 7875.05J – 814.47J=0

Qciclo=∑𝑛𝑟=1 𝑄𝑖 Qciclo=-7060.58J + 7875.05J + 0= 814.47J

Wciclo=∑𝑛𝑟=1 𝑤𝑖 Wciclo= -482.82 + 0 – 581.776J = -1064.60J

15.-

DATOS: SUSTITUCION
𝑎𝑡𝑚∗𝑙
1𝑚𝑜𝑙∗0.082 ∗353.15𝑘
𝑘∗𝑚𝑜𝑙
N=1mol CH4 𝑉1 = 0.9872 𝑎𝑡𝑚

P1=1 bar =0.9872 atm V1=29.33L

1.31 1𝑏𝑎𝑟
T1=80°C=353.15 K 𝑉2 = √ ∗ 29.33𝐿 = 170.09𝐿
0.1𝑏𝑎𝑟

𝐶𝑝 29.33𝐿 1.31−1
= 𝑟 = 1.31𝐾 T2=353.15K( ) =204.79
𝐶𝑟 170.09𝐿

Exp.(-) rev ADIAB ∆H=1mol * 35.31-8.314)J/Kmol

P2=0.1 bar =0.09872atm ∆H=-5238.59 J

a)V2 * V1=? ∆u=-1mol(35.31-8.314)J/Kmol(204.79-353.15)K

b) T=P ∆u= - 4005.13J

c) ∆u,∆H

16.-

DATOS: SUSTITUCION:
𝑎𝑡𝑚∗𝐿
𝜕𝑢 1𝑚𝑜𝑙∗0.082 ∗298.15𝐾
𝐾∗𝑚𝑜𝑙
( ) = 𝑁2 =? 𝑉=
𝜕𝑣 1𝑎𝑡𝑚

𝐿2 ∗𝑎𝑡𝑚
A=1.3481 𝑚𝑜𝑙 2
V=24.44 L

𝐿2 ∗𝑎𝑡𝑚
𝜕𝑢 1.34891
𝑚𝑜𝑙2
T=1atm ( )=
𝜕𝑣 (24.44𝐿)2

𝜕𝑢 𝑎𝑡𝑚
L=1mol ( ) = 2.26 ∗ 10−3
𝜕𝑣 𝑚𝑜𝑙 2