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] EGT-IP-OHM
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SECT ION 'A''
l .(b) "7iRf H20 lWT J-00 mol 1 25·0 °C セ@ 1·00 attn it 30· ooc am t ·00 atm W \iffifT t, Cfif
セ@ 3!itti\Cfi セN@ U, q;r qftR!i1 Fゥャmセ@ 1 セ@ セ@ セ@ 1
oac 1R 0-9970 g/cmJ wn
1oooc セ@ 0·9956 glcrn) t I
Calculat e the intc.-mal energy. U when l-00 mol of H20 goes from 2S -ooc and.
] ·00 atm to 30·00C and 1·00 atm. Densities of water arc 0·9970 gfcrnl at OOC and
0-9956 g/cm3 at I oooc. ]0
Conside r the futmQtion of MgO(s). Assume that AJ( and セ [@ are independent of
エ」クョー・イ。オセ N@
0
mァHウIKサP R HァI セ@ MgO(s) Mlr = -602 kJ/mol
0
ASr = -] 08 J/Kin1ol
Q
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1.(d) エゥセu。、ャ@ 3f1Gitf f«-;ID d C1itrr ゥェアZク[オセ@ • 3TTtm: 'tR mォヲ ゥ rゥセエj@ セ@ Sll lSi I エゥdセ@ t?> :
"3m' セrウ@ d セ@ セ[N@ iirwf セ@ セ@ セ@ amm "'« (Cf)J セ@ M ゥrセI@ Prikffcl R'ld
。キヲGャセ ャ 。ゥエ@ セ@ セ]@ ウイセヲゥョ@ "lt1 セ Z@ ウュセエ、イ@ セ@ セ@ 。エイセQ@ セヲ[イ」エ@ セ@
(A) Brz. +21- 2Br-- +1 2
3 EGT-P-CHM
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z.(a) (i) セ@ "<Fn セ@ セ@ ? セ@ ウョヲエセc、ャ@ セ@ セ@ セ@ セ@ ・セrA」エ@ ?
(iii) WR セ@ セア、N ゥヲャ@ CfiT lWl ᄋ セュゥャ@ (fliT -Mt セcヲa@ cfit @.afct セ@ tm tit
セ@ "flN w:rr セ@ セ ᄋ@ -a m1Rtl セ@ rn itrrT ?
(ii) Determine the number of radial ョッ、 ・ウセ@ angulal' nodes and tota.l number of
oodes in the foUowing orbitals ; 2p', 3s, Jp. 4d. Sf. 5
(ii) Discmss the effect of tempcralll rc on the viscosity of liquids and gases. S
l.{c) セゥTヲF」エ@ ᄋセ@ セ@ 3fTiitr セ@ 'CIU \ffutK:M Tゥャセqo@ iセ@ セヲゥ サBcT@ i\i cャエヲ L ャ セ@ 5Pl
ii Cll4CIWfd セi@ gャ 、ヲセ@ I
..
(0 Hi (ii) Nc 2 (iii) CN- (iv) NO (v) HF
Ca1culate the bond order for the following molecules /ions. Arrange tbcm as per the
increasing order of lheir stability. GivG reasons.
(i) Hi (i1) e (iii) CN- (iv) 0 (v) HF 15
2
セpZイ@
6·1'9A *3ITlRT 3fk セ@
'tiR
ゥヲャオセ@
GCP \ Q セU@ "iiiT ᄋ セ@ 1·'99 gJe.e セ@
3f1'lTrft 'l#?r セ@ q;f q セエQ
セ@ セ @ セ@ [ ·00g "Wf11J it
イ@ セ@ 1f.it ll> 1
(ii) The ー ッ エ。ウ ゥ セュ@ chloride crystal structure is like tl1at of sodium chloride.
Tho unit cell contains four potassium ions and four chloride ions. Given that
the size of unit celt as 6· 29 A and the density of potassium chloride as
1セ Y@ glc.c. Calculate the number of potassium ions and chloride ions in 1·00 g
of the salt. 5
EGT-P-C'H'M 4
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J.•(a) (i) lf'q1t ;a&t1itfdch1r セ@ i5f rim セB@ セ@ セ@ tR セ@ セ@ セ@ セ@ "tR セ ᄋ@
セ@ セ@ wmri 1:R 3Wn セ@ @セ tbt iltt;t I
(ii) Jl1R P m... 3·00 atm V 1 = 500 CitJ3
P1 1·00 atm V 2 = 2000· cml
cゥヲGrャ@セ (a) H「Iセ@ iエセ N セ@am ii Cfiiltf, wセョ T@ "mt' qftlM11f セpゥ@ I
P'
(a) {b)
v 'V
(t) Using the statement of fゥイsセ@ law of ャエ・イュッケ。ゥ」セ@ argue upon. the various
effects on rising clouds as it goes to hlgber altitudes. 5
(ii) [f p1- 3•00 attn v.t 1M 500 cml
pl セ@ 1·00 a:tm V2 - 2000 cmlo
Calculate the worlr, W:revcnrliJic for the processes shown in. figure (.e) and {b). 10
5 EGT- P-CHM
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J.(d) セM@ Bt.,:q•am "4n セ@ m- セ@ .... R:ttil セ@ (i) セ@ (1i) セ@ セ@ %f'Wfif fil;zrr セ@ MR«
セ@ l セ@ セ@ cfa at:I IMI '1ft tfnAll{ I
Draw d1agrams showing the cap·illary action of (i) water and (ii) mercury in two
glass rubes of different radii. Explain their behavior also. JO
{i) What arc crystal defects? 'Give a brief aooonnt on stoichiometric defects.
10
4.(b) (i) セ@ セヲ@ fmr セ@ QSイゥヲa u セ セ@ mRVr -q{ セi@ w セ@ fcfi セ@ t:!c;,il&i ql{qJ.:t セ@
セpvB]・ュ@ セᆱ エ 。エ」Zゥャ@ |T rcTmEセpv] セュエ@ iセ@
'il'f dili aq I M II セ@ <fl mMセ@ I'
(i.) Consider 1he reversible expansion of a perfect gas. Provide the physical
interpretation for tbo fact py1' セ@ セ 」ッョウエ。@ for an adiabatic change, whereas
PV - constant for an isothermal change. 5
(ii) Wba't happens to the air temperatum in a valley when cold air blo-wing from
the mountain tops descends into the valley ? 5
EGT-P-CHM 6
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(i) One side of g]ass cylinder is mi'l:ially failed with H2 at a pTcssure p and. otber
side with N 2 at a press-ure 2P: This g]ass cylinder is cl-osed at both ends and a
glass filter in the midd'te of the cylmder divides it into two co.mpanments of
equai volun1e. Describe what ィ。ー・ョウセ@ sta_rting at エゥョQ・セ@ t -= 0 at constanl
tempet'.ature and assunwg 1lbat the pores of fl]tel' have a. diameter much smaller
than the mean free paths of the gases. 10
(1i) Account for the difference between vapour and gas on tbe bas]s of critiC3l
teroperattl!l!. S
セ
(ii) Label and compare the phase· diagrams given above ;
doj@ 5
7 EGT-P•CHM
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5.(b) ;t.l'"¥ セ@ till d l q セ@ セ@ lQH 4il セ@ l( I
(B) [Oo(NH:3)J[CoClG1
(A) Na.[B(N03)4]
'(13) [Co(NH:J6]'[CoC]6 ] 10
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Identify the products and draw the structure of A.
10
t HゥセaコI@ 0 5 15 25 3:5
HCI (mJ) 16-0 10·24 6·13 4·32 3·41
(ii) In the hydrolysis of ethyl accta.to using equal conce-ntrations of ester and
N aOH, the following r-esults were obtained :
t (minutes) 0 5 15 25 35
(ii) ヲ\セエT@
セIヲ。pエ\ゥ@
4358 .A 'iif セ@
セ@ @セ セ@
セ@
Gwヲゥャセ@
セ@
セ@
ュZ]エ @セ
Gャ ゥエセ@ セQ@ * MャエゥGQセ@Y
tf'nfm 14,000 er-gs sec-L セ@ セ@ 3i'R
it
1105 sec セ@ '3C\'tf61"1 ltl セ@ 0·075 セjャゥQ\@ il4\it \ヲゥtセ@ "PT t I f4i'14<i セ@
セ@ セ@ <fiH セt@ qq, 80· l% SrセュオN@ セ@ I +tl"l!Ji セ@ Ciil ア セwゥヲ@ ィャエ セ mq^@ I
9 EGT-P-CHM
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(i) Distinguish flttores(;enoe from phosphorescence. 5
(ii) In the pbotobromLnation of cinnamic acid to dibromocinnamic acid using light
of wavelength 43 S8 A a light intensity of 14,000 ergs sec- 1 produred, and a
decrease of 0·07 5 millimole of bromine during an exposure for
1105 sec. lbe solutioo absorbed 80· 1% of the Jight passing through it.
Ca1culate 'the quantum yield. 5
&.(c) (i) L エゥ L Tセgエ L ゥヲ・エイ@ 311iiv QNgiセ@ 'tfif セ@ セ@ [Ni(H10J6P+ セ@H セ@ セ Qイェ。エTャア@ セ@ l,
セヲャTQ@ -qm G) Sヲセャ、@ セGヲQ@ il セ@ セrエ@ セ@ @セ I
(U) Using Orgel diagra_m. assign the absorption bands of [Ni(H20)Jl+ at 8500,
J3800 and 253<00 em-1 msolution. Calculate the l 0 Dq value. 10
Vセ、I@ VQセ@ lfiT jヲエセI ゥ cヲゥ、 Z@ fim セ@ セquヲ@ セ@ セ@ Wiffi t ? ァ ヲ セャHヲエGゥ@ <fi\' fl{ififl セ@
セ@ cT[Zキ ゥ セqi@ l セ@ セ@ セMLwャNGQ@ セ@ tfit セ@ セ@ R:Uioft エゥャセ@ I
How diborane can be synthesized industrially 1 Draw lhe structure of dibcmme.
C.ommeot on the nature of boron-hydrogen bond present in it. l0
7..(a} (i) BET e+f\lM:OI fef&q I セ@ VセQゥエ、@ セ@ 'tft 641t§tlr ゥサ[NIセア@ I セ ᄋ@ セJエゥ\Q@ セ@
pエセヲ。@ セ@ セ@ セ@ jar wm: aqQl4ll セ@ セ@ ?
(ii) ME4"1i•n |SセHPQ@ 1R 。イセォmQ@ ifit セTQmヲu@ セ M auGlrf セJGエ@ 1
(i) Write BET equation. Exp]ain the terms involved in iL How is it useful for tbe
determination of surfao: area? 10
7.(b) [2Fe-2S] afR [4F o-4S] セヲエZjャゥュ@ セ@ セ@ セ@ 'ifit tl6t'11 ifif m atil ャセサ@ I
{R f セ ・ M Rs}@ @セ 31'icttflfiij aft\ 3114Ria セゥヲ@ Q1g セ@ SQlセ\キji@ 3iijf«< "'Cf\ fluloft Tゥャセア@ I
egtセpNchm@ 10
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7..{c) {i) セ@ 'AiitM1 it キセエjt@ 1fit t11tt1"4a: セ@ 。セ\ P Q@ セ@ +3 mm t, lU 1R
fecq Qft 4illfGt q セ@
(i) The commonly obscnr.ed oxidation ウエ。セ@ of Janthanoids iro aqueous solution
is +3. - Comment 5
(ii) Calculate the effecliv·e magnetic moment ッヲcセ BG サz@ 5·8) at roo:m temperature.
10
7N セ 、 I@ セ@ セ@ ifft AISfili:"i"'l セ@ 'i;fij 'WiPT セG@ [PtCl4f-- it w セ@ arrtr frlti1 セヲ・、@ IEI"t jqq;(il
ア}Iセ_@
(m a pエセュ@ r.iil«4tu "ifii セ@ .. : Br- > a - > py > NH1 )
Br セM
I
. - - - - . - - - - py
Pl
セ@ .
f
'
セN@
Cl. セ@ - - - - - -- セ Mセ@
How do you prepare the aoove isomers starting from [PtClJf:z- using fue concept of
trans effect ?
(Order of trans directing ahnity : Br- > 」セ M > py > NH1) lO
(j) pイ・、セ」エ@ the product orf 'tne foUowiog reactions with. justification:
(ii) エQ\セヲJG@ 31Ti'W4il!fi セ@ セ@ セ@ セ ᄋ@ 7ti wfM lt; [Ro 2Cl 8 ]2- (Z = 75) lf
ュLァ M セ@ セ@ セ@ lffir.rr qiJ セ@ セ@ I 10
(ii) Determine the nUillber of metal-metal bond(s) m {rセP X }RM {Z = 75·) using
simplified MO energy level diagram. 5
11
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S.(b) (i) jエャセヲ・Jゥ@ セ@ sャTゥ]HjセiQp\ヲ@ $4dl セ@ -4it qfhtitill 3ik «41tcltll ,tfilfGtl{ I
:a.(c) ヲャ Q Zゥャセ@ c 3fl\ キセウイッGャ@ P-4so @セ セ@ セ@ Hセ@ セゥェTャ|jLiQ G@ w.t (liliD)) 'ili1
t& lfq'!ii giBeセH@ iセ@ 、ィエ\・ エセ Gヲイャゥ@ Wlirlf 1:R 'ifiri c:Qf.Jll( I
Draw the active site ( cooniination sphere only) of cytochrome C and cytochr-ome
P-450. Discuss their biocbamictll fuoction. 15
EGT-P-CHM 12
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