UNIVERSIDAD NACIONAL DEL CALLAO

FACULTAD DE INGENIERÍA QUÍMICA

Escuela Profesional de Ingeniería Química

ASIGNATURA: ANALISIS INTRUMENTAL

TEMA:

 “GRAFICAS POTENCIOMETRICAS”

INTEGRANTES:

 Moran Caballero Juan Pablo

PROFESOR:

 Ing.Mg. Ricardo Rodriguez Vilchez

BELLAVISTA 10 DE JUNIO DEL 2019

EJERCICIO 1
Ácido débil Vs Base Fuerte (NaOH 0.100M)
Volumen (ml) pH
0.00 2.89
2.00 4.52
4.00 5.06
10.00 5.89
12.00 6.15
14.00 6.63
15.00 7.08
15.50 7.75
15.60 8.40
15.70 9.29
15.80 10.07
16.00 10.65
17.00 11.34
18.00 11.63
20.00 12.00
24.00 12.41

Solución:
Volumen (ml) pH ∆𝑽𝟏 𝒅𝒑𝑯 ∆𝑽𝟐 𝒅𝟐 𝒑𝑯
𝒅𝑽 𝒅𝑽𝟐
0.00 2.89 1.00 0.815 2.00 -0.2725
2.00 4.52 3.00 0.27 5.00 -0.0329
4.00 5.06 7.00 0.13833 9.00 -0.00208
10.00 5.89 11.00 0.13 12.00 0.055
12.00 6.15 13.00 0.24 13.75 0.14
14.00 6.63 14.50 0.45 14.875 1.186
15.00 7.08 15.25 1.34 15.40 17.2
15.50 7.75 15.55 6.5 15.60 24.00
15.60 8.40 15.65 8.9 15.70 -11.00
15.70 9.29 15.75 7.8 15.825 -32.66
15.80 10.07 15.9 2.9 16.20 -3.683
16.00 10.65 16.5 0.69 17.00 -0.4
17.00 11.34 17.5 0.29 18.25 -0.07
18.00 11.63 19.00 0.185 20.50 -0.0275
20.00 12.00 22.00 0.1025
24.00 12.41
Gráficas:

dpH/dV Vs V(ml)
dpH/dV

V(ml)
 𝒅𝒑𝑯𝟐
Vs V(ml)
𝒅𝟐 𝑽
𝒅𝒑𝑯𝟐
𝒅𝟐 𝑽

V(ml)

EJERCICIO 2
[𝑂𝐻]%Vs Fem de celda

Volumen( ml) Fem( ph)

19.5 6.46
19.6 6.59
19.7 6.73
19.8 6.89
19.85 7.04
19.9 7.32
19.95 7.91
20.0 8.16
20.05 8.35
20.1 8.52
20.2 8.68
Solución:
V(ml) E(pH) ∆𝑽𝟏 𝒅𝒑𝑯 ∆𝑽𝟐 𝒅𝟐 𝒑𝑯
𝒅𝑽 𝒅𝑽𝟐
19.5 6.46 19.55 1.3 19.6 1.0
19.6 6.59 19.65 1.4 19.7 2.0
19.7 6.73 19.75 1.6 19.7875 18.66
19.8 6.89 19.825 3.0 19.85 52.0
19.85 7.04 19.875 5.6 19.9 124.0
19.9 7.32 19.925 11.8 19.95 -136.0
19.95 7.91 19.975 5.0 20.0 -24.0
20.00 8.16 20.05 3.8 20.05 -8.0
20.05 8.35 20.075 3.4 20.1125 -24.0
20.10 8.52 20.15 1.6
20.20 8.68

Gráficas:
𝒅𝒑𝑯𝟐
Vs V(ml)
𝒅𝟐 𝑽

V(ml)
EJERCICIO 3:
Redox –Volumen (KSCr2O7) Vs E (mV)
Volumen(ml) E(mV)
0 50
1 60
2 68
2.5 74
3 82
3.1 83
3.2 86
3.3 90
3.4 92
3.5 97
3.6 104
3.7 120
3.8 152
3.9 158
4 162
4.5 170
5 176

Volumen(ml) E(mV) ∆𝑽𝟏 𝒅𝑬 ∆𝑽𝟐 𝒅𝟐 𝑬

𝒅𝑽 𝒅𝑽𝟐
0 50 0.5 10 1 -2
1 60 1.5 8 1.875 5.33
2 68 2.25 12 2.5 8
2.5 74 2.75 16 2.9 -20
3 82 3.05 10 3.1 200
3.1 83 3.15 30 3.2 100
3.2 86 3.25 40 3.3 -200
3.3 90 3.35 20 3.4 300
3.4 92 3.45 50 3.5 200
3.5 97 3.55 70 3.6 900
3.6 104 3.65 160 3.7 1600
3.7 120 3.75 320 3.8 -2600
3.8 152 3.85 60 3.9 -200
3.9 158 3.95 40 4.1 -80
4 162 4.25 16 4.5 -8
4.5 170 4.75 12
5 176
Gráficas:
𝒅𝑬𝟐
Vs V(ml)
𝒅𝟐 𝑽

V(ml)