Reacción R 1.

987
1 2C + O2 = 2CO
2 CO2 = C + O2
GENERAL CO2 + C = 2CO
A B C
1 -53400 0 -41.9
2 94200 0 0.2
TOTAL 40800 0 -41.7

T (K) DG kp PCO %CO

300 28290 2.4493E-21 4.9491E-11 4.9491E-09
350 26205 4.3202E-17 6.5728E-09 6.5728E-07
400 24120 6.6123E-14 2.5714E-07 2.5714E-05
450 22035 1.9836E-11 4.4538E-06 0.00044538
500 19950 1.9017E-09 4.3607E-05 0.00436074
550 17865 7.9527E-08 0.00028197 0.02819661
600 15780 1.7851E-06 0.00133519 0.13351854
650 13695 2.4828E-05 0.00497037 0.49703721
700 11610 0.00023708 0.01527932 1.52793152
750 9525 0.00167567 0.04010563 4.01056307
800 7440 0.00927509 0.09178133 9.17813259
850 5355 0.04197803 0.18496867 18.4968666
900 3270 0.16064597 0.32845294 32.8452937
950 1185 0.53378365 0.51093521 51.0935208
1000 -900 1.57293631 0.69389277 69.3892771
1050 -2985 4.18174367 0.83376296 83.3762963
1100 -5070 10.1718388 0.91728099 91.7280992
1150 -7155 22.9019603 0.95977755 95.977755
1200 -9240 48.1917925 0.98006851 98.0068509
1250 -11325 95.5488509 0.98974765 98.9747648
1300 -13410 179.726571 0.99449706 99.4497061
1350 -15495 322.607276 0.99691933 99.6919325
1400 -17580 555.378103 0.99820588 99.820588
1450 -19665 920.944321 0.99891651 99.891651
1500 -21750 1476.50534 0.99932364 99.9323641
1.987 Reacción
FeO + CO = Fe + CO2
1 FeO = Fe + 1/2 O2
2 C + 1/2 O2 = CO
3 C + O2 = CO2
A B C
1 63310 0 -15.62
2 26700 0 20.95
3 -94200 0 -0.2
DG -4190 0 5.13
T (K) DG kp PCO %CO
300 -2651 85.3909733 0.01157528 1.15752834
350 -2394.5 31.2836125 0.03097547 3.09754678
400 -2138 14.7314535 0.06356692 6.35669171
450 -1881.5 8.20081115 0.10868607 10.8686069
500 -1625 5.13269881 0.16306035 16.3060348
550 -1368.5 3.49813653 0.22231428 22.2314284
600 -1112 2.54143634 0.28237131 28.2371305
650 -855.5 1.9394073 0.34020464 34.020464
700 -599 1.53826693 0.3939696 39.3969598
750 -342.5 1.25838256 0.44279478 44.2794777
800 -86 1.05559191 0.48647788 48.6477883
850 170.5 0.90397796 0.52521616 52.5216163
900 427 0.78759266 0.55941156 55.9411562
950 683.5 0.69621941 0.58954637 58.9546374
1000 940 0.62308335 0.61611131 61.6111306
1050 1196.5 0.56355543 0.63956799 63.9567989
1100 1453 0.51438895 0.66033234 66.033234
1150 1709.5 0.4732537 0.67876972 67.876972
1200 1966 0.43844273 0.69519626 69.5196257
1250 2222.5 0.40868266 0.70988309 70.9883088
1300 2479 0.38300793 0.72306165 72.3061653
1350 2735.5 0.36067547 0.7349291 73.49291
1400 2992 0.3411058 0.74565333 74.5653326
1450 3248.5 0.32384147 0.75537745 75.5377454
1500 3505 0.30851735 0.76422372 76.422372
 R 1.987 Reacción
MgO + CO = Mg + CO2
1 MgO = Mg + 1/2 O2
2 CO = C + 1/2 O2
3 C + O2 = CO2
A B C
1 144350 2.95 -33.95
2 26700 0 20.95
3 -94200 0 -0.2
DG 76850 2.95 -13.2
T (K) DG kp PCO %CO
300 75082.2523 1.986512E-55 1 100
350 74856.7503 1.792549E-47 1 100
400 74640.4308 1.640546E-41 1 100
450 74432.1396 7.044087E-37 1 100
500 74230.9808 3.556117E-33 1 100
550 74036.2385 3.786842E-30 1 100
600 73847.3277 1.255752E-27 1 100
650 73663.7614 1.698027E-25 1 100
700 73485.1275 1.135039E-23 1 100
750 73311.073 4.319171E-22 1 100
800 73141.2924 1.040097E-20 1 100
850 72975.518 1.718569E-19 1 100
900 72813.5139 2.074918E-18 1 100
950 72655.0704 1.923705E-17 1 100
1000 72500 1.425033E-16 1 100
1050 72348.1339 8.709979E-16 1 100
1100 72199.3193 4.509527E-15 1 100
1150 72053.4174 2.021131E-14 1 100
1200 71910.3016 7.984757E-14 1 100
1250 71769.8557 2.823117E-13 1 100
1300 71631.9728 9.048472E-13 1 100
1350 71496.5542 2.657985E-12 1 100
1400 71363.5088 7.223247E-12 1 100
1450 71232.7516 1.830729E-11 1 100
1500 71104.2038 4.357802E-11 1 100
 R 1.987 Reacción
CdO + CO = Cd + CO2
1 2 CdO = 2 Cd + O2
2 CO = C + 1/2 O2
3 C + O2 = CO2
A B C
1 87250 0 -49.95
2 26700 0 20.95
3 -94200 0 -0.2
DG 19750 0 -29.2
T (K) DG kp PCO %CO
300 10990 9.843013E-09 1.0000000 99.999999
350 9530 1.118684E-06 0.9999989 99.9998881
400 8070 3.893964E-05 0.99996106 99.9961062
450 6610 0.000615857 0.99938452 99.9384522
500 5150 0.005607255 0.99442401 99.4424011
550 3690 0.034167081 0.96696174 96.696174
600 2230 0.154047924 0.86651514 86.6515141
650 770 0.550910519 0.64478252 64.4782525
700 -690 1.642273683 0.37846193 37.8461931
750 -2150 4.232153455 0.19112589 19.1125893
800 -3610 9.68919721 0.0935524 9.3552395
850 -5070 20.12303269 0.04734169 4.73416869
900 -6530 38.53290724 0.02529538 2.52953822
950 -7990 68.90827023 0.01430446 1.43044592
1000 -9450 116.2698099 0.00852734 0.85273439
1050 -10910 186.6486696 0.00532911 0.53291079
1100 -12370 287.0091551 0.00347211 0.34721118
1150 -13830 425.1253107 0.00234673 0.23467275
1200 -15290 609.424262 0.0016382 0.16382049
1250 -16750 848.8096252 0.00117673 0.11767341
1300 -18210 1152.477212 0.00086694 0.08669439
1350 -19670 1529.733325 0.00065328 0.06532817
1400 -21130 1989.823618 0.0005023 0.05023047
1450 -22590 2541.778209 0.00039327 0.03932706
1500 -24050 3194.276585 0.00031296 0.0312962
 R 1.987 Reacción
1/2 MoO2 + CO = 1/2 Mo + CO2
1 1/2 MoO2 = 1/2 Mo + 1/2 O2
2 CO = C + 1/2 O2
3 C + O2 = cO2
A B C
1 70250 2.3 -28.4
2 26700 0 20.95
3 -94200 0 -0.2
DG 2750 2.3 -7.65
T (K) DG kp PCO %CO
300 2164.2137 0.0264997 0.9741844 97.41844
350 2120.4748 0.0474031 0.9547423 95.47423
400 2083.8952 0.0726638 0.9322585 93.225852
450 2053.575 0.1005924 0.9086016 90.860157
500 2028.8155 0.1297574 0.8851458 88.514582
550 2009.0588 0.1590771 0.8627554 86.27554
600 1993.8487 0.1877937 0.841897 84.189704
650 1982.8055 0.2154096 0.8227679 82.276788
700 1975.6078 0.241622 0.8053981 80.539813
750 1971.9807 0.2662672 0.7897227 78.972273
800 1971.6856 0.2892784 0.7756277 77.562769
850 1974.514 0.3106533 0.7629783 76.297829
900 1980.282 0.330432 0.7516356 75.163557
950 1988.8261 0.3486806 0.7414654 74.14654
1000 2000 0.3654804 0.732343 73.234297
1050 2013.6722 0.3809203 0.7241547 72.415475
1100 2029.7235 0.3950916 0.7167988 71.679883
1150 2048.0458 0.4080847 0.7101845 71.018455
1200 2068.5402 0.4199873 0.7042316 70.423163
1250 2091.1163 0.4308829 0.6988692 69.886922
1300 2115.6906 0.4408498 0.6940349 69.403486
1350 2142.1864 0.4499615 0.6896735 68.967347
1400 2170.5323 0.458286 0.6857365 68.573654
1450 2200.6623 0.4658862 0.6821812 68.218119
1500 2232.5148 0.4728201 0.6789696 67.896957
 120

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200 400 600 800 1000 1200

T (K)
 CO2 + C = 2CO
FeO + CO = Fe + CO2
MgO + CO = Mg + CO2
CdO + CO = Cd + CO2
1/2 MoO2 + CO = 1/2 Mo + CO2

1000 1200 1400 1600