Unknown solid +

NaOH(40%) 3ml

Ammonia odour on Yellow or brown Oily drops or -Ve

cold or after boiling color after layer of oil Hydrocarbons/Phenols/Carboxylic acid/Sod.salt of acid
Amm.salt of acid boiling Aniline salts
Acidity test
Solution of salt+2ml Carbohydrates
conc. HCl Soolution+1ml
BaCl2 -Ve Effervescence
-Ve White ppt. Hydrocarbons/phenols Carboxylic
Amm.salt of Amm.salt of -Ve /sod.salt of acid acid
Aliphatic acid Aromatic acid Aniline HCl
Metalic residue test Soluble in H2O Insoluble in
White ppt. Aliphatic acid H2O
N.S Confirmatory test Solution+2drops
Conc. H2SO4 test Aniline -Ve Black Aromatic acid
+CaCl2 of FeCl3 +shake
H2SO4 Hydrocarbons residue+Eff. N.S +CaCl2 Confirmatory
/phenols Sod.salt of acid test Solution+2drops
White ppt. Eff. +no Violet color Conc. H2SO4 test of FeCl3 +shake
Amm.Salicylat Buff ppt. White ppt.
on cold change Solution of ‫نفس اسكيم‬
e Amm.(Benzoat on cold -Ve
Amm.Oxalate solid+H2O ‫االمونيا‬ Eff. +no
e/Cinnamate/ (OR) Oxalic Violet color (Benzoic/Cinnamic/
Phthalate) Ethanol+2drops of
change Salicylic
White ppt. after Phthalic)acid
Eff. FeCl3 White ppt.
scratching +charring after Eff.
Amm.Tartarate Phthalein test Phthalein test
-Ve Any color(FeCl3 ‫ما‬ scratching +charring
Hydrocarbons ‫)عدا لون‬ Tartaric
White ppt. -Ve Pink color Phenols Eff. +yellow -Ve Pink color
Eff. +yellow
after bioling Amm.(Benzoate/ Amm.Phthalate White ppt. color Phthalic
color Solid+3ml (Benzoic/
Amm.Citrate Cinnamate) after bioling acid
H2O+bioling Cinnamic)
Citric acid
Unsaturation Oily drops
test
Naphthalene Unsaturation
test
Decolorization
Amm.cinnimate -Ve
Anthracene Decolorization
Cinnamic
-Ve
Amm.Benzoate
-Ve
Benzoic

Identification Monohydric Phenols Dihydric Phenols Trihydric Phenols

Phenol α-Naphthol β-Naphthol Catechol Resorcinol Hydroquinol Pyrogallol
of Phenols
FeCl3 Test Violet color Pale green and with excess of FeCl3 it Green color Violet color Green ppt. Red color
turns into brown color
Phthalein test Pink color Deep green color Pale green color Blue color Reddish solution+Green Blue violet color -Ve
fluorescence
 Unknown slution+one drop of I2

Violet/Black/Blue color -Ve

Starch Mono/Di Saccharides

Fehling's test

-Ve Orage/Red/Yellow ppt.

Sucrose (Glucose/Fructose/Maltose/Lactose)

Barafoed's test

Red ppt. -Ve

MonoSaccharides(Glucose/Fructose) DiSaccharids(Maltose/Lactose)

Silvanof's test

Reddish brown ppt. -Ve

Fructose Glucose