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080
T 47
Contents
Foreword .................................................................................................................................................... II
1 Scope.....................................................................................................................................................1
2 Normative reference ............................................................................................................................1
3 Terms and definitions..........................................................................................................................1
3.1 Zinc-air battery .............................................................................................................................. 1
3.2 Mechanical switching zinc-air battery........................................................................................... 1
3.3 Cell 1
3.4 Battery module .............................................................................................................................. 1
3.5 Rated capacity ............................................................................................................................... 1
4 Symbol ..................................................................................................................................................1
5 Requirements .......................................................................................................................................2
5.1 Cell 2
5.2 Battery module .............................................................................................................................. 3
6 Test methods ........................................................................................................................................3
6.1 Test conditions............................................................................................................................... 3
6.2 Cell test.......................................................................................................................................... 4
6.3 Battery module test........................................................................................................................ 6
6.4 Test procedures.............................................................................................................................. 8
7 Inspection rules....................................................................................................................................9
7.1 Inspection items............................................................................................................................. 9
7.2 Factory inspection ....................................................................................................................... 10
7.3 Type test ...................................................................................................................................... 10
8 Mark, package, transport and storage ............................................................................................10
8.1 Mark ............................................................................................................................................ 10
8.2 Package ....................................................................................................................................... 11
8.3 transport....................................................................................................................................... 11
8.4 Storage......................................................................................................................................... 11
I
GB/T 18333.2—2015
Foreword
This standard was drafted according to the rules stated in GB/T 1.1-2009.
This standard shall replace GB/Z 18333.2-2001 Zinc-Air Batteries for Electric Road Vehicle; compared
with GB/Z 18333.2-2001, the main technical changes are as follows, except editorial changes:
- Modify test subjects and corresponding test items, assessment on safety of cells and assessment on
electric property and safety of battery module;
- Add I5 test capacity, I3 test power characteristic, high and low temperature discharge capacity,
charge retention and battery repeatability after the cathode and electrolyte are replaced;
- Add safety cell requirements and test methods (see 5.1.10 and 6.2.10);
- Add requirements and test methods of battery module, appearance, polarity, dimensions and quality,
pourability, discharge performance, safety and vibration resistance (see 5.2 and 6.3);
- Modify requirements and test methods of working life of air anode (see 5.1.9 and 6.2.9).
This standard is under the jurisdiction of National Technical Committee of Auto Standardization
(SAC/TC 114).
Drafting unit of this standard: Wuhan Hongyuanweili New Energy Technology Co., Ltd., Dongfeng
Yangste Automobile (Wuhan) Co., Ltd., Tianjin University, China Electronics Technology Group
Corporation Eighteenth Institute, and China Automotive Technology & Research Center.
Main drafters of this standard: Liu Weichun, Lei Hongjun, Qin Xue, Ma Hongbin and Meng Xiangfeng.
The release of all previous versions of the standards substituted by this standard is as follows:
— GB/Z 18333.2—2001.
II
GB/T 18333.2—2015
1 Scope
This standard specifies the terms and definitions, symbols, requirements, test methods,
inspection rules, marks, packages, transport and storage of zinc-air battery of electric
vehicle (hereafter referred to as battery).
This standard applies to the zinc-air battery of electric vehicle that supplements energy by
mechanical switching.
2 Normative reference
The following documents are necessary for the application of this document. For dated
normative references, only the dated version applies. For references undated, their latest
versions (including all amendments) are applicable to this document.
GB/T 2423.17 – 2008 Environmental Testing for Electric and Electronic Products - Part 2:
Test Methods – Test Ka: Salt Mist (IEC 60068- 2-ll:1981, IDT)
GB/T 2900.41 Electro-technical Terminology--Primary Cells and Batteries
GB/T 19596 Terminology of Electric Vehicles
4 Symbol
The following symbols apply.
C5 - 5-hour-rate rated capacity, in ampere • hours (Ah);
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GB/T 18333.2—2015
C5‘– 5-hour-rate actual capacity after 7 days of standing, in ampere ·hours (Ah);
I3– 5-hour-rate discharge current, which is equal to C3/3, in amperes (A);
I3– 3-hour-rate discharge current, which is equal to C3/3, in amperes (A);
QT – Air supply volume theoretically required by the battery, in cubic meters per hour
(m3/h); n - number of cells;
R Nominal internal resistance of battery, in milliohms (mΩ);
5 Requirements
5.1 Cell
5.1.1 Appearance
According to inspection in 6.2.1, the battery shall be smooth and complete without
deformation, plaque, crack or alkaline liquor on surface, and its marks and signs are clear
and correct.
5.1.2 Polarity sign
According to inspection in 6.2.2, the polarity signs at battery terminal shall be correct.
5.1.3 Dimensions and quality
According to inspection in 6.2.3, the dimensions and quality of battery shall meet the
product technical conditions supplied by the enterprise.
5.1.4 Pourability
According to inspection in 6.2.4, no leakage is allowed on battery.
5.1.5 Discharge performance
According to inspection in 6.2.5, the average discharge capacity cannot be less than 95%
of nominal capacity when the discharge current is I5, and the average capacity is not less
than 65% when the current is I3.
5.1.6 Low-temperature characteristics
When the battery is tested under specified conditions, the discharge capacity of battery
shall be not less than 60% of initial rated capacity and its terminals and appearance are
intact according to inspection in 6.2.6.
5.1.7 High-temperature characteristics
When the battery is tested under specified conditions, the discharge capacity of battery
shall be not less than 80% of initial rated capacity and its terminals and appearance are
intact according to inspection in 6.2.7.
5.1.8 Charge retention
According to inspection in 6.2.8, the battery capacity measured shall be not less than 80%
of rated capacity.
5.1.9 Working life of air anode
When tested under specified conditions, the working life of air anode shall be not less than
300 cycles according to inspection in 6.2.9.
5.1.10 Safety and reliability
5.1.10.1 No explosion, fire or leakage is allowed when a short-circuit test is carried out according to
6.2.10.1.
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GB/T 18333.2—2015
5.1.10.2 No explosion or fire is allowed when a squeezing test is carried out according to 6.3.6.2.
5.1.10.3 No explosion or fire is allowed when a squeezing test is carried out according to 6.3.6.2.
5.1.10.4 No explosion, fire or leakage is allowed when a discharge test is carried out according to
6.3.6.5.
5.1.10.5 No explosion or fire is allowed when a salt mist test is carried out; the plaque within each
1cm2 of connecting sheet shall be less than 2mm2 and appears at two places as a
maximum.
5.2 Battery module
5.2.1 Appearance
According to inspection in 6.3.1, the battery shall be smooth and complete without bruise,
deformation, plaque, crack or alkaline liquor on surface, and its marks and signs are clear
and correct.
5.2.2 Polarity sign
According to inspection in 6.3.2, the polarity signs at battery terminal shall be correct.
5.2.3 Dimensions and quality
According to inspection in 6.3.3, the dimensions and quality of battery shall meet the
product technical conditions supplied by the enterprise.
5.2.4 Pourability
According to inspection in 6.3.4, no leakage is allowed on battery.
5.2.5 Discharge performance
According to inspection in 6.3.5 the discharge capacity cannot be less than 90% of nominal
capacity when the discharge current is I5, and the capacity is not less than 60% when the
current is I3.
5.2.6 Safety and reliability
5.2.6.1 No explosion or fire is allowed when a short-circuit test is carried out according to 6.3.6.1.
5.2.6.2 No explosion or fire is allowed when a squeezing test is carried out according to 6.3.6.2.
5.2.6.3 No explosion or fire is allowed when a drop test is carried out according to 6.3.6.3. 5.2.6.4
No explosion or fire is allowed when a heating test is carried out according to 6.3.6.4.
5.2.6.5 No explosion, fire or leakage is allowed when a discharge test is carried out according to
6.3.6.5.
5.2.6.6 According to inspection in 6.3.6.6, the product shall have necessary vibration resistance.
When tested under specified conditions, its discharge voltage shall be kept normal without
mechanical damage, leakage, fire or explosion.
6 Test methods
6.1 Test conditions
6.1.1 Environmental conditions
Unless otherwise specified, the test shall be carried out under the following environmental
conditions:
a) Test temperature: 25 °C±2 °C;
b) Relative humidity: 25%〜85%
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GB/T 18333.2—2015
c) Atmospheric pressure:86kPa〜106kPa;
d) Air supply volume: the air volume supplied for zinc-air battery in the test shall be
more than 4 times of theoretical air supply volume, or shall meet the manufacturer’s
requirement on air supply volume.
The theoretical air supply volume required by zinc-air battery is expressed by formula (1):
Wherein,
QT - Air supply volume theoretically required by zinc-air battery, in cubic meters per hour
(m3/h) at 1 standard atmospheric pressure;
n – number of cells.
6.1.2 Precision of test instrument, meter and apparatus
The precision of test instrument, meter and apparatus is shown in Table 1.
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GB/T 18333.2—2015
Wherein,
H – Charge retention, %;
C5’ – Actual capacity after 7 days of standing, in ampere ·hours (Ah);
C5 – Battery rated capacity, in amperes (Ah);
6.2.9 Working life of air anode
The working life of air anode shall be tested according to the following steps:
a) Replace the cell’s zinc electrode and electrolyte;
b) Keep still for 20min;
c) Discharge the tested battery cell sample at I5 (A) until the cut-off voltage reaches 0.7
V;
d) Repeat steps a)-c) as a cycle; recycle 300 times or find obvious electrolyte dipping
(i.e. there are more than two places of electrolyte dipping within 30 x 30 mm2 of air
cathode);
e) Number of accumulative cycles.
6.2.10 Safety and reliability test
All safety tests are conducted with sufficient environmental protection; remove the active
protection circuits, if any.
6.2.10.1 Short-circuit test
After fully charged in a mechanical switching way according to 6.1.3, the battery cell shall
be kept still for 30min at 25 °C ±2 °C, and use a proper conductor (with resistance <5 mn)
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GB/T 18333.2—2015
to force positive and negative terminals of battery directly short-circuited for 50s. Observe
for 1h.
6.2.10.2 Drop test
After fully charged in a mechanical switching way according to 6.1.3, the battery cell shall
be kept still for 30min at 25 T 士 2 °C; keep cell terminals downward, let it free drop onto
cement ground from a height of 1.5m, and observe for 1h.
6.2.10.3 Heating test
After fully charged in a mechanical switching way according to 6.1.3, the battery cell shall
receive an over-discharge test according to the following steps:
a) Place the battery cell into temperature chamber, heat the chamber at 5 °C/min to
130 °C ±2 °C, and then stop heating after keeping this temperature for 30min.
b) Observe for 1h.
6.2.10.4 Over-discharge test
After fully charged in a mechanical switching way according to 6.1.3, the battery cell shall
receive an over-discharge test according to the following steps:
a) The battery cell discharges at 2I3(A) till the cell voltage is up to 0V; then force to
discharge at 2I3(A) continuously for 30min;
b) Observe for 1h.
6.2.10.5 Salt mist test
After fully charged in a mechanical switching way according to 6.1.3, the battery cell shall
receive an over-discharge test according to the following steps:
Carry out salt mist continuously for 24h with the salt mist test methods of Test Ka in GB/T
2423.17-2008.
6.3 Battery module test
The battery module samples for testing shall meet the following conditions:
- Total voltage is not less than 5 times of battery cell voltage;
- The rated capacity of battery module is not less than that of cell.
6.3.1 Appearance
6.3.1.1 Appearance inspection
Carry out visual inspection to check whether the battery module is flat and dry without
bruise on surface.
6.3.1.2 Mark inspection
Carry out visual inspection to check whether the battery module marks are complete, clear
and correct.
6.3.2 Polarity sign
Measure terminal voltage of the tested battery module with a voltmeter, to check whether it
is consistent with the polarity sign of terminal.
6.3.3 Dimensions and quality
6.3.3.1 Dimension inspection
Measure dimensions of battery module with a measuring tool.
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GB/T 18333.2—2015
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GB/T 18333.2—2015
d) Maximum acceleration:30m/s2;
e) Vibration time:3h;
f) Observing for 1h.
6.4 Test procedures
6.4.1 See cell test procedures in Table 2.
1 Appearance 6.2.1
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GB/T 18333.2—2015
No. Test Item Chapter/Article No. of Inspection Method Battery Module No.
1 Appearance 6.3.1
8 Short-circuit 6.3.6.1 4#
9 Squeezing 6.3.6.2 5#
10 Drop 6.3.6.3 6#
11 Heating 6.3.6.4 7#
12 Over-discharge 6.3.6.5 8#
7 Inspection rules
7.1 Inspection items
See Table 4 for inspection classification, inspection items, Chapter/Article No. of
requirements, quantity of samples and inspection cycle.
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GB/T 18333.2—2015
High-temperature
7 5.1.7
discharge characteristics
Note: totally 25 battery cells and 12 battery modules are to be sampled; wherein, 4 cells
and 3 modules are used as standby.
7.2 Factory inspection
7.2.1 Prior to delivery, each batch of products shall receive factory inspection according to items
of room-temperature discharge performance inspection.
7.2.2 If one or more items are found non-conforming during factory inspection, return the product
to the production department for rework and general examination, and then resubmit it for
acceptance. If there are still one or more items found non-conforming during re-inspection,
the product will be judged non-conforming.
7.3 Type test
7.3.1 It is required to conduct type inspection in case of any of the following situations:
a) Commissioning of new products and transferring of old products;
b) Transfer between factories;
c) Resuming production after discontinued;
d) Major changes of structure, process or materials;
e) Once every two years.
7.3.2 Judgment rules: if one item is non-conforming during the type test, it will be deemed as
non-conforming.
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GB/T 18333.2—2015
6.2.10.6 Product name, model, specification, quantity, manufacturer name, address and
post code;
6.2.10.7 Product standard No.:
6.2.10.8 Net weight and gross weight of each box;
6.2.10.9 Indicate words such as “Damp-proof”, “Do not place upside down” and “Handle
gently”.
8.2 Packaging
8.2.1 The battery package shall meet damp-proof and vibration-resistant requirements.
8.2.2 The documents of attached products shall be placed inside the packaging box.
a) Packing list (referring to multiple packages);
b) Product qualification certificate:
c) Product Operation Instruction;
d) The package of zinc electrode must be sealed and isolated from air, and resistant to
vibration and damage.
8.3 transport
8.3.1 The product shall not be subject to severe mechanical collision, sun exposure or rainfall, or
placed upside down during transport.
8.3.2 The product shall be handled gently, but cannot be thrown, rolled or heavily pressed during
loading and unloading.
8.4 Storage
8.4.1 The product shall be stored at a dry, clean and well-ventilated place with temperature of
5 °C-35 °C.
8.4.2 The product shall be prevented from direct sunlight to avoid contact with any harmful gas
and liquid. The distance from heat sources (heating installation, etc.) is not less than 2m.
8.4.3 The product cannot be placed upside down or horizontally, or subject to any mechanical
impact or heavy load.
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National Standard of the People's Republic of China
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Printing date: April 29, 2015 F009A