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CS ( tAJN) EXAM:2014 ffllilG'll DETACHABLE

(ft ltl f1 fa,.$11'1 (11'Pr-セ@ I)


CHEMISTRY (Paper I)

Tim: Allowed : Three Hours Mt)l.imum Marrb ; 2 SO


セMエイョG@ fl+aij;odf セ@ セ@
セ@ セ@
l8f セ@ セ@ lt 1.'f f.:cqfaf?la セ@ • セ@ tAIFt"h; 'fi I
m trni1ff-l セ@ -it it mil ftmRita f セ@ セ@ am セ@ セ@ -ij セ@ i I
アサャセ Q ュ@ q;) セヲゥ@ \ltR セ@ r
セZイN@ li"«m 1 セ@ .s Jtfrtcn4 G。エイセ@ liffi" it M。セ@ セゥエ@ BゥャMェ M ZアIャヲセ@ セ@ セ\ヲュ@
イゥセGSuエ@ 1
セOGwヲ。ゥア[キュ@ 1
セ@ セ@ セ@ セ@ lflnm セ@ セ@ セ@ セ@ fGt'tfifil セ@ セᄋ M セiエ@ miTt, 3iR セ@ セ@
llil セ@ セ@ ャエヲ MHヲャセ@ セュH セN I@ セアゥᄋ@ セAF・ャヲ|@ AAT! セ@ セ@ セ@ セ@
セi@ SセエQ@ セ@ セ@ 31Rlf{'ffi fエAGセ@S 1fTOfJf ゥエセ ᄋ@ 'R セ@ 。ゥGヲセ@ セ i@
セ@ jQ Q Tセエゥ\ヲ@ セN@ セ@ 3fmit -cit, セ@ q;r セ@ セ@ セ@ @セ セQヲエサ@ "it セ@ Gfiflifl セ@ '
セ@ セ@ |ゥセ、@ 'l m" @セ (lq1f セv\エgQ@ }l"itfffir セ@ @セ if セ@ f I
セ@ jエャ。 ᄋ Zエセア[@ セL@ en aqgffi セ@ 'qlT セ@ セ@ atJr セ@ セ@ セ@ I
ュセエwョGL@
セ@ セ@ セ@ 11Vf.n セ セ i\セ@ 1 セ@ cヲゥャ・セ@ m, mセ@ i6 セ@ セ@ セ@ セ@ セ@ セ@
セ@ セ@ 3{mr: h lTtiT mI セMァ`エ \ャゥイ@ if WRft セ@ pr セ@ m セ@ セャ@ セ@ セ@ セ@ セ@ セ@ "\il"RT
[ア Q セQサ@ I
QUESTION P. PER SP'E CIFIC INSTRUCTIONS
Please 111ead eac:b of the followtDg lnstru.ctlo>os Clll'ttf'uUy bef0re attempting qllesdons.
TheR a_re EIGHT questions divided in TWO SECTIONS and printed both in HINDI and in
ENGLISH.
Candidate bas to attempt Fl VE quest:ion..4\. in aU.
Question Nos. .J and 5 are co:mpuJsory and out of the TCirulnring, THREE are t<a be att.empted
e·hoosbi,g at 1earst ONE CJUt$tiu:n from each Section.
The number of marks Ciirried by Et question/ part is indkated 。Nァゥョセ ャ@ it.
Answers must be written in the medium C:tU!horized in the Admission. Certi fic:ale wbic: h must be
セエ。ャ」、@ clearly 011 •be <:over of t his qZオ」ウエゥッョMュaセキイ@ (QC:A) Booklet in the space
provided. No martc.s wm be given for answetS wriUc:n in a medium other dlan the aathorized ッョセ N@
Coordinate diagrams. wherever required, :S;hall be drawn in the space -provided for answering
ilie queStion itself,
Unless oeherwisc- ュ・ョエゥッ、セ@ symbo]s and nomtio-ns oarcy tlleir usual standa:rd meanmg.s..
.Assume &urita'ble dam,. if considered nccessaey. and indicate the same cloady.
\Vord limit in questions, whercveT specified, should be adhered to.
AUernpts of questions :s.lmll ba- counted in sequential order. Unless struck off, attempt of a
question sbaD be OOIJilted even if attempted pa.rUy. Any page ar pon.ion of the page left
blank in the Qocsti:on-cum.- Answer Booklet must be clearly struck off.

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SECT ION 'A''

t .(a) セ@ カ 」ゥエセ Gゥセjエ 」エm i@ itt I セH」・ョエイィ。QPゥEアャヲ@


セ@ セ@ tfil ti141Mm "ltl1f t ?
A particle in a rigid box of length 'L" is in its ground state. 'What is the pr·obability
of finding tbc particle i.n the centre half of tOO box ? 10

l .(b) "7iRf H20 lWT J-00 mol 1 25·0 °C セ@ 1·00 attn it 30· ooc am t ·00 atm W \iffifT t, Cfif
セ@ 3!itti\Cfi セN@ U, q;r qftR!i1 Fゥャmセ@ 1 セ@ セ@ セ@ 1
oac 1R 0-9970 g/cmJ wn
1oooc セ@ 0·9956 glcrn) t I
Calculat e the intc.-mal energy. U when l-00 mol of H20 goes from 2S -ooc and.
] ·00 atm to 30·00C and 1·00 atm. Densities of water arc 0·9970 gfcrnl at OOC and
0-9956 g/cm3 at I oooc. ]0

mァHウIKMAP R HァIセ@ MgO(s) .Mir = -602 kJ/mol


6Sr- =-108 J/K/mol
0

(i) OOC セ@ M.gO(s) セ@ ヲイエアッセ@ セ@ セ@ セ セ g[@ <Iii 'lftWlft*t Bセ_ゥエ@ I qm セ@ SQセ、ゥヲ[ア ゥ@


ooc 1R セ]@ liT セ ]@ t ?

(ii) セ@ qit$ @セ セ@ t, セエn\@ MgO \セゥヲ@ p..qflJf セ Z@ セ@ セ Z@ (Fn 3Jlq(f: ゥヲセZ@


セ@ セ@ セ@ 1 3tlR セN@ m- ii:I IGQI 4ilW.QO -.m セ@ ? 3flR セL@ mセ@ l'fN qiJ

qftq;wi lfilRill( fGteq< セヲャ[Zア@ q\1 セ Z@ srttRfa• セ@ セ@ ?

Conside r the futmQtion of MgO(s). Assume that AJ( and セ [@ are independent of
エ」クョー・イ。オセ N@

0
mァHウIKサP R HァI セ@ MgO(s) Mlr = -602 kJ/mol
0
ASr = -] 08 J/Kin1ol
Q

(i) Ca:lculate for the formation of MgO(s) at 0°C. ls this r-eaction


セg@ r
spon.tanoous or non-spontaneous at 0°C. 5

( u) Is ther-e a temperature at whi oh formation of MgO switches from spontaneous


to non-spontaneous or vice-ver sa? If no,. explain why not? ]fyes, calculate the
temperatu11e at whi.ch the spontani ety of the reaction switches ? 5

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1.(d) エゥセu。、ャ@ 3f1Gitf f«-;ID d C1itrr ゥェアZク[オセ@ • 3TTtm: 'tR mォヲ ゥ rゥセエj@ セ@ Sll lSi I エゥdセ@ t?> :

(i) BeF 21 セ@ t セ@ SF 2 ct?i aftq tI


(ii) P セ@ ゥォGヲエ\セ@ PCI'S 3ftt pcャセ@ セ@ ififfin t セ@ N セ@ セ@ NC1 3 l\ ゥャ ャ セ イ@ i- I
Bxp1ain the following on the basis of VBT and. hybridization:
(i) BeF2 is linear whereas SP2 is. angular. 5
(if) P fonns two chlorides PCl.s and PC11 wllere.as N forms ,o n]y one NO). S

l.(e) セ@ :ri tif ウエセijィ・ イ ゥSエ@ セ@ ·ElfPI セ@ セ@

(i) 12 + 2e- )·2r; E:=·= +0·S4V

(il) 2Br- )'Br1 KR ・ M セe P


M M ャᄋ PYv@

(iii) Fe •Fe2+ KRM・ M[bセZ@ + 0·44V

"3m' セrウ@ d セ@ セ[N@ iirwf セ@ セ@ セ@ amm "'« (Cf)J セ@ M ゥrセI@ Prikffcl R'ld
。キヲGャセ ャ 。ゥエ@ セ@ セ]@ ウイセヲゥョ@ "lt1 セ Z@ ウュセエ、イ@ セ@ セ@ 。エイセQ@ セヲ[イ」エ@ セ@
(A) Brz. +21- 2Br-- +1 2

(B,) Fe+ Dr2 e + 2"B. r-


,pl+

(C) Fe+l;2; >f セ ・ R @K + 21-
(D) I 2 + 2Br- >21- + Br1

Observe the following half ceU reactions :


(l) I 2 +ie - >21- ; E 0 -= +0·S4V

{ii) 2Br- Br2 + 2e- ; Eo;; -1 ·09V

(iii) Fe f'e2 • + 2e·- ; Ec セ@ +0·44 V


Using the above· Standard Electrode Potential Values, explain the spontaneity or oon·
spontaneity for the following reactions :

(A) Br2 +21- >2Br- + 1.2


{B) Fe+Br2 tFe2+ +2Br-

(C) Fe+I1 Fe2 + +21-

(D} 12 +2 Br- 2I- -r Br2 10

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z.(a) (i) セ@ "<Fn セ@ セ@ ? セ@ ウョヲエセc、ャ@ セ@ セ@ セ@ セ@ ・セrA」エ@ ?

(ii) pエj[ェヲセ。@ @セ ゥエセ@ セN@ Efi)oftq セ@ ail\ セ@ セ エ|ゥ\Z ャ@ セ@ mr セュヲエ。@


c#i),f.Jttt : 2p, 3s1 3p, 4d, Sf.

(iii) WR セ@ セア、N ゥヲャ@ CfiT lWl ᄋ セュゥャ@ (fliT -Mt セcヲa@ cfit @.afct セ@ tm tit
セ@ "flN w:rr セ@ セ ᄋ@ -a m1Rtl セ@ rn itrrT ?

(i) \Vhat is an orbital and bow is it related to the probalbility density? S

(ii) Determine the number of radial ョッ、 ・ウセ@ angulal' nodes and tota.l number of
oodes in the foUowing orbitals ; 2p', 3s, Jp. 4d. Sf. 5

(iii) Would it be _poss1ble to determine lhe position and momentum of an electron


simt11hrneously and accurately if the value of l''l ankts セ 」ッョウエ。@ is zero ? 5

2.(b) (i) ゥエャセ@ atflw1 セ@ セ@ <Ji) l'11! TGャセア ⦅ ャ@

(1i) セ@ セ@ セ@ cfiJ セ\GャゥQ、@ lR ((Tq セ@ セ@ lR "firi セpエア@ I

(i) Explain. the significance of KeLvin equation. S

(ii) Discmss the effect of tempcralll rc on the viscosity of liquids and gases. S

l.{c) セゥTヲF」エ@ ᄋセ@ セ@ 3fTiitr セ@ 'CIU \ffutK:M Tゥャセqo@ iセ@ セヲゥ サBcT@ i\i cャエヲ L ャ セ@ 5Pl
ii Cll4CIWfd セi@ gャ 、ヲセ@ I
..
(0 Hi (ii) Nc 2 (iii) CN- (iv) NO (v) HF
Ca1culate the bond order for the following molecules /ions. Arrange tbcm as per the
increasing order of lheir stability. GivG reasons.
(i) Hi (i1) e (iii) CN- (iv) 0 (v) HF 15
2

l.(d) (1) tq em セ セ@ セnGBャ@ " 'NitOt 1

(ii) セfヲャ@ セ i セ@ cfit finf6"11 Ei<il"11 ・Qサァ セ@ 'I '#ll(IQOS @セ l


I @セ セ@ if セ@
titffitltlr セ@ セ@ \エゥGヲャセ@ amR セ@ 11 I セ@ fu;f - @セ ( 3Wfl'tf)

セpZイ@
6·1'9A *3ITlRT 3fk セ@
'tiR

ゥヲャオセ@
GCP \ Q セU@ "iiiT ᄋ セ@ 1·'99 gJe.e セ@
3f1'lTrft 'l#?r セ@ q;f q セエQ
セ@ セ @ セ@ [ ·00g "Wf11J it
イ@ セ@ 1f.it ll> 1

(i) Derive Bragg's equation.

(ii) The ー ッ エ。ウ ゥ セュ@ chloride crystal structure is like tl1at of sodium chloride.
Tho unit cell contains four potassium ions and four chloride ions. Given that
the size of unit celt as 6· 29 A and the density of potassium chloride as
1セ Y@ glc.c. Calculate the number of potassium ions and chloride ions in 1·00 g
of the salt. 5

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J.•(a) (i) lf'q1t ;a&t1itfdch1r セ@ i5f rim セB@ セ@ セ@ tR セ@ セ@ セ@ セ@ "tR セ ᄋ@
セ@ セ@ wmri 1:R 3Wn セ@ @セ tbt iltt;t I
(ii) Jl1R P m... 3·00 atm V 1 = 500 CitJ3
P1 1·00 atm V 2 = 2000· cml
cゥヲGrャ@セ (a) H「Iセ@ iエセ N セ@am ii Cfiiltf, wセョ T@ "mt' qftlM11f セpゥ@ I
P'

(a) {b)

v 'V
(t) Using the statement of fゥイsセ@ law of ャエ・イュッケ。ゥ」セ@ argue upon. the various
effects on rising clouds as it goes to hlgber altitudes. 5
(ii) [f p1- 3•00 attn v.t 1M 500 cml
pl セ@ 1·00 a:tm V2 - 2000 cmlo

Calculate the worlr, W:revcnrliJic for the processes shown in. figure (.e) and {b). 10

3+{b) セ@ セ@ L セ N@ sucn•enan if 。[Fヲャ \[セ@ tffRI セ@ g'rif lPm, セ@ セon@ tn mI


Show that tv..·o pha:ses arc in thermal equilibrium only if their temperatut'C" are same.
10
3.(•c } (i) セ@ セ@ 3ik セ@ w·-ij;- セ@ セゥヲ@ |Sgi G セi@ セ@ gQ:, ilG G ゥUT 、ャセ@ II

(ii) tfi R( BG i Q セg@ 151' f4fl Q"i , セ@ セ@ セ@ セ@ 1flf1f ij 0-0073 9 gm AgNOJ t•


セ@ fuffi セIゥヲ@ S ifN if セ@ 31 4$4f!l\ ftim 1l'm t I キゥエセ@ it セ@ セ@
0·078 gm セH@ セ@ '-R セ@ "dt 1Fn 't fli I ·lPfPI @セ affi' .q, セ@ セ@
A"WM il 23·1 4 g セ@ ark 0-236 ,g m セ \@ BGャセ・@ tn I Ag+ 'ifi1 ml1•141'1i4
セ@ lftm ? セ@ dt4"1ZTI セ@ 'iifG @セ @セ セHQ T N GQ@ -ij (a) 23· 14 gm セ@ 3ftt
(b) P セ ᄋ RSV [@ gm RIJ,.-iij( "1 lセH@ t· I
(i) Distinguish between Galvanic ceUs and conoenh-ation cc=lls with an excnnple
セ@ 5
(ii) A silver nitrate solution con1aiiDing 0-00739 gm of aァnセ@ per gm of \llater is
electtoJysed between silver el·ee1rodes. Durmg the experiment 0·078 gm of Ag
was deposited on the cathode. At th.e end of the experiment anode solution
contained 23·14 gm of H20 and 0·236 gm of AgN03. ·What iB the traosport
number of Ag+-? Afte-r electrolysis, 1he anode solution has {a) 23·14 g:m water
and (b) 0··236 gm AgN01 . 10

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J.(d) セM@ Bt.,:q•am "4n セ@ m- セ@ .... R:ttil セ@ (i) セ@ (1i) セ@ セ@ %f'Wfif fil;zrr セ@ MR«
セ@ l セ@ セ@ cfa at:I IMI '1ft tfnAll{ I

Draw d1agrams showing the cap·illary action of (i) water and (ii) mercury in two
glass rubes of different radii. Explain their behavior also. JO

{i) What arc crystal defects? 'Give a brief aooonnt on stoichiometric defects.
10

(1i) Explain the conduction mechanism io semiconductors. 5

4.(b) (i) セ@ セヲ@ fmr セ@ QSイゥヲa u セ セ@ mRVr -q{ セi@ w セ@ fcfi セ@ t:!c;,il&i ql{qJ.:t セ@
セpvB]・ュ@ セᆱ エ 。エ」Zゥャ@ |T rcTmEセpv] セュエ@ iセ@
'il'f dili aq I M II セ@ <fl mMセ@ I'

(H) セ@ 'EI1if セ@ セ@ セ@ m セ@ lflR セ@ mar t \jfi( セ@ セ@ fiH¥AU 1R セ@ セ@ セ@


セ@ Jll•qd(OI セ@ 'Effi!T it JIKft ·• ?

(i.) Consider 1he reversible expansion of a perfect gas. Provide the physical
interpretation for tbo fact py1' セ@ セ 」ッョウエ。@ for an adiabatic change, whereas
PV - constant for an isothermal change. 5

(ii) Wba't happens to the air temperatum in a valley when cold air blo-wing from
the mountain tops descends into the valley ? 5

4.(c) (i) セ@ .q, Q!'i セ@ セ@ mRtr..« eft セ@ セ@ H 2 PfijCfil セ@ P t• セ@ セ@ N2


Mtt ttlI セ@ 2P t. it セ@ セ@ I セ@ 'CfiR セ@ lfl R:lrs( セ@ -ttro -e セ@ atn' セ@ 'JRll
it 1fifq セ@ セ@ セ@ H セヲTYQI@ セ@ セ@ セ@ セ@ セ@ セ@ Ril'"lilil 3l l.ttd1i1 m t
- ゥャセ@ t- 1 セ@ セ@ セ@ セ@ 'Q)T ami mn セ@ "Jf1Hf セ@ tJlf ゥエセ@ l'fiR' tt m
セ@ "'Nil( "F6 セ@ -ii *'" tf1l1f t= o 3fk ッイZセ@ 3FR t (fif <FIT セ@ セ@ 1

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(i) One side of g]ass cylinder is mi'l:ially failed with H2 at a pTcssure p and. otber
side with N 2 at a press-ure 2P: This g]ass cylinder is cl-osed at both ends and a
glass filter in the midd'te of the cylmder divides it into two co.mpanments of
equai volun1e. Describe what ィ。ー・ョウセ@ sta_rting at エゥョQ・セ@ t -= 0 at constanl
tempet'.ature and assunwg 1lbat the pores of fl]tel' have a. diameter much smaller
than the mean free paths of the gases. 10
(1i) Account for the difference between vapour and gas on tbe bas]s of critiC3l
teroperattl!l!. S

44(d) (i) セ@ TjG l セャjNZM|D@ セ@ セ@ sャエセ ᄋ エuG@ セゥヲ@ セ@ ..IHI1 セ@ セ@ セ@ セ@ i tV,IIWfq;;'


mit t セ@ セ ア@ ltfi'l 'UI' 1m * セ@ 6Chii([i;f'lth itrit t ?
(i) Explain why fusion 」オイカセ@ of ice has negative slope wb.erteas suhli.mation cwve
has positive slope in the phase diagratn. S
(ii,) セ@ セ@ セ@ 1AAOO セ@ lfit セ@ ᄋ セ@ セ@ g<Vfl セ@ I


(ii) Label and compare the phase· diagrams given above ;
doj@ 5

(!lOs 'B' SECTIO - ' B "

SL(a) H {aq) +OH-(aq) kk, H 2 0(1) セ@ セ@ qfOfa SQヲGエセャ@ セ@ セ@ セ@ '@.1rditi k 1 iR 1fPif


-l
1·4 )( [0 11 dm3.moJ- 1.!r1 t I
3J1R "iN{ セ イ pj、@ 。ャセ@ Fsfitl l! セ@ セ@ sn<llPrf Zmゥエセ@ セ@
(i) [H1, = [OH-J0 = 0·10 moldm-l
(ii) [111 0 [OH-] 0 - 1M ッ セ@ l o-7 motdm- 1

mセ@ セ@ Cfll q'R<bHJI1 エゥャセア@ I


-
The rate constant k 1 foT the reaction described by H +( aq) +OH - ( aq)
k
H 1OU) is T" -I
1·4XlrO11 dmj .moJ-I .s- 1•
Calculate the half life of the above ,r eactio n if the initial c()nditions a.re
(i) [Ii•]0 .. [OH-]0 .. 0•10 motdm-3
(ii) [W]0 = [OH-] 0 = 1·0>< 10- 1 mol.drn.-1 1,0

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5.(b) ;t.l'"¥ セ@ till d l q セ@ セ@ lQH 4il セ@ l( I

(i) \itil fm' 'lfil セ@ 'P' セ@ セ@ ir セ@


(ii) セ@ セ@ W セ@ ' P" セ M セ@ ll II

Explaiu l。ョセ@ adscuption iso1he:rm


(i) when the gas ーョ スセ ウ オイ・@ c ー セ@ is very snmU and

(ii) when the gas pressure c P; is very hiigh. LO

Sl(c) (i) Qゥエgセ\s、@ • セ@ ti<ii'U セ@ -m gゥセエャキ」@ セ@


(A} セ@ Q HV M セゥヲI ᄋ@ セ@ (0}

(B) セ M エイセ Gmiセヲ@ HisGセヲエゥ@ セI@ ifiliitl<"l (fil) セ@ セ@ (VI)


(ii} frtR11+l Rsid q;r IUPAC iWf rャセ@ .:
(/\) 。セ HI SIT}@

(B) [Oo(NH:3)J[CoClG1

( i} Dr-aw the structure of the following complexes :

(A) his (116-benz.ene) chromium (0)


(B) fac-triaqua.tris (dimethylamine) cobalt (ill) tetrao·7>osu!fate (VI)

(ii) Givq-IDPAC nomencLature of

(A) Na.[B(N03)4]
'(13) [Co(NH:J6]'[CoC]6 ] 10

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Identify the products and draw the structure of A.

10

5·.(c} Ho>+ (z VWIcゥイセ@ セQr@ *ll'Gtl{ 1


find out the ground state term symbol of HoJ+(z セ@ 67). 10

6+(a) (i) セ@ \i4dcti tR ュゥエGセ@ <fir izゥエFャセ@ 」「ャ N セ@ セ@

<H) セ@ {ttti& セ@ セ@ セアᄁQL@ it セ@ am- Vヲセアjエ@ m* ゥェ ャ セᄃゥヲエャ@ q;J aeu(l4<


セ@ illFiPT セ@ セ@ セ@ t PtGtf'A f0q '1ftuiiij ln9 セ@ it :

t HゥセaコI@ 0 5 15 25 3:5
HCI (mJ) 16-0 10·24 6·13 4·32 3·41

(i) Explain tbe effect of te'mpor8ture on イ。セ@ constant 5

(ii) In the hydrolysis of ethyl accta.to using equal conce-ntrations of ester and
N aOH, the following r-esults were obtained :

t (minutes) 0 5 15 25 35

HCl (ml) l6-0 10·24 6·13 4·32 3-4[

Show that the reaction is of second order. lO

6.(b) (i) S4fdG1f8 iifif セ@ -6 QTセgゥャ@ 」ゥIヲセqャ@ I

(ii) ヲ\セエT@
セIヲ。pエ\ゥ@
4358 .A 'iif セ@
セ@ @セ セ@
セ@
Gwヲゥャセ@
セ@
セ@
ュZ]エ @セ
Gャ ゥエセ@ セQ@ * MャエゥGQセ@Y
tf'nfm 14,000 er-gs sec-L セ@ セ@ 3i'R
it

1105 sec セ@ '3C\'tf61"1 ltl セ@ 0·075 セjャゥQ\@ il4\it \ヲゥtセ@ "PT t I f4i'14<i セ@
セ@ セ@ <fiH セt@ qq, 80· l% SrセュオN@ セ@ I +tl"l!Ji セ@ Ciil ア セwゥヲ@ ィャエ セ mq^@ I

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(i) Distinguish flttores(;enoe from phosphorescence. 5
(ii) In the pbotobromLnation of cinnamic acid to dibromocinnamic acid using light
of wavelength 43 S8 A a light intensity of 14,000 ergs sec- 1 produred, and a
decrease of 0·07 5 millimole of bromine during an exposure for
1105 sec. lbe solutioo absorbed 80· 1% of the Jight passing through it.
Ca1culate 'the quantum yield. 5

&.(c) (i) L エゥ L Tセgエ L ゥヲ・エイ@ 311iiv QNgiセ@ 'tfif セ@ セ@ [Ni(H10J6P+ セ@H セ@ セ Qイェ。エTャア@ セ@ l,
セヲャTQ@ -qm G) Sヲセャ、@ セGヲQ@ il セ@ セrエ@ セ@ @セ I

(ii)' セ@ .3lfui 1i "WWr セL L@ セVQTwゥ@ oft [Ni(H20')6]H セ@ セ@ セ GQ@ ':ill セ@ XUP セ@


13 800 aft;: 25 300 cnri ICR t. セ@ セ、@ Hセ G ゥヲオエI@ cQAtc:t I Dq セ@ セ@ ltif
iffttf;t1'1 セ@ セv^@ I

(i) Determine tho geometry of [Ni(H20)6]2-t 1(paramagnetic complex with two


unpaired electrons) using valence bond theory. 5

(U) Using Orgel diagra_m. assign the absorption bands of [Ni(H20)Jl+ at 8500,
J3800 and 253<00 em-1 msolution. Calculate the l 0 Dq value. 10

Vセ、I@ VQセ@ lfiT jヲエセI ゥ cヲゥ、 Z@ fim セ@ セquヲ@ セ@ セ@ Wiffi t ? ァ ヲ セャHヲエGゥ@ <fi\' fl{ififl セ@
セ@ cT[Zキ ゥ セqi@ l セ@ セ@ セMLwャNGQ@ セ@ tfit セ@ セ@ R:Uioft エゥャセ@ I
How diborane can be synthesized industrially 1 Draw lhe structure of dibcmme.
C.ommeot on the nature of boron-hydrogen bond present in it. l0

7..(a} (i) BET e+f\lM:OI fef&q I セ@ VセQゥエ、@ セ@ 'tft 641t§tlr ゥサ[NIセア@ I セ ᄋ@ セJエゥ\Q@ セ@
pエセヲ。@ セ@ セ@ セ@ jar wm: aqQl4ll セ@ セ@ ?
(ii) ME4"1i•n |SセHPQ@ 1R 。イセォmQ@ ifit セTQmヲu@ セ M auGlrf セJGエ@ 1

(i) Write BET equation. Exp]ain the terms involved in iL How is it useful for tbe
determination of surfao: area? 10

(ii) .Exp1am the mecllanism of re-action on heterogeneous cata1ysis.. s

7.(b) [2Fe-2S] afR [4F o-4S] セヲエZjャゥュ@ セ@ セ@ セ@ 'ifit tl6t'11 ifif m atil ャセサ@ I
{R f セ ・ M Rs}@ @セ 31'icttflfiij aft\ 3114Ria セゥヲ@ Q1g セ@ SQlセ\キji@ 3iijf«< "'Cf\ fluloft Tゥャセア@ I

Draw the actlve site structure of [2Fe-2S] and [4Fe-4S] ferredaxins_


Comment on the oxidation state of metal in oxidised and reduced forms of
[2Fe-2S]. W

egtセpNchm@ 10
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7..{c) {i) セ@ 'AiitM1 it キセエjt@ 1fit t11tt1"4a: セ@ 。セ\ P Q@ セ@ +3 mm t, lU 1R
fecq Qft 4illfGt q セ@

(ii) セ@ mtf セ@ Gel (Z =58)$ lf'Jmt Gェ。エャセ B@ セ@ :q;r qf(i$i'l'9 4ilPmQ I

(i) The commonly obscnr.ed oxidation ウエ。セ@ of Janthanoids iro aqueous solution
is +3. - Comment 5

(ii) Calculate the effecliv·e magnetic moment ッヲcセ BG サz@ 5·8) at roo:m temperature.
10

7N セ 、 I@ セ@ セ@ ifft AISfili:"i"'l セ@ 'i;fij 'WiPT セG@ [PtCl4f-- it w セ@ arrtr frlti1 セヲ・、@ IEI"t jqq;(il
ア}Iセ_@
(m a pエセュ@ r.iil«4tu "ifii セ@ .. : Br- > a - > py > NH1 )
Br セM
I
. - - - - . - - - - py
Pl
セ@ .

f
'
セN@
Cl. セ@ - - - - - -- セ Mセ@
How do you prepare the aoove isomers starting from [PtClJf:z- using fue concept of
trans effect ?
(Order of trans directing ahnity : Br- > 」セ M > py > NH1) lO

(j) pイ・、セ」エ@ the product orf 'tne foUowiog reactions with. justification:

(A) CIF + BF3

(B) CIF + CsF

(C) CIF3 + BF3

(D) 12 + Br2 ->

(ii) エQ\セヲJG@ 31Ti'W4il!fi セ@ セ@ セ@ セ ᄋ@ 7ti wfM lt; [Ro 2Cl 8 ]2- (Z = 75) lf
ュLァ M セ@ セ@ セ@ lffir.rr qiJ セ@ セ@ I 10

(ii) Determine the nUillber of metal-metal bond(s) m {rセP X }RM {Z = 75·) using
simplified MO energy level diagram. 5

11
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S.(b) (i) jエャセヲ・Jゥ@ セ@ sャTゥ]HjセiQp\ヲ@ $4dl セ@ -4it qfhtitill 3ik «41tcltll ,tfilfGtl{ I

{ii) ャh セiIGゥャB@ *. エ[ェャセ


.. '
Bエ@ ·'26 セ@
... -
スicヲゥeセr i HQT@ Plitii セ@ セ@ セ@ セ@ エゥャセ@ I

(i) Define and explain Binstein,s Jaw of photochemical equivalence·. S

{ii) Discuss the pbotocllemicai reac-tions between hydrogen and chlorine. 5

:a.(c) ヲャ Q Zゥャセ@ c 3fl\ キセウイッGャ@ P-4so @セ セ@ セ@ Hセ@ セゥェTャ|jLiQ G@ w.t (liliD)) 'ili1
t& lfq'!ii giBeセH@ iセ@ 、ィエ\・ エセ Gヲイャゥ@ Wlirlf 1:R 'ifiri c:Qf.Jll( I
Draw the active site ( cooniination sphere only) of cytochrome C and cytochr-ome
P-450. Discuss their biocbamictll fuoction. 15

8'•(d) [PtC12Br2(NH>h1 セ@ lflfi セ@ セ@ エKュ。セ@ il; '«J1Rft.t gャJセ@ I


Draw aU possible stcreoisomers of {p エ ci Q bイ R HnhセゥjN@ 10

EGT-P-CHM 12
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