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Guidelines
September, 1996
CAPP Pub. #1996-0014
*
The Canadian Association of Petroleum Producers (CAPP) represents 180 companies whose activities
focus on exploration, development and production of natural gas, natural gas liquids, crude oil,
synthetic crude oil, bitumen and elemental sulphur throughout Canada. CAPP member companies
produce approximately 95 per cent of Canada's natural gas and crude oil. CAPP has 115 associate
member companies who provide the broad range of services that complete the infrastructure of this
country's upstream petroleum industry.
The Canadian Energy Pipeline Association (CEPA) is the voice of the Canadian energy pipeline
industry. Our 11 member companies are responsible for transporting more than 95 per cent of the
crude oil and natural gas produced in Canada. As the Association for the transmission pipeline
companies, CEPA's mission is to provide effective representation to governments, regulators and the
public. We establish the pipeline industry as a key stakeholder in the Canadian economy and as a
leader in the areas of operational and environmental stewardship.
Disclaimer
This report was prepared for the Canadian Association of Petroleum Producers
(CAPP) and Canadian Energy Pipeline Association (CEPA) and prepared by Tera
Environmental Consultants (Alta.) Ltd. and CH2M Gore and Storrie Limited. While
it is believed that the information contained herein is reliable under the conditions
and subject to the limitations set out, neither Tera Enviromnental Consultants (Alta.)
Ltd. and CH2M Gore and Storrie Limited nor CAPP guarantee its accuracy. The use
of this report or any information contained will be at the user's sole risk, regardless
of any fault or negligence of Tera Environmental Consultants (Alta.) Ltd. and CH2M
Gore and Storrie Limited or CAPP.
EXECUTIVE SUMMARY
their members with a summary of the environmental concerns associated with hydrostatic 'I
testing, guidelines used to minimize the risk of environmental impacts and an overview of the II
environmental regulatory requirements associated with hydrostatic testing.
Testing of new pipelines presents relatively limited potential for environmental impacts and,
consequently, the sampling and protection measures recommended are generally straight
forward. However, the testing of in-service pipelines has a greater potential for environmental
impact and typically requires more extensive planning. Water used for these tests may
require treatment prior to release and more extensive sampling.
Members of CAPP and CEPA operate pipelines that traverse many of the provinces and
territories of Canada. This report provides the members of CAPP and CEPA with an overview
of the environmental regulatory requirements associated with hydrostatic testing in areas of
Canada in which the members are active.
The environmental regulatory requirements for the withdrawal and release of hydrostatic test
water vary according to the jurisdiction in which the testing is to occur. Nevertheless, most
jurisdictions require approvals be in place for both water withdrawal and release. Acquisition
of approvals for hydrostatic testing of new pipelines is generally relatively straightforward,
Pagei
Approvals obtained from government agencies for water withdrawal typically include the
source waters to be used, the withdrawal rate, screening requirements, total volume to be
taken, cost of the water and period of withdrawal.
Government agencies typically approve the release location, discharge rate and minimum
acceptable water quality criteria on test water discharge approvals.
Pageii _
The Hydrostatic Test Water Management Guidelines were prepared under the guidance of
the Hydrostatic Water Management Task Force composed of:
!I
Ken Jenner Cyril Karvonen 'i
AEC Pipelines, Alberta Energy Company Pembina Corporation 'I
Edmonton, Alberta Calgary, Alberta Ii,
Ian Mackenzie Wayne Marshall
Alberta Environmental Protection National Energy Board
Edmonton, Alberta Calgary, Alberta
John Sutherland
Alberta Energy and Utilities Board
Calgary, Alberta
Core Water Test water between the zones of interface water where the
potential for contamination is least during testing of
previously in-service pipelines.
DO Dissolved oxygen
EC Electrical conductivity
Interbasin transfer The movement of water from one major drainage basin to
another; some jurisdictions consider major rivers (eg.
North Saskatchewan and South Saskatchewan) as
individual drainage basins while others consider all
watercourses that flow to the same final destination as
part of one drainage basin (eg. Hay, Peace, Athabasca and
Liard rivers would all be part of the MacKenzie River
drainage basin).
Interface Water The water immediately behind the lead pig and in front of
rear pig where the potential for contamination is greatest
during testing of previously in-service pipelines.
Page v
EXECUTIVE SUMMARY . . • . . . • • • • • . . . • . . . . • • • . • . . • . . • • • • • • • • • • . . . . • • • . •• 1
ACKNOWLEDGEMENTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . III
LIST OF APPENDICES Ii
I
APPENDIXA WATER HANDLING FLOW DIAGRAMS
APPENDIX B HYDROCARBON SPECTRUM DIAGRAM
APPENDIX C EXAMPLE CHAIN OF CUSTODY RECORD
APPENDIX D TREATMENT TECHNOLOGY SUMMARIES
APPENDIX E SPILL CONTINGENCY PLAN
APPENDIX F TESTING RELATED CONVERSIONS
I
Ii
APPENDIX G ALBERTA ENVIRONMENTAL PROTECTION CODE OF ii
PRACTICE FOR DISCHARGE OF WATER FROM
HYDROSTASTIC TESTING OF PETROLEUM, LIQUID
AND NATURAL GAS PIPELINES
LIST OF FIGURES
LIST OF TABLES
Pressure testing of a new pipeline is required prior to commissioning to prove its integrity at
operating pressure. Hydrostatic testing is the most common pressure testing method. Testing
of an in-service pipeline may be done as part of a preventative program to verify pipeline
integrity. In-service pipelines may also be tested if operating pressures are to be increased,
modifications to the pipeline are made or a change in line service is planned. Approval from
regulatory agencies must be acquired prior to testing. Regulatory approvals have been put in
place to minimize the risk of unacceptable environmental impact or adverse impacts on other
water users as a result of testing activities. Mitigative measures outlined in this report have
been designed to minimize the potential for environmental impacts during testing.
This report has been prepared to provide the Canadian Association of Petroleum Producers'
(CAPP) and Canadian Energy Pipeline Association's (CEPA) members with a summary of
environmental considerations related to hydrostatic testing. It includes a summary of:
potential environmental impacts or concerns associated with hydrostatic testing; guidelines
for minimizing these environmental impacts; treatment/release options for handling test water
contaminated with hydrocarbons, test additives, metals or other deleterious materials; and
a review of environmental regulatory requirements related to hydrostatic testing in regions
of Canada where CAPP and CEPA members are active. The purpose of this document is not
to identify rigid practices that must be implemented during all hydrostatic testing operations.
Rather, this report has been designed to:
• identify potential environmental impacts that could arise from water withdrawal,
handling and release during testing;
• provide environmental protection measures that pipeline companies may wish to adopt
in their testing plans;
• identify and describe options from which companies may select the most appropriate
method to treat or release contaminated test water;
1-1
1-2
Hydrostatic testing involves the filling of a section of pipeline to be tested with water, adding
additional water to the pipeline until the desired test pressure is reached and maintaining the
pressure in the pipeline for a period specified by regulatory authorities. Pipelines are
hydrostatically tested in order to prove the integrity of the pipe and welds to the owner
company, regulatory authorities and the public. This procedure is conducted on new pipelines
as well as on in-service pipelines when a change of service is proposed, an increase in
operating pressure is planned or to verify the integrity of the pipeline. Hydrostatic testing
must be conducted in accordance with CSA Z662-94 - Oil and Gas Pipeline Systems. This
national standard stipulates test pressures, test durations and other engineering
requirements.
Failure of an operating pipeline can result in health and safety concerns, damage to property
and has the potential for significant environmental impact. Consequently, it is important to
ensure that a pipeline is free of leaks and is capable of maintaining its integrity at an
approved operating pressure in order to limit the risk to the public and the environment.
Safety of the public and workers along the right-of-way are also of concern during testing due
to the high test pressures involved. Companies conducting tests are required to follow all
safety precautions and regulations. Companies are required to post warning signs and advise
the public of danger.
The pipeline section to be tested is then filled with test water which is confined between a
minimum of two pigs. The volume of water required for a test is dependent upon the length
of the test section, diameter of the pipe (Table 2.1), season of testing (i.e. if hot water is to be
circulated prior to initiation of the test), need for contingency water in case of a test failure
and quantity of additives to be used. Since the transportation of water to a fill site can be very
expensive, fill points are usually situated at locations where the pipeline crosses or closely
approaches a watercourse or waterbody with an adequate water supply available for testing.
2-1
2-2
pipeline from one test section to another in order to minimize water requirements. Since the ;!
!
test section of an operating pipeline may be downstream from the nearest terminal or fill
point, the water may be required to travel along the pipeline for a considerable distance prior !~
to reaching the test section. Water used during testing of an in-service pipeline will come in II
il
contact with any residual hydrocarbons and contaminants on the wall of the pipeline,
hydrocarbons encountered at bypasses and stations as well as hydrocarbons encountered at II
the interfaces. Therefore, contamination of the test water with hydrocarbons will occur to II
some extent.
The potential exists for water to freeze in a pipeline under test when ground temperatures are
below freezing. To avoid this occurrence, either additives such as methanol or ethylene glycol
are added to the water during filling to reduce the freezing point of the test water or heated
water is circulated through the test section for several hours until the temperature of the pipe
and surrounding ground reach 2' to 4' C. Larger diameter pipelines (ie. ~ 406.4 mm a.D.) are
less susceptible to freezing below ground than smaller pipelines but may still require above
ground piping and valving to be protected and heated.
Some pipeline companies use other additives during testing to minimize the risk of corrosion
to the pipeline when the pipe is filled with water. The potential exists for bacterial activity
in the source water to result in internal corrosion of the pipe. A biocide batch may be run after
dewatering to eliminate any remaining bacteria while avoiding contamination of the test
water. Since the presence of oxygen in the water can accelerate corrosion, some companies
add oxygen scavengers to the test water to remove free oxygen. Under some circumstances,
biocides may be added to the test water to minimize impacts on down hole formations if test
water is discharged to an injection well. Biocides may also be used to kill bacteria, fish
pathogens or other undesirable aquatic biota when water is to be transferred from one
drainage basin or waterbody to another during testing. Some test additives such as
mercaptans, other odourants or dyes (e.g. Flourescein) are sometimes used during testing to
assist in the location of small leaks. Additional information on test additives is presented in
Section 4.1.
2-3
If the pressure remains constant, the test is deemed successful and the test section can be
depressurized. The test water is commonly discharged from the pipeline by inert gas (e.g.
nitrogen) or product to push the pigs through the pipe. In some cases (eg. new pipelines)
compressed air may also be used for dewatering. Additional pig runs are then generally
conducted until no more water can be removed from the pipe by this method. A final slug of
methanol may be used to dry the pipeline. If the test does not maintain pressure throughout
the required period, this indicates there is a pipeline leak which must be located. Then, the
pipeline must be exposed to repair the leak and the pipeline retested. Occasionally, a pipe
under test will suddenly fail and discharge test water. Test failures can result in flooding of
localized areas or the degradation of soil or water quality if the source water was of low quality
or the test water has been contaminated with hydrocarbons or additives. In order to minimize
the risk to the public, warning signs are erected at road crossings and other points of entry to
the pipeline right-of-way under test, and in populated areas, blasting mats may be placed and
evacuation of nearby residents required.
Water used to test new pipelines is often discharged onto noncultivated lands, (e.g. pasture,
bar ditches) or into storm sewers, disposal wells, ponds, lakes or watercourses. Since the
potential exists for contamination of the test water with hydrocarbons during testing of in-
service pipelines, subsequent treatment or special release measures may be required for the
test water upon completion of the test.
Testing of in-service oil, product and condensate pipelines have the greatest potential for
contamination of test water, while contamination during testing of gas or natural gas liquid
pipelines generally results in lower levels of contamination and testing of new pipelines has
the least potential for contamination.
The portion of water that is most contaminated with hydrocarbons is referred to as the
interface waters. Although the volume of the interface water varies according to the length
of the test section, hydraulic conditions and other factors, the volume of the interface water
2-4
I:
I
I:\:
u
Ii
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2-5
I"I'I
II
CORE
• •
INTERFACE
•
•INTERFACE
WATER WATER
PROFILE
N.T.S.
NOTE: Pig type and number should be selected to minimize core water contamination.
2-6
Planning of a hydrostatic test program involves the selection of an appropriate test water
source. Figure 1 (Appendix A) provides a summary of the water withdrawal decision making
process. Ideally the source water should be:
• of high quality;
• economical.
Most operators attempt to use the highest quality source water available for testing to
minimize the risk of pipeline corrosion and optimize test water release options. However, the
selection of a water source is also affected by the volume required, availability and cost. Test
volumes required can vary significantly depending upon the diameter of the pipeline
(Table 2.1) and length of the test section. Potential source waters include surface water,
potable municipal water supplies and groundwater. Regulatory approval, for both water use
and activities related to the withdrawal of water from the water source, is required, as
discussed in Sections 8.0 and 9.0.
Potable water supplies are generally among the highest quality source waters since they are
required to meet the Canadian drinking water guidelines. These water sources are unlikely
to introduce substances of concern into the hydrostatic test water but could cause concern in
the event of a test failure on a new pipeline, or, cause test water release problems. The metals
and chlorine found in some potable waters could adversely affect sensitive aquatic species.
When testing in-service pipelines, chlorine, if present in high concentrations could combine
with residual hydrocarbons to produce undesirable compounds. Under these circumstances
testing for residual chlorine and/or treatment measures (e.g, aeration) may be required.
3-1
The main objective of analyzing the source water is to confirm that substances that could pose
a discharge problem are not being introduced. Surface water or groundwater may be tested
for total dissolved solids, salts (electrical conductivity, sodium absorption ratio), pH, trace
metals and suspended solids. Additional analyses may be conducted if there is a concern of
introducing substances that could adversely affect the environment. Sampling and analytical
methods are discussed in Section 5.0.
The selection of a test water source is also dependent upon the ability to obtain approval from
regulatory agencies and the landowner. For example, an alternate source may be required if
a landowner or water management agency denies access to an otherwise ideal source of test
water.
The potential exists during water withdrawal to adversely affect aquatic biota, soils and land
use. The degree of risk to these environmental components is influenced by the:
• volume withdrawn;
3-2
Overwintering fish and incubating eggs of fall spawning fish may be particularly sensitive to II!
reduced streamflow since streamflows are lowest in many regions of the country during the
winter months and adequate water depth and streamflow are required to prevent freezing of
the body of water to the bottom. Inadequate screening of water intakes and excessive intake
velocities can result in mortality if fish eggs or small fish are withdrawn from the body of
water.
Fish and fish habitat could also be adversely affected by intake site preparation (excavation
of sumps or clearing of riparian vegetation) or by an accidental spill of fuel or lubricants
during water withdrawal activities. Instream activities during sensitive life history phases
(spawning, incubating, rearing and overwintering) have a higher potential for affecting fish.
Aquatic furbearers and waterfowl could be adversely affected by inadequate water levels if a
large volume of water was withdrawn during sensitive time periods (e.g. under ice covered
conditions or during staging or nesting periods). A substantial reduction in water levels may
result in den abandonment or the loss of, or reduction in, preferred food sources for furbearers.
Severe reductions in water levels could adversely affect waterfowl by increasing access by
predators to nests and reducing food availability. Alteration or loss of riparian wildlife habitat
could also occur as a result of water withdrawal activities. Accidental spills of fuel or
lubricants could adversely affect waterfowl and aquatic furbearers and their habitats.
Auditory and visual disturbances arising from water withdrawal activities during sensitive
time periods could result in nest abandonment by waterfowl or nesting raptors as well as
temporary abandonment of optimum habitat by other wildlife species.
3-3
Excessive water withdrawal rates or volumes can adversely affect other water users such as Ii
irrigators, livestock, landowners, land users or recreationists if water is withdrawn from small II
watercourses or bodies of water. Access to water withdrawal points can result in rutting and ii
compaction of soils, loss of crop production as well as loss of timber. If trucking of water is
required from the source to the fill point, heavy truck traffic could result in road damage, II
i
safety concerns and dust problems.
I,
3-4
3-5
3-6
River or
Sorbant Boom
Hydraulic hoses
PROFILE
N.T.S.
NOTES:
1. Install a riveror sorbant boom around instream pumps where hydraulic hoses are
in useand contamination of the body of water could occur should hydraulic hose
failure occur.
4. Employ sorbant pads to remove any excess hydraulic fluid not captured by the
boom.
Canadian Association of
Petroleum Producers INSTREAM FILL PUMP - SORBANT BOOM
and
Canadian Energy
Pipeline Association Date: September, 1996 Figure No. 3.1
3-7
This section describes the nature and composition of hydrostatic test waters resulting from
the testing of new pipelines, in-service gas pipelines and in-service liquid petroleum pipelines.
Factors affecting the composition of hydrostatic test waters such as the quality of source water
used for hydrostatic testing, additives to hydrostatic test water and the nature of products
previously transported in the pipeline are discussed.
For each of the three types of pipelines (new, in-service gas and in-service liquid petroleum),
typical concentration ranges for a number of water quality parameters are provided and
expected substances of concern are identified.
The above information is useful in developing a water handling decision process, as shown in
Figure 2 in Appendix A Once expected contaminants and contamination minimization
methods have been identified, a sampling and analytical program can be established and
discharge and treatment options assessed. These aspects of the water handling decision
process are discussed in Sections 5, 6 and 7, respectively.
4.1 Characterization
A key factor affecting the composition of hydrostatic test discharge water is the quality of the
source water used in the test. The nature and quality of source water were discussed in
Section 3.1.
4-1
Hydrostatic test waters may contain a number of additives, depending upon the nature of the
source water, the time of year of testing and other case specific factors. Additives may include:
antifreezes, biocides, corrosion inhibitors, oxygen scavengers and leak detection tracers.
Antifreezes may be added, particularly during winter testing. Methanol, being the least
expensive, is most commonly used. It is normally supplied by a pipeline services contractor
as a methanol-water mixture (e.g. typically 20-40% methanol), recovered in tanks after testing
and returned to the supplier for recycling. An adverse effect of antifreezes is an increase in
chemical oxygen demand, which could in turn affect aquatic life if a break or leak in the line
i
occurs. An alternative to adding antifreeze is to heat the hydrostatic water prior to testing
the line. However, warmer water may be more likely to remove contaminants from the II
'I
pipeline wall and keep them in solution.
I'I
Biocides may be added to hydrostatic test waters to kill microorganisms. This may be required
to prevent corrosion of the pipeline by sulphate reducing bacteria during testing and/or to
prevent the interbasin transfer of undesirable biota. However, some pipeline companies have
found biocides to be unnecessary because of the short time that the water is in the line. In this
case, a biocide wash is run after hydrostatic testing and before filling the line with petroleum
product. Some operators use chlorinated municipal water to achieve the necessary disinfection
while other operators add over-the-counter bleach products in concentrations of 100 to
300 ppm. Biocides have a toxic effect on aquatic species. In some cases, chlorine could lead
to the formation of chlorinated hydrocarbons, for example, if the concentration of chlorine is
high.
Corrosion inhibitors are not often added to hydrostatic test waters to prevent corrosion during
testing, because the test water is only in the pipeline for a short period of time and the
opportunity for corrosion is limited. Some operators that previously used corrosion inhibitors
have ceased their use because no noticeable benefit was observed. Corrosion inhibitors
typically contain quaternary amines in a solvent carrier, which may be problematic from a
treatment and release perspective. Corrosion inhibitors may be toxic to aquatic life.
Oxygen scavengers may be used to prevent pipeline corrosion. Aquatic life can be adversely
affected by oxygen scavengers due to their capacity to reduce available oxygen required by
aquatic life. However, like corrosion inhibitors they are rarely used during hydrostatic
pressure tests.
Leak detection tracers are added by some operators during hydrostatic testing of pipelines.
Both visual and odour detection tracers are used. Fluorescein, which is a tracer dye, is highly
4-2
An odour tracer contains an odorous chemical that has a high vapour pressure and readily
migrates through soil. Trained dogs can detect the chemical at concentrations below 1 ppb.
The chemical composition of the tracer is proprietary, however, alkyl sulphide is a key
ingredient. Mercaptans may also be used as an odour tracer. Pipeline operators walk the
pipeline with vapour detectors or other analytical instruments to detect line leaks.
Sulphur hexafluoride gas is used by some companies for leak detection. It is added to the
hydrostatic test water and an instrument is used to detect the gas from leaks along the line.
Sulphur hexafluoride gas is considered nontoxic and it has minimal solubility in water.
However, it is a greenhouse gas with a high global warming potential (24,900 times that of
carbon dioxide), which liberates upon depressurization and dewatering ofthe pipeline.
All new pipelines require pressure testing before commencing operation. Consequently, new
pipelines account for most hydrostatic testing that is currently conducted in Canada.
However, an increasing number of in-service pipelines are being tested when the pressure
rating of the pipeline is to be increased, a change in service is planned or as part of a
preventative program to ensure pipeline integrity. While regulators do not require routine
testing of in-service pipelines, individual pipeline companies may choose to conduct routine
testing as part of a corporate initiative.
The quality of hydrostatic test water discharged from new pipelines may vary considerably
from that released from in-service pipelines. In general, hydrostatic test water from new
pipelines is less contaminated than water from in-service lines since there is no residual
petroleum product in the line. Substances that would be expected to be present in the
hydrostatic test water from new lines include metals from the pipeline steel, and welding
debris. The extent of contamination may vary depending on whether the pipeline is internally
coated or uncoated and how well it was cleaned before testing; coated pipelines would be
expected to release metals in lower concentration than uncoated pipelines.
Substances which may be of potential concern during hydrostatic testing of in-service gas
pipelines include carry over products from compressor stations and gas processing such as
4-3
Testing of liquid petroleum pipelines can result in contaminated hydrostatic test water due
to contact with residual material on the pipeline walls. Liquid petroleum products include
crude oil, condensate, NGL, fuel oil and other refined products. A wide range of hydrocarbons
could be present in hydrostatic test water used for testing of in-service liquid petroleum
pipelines depending upon the type of product previously transported in the pipeline.
Hydrocarbons may range from light aliphatic compounds to heavier naphthenic and aromatic
compounds, as illustrated in the hydrocarbon spectrum diagram in Appendix B. Similar to
testing of in-service natural gas pipelines, some substances may also carry over from pipelines
connected to upstream processing plants as well as substances encountered at by-passes and
stations.
Table 4.1 provides water quality data for hydrostatic test waters discharged from new
pipelines, in-service gas pipelines and in-service petroleum products pipelines. The
information shown is based on data provided by several pipeline companies in Canada and
results of studies conducted by the Gas Research Institute (1992, 1996). Because the
composition of hydrostatic test water varies on a case-by-case basis, ranges have been provided
for most parameters. CCME Canadian Water Quality Guideline Criteria are also provided in
Table 4.1 for comparison. However, they are not meant to represent the maximum allowable
contaminant concentrations for discharge waters.
There is variability in the water quality data shown in Table 4.1. This is primarily because
there is a limited water quality data base and many data gaps still exist. The data base
should improve as more pipeline companies conduct hydrostatic testing and monitor the
discharge water quality. Pipeline companies are encouraged to keep records of their water
quality data for their own purposes and also to help improve this data base.
4-4
Concentration (mgfL)l
IN·SERVICE
LIQUID CCME CCME
WATER IN-SERVICE PETROLEUM FRESHWATER CCME LIVESTOCK
QUALITY NEW PIPELINE GAS PIPELINE PIPELINE CCMEDW AQUATIC LIFE IRRIGATION WATERING
PARAMETER DISCHARGE' DISCHARGE' DISCHARGE' CRITERIA' CRITERIA' CRITERIA' CRITERIA'
Benzene <0.002 - 0.0046 <0.001 - 0.100 ND -18.0 0-005 0-3 NL NL
. ~
Phenols
<1-43
<0.001- 0.61
<1-79
ND -0.964
1- 5630
NL
NL
0-001
NL
NL
NL
NL
NL
'" 0:
0
COD 6 - 240 <10 - 993 7 - 66 NL NL NL NL
pH (no units) 4.5 -10.1 5.45 - 8.6 6.6 - 8.1 6.5 - 8.5 6.5 - 9.0 NL NL
~
i5
EC (uS/em)
Chlorine
18 - 2370
12 - 28
34 -760
NDA
NDA
NDA
NL
NL
NL
0.002
NL
NL
NL
NL
(residual)
Chloride NDA NDA 23.2 - 128 250 NL 100 - 700 NL
." -_.
TABLE 4.1 Cont'd
Concentration (mgIL)l
IN-SERVICE
LIQUID CCME CCME
WATER IN-SERVICE PETROLEUM FRESHWATER CCME LIVESTOCK
QUALITY NEW PIPELINE GAS PIPELINE PIPELINE CCMEDW AQUATIC LIFE IRRIGATION WATERING
PARAMETER DISCHARGE' DISCHARGE' DISCHARGE' CRITERIA' CRITERIA' CRITERIA' CRITERIA'
Aluminium 0.05 - 2.03 0.04 - 0.4 0.02 - 0.19 NL 0.005 - 0.1 5 5
Arsenic 0.0012 - <0.002 <0.002 - 0.06 NDA 0-025 0-05 0·1 0.5-5.0
Barium 0.01- 0.066 <0.02 - 0.06 0.02 - 0.122 1 NL NL NL
Beryllium <0.001- 0.003 NDA <0.001 NL NL 0-1 0·1
Boron <0.04 - 0.3 NDA ND-0.12 5 NL 0.5 - 6.0 5
Cadmium <0.0002 - 12 <0.01- 0.016 ND - 0.005 0.005 0.0002-0.0018 0.01 0.02
Chromium 0.005 - 0.01 NDA <0.002 - 0.008 0-05 0.002 - 0.02 0-1 1
'"
"" Cobalt <0.001 - 0.009 <0.005 - 0.04 ND - 0.003 NL NL 0-05 1
;:!
'"
:;: Copper <0.001 - 1.19 0.001- <0.10 <0.001 - <0.01 1 0.002 - 0.004 0.2 -1.0 0.5 - 5.0
. Iron (total)
Lead
0.05 - 46
<0.001 - 0.696
0.003 - 29.0
<0.001 - 0.077
0.02 - 33.4
<0.02 - <0.04 0.01
0.3 0-3
0.001- 0.007
5
0-2
NL
0.1
'" Manganese 0.01- 1.9 0.1- 0.3 0.121 - 0.319 0.05 NL 0-2 NL
Mercury <0.00005 NDA <0.0001 0.001 0.0001 NL 0-003
Molybdenum <0.004 - 0.073 NDA <0.003 - <0.02 NL NL 0.01- 0.05 Q.5
Nickel <0.01- 0.18 <0.02 - 0.1 <0.01- <0.02 NL 0.025 - 0.150 0-2 1
Selenium <0.0005 - 0.004 <0.002 - 0.004 NDA 0-01 0-001 0.02 - 0.05 0.05
Silver <0.001- 0.003 NDA ND - <0.05 NL 0-0001 NL NL
Sodium 2.1- 390 20 - 240 2.72 - 79.4 200 NL NL NL
Vanadium 0.004 - 0.06 <0.025 - 0.06 <0.003 - 0.272 NL NL 0.1 0-1
7.in, 0004 - 140 ,0 OOQ _ 0 1A O""7_1~ < "OQ QMAR <0
>I< Nljenondetectable
NDA = no data available
NL = no limit established
The water quality parameters have been divided into four main categories:
• Organics;
• Inorganics;
• Metals; and
• Other parameters.
• Free hydrocarbons;
• Emulsified hydrocarbons; and
• Dissolved organics
Benzene, toluene, ethylbenzene, xylenes (BTEX)
Polynuclear aromatic hydrocarbons (PARs)
Phenols
Glycols (if added)
Methanol (if added).
BTEX, PARs and phenols may be present as dissolved organics and free emulsified hydro-
carbons. Glycol and methanol will be present in a dissolved form, if used as additives.
• pH
• Total suspended solids (T88)
• Total dissolved solids (TD8)
•. EC
• 8AR
• Temperature
• Residual chlorine
• Chloride
• Dissolved oxygen (DO)
• Amines
4-7
Trace metals may be present in dissolved or particulate forms likely as metal oxides or
sulphides.
These are the substances commonly found in hydrostatic test waters. Additional substances
may be of concern if they are regulated by government authorities or pose an environmental \~
j"
or health risk. This may be the case if the hydrostatic test water is released to an
environmentally sensitive, highly populated or tightly regulated area. II
'I
A more detailed discussion of hydrostatic test water characteristics for new, in-service gas and III,;
in-service liquid petroleum pipelinesis provided below.
II
New Pipelines iIi
Ii
Table 4.1 provides ranges of water quality data for hydrostatic test waters from new pipelines, II
'I
including new pipeline for gas service and liquid petroleum service, internally coated and
uncoated pipelines, and small and large lines. A variety of discharge criteria are also included
for the purposes of comparison. The water quality data shown in Table 4.1 were obtained from
a limited data base for a range of new pipelines.
Based on the data provided in Table 4.1 and data from a 1992 GRI study, the main water
quality parameters typically of concern for new lines are metals. Among these metals are iron,
manganese and zinc. For each of these metals, the concentrations are above either the CCME
drinking water or freshwater aquatic life criteria. Even though the drinking water standards
for these metals are set for aesthetical rather than toxicological concerns, the trend in some
jurisdictions for discharge criteria is increasingly towards the Canadian drinking water
quality guidelines. However, zinc may be toxic to aquatic life, if present at concentrations
above CCME criteria of 0.03 ppm.
Iron levels as high as 46 mg/L have been measured in hydrostatic test water from new
pipelines, however, iron concentrations are typically less than 10 mgIL. Manganese levels as
high as 1.9 mg/L have been measured but they are typically less than 0.3 mg/L. Zinc levels
are typically less than 0.1 mg/L.
4-8
Residual chlorine levels may be a concern if a chlorinated water source is used or if chlorine
is added as a biocide to the test water.
A typical pH range for hydrostatic test water from new pipelines is about 6.5 to 8.5. However,
the pH may fall outside of this range, depending on the pH of the source water.
Total dissolved solids (TDS) levels are generally not of concern; however, elevated TDS levels
may occur if the source water for hydrostatic testing has high TDS. Total suspended solids II
(TSS) levels are typically less than 100 mg/L, however, levels as high as 966 mglL have been
measured in some hydrostatic test waters from new pipelines. This concentration level may
Ii
I. .!·
,:
have been the result of excess debris in the line, particularly if the line was not pigged before
testing.
Temperature may be a water quality parameter of concern if the hydrostatic test water is
discharged to a receiving water. A change in temperature of the receiving water body could
have adverse effects on the aquatic life.
Organics are generally not substances of concern for hydrostatic test waters from new
pipelines. Benzene, toluene, ethylbenzene and xylenes (BTEX) levels are well below the
CCME criteria for drinking water and freshwater aquatic life. Phenol levels as high as 0.05
mg/L have been measured, which exceeds the CCME criteria for freshwater aquatic life,
however, phenol levels are typically less than 0.001 mg/L, Oil and grease levels are typically
less than 50 mg/L.
Sodium adsorption ratio (SAR) data are not included in Table 4.1 as they were not readily
available. However, the SAR of hydrostatic test water could be an important water quality
parameter. For example, a release of water with high SAR to land could have an adverse
effect on soil conditions.
Table 4.1 provides ranges of water quality data for hydrostatic test waters from in-service gas
pipelines, as well as various discharge criteria.
4-9
• The discharge waters contained low levels ofTOC, COD, oil and grease, iron, TSS
and TDS.
• Oil and grease concentrations varied over a wide range during hydrostatic testing
(up to 2 orders of magnitude).
• Acute toxicity studies indicated that the discharge waters were not acutely toxic
to fathead minnows, but were acutely toxic to daphnia.
Based on the data provided by Canadian pipeline companies, it appears that organic
substances may be of concern in some cases. Elevated oil and grease as well as phenol levels
have been measured in some hydrostatic test waters from in-service gas pipelines. This is
likely the result of carry over products.
As with new pipelines, in-service gas pipelines may have elevated levels of iron, manganese
and zinc. Of these, iron appears to be the main concern. Iron levels as high as 29 mglL have
been measured. Manganese levels typically exceed the CCME drinking water criteria but
generally meet the CCME irrigation criteria. Zinc concentrations are well below the drinking
water and irrigation criteria but may exceed the CCME freshwater aquatic life criteria.
Elevated levels of other metals have been reported for hydrostatic test waters from in-service
gas pipelines. These include aluminum, cadmium, copper and lead. However, the levels of
these metals are not typically of concern.
4 -10
Typical pH ranges for hydrostatic test water from in-service gas pipelines is about 6.5 to 8.5.
However, the pH may fall outside of this range, depending on the pH of the source water.
TDS levels are generally not of concern. While some elevated levels have been measured,
these are likely because the source water for hydrostatic testing had high TDS. Typically, TDS
levels are below 500 mg/L.
TSS levels are typically less than 1000 mg/L, however, levels as high as 2,348 mg/L have been
measured in some hydrostatic test waters from in-service gas pipelines. This concentration
level may have been the result of excess debris in the line (e.g. inactive pipeline), particularly
ifthe line was not pigged before testing.
Temperature may be a water quality parameter of concern if the hydrostatic test water is
discharged to a receiving water. A change in temperature of the receiving water body could
have adverse effects on the aquatic life.
SAR data are not included in Table 4.1 as it they were not readily available. However, the
SAR of hydrostatic test water could be an important water quality parameter. For example,
a release of water with high SAR to land would have an adverse effect on soil conditions.
Table 4.1 provides water quality data for hydrostatic test waters from in-service liquid
petroleum pipelines, as well as various discharge criteria. The data shown are for core waters
rather than interface waters.
The main substances of concern are organics such as free, emulsified and dissolved
hydrocarbons. Elevated levels of oil and grease, TPH, BTEX and phenols can be expected in
hydrostatic test water from in-service liquid petroleum pipelines, indicating the need for some
treatment before discharge.
As shown, there is a wide variation in organic concentrations. This variability may be because
the organic concentration is highly dependent on the location and time of sampling. For
example, BTEX compounds may volatilize and biodegrade over time when exposed to air.
Therefore, samples collected immediately after discharging will have a higher BTEX
concentration than those collected after being exposed to air (e.g. in a pond, dugout or open
tank). Immediately after discharging, BTEX levels are typically in the low ppm range and
4-11
Other substances that may be of concern are: iron; trace metals; suspended solids; and
dissolved solids.
Iron levels as high as 33 mg/L have been measured in hydrostatic test water from in-service
liquid petroleum pipelines; however, iron concentrations are typically less than 10 mg/L,
Manganese levels typically exceed the CCME drinking water criteria but generally meet the
CCME irrigation criteria. Zinc concentrations are below the drinking water and irrigation
criteria but may exceed the CCME freshwater aquatic life criteria.
Other metals that may be of concern in hydrostatic test waters from in-service liquid
petroleum pipelines are aluminium, copper, cadmium and lead. While the concentration of
these metals are typically below the CCME drinking water and irrigation criteria, they may
exceed the CCME freshwater aquatic life criteria.
Residual chlorine levels may be a concern if a chlorinated water source is used or if chlorine
is added as a biocide to the test water.
Typical pH ranges for hydrostatic test water from in-service liquid petroleum pipelines are
about 6.6 to 8.1. Measurements outside this range were not reported.
TDB levels are generally not of concern, however, elevated TDB levels may occur if the source
water for hydrostatic testing has high TDB. While TBB levels are typically less than 1000
mg/L, higher levels may occur in some hydrostatic test waters from pipelines as a result of
excess debris in the line (e.g inactive line).
BAR data are not included in Table 4.1 as they were not readily available. However, the BAR
of hydrostatic test water could be an important water quality parameter. For example, a
release of water with high BAR to land would have an adverse effect on soil conditions.
Temperature may be a water quality parameter of concern if the hydrostatic test water is
discharged to a receiving water. A change in temperature of the receiving water body could
have adverse effects on the aquatic life.
Chloride levels between approximately 23 and 128 mg/L have been measured in hydrostatic
test water from in-service liquid petroleum pipelines. These levels are below the CCME
drinking water criteria and only slightly above the lower limit of the irrigation criteria range.
4 - 12
Contamination minimization methods vary depending on the type of pipeline (new or in-
service) and the products carried. Tbis section describes contamination minimization methods
currently used by pipeline companies. They have been divided into three categories: general
considerations, pipeline preparation and interface management. Consideration should be
given to these measures during the planning stage of a hydrostatic test.
General Considerations
Some general considerations for minimizing contaminant levels in hydrostatic test water are
provided below. These focus on the quality of source water, water additives and discharge
water handling practices.
• Use a bigh-quality water source (see Section 3.1). Source waters with high levels
of salt content (especially sodium or chlorides) should be avoided, if possible.
Salts cannot be practically removed and they could cause adverse impacts if
released during a failure of the test, or discharged onto the ground or a body of
water of high water quality.
• Avoid or minimize the use of additives ifpossible (see Section 4.1). For example,
use non-toxic, biodegradable or photodegradable additives and minimize dosages.
• For in-service lines, recognize the potential for hydrocarbon contamination from
carry over products (e.g, from compressor stations, processing facilities, etc.),
4 - 13
• If storing hydrostatic test water before treating or discharging, use clean tanks.
Pipeline Preparation
• Pigging new lines to remove mill scale, rust and debris. A combination of brush
pigs followed by polyurethane pigs is used by some companies. II
II
II
• Draining in-service lines of product and purge with an inert gas (e.g, nitrogen) IiI:,
before hydrostatic testing to remove hydrocarbon products from branch II
II
connections.
• Pigging in-service lines before testing to remove hydrocarbon products and debris.
• Cleaning the pipeline with detergent or a solvent before hydrostatic testing. The
objective of cleaning is to prevent contamination of the test water, allowing it to
be discharged directly without treatment. One company in the U.S. successfully
used this procedure on an in-service gas line that had been pre-pigged to remove
liquids and debris (Hamilton 1994). Cleaning batches of caustic soap were run
through the pipeline and collected for offsite treatment and release. The volume
of cleaning batches represented only a small percentage of the test water. Most
of the hydrostatic test water met the regulatory discharge criteria for oil and
grease.
Pipeline preparation measures may be more applicable to new pipelines and inactive gas and
liquid petroleum pipelines.
Interface Management
Most in-service liquid petroleum pipelines are not drained of product before hydrostatic
testing. Instead, the petroleum product is used to push the hydrostatic test water through the
line and a series of pigs are used to provide a barrier between the petroleum product and the
test water (see Figure 2.1). The presence of residual petroleum product on the pipeline walls
4 -14
Hydrostatic test waters from in-service pipelines are comprised of interface waters and core
water, which should be managed separately. The interface waters lie between the core water
and the petroleum product, and generally have considerably higher organic concentrations
than the core water and may require additional treatment. By minimizing the volume of
water requiring treatment, equipment and operational costs can be minimized.
Some measures that can be taken by pipeline companies to minimize contamination of core
waters by interface waters and petroleum products are:
4 - 15
Sampling and analysis are an important component of the water handling and release decision
processes associated with hydrostatic testing (see Figures 2 and 3 in Appendix A). Sampling
and analysis are normally carried out to identify and quantify substances of concern. This
information is useful in assessing treatment and release options, assessing potential environ-
mental effects of a hydrostatic test water release, demonstrating compliance with regulatory
requirements and protecting against environmental liability.
This section describes sampling and analytical methods applicable to hydrostatic testing
source waters, release waters and receptors (for example, receiving waters or land). A
discussion of applicable sampling methods and locations is provided, along with a description
of applicable analytical methods for potential parameters of concern identified in Section 4.0.
The use of field analysis or screening techniques is also discussed along with quality control
procedures and practices.
A variety of samples may be collected for analysis during hydrostatic testing. These may
include baseline samples such as the source water; receiving waters or soils; intermediate
samples of hydrostatic test water; release water samples; and post-test samples of receiving
soils or waters.
Baseline sampling may involve the collection of source water samples or samples of receiving
waters or soils. Analytical data on these samples help to predict the water quality of the test
and release water as well as the potential effect on receptors. This information is useful in
evaluating suitable treatment and release options, and environmental protection measures.
Samples of source waters may be collected at the source (e.g. lake, dugout, river, groundwater
well, etc.) or during pipeline filling. However, it is beneficial to sample and test the source
water before hydrostatic testing to ensure suitability for testing and appropriateness of the
discharge location. Samples of receptors should be collected from locations expected to be
impacted by the release of discharge water (e.g, near discharge locations).
Intermediate sampling involves the collection of hydrostatic test water samples after the
pipeline is filled but before dewatering. These samples may be collected from either end of the
pipeline or at available locations along the pipeline (e.g. valves, air bleeds, etc.). Analysis of
5-1
Discharge water samples may be collected at various intervals during dewatering or after
dewatering is completed, assuming the discharge water is contained (e.g, in tanks or dugouts).
A study by the Gas Research Institute (GRI 1992) found that it may be difficult to collect
representative samples of hydrostatic test water directly from the pipeline outlet because of
the dynamic flow conditions. It was recommended that samples of hydrostatic test water be
collected at regular intervals throughout the test, particularly when the water characteristics
,i
are expected to change.
I
Grab samples can be collected manually at the pig trap at regular time intervals to identify
changes in water quality, as well as distinguish and segregate waters of varying composition.
Segregation of highly contaminated and less contaminated waters is likely necessary for
subsequent treatment and release (e.g. interface waters from core waters).
Representative samples of hydrostatic test water can be collected by compositing single grab
samples to obtain average water characteristics over a given time. Equal volumes of water are
collected at specific time intervals and combined in a sample container. For example, a one
hour 1000-mL composite sample can be obtained by collecting four 250-mL samples at 15
minute intervals. According to Gas Research Institute (1992) report, it may be sufficient to
sample core water at the beginning, middle and end of a discharge to obtain an overall
representative sample.
If the water characteristics are not expected to change with time, a single grab sample from
the pipeline outlet may be considered representative. Also if tankage or a holding pond is
available for storing the discharge water, a single grab sample may be taken from the holding
facility as representative of the total contents. However, care should be taken when sampling
through oil and water layers.
Post-test sampling involves collection of receptor samples (receiving water or land) after
releasing the discharge water. The objective is to assess and document the environmental
effect of the discharge water on the receptor and demonstrate regulatory compliance where
applicable. Depending on the type of receptor and the goals of post-test monitoring, samples
may be collected at various locations and time intervals. For example, samples may be
collected immediately after releasing the discharge water (to assess acute or immediate
effects) or some time after the release (to assess chronic or longer term effects).
For more information on specific water sampling methods and protocols refer to:
5-2
o U.S. EPA. 1983. Methods for Chemical Analysis of Water and Wastes. EPA
600/4-79-020, Revised March 1983. U.S. EPA Environmental Monitoring
Laboratory, Cincinnati, OR.
For more information on specific soil sampling methods and protocols, refer to:
o Carter, Martin R. (ed.), 1993. Soil Sampling and Methods of Analysis. Canadian
Society of Soil Science. Lewis Publishers. Boca Raton. Florida. II
Ii
I!
o McKeague, J.A. (ed.), 1981. Manual on Soil Sampling and Methods of Analysis,
2nd edition. Canadian Society of Soil Science.
Ii
ti
II
Analytical Parameters
The analytical parameters for baseline samples, hydrostatic testing discharge water and
receptors will vary on a case-by-case basis depending on the nature of the pipeline and pipeline
contents, regulatory requirements and discharge criteria, and treatment provided. Table 5.1
provides a summary of analytical parameters for source water; discharge water from new or
in-service pipelines; and receptors. Companies are encouraged to consider these parameters
when developing their monitoring program.
o Are there parameters that are not regulated but may adversely affect the
environment?
o Are there parameters that may affect treatment and release options?
5-3
Source Water
Potable Water Typically no analyses required as potable Parameters expected to be present that are regulated or
water meets Canadian drinking water could affect treatment or release options. For example:
standards
· parameters that have more stringent CCME
freshwater aquatic life criteria (e.g. chlorine,
cadmium, copper, lead, zinc)
Other source Depends on whether release of test water is Parameters expected to be present that are regulated or
waters (e.g. to land or to a receiving water. Typical could affect treatment or release options. For example:
groundwater, analyses include:
surface water,
industrial
·· Release to land: pH, BAR, EC or TDS ·· chlorine
metals such as iron, manganese, cadmium, copper,
water) Release to water: pH, TSS, EC or TDS, lead, and zinc
iron
· organics such as BTEX, phenol, TPH
Release Water
New pipelines Depends on whether release of test water is Other parameters that are regulated or could affect
to land or to a receiving water. Typical treatment or release options. For example:
analyses include:
In-service liquid Depends on whether release of test water is Other parameters that are regulated or could affect
petroleum to land or to a receiving water. Typical treatment or release options. For example:
pipelines analyses include:
Receptors
Receiving
Water ·· pH
TSS
Parameters that are regulated or may adversely effect
the environment:
· TDS orEC
·· organics if present in release water
metals if present in the release water
5-4
Though not necessarily required by regulators, baseline sampling of the source water may be
beneficial to ensure adequate water quality for hydrostatic testing and to help predict the
water quality of the release water. This information is also useful in evaluating appropriate
treatment and release options.
i"
Generally, potable water sources do not require analysis since they are required to meet the
Canadian drinking water standards. However, CCME freshwater aquatic life criteria are
more stringent than drinking water criteria for some parameters.
Source waters from groundwater, surface water or industrial sources may be analyzed for
regulated parameters that are expected to be present or parameters that could affect
treatment and release options. Analytical parameters will vary depending upon whether the
release of hydrostatic test water will be to land or to a receiving water. At a minimum, source
waters from surface waters or groundwaters should be analyzed for pH, TDS (or EC) and TSS,
as well as SAR (if released to land) and iron (if released to water). Analyses may also be
conducted for other regulated parameters such as chlorine, metals or organics. Analyses for
these parameters should be conducted if they are suspected of being present.
The analytical parameters for release waters will depend on the nature of the pipeline (e.g.
new, in-service gas or in-service liquid petroleum) and regulatory requirements. At a
minimum, release waters should be analyzed for regulated parameters or parameters that
affect treatment and release. Analytical parameters will vary depending upon whether the
release of hydrostatic test water is to land or to a receiving water. Typical analyses for release
water from new pipelines are: pH, TSS, TDS or EC, SAR (if released to land) and iron (if
released to water). Waters from in-service gas and liquid petroleum pipelines should be
analyzed for these parameters as well as TPH and BTEX (if released to water). Other
analyses may be required for release waters from new or in-service pipelines, such as toxicity,
chlorine, phenols, additional metals, or temperature.
Analyses of receptors either before or after the release of discharge water may be required by
regulatory authorities. However, it may also be conducted as part of a corporate initiative to
demonstrate regulatory compliance or ensure no adverse effect on the environment. The
analytical parameters for receptors vary depending on the type of receptor (e.g. receiving
water or soil), water quality of the release water, regulatory requirements and environmental
sensitivity. However, the focus of monitoring programs for receptors should be on parameters
5-5
There may be additional sampling and analyses requirements as part of the discharge water
treatment system. Analyses are typically required to monitor the treatment process operation
and performance.
:.\
Analytical Methods i
II
Tables 5.2 and 5.3 provide summaries of analytical methods for a wide range of parameters
in water and soil samples, respectively. The methods have been grouped into four main il
categories: organics, inorganics, metals and other parameters. Information provided in these
tables includes test type, test method, parameters measured by the test, recommended sample
volume, sample container requirements, preservative required, maximum recommended
storage time and typical analytical costs.
Once the analytical parameters have been identified for a specific sample (e.g as outlined in
Table 5.1), Tables 5.2 and 5.3 can be used to select appropriate analytical methods and
determine sample handling procedures. The cost information provided in these tables is based
on individual pricing provided by four laboratories at the time of preparation of this document.
They do not take into account any discounts that laboratories may offer. As well, the costs
reflect regular turn-around times (typically 7 to 10 working days); these prices may be marked
up 50- to 100-percent for faster turnaround times.
Most of the analytical test methods provided in Tables 5.2 and 5.3 are based on either:
• Franson, M.A.H. (ed.) 1995. Standard Methods for the Examination of Waster and
Wastewater, 19th edition. American Public Health Association, Water Works
Association, Water Environment Association.
• U'.S. EPA. 1983. Methods for Chemical Analysis of Water and Wastes. EPA 600/4-79-
020, Revised March 1983. U.S. EPA Environmental Monitoring Laboratory,
Cincinnati, OH.
• Carter, Martin R.(ed.). 1993. Soil Sampling and Methods of Analysis. Canadian
Society of Soil Science. Lewis Publishers, Boca Raton, Florida.
5-6
• CCME. 1993. Guidance Manual on Sampling, Analysis and Data Management for
Contaminated Sites. Volume II. Winnipeg, Manitoba.
As an alternative or in addition to third party laboratory analyses, some field screening and
analytical techniques may be used. They have the advantage of providing real time data,
which cannot be obtained if samples are shipped to a laboratory for analyses. Real time data
may be critical in situations where there are no holding facilities for the discharge water (e.g.
released directly to land or a receiving water). In this case, laboratory analysis can be used II
1.1
to confirm the field analysis and demonstrate compliance. Field screening methods may also
I!
be advantageous to monitor the performance of treatment processes for the removal of i:~
Ii!
contaminants of concern. II~~
Some analyses are best performed in the field, such as pH, temperature, EC and chlorine. II
Relatively inexpensive and easy-to-operate equipment is used to conduct these analyses. II
[1
I!
A qualitative assessment of the discharge water can be carried out in the field. For example,
the presence of hydrocarbons can be detected by visual evidence such as an oily sheen or by
odour. A visual inspection may also be a gross indicator of TSS in the discharge water.
Recording this type of information during dewatering of the pipeline can provide useful
information regarding the quality of the water.
As discussed earlier, screening analyses of the pre-test water (e.g. after the line is filled but
before hydrostatic testing) may help predict the water quality of the discharge water. GRI
(1992) indicated that pre-test analytical results can be used to estimate the mass loadings in
the pipeline discharge water within 20-percent accuracy in most cases. This method requires
that the results be weighted based on the pipeline length assumed for each sample point.
Portable meters, such as an organic vapour analyzer (OVA) or HNu meter can be used to
screen for volatile hydrocarbons. These meters are reasonably easy to calibrate and operate.
However, they are gross indicators of volatile organics and are relatively insensitive to small
changes in concentration. Nonetheless, they may be useful in determining if volatiles such as
BTEX compounds are present.
5-7
1996
MAXIMUM TYPICAL
ANALYTICAL SAMPLE CONTAINER AND STORAGE ANALYTICAL
TEST METHOD PARAMETERS VOLUME PRESERVATION TIME COST
TOC SM5310B orC Total organic carbon 100mL Polyethylene or Glass 28 days $30-$40
EPA 415.1 or
EPA 415.2 Addition of HSP04 or ~S04
to pH <2, refrigeration
COD SM5220B Organics that can be 100mL Polyethylene or Glass 28 days $30-$45
EPA 410.1 oxidized by strong inorganic
oxidizing agent Addition ofH,SO, to pH <2,
refrigeration
on BOD SM5210B Organics that can be 500mL Polyethylene or Glass 48 hours $30-$50
EPA 405.1 oxidized by microorganisms
00
(biodegradable organics) Refrigeration
00
U TPH Purgeables: Purgable organics - BTEX 3 x 40 ro.L vials Amber Glass with teflon- 14 days $150 - $250
.... SM6210D and hydrocarbons to Cs - C10 for purgable lined cap; no head space
~
~
EPA 8240D
EPA 5030
fraction
Refrigeration
1996
MAX1MUM TYPICAL
ANALYTICAL SAMPLE CONTAINER AND STORAGE ANALYTICAL
TEST METHOD PARAMETERS VOLUME PRESERVATION TIllIE COST
Phenol 8M 5530C Total phenolics 1000mL Glass 28 days $30-$40
EPA 420.1
Addition of H 2S04
Volatile 8M 6210D Organic solvents (53 3 x 40 mL vials Amber glass with teflon- 14 days $200-$350
Organics EPA 8240 compounds in total, lined septum; no head space
EPA 8260 including acetone, benzene,
r.JJ chloroform, MEK, MIBK, Addition of HOI to pH < 2,
c dichlorobenzene, methylene refrigeration
~
chloride, etc.)
Acid 8M 6410B Phenolics (20 compounds in 1000mL Amber glass with tetlon- Extraction 7 $275-$450
Extractables EPA 8270 total, including benzoic acid, lined cap days
I:l: phenol, chlorinated phenols)
0 Refrigeration Analysis
40 days
cr Base-neutral 8M 6410B Amines, chlorobenzenes, 1000mL Amber glass with teflon- Extraction 7 $600-$850
<0 Extractables EPA 8270 nitro-anilines, nitroso- lined cap days
compounds (71 compounds
in total) Refrigeration Analysis
40 days
PARs 8M 6410B Polynuclear aromatic 1000mL Amber glass with teflon- Extraction 7 $200-$375
EPA 8270 hydrocarhons(21 lined cap days
compounds in total,
including naphthalene, Refrigeration Analysis
acenaphtene, 40 days
acenaphtylene, anthracene,
benzolalanthracene,
cmysene,pyrene,
dibenzofuran,
phenanthrene)
1996
MAXIMUM TYPICAL
ANALYTICAL SAMPLE CONTAINER AND STORAGE ANALYTICAL
TEST METHOD PARAMETERS VOLUME PRESERVATION TIME COST
pH SM4500 H+B Hydrogen ions (pH) 100mL Polyethylene or glass Analyze $5-$10
EPA 150.1 or immediately
EPA 9040 Field test Refrigeration
Temperature SM2550B Temperature Field test Field test Measure Field test
EPA 170.1 immediately
TSS SM2540D Total suspended solids 1000 mL (for TSS Polyethylene or glass 7 days $10-$20
EPA 160.2 (organic and inorganic) and TDS) Field filtered
Refrigeration
TDS SM2540C Total dissolved solids 1000 mL (for TSS Polyethylene or glass 7 days $10-$20
EPA 160.1 (organic and inorganic) and TDS)
0 Refrigeration
~
Ee SM2510B Electrical conductivity 100mL Polyethylene or glass Analyze Field test
EPA 120.1 or Immediately
EPA9050A Field test Refrigeration
'"
~ Total Anions SM4110e All anions except fluoride 100mL Polyethylene or glass 7 days $50-$100
>-'
o EPA300.0
Refrigeration
Total Cations SM 3120 Cations included with reAP 100mL Polyethylene or glass 6 months $60-$70
EPA 6010 metals scan
Addition ofHNDato pH < 2,
refrigeration
Residual SM4500 Free residual chlorine. 500mL Field Test Aoalyze Field test
Chlorine Recommended that test be or immediately $30-$35
conducted in the field. Field test
Ammonia SM4500H Ammonia 500mL Polyethylene or glass 28 days $10-$20
(NH,-N) EPA 350.1
Addition of H 2S04 to pH <2,
refrigeration
SAR SM3500B,e Sodium adsorption ratio 1000mL Polyethylene or glass, 7 days
cess 18.2, 18.3, 18.4 refrigeration
(for calculation)
1996
MAXIMUM TYPICAL
ANALYTICAL SAMPLE CONTAINER AND STORAGE ANALYTICAL
TEST METHOD PARAMETERS VOLUME PRESERVATION TIME COST
Iron SM3120 Fe 100mL Polyetheylene 6 months $10 - $20
EPA 200.7/
SW846-6010 Addition ofHNUs to pH<2,
00 refrigeration
~
J';l Metals (lCAP 8M 3120 AI, Ba, Bo, Cu, Cd, Cr Fe, 100mL Polyetheylene 6 months $40-$90
::s Scan) EPA 200.7/
8W846-6010
Pb, Mg, Mo, Mn, Ni, P, K,
Na, si, Sn, V, Zn
Field filtered
Addition of ENOs to pH<2,
refrigeration
0
~
Notes: SM = Standard Methods for Examination of Water and Wastewater, 19th Edition
EPA = U.S. Environmental Protection Agency
MAXIMUM 1996
ANALYTICAL SAMPLE CONTAINER AND STORAGE ANALYTICAL
TEST METHOD PARAMETERS VOLUME PRESERVATION TIME COST
TPH Purgeables: Purgable organics - 200 g' 500 mL glass' Extraction: $200-$275
EPA 8240 BTEX and hydrocarbons 14 days
EPA 5021/8000 to C, - ClO Refrigeration (purgeables)
7 days
Extractables: Extractable organics - (extractables)
EPA 3510 hydrocarbons containing Analysis:
EPA 3550 ell - C30
40 days
Oil and SM5520E Solvent extractables 200 g' 500 mL glass' N/A $30-$50
Grease EPA 9071
Refrigeration
'" BTEX EPA 8240 Benzene, Toluene, 200 g' 500 mL glass' 14 days $100-$175
t<: a:
0 EPA 5021J8000 Ethylbenzene, Xylenes
.... Refrigeration
0 soil) Refrigeration
EPA 8270B
PARs EPA 8270 Polynuclear aromatic 200 g' 500 mL glass' Extraction $395
hydrocarbons (21 within 7 days
compounds in total, Refrigeration
including naphthalene, Analysis
acenaphtene, within 40
acenaphtylene, days
anthracene,
benzo[a]anthracene,
chrysene, pyrene,
dibenzofuran,
phenanthrene)
----- ._~==~
TABLE 5.3 Cont'd
MAXIMlJM 1996
ANALYTICAL SAMPLE CONTAINER AND STORAGE ANALYTICAL
TEST METHOD PARAMETERS VOLUME PRESERVATION TIME COST
pH CSSS 16.3 Hydrogen ions (pH) 200g" 500 mL glass' N/A $10
EPA9045A
Refrigeration
EC CSSS 18.2, Electrical conductivity 200 g' 500 mL glass' N/A $7-$17
18.3,18.4
Refrigeration
0 Sodium EPA 6010 Sodium 200 g' 500 mL glass' 7 days $50-$100
~
~
Chloride SM41l0C
EPA 300.0
Chloride 200g"
Refrigeration
500 mL glass' N/A $20-$30
0
en Z (hot water Refrigeration
.... extractable)
>-"
co SAR CSSS 18.2, Sodium adsorption ratio 200g" 500 mL glass' N/A $30-$60
18.3,18.4
Refrigeration
Metals EPA 6010 Al, Ba, Bo, Cu, Cd, Ca, 200 g' 500 mL glass' or plastic bag 6 months $60-$90
rn (lCAP EPA 7471 Cr, Fe, Pb, Mg, Mo, Mn,
Scan) Ni, P, K, Si, Na, Sn, V, Refrigeration
~
rz1
Zn
::s
Another option for field analyses, is to locate a mobile laboratory at the dewatering location.
The advantage of a mobile laboratory is that real time data is obtained using approved
analytical methods, however, the cost for a mobile laboratory is high (e.g. $1,500 to
$3,000/day). Nevertheless, the use of a mobile laboratory in some instances may be justified;
for example, if numerous analyses are required over a short period of time.
Once representative samples are collected they must be handled correctly. This includes the
use of appropriate sample containers, addition of necessary preservatives, field filtering,
proper labelling of containers and chain of custody documentation. Labels should include the
name of sample, collector, date and time of collection, location, field measurement data (e.g.
temperature, pH) and any other information such as project identification.
Chain of custody procedures are a means of tracking a sample from the point of collection
through to final data reporting. Records should be kept by the sample collector, sample
transporter and receiving laboratory. An example of a chain of custody record form is provided
in Appendix C. Laboratories typically have their own in-house chain of custody procedures.
Typical QAlQC procedures also involve the collection of duplicate samples for analysis. As
well, field blanks may be taken. Duplicate samples are taken to determine the precision of the
analytical method. Two separate samples are taken from the same source, collected in
separate containers and analyzed independently.
5 - 14
5 - 15
i
I
'I,
1:
I
'I
i}
The following sections describe various aspects of discharge water handling and release, as
shown in the release decision process flowchart in Figure 3 in Appendix A. These subsections
include a discussion of various release options for the discharge water, as well as potential
environmental effects and protection measures that can be taken to minimize these effects.
Treatment options for discharge waters are discussed in Section 7.0 of this guide. I
I
I
6.1 Discharge Water Release Options
Following hydrostatic testing of a pipeline, the discharge water must be managed and released
properly. A discharge water release strategy should be developed that meets the following
objectives: minimizes environmental risk; complies with applicable regulatory requirements
and criteria; and provides a final release method that is economically feasible.
The development of a discharge water release strategy is case-specific and will vary depending
on a number of factors. Among these are:
The method of dewatering may also affect discharge water release options. For example, if the
flowrate and composition can be controlled (e.g. by providing tankage and/or treatment), a
wider range of release options may be available.
6-1
The volume and composition of discharge water both affect the selection of a release method.
The composition, together with regulatory requirements, will dictate whether or not treatment
is required before release and what receptors may be suitable. Treating the discharge water
may increase the number of potential receptors. However, the economics of treatment may
not be favourable. This is discussed in Section 7.0. Consideration should also be given to the
quality of the test water source to determine an appropriate discharge location. For example,
test water drawn from a slough may not be acceptable for release into a watercourse, water
body or onto land if salt concentrations are high.
Regulatory requirements and potential environmental effects both play key roles in selecting
discharge water release options. For example, discharge water releases to environmentally
sensitive receptors or to locations with stringent regulatory requirements may not be feasible
without some level of treatment, which in turn has cost implications.
Potential Receptors
There are a variety of potential receptors for discharge waters from hydrostatic testing. These
include releases to:
Release to land or a receiving body of water is normally acceptable only for relatively
uncontaminated test waters. This may require treatment of the discharge water for
contaminant removal.
Discharge water may be released directly to land or it may be irrigated to provide a more
uniform distribution of water over a greater land area. Receiving waters may include
watercourses or standing water such as lakes, peat lands, wetlands and ponds. Discharge
waters may be returned to the source or to another acceptable receiving water. In either case,
the quality ofthe discharge water should be of comparable water quality to the receiving water
6-2
Discharge to a municipal sewage treatment plant may be acceptable provided the substances
in the water are treatable and will not upset the treatment processes. The treatment facility
must also be willing to accept the water. Most municipalities have by-laws regulating the type
of water suitable for discharge to sewers and often charge a fee.
Discharge waters with substance levels unacceptable for direct release onto land, bodies of
water or municipal sewage treatment plants may be sent to an offsite facility for treatment,
such as a refinery, a processing plant, or a dedicated hydrostatic test water treatment facility.
A dedicated hydrostatic test water treatment facility is generally only constructed if a pipeline
company expects to be treating large volumes of hydrostatic discharge water or testing
repeatedly.
Contaminated discharge waters may also be sent offsite to a disposal facility if locally
available. Examples of current offsite disposal options include injection into an approved deep
well or salt cavern. However, the acceptability and availability of deep-well and salt-cavern
disposal locations varies across Canada and regulatory approval is required before disposal.
In some cases, it may be feasible to store the discharge water for reuse in subsequent
hydrostatic tests. This will depend on the volume and composition of the discharge water, the
storage time required and the location of subsequent hydrostatic testing.
One of the main costs associated with the release of discharge water is for treatment before
release. These costs are discussed in Section 7.0. Other release costs include: regulatory
permits and approvals; monitoring and analytical requirements; and pumping and
transportation costs. Off-site disposal facilities also charge a fee for release of discharge
waters. This fee will vary depending on the volume and composition of the discharge water
and the fee structure ofthe particular disposal facility.
Regulatory Requirements
Some regulatory requirements apply to most discharge water release options. In general,
releases to the environment (e.g, land or receiving water) have the most stringent regulatory
requirements while discharges to approved disposal facilities have the least stringent
requirements. See Sections 8.0 and 9.0 for details on regulatory requirements.
6-3
The potential exists during test water discharge operations to adversely affect aquatic biota,
downstream water users, soils and land use. The potential for impacts is influenced by the:
Improper selection of a water discharge site or poorly conducted water discharge operations
could adversely affect fish and fish habitat. A significant increase in flow of a watercourse,
due to poorly controlled rate of discharge of test water, could result in bank erosion, substrate
scouring or downstream flooding. Similarly, erosion of soils from poorly controlled discharge
of test water adjacent to a watercourse could result in the introduction of significant levels of
sediment to the watercourse. The potential also exists for transfer of undesirable biota (e.g,
fish pathogens or parasites) from one drainage basin to another if the source ofthe test water
is located in one drainage basin (eg, Milk River) and the test water is released into another
drainage basin (eg, Saskatchewan River). In some regions, even transfer of water from one
watershed to another is of concern due to the presence of problem weeds or other undesireable
biota. The definition of "drainage basin" varies depending upon the jurisdiction and,
consequently, regulatory authorities should be consulted with regard to interbasin transfer
approval.
The discharge of test water containing contaminants that are toxic (e.g. hydrocarbons) to
aquatic fauna or flora could also adversely affect fish or fish habitat. Sudden fluctuations in
water temperature, resulting from the discharge of test water which is warmer or colder than
the receiving body of water, could adversely affect incubating eggs, fry and, in severe cases,
adult fish. An increase in concentration of metal ions could also adversely affect fish.
6-4
Excessive test water discharge rates or volumes could result in flooding of waterfowl nests,
aquatic furbearer dens or a reduction in aquatic habitat. Aquatic furbearers, waterfowl and
their habitats could also be adversely affected by the discharge of test water that contains
contaminants toxic to aquatic flora or fauna. The presence of workers and equipment during
test water discharge operations could also adversely affect waterfowl, aquatic furbearers and
other wildlife species if the activities are conducted during sensitive time periods.
A reduction in soil capability could result if test water containing contaminants that are
deleterious to the soil was discharged on the ground. Adverse impacts on soil capability could
also occur if a poor quality source oftest water (e.g, saline water from sloughs) was discharged
on the ground. Should a failure in the pipe occur during a test, soil capability could also be
reduced if a poor quality source of test water is used or contaminants that are harmful to the
soil are present. The potential exists for soil erosion if excessive test water discharge rates
occur or inadequate energy dissipation measures are used during test water discharge.
Vegetation
Excessive water discharge rates or volumes could result in flooding of vegetation. Damage or
mortality of vegetation could also occur if low quality source water or test water containing
contaminants was released onto vegetation.
Land Use
Improper selection of water discharge sites can result in flooding of poorly drained lands. The
release of test water with high concentrations of hydrocarbons, additives or long lasting dyes
into a body of water could cause health hazards or reduce the aesthetic appreciation of the
area and/or alarm the public. Landowners could be adversely affected if the soil capability or
vegetation is adversely affected by the discharge of water.
An above ground discharge line can result in damage to crops during installation and removal
as well as a short term inconvenience to landowners. Leaks in the discharge line can result
in a reduction in agricultural capability if the quality ofthe test water is low.
6-5
Release of hydrostatic test water could result in hydrocarbon odour, mercapton odour, pump
equipment emissions, health affects from benzene and greenhouse gas emissions (eg. SF, and
others). When mercaptans or odourants are added to the test water and the test water is
discharged onto the ground or into a body of water, the potential exists for a strong, persistent
odour to be present.
Although the potential exists for numerous environmental impacts to occur during the
discharge of hydrostatic test water, protection measures are available to mitigate these
impacts. The following environmental protection measures should be implemented, where
appropriate, in order to minimize impacts on the environment.
6-6
6-7
21.
is to be discharged to a watercourse.
Select discharge sites where dewatering will not result in
flooding, erosion or lowering in agriculture capability.
!
,.
Avoid discharging test water onto lands with long or steep ,'~
6-8
6-9
RIP RAP
PLAN VIEW
N.T.S.
II
DISCHARGE ONTO
PLYWOOD SHEETING
ORTARPAULINS
DISCHARGE PIPE
B.
DEFLECTOR OR JUMP
WELDED TO DISCHARGE
PIPE
PROFILE
N.T.S.
Notes:
1. Dissipate the energy of water discharged during dewatering to prevent soil erosion and damage to the
beds and banks of bodies of water. Erosive energy can be dissipated as shown above or by other methods
Including: arcing pipe into the air: using a muffler-style energy dissipater; directing the !low at swamp
mats, plywood or rock riprap. Choice of the most appropriate method depends upon volume and
pressure of discharge water. A method that provides better energy dissipation and erosion control is
required when many kilometres of large diameter pipeline is to be dewatered at a high discharge rate than
a short smail diameter pipeline at a low discharge rate. If surging is anticipated, utilize a robust method.
3. Dewater at same rate used to withdraw water. If erosion control measures are found to be inadequate,
lower the dewatering rate or stop operations until satisfactory measures are in place.
Source: Interprovincial Pipe Line Inc., 1991. Environmental Manual for Pipeline Construction, Edmonton,
Alberta.
6 - 10
II
7.0 Treatment
7.0 TREATMENT
Treatment may be a key component of a discharge water release strategy as shown in the
water handling and water discharge decision process flowcharts in Figures 2 and 3 in
Appendix A. While release without treatment may be an option for some hydrostatic
discharge waters (e.g. uncontaminated water from new pipelines), many will require some
form of treatment as part of the overall discharge water release strategy.
The objectives in treating discharge waters are to minimize environmental impact and liability
as well as comply with regulatory requirements associated with their release. Nevertheless,
the cost of treatment must also be considered. Treatment needs for hydrostatic testing
discharge waters should be evaluated for each testing program and strategies implemented
to minimize treatment requirements as well as optimize release options.
This section addresses various aspects of discharge water treatment including: factors
affecting treatment requirements; description of applicable treatment processes; and examples
of treatment trains used by the pipeline industry.
The need for and extent of treatment required varies on a case-by-case basis. Factors to
consider when evaluating treatment requirements are:
Discharge water from new pipelines is relatively uncontaminated and may require minimal
treatment, if any. The main substances that may be of concern and require removal are total
suspended solids (TSS) and possibly some metals (typically iron). Organic substances are
generally not a concern. Treatment systems for discharge waters from new pipelines are
usually relatively simple and inexpensive (e.g, filtration and aeration).
7-1
Although TDS may be a substance of concern in some discharge waters, it is not economically
feasible to remove it. TDS normally originates from the hydrostatic test source water;
therefore, measures should be taken to select high-quality source waters rather than treat for
TDS removal.
Chlorine is usually only a concern if it is added as a biocide during testing or the source water
is chlorinated potable water. Where possible, the addition of chlorine or other biocides should
be minimized. However, free chlorine may be removed during pipeline dewatering through
aeration.
Applicable discharge criteria (either regulatory or internal) will play an important role in
determining treatment requirements. These criteria will indicate which parameters require
removal and to what extent. For comparison, CCME water quality criteria are provided in
Table 6.1.
The availability of suitable release locations may also affect the treatment requirements. For
example, if release locations are limited and they involve environmentally sensitive receptors,
more stringent treatment requirements will likely be required. Conversely, if a number of
release locations are available and they do not involve environmentally sensitive receptors,
treatment requirements will likely be less stringent. No treatment may be required for some
release options, such as offsite disposal.
Treatment Processes
There are a variety of treatment processes that can be used to remove substances of concern
from hydrostatic discharge waters. These range from simple and inexpensive unit processes
to more complex and costly operations. This subsection describes several unit processes that
are currently being used or considered by the pipeline industry for removal of the potential
contaminants identified in Section 4.0. These unit processes include:
7-2
For each of the above treatment processes, a summary is provided that includes the following
information: primary and secondary contaminants removed; process description; design
criteria; performance review and related experience; and advantages and disadvantages.
Treatment technology summaries for these processes are presented in Appendix D.
Table 7.1 provides a summary of these processes, indicating what contaminants of concern are
typically removed. This table can be used as a reference guide when evaluating various
treatment processes for discharge waters. However, the selection of treatment processes may
depend on other factors such as operational constraints and economics.
The selection of one treatment process over another for a specific application requires a
detailed technical and economic feasibility study. Cost is a major consideration in the
selection of a treatment process. However, generic cost data has not been provided for the
treatment processes listed in Table 7.1. Treatment costs vary widely on a case-specific basis
depending on the following:
7-3
CONTAMINANT REMOVED
DISSOLVED
TREATMENT FREE EMULSIFIED SUSPENDED HYDROCARBONS TRACE
PROCESS OIL OIL SOLIDS BTEX Phenols METALS
Coalescence X 0 0 - - N/A
Flotation X 0 0 - - N/A
I
II
'I
Filtration 0
I:
hay bales X 0 - - N/A I'
cartridge/bag filters X X - - N/A
media filter 0 X - - N/A i:
I
Granular Absorbent N/A X 0 - - N/A Ii
Media Filtration
Most Removed X
Some Removed 0
None/Very Little Removed
Not Applicable N/A
3 volatile and semi-volatile compounds only (for example BTEX; phenol not removed)
4 iron oxidation
7-4
The volume of discharge water and the required throughput affect the treatment cost. If a
large volume of water requires treatment over a short period of time, high treatment
throughputs are necessary. This could require oversizing of treatment equipment, which can
be costly. Another cost consideration with respect to discharge water volume is that the unit
cost for treatment ($/m 3) generally decreases as the volume increases.
Holding ponds or tanks can be used to provide storage for the discharge water before
treatment. The costs associated with constructing a storage pond and purchasing or leasing
tanks can be significant; however, these collection and holding facilities allow for greater
flexibility in the treatment and release system. For example:
• It may allow for smaller sizing of subsequent treatment equipment (for example, lower
treatment flow rate required).
• Some treatment for contaminant removal may occur (e.g, settling of suspended solids,
oil removal, loss of volatile hydrocarbons such as BTEX, biodegradation and
photodegradation of some contaminants and additives).
• The use oftanks or ponds may allow for the segregation of more contaminated discharge
water (e.g. interface water) from less contaminated water (e.g, core water).
An economic analyses should be carried out to compare the cost of holding ponds or tanks and
treatment equipment requirements. As well, the cost of having the pipeline out of service
should also be considered. Potential environmental concerns related to holding ponds (eg.
fencing, waterfowl scare measures, etc.) need to be considered and addressed.
The location of pipeline dewatering and treatment can affect the treatment costs. For
example, transportation, mobilization and demobilization costs for equipment or contract
services will be higher for more remote locations.
7-5
Treatment costs vary not only with the type of treatment processes used but the type of
installation or service involved. Treatment of hydrostatic discharge waters can be achieved
using: contract services; portable or temporary treatment facilities; or permanent treatment
facilities. If contract services are used, a contractor is responsible for treating the discharge
water (e.g. providing equipment, personnel, etc.). Contract services may be provided on a cost
plus or lump sum fee basis. The costs generally include equipment mobilization and
demobilization in addition to treatment.
Portable or permanent treatment facilities can be built by an operator for treating discharge
waters. Since hydrostatic testing is often a "one time" event, the construction of a permanent
treatment facility for a specific test may not be practical. Unless the discharge water can be
readily delivered to a central treatment facility, on-site treatment with portable or skid
mounted equipment may be necessary. A treatment facility could be located at a refinery or
another central location that is accessible to several pipelines. A refinery has the advantage
of available infrastructure.
Treatment costs are also affected by operating requirements, such as labour, monitoring and
maintenance requirements, as well as the type and volume of treatment chemicals and
disposable materials (e.g. filters, etc.) required.
In this subsection, four treatment systems are described that have been used or are being
considered by Canadian pipeline companies to treat hydrostatic discharge water before
release. These include:
• Contract services for discharges from new pipelines and in-service gas pipelines
7-6
• Permanent treatment facility for discharge water from an in-service liquid petroleum
pipeline
There are various companies within Canada offering contract services for the treatment of
discharge water from hydrostatic testing. Typically, these services have been applied to
discharge waters with relatively low contaminant levels (e.g, from new pipelines or in-service
gas pipelines).
The treatment systems generally consist of the same basic features, with some minor
differences. Key components of the treatment are:
• a feed or surge tank to control the flowrate to downstream equipment and provide
degassification
• disposable cartridge or bag filters for suspended solids and oil removal
• granular activated carbon vessels for the removal of fme oil, some dissolved organics and
oxidized iron
The treatment systems, which are skid-mounted and portable, are typically rated for about
2000 gallons per minute. However, some companies claim ratings of up to 5000 gallons per
minute.
To achieve this high throughput with the equipment provided, high carbon loading rates are
required. The loading rates are in the order of about 14 to 20 gpm/ft", compared to 3 to 5
gpm/ft", which are more typical in carbon adsorption processes. Consequently, contact times
7-7
These treatment systems are primarily used to remove suspended solids and oil. Oxidized iron
is also removed as a suspended solid. Because of the low carbon contact times, the removal
of dissolved organics (such as BTEX and phenol) are likely low. However, removals of
dissolved organics could be increased iflower loading rates and longer contact times are used.
The cost for these contract treatment services vary depending on the volume of water treated,
water throughput and treatment location. For the high throughputs discussed above (e.g.
2000 gpm) treatment costs typically range from about $2.50 to $7.00 per cubic metre of
discharge water. These prices include equipment mobilization and demobilization, treatment,
provision of a technician, and disposal of used treatment media. Higher costs would be
expected for lower throughput rates.
A temporary treatment facility was located at a pump station to treat hydrostatic test water
from an out-of-service liquid petroleum pipeline to be reactivated. Surface water was used as
a source water for hydrostatic testing and no additives were used. The main contaminants of
concern (e.g, present in the discharge water and regulated) were: pH, TSS, BTEX, phenol,
COD and iron. Approximately 25,000 m" of discharge water were treated over a six week
period.
Because of elevated iron levels in the discharge water, aeration was provided in the storage
tanks to oxidize the iron and the iron oxide precipitate was allowed to settle. Some iron oxide
was also removed in the cartridge filters.
The granular absorbent filter vessels and granular activated carbon vessels were rented for
the treatment period. Aside from the storage tanks, the treatment system was skid-mounted.
7-8
Normal operation of the treatment system included: pumping the water through the treatment
system; monitoring effiuent flow and quality; monitoring treatment system performance;
providing routine maintenance (e.g. backwashing and changing filters); and conducting
sampling and analyses. A field test kit was used to monitor BTEX levels for process control
purposes. Samples for compliance monitoring were collected and sent offsite for most analyses
required.
The discharge criteria are shown in Table 7.2. The treatment system was able to meet these
criteria for the contaminants of concern, with the exception of phenol on one sampling
occasion. However, the discharge water was not released to a receiving stream but held in a
containment pond.
TABLE 7.2
DISCHARGE CRITERIA
TSS 25 40
COD 50 75
nR 6.0 - 9.0 nR units 6.0 - 9.0 DR units
Oil and zrease No visible sheen No visible sheen
Iron 0.3 0.5
.
Benzene 0.3 0.5
Ethvlbenzene 0.7 1.1
Toluene 0.3 0.5
Phenols 0.001 0.0015
Wastes generated from the treatment process included used bag filters, spent granular
absorbent media and spent activated carbon media. The bag filters and spent granular
7-9
The total treatment cost for this treatment system was approximately $180,000 or $7/m 3 of
discharge water. The cost for subsequent treatment systems would likely be less since
engineering costs would be reduced (e.g, system already designed and process information is
readily available).
A portable treatment facility has been designed to treat discharge water from a proposed
hydrostatic test of an in-service liquid petroleum pipeline. The treatment facility will be
located at a terminal. Water from an irrigation canal will be used as the source water. [I
~.~
Additives will be used during the hydrostatic test including: aniline dye, sulfur hexafluoride
and a valve sealant. II
Ii
Approximately 160,000 m" of core water will be treated over a 14 week period at a nominal
rate of 300 US gpm. The main contaminants of concern are: TSS, free and emulsified oil, iron,
BTEX and phenol. The expected composition of the core water and the discharge criteria are
I
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summarized in Table 7.3. fi
TABLE 7.3
EXPECTED COMPOSITION AND DISCHARGE CRITERIA
(all concentrations mgIL unless noted)
7 -10
Core water and separated interface water will be held in a new 1,000,000 bbls (160,000 m")
lined storage pond. The pond will be constructed of native clay and lined with 60 mil high-
density polyethylene. The pond will allow for storage of the large volume of water requiring
treatment. As well, it will allow for gravity separation of free oil and suspended solids from
the water. The free oil will be removed by skimming, Suspended solids will settle to the
bottom ofthe pond. Natural aeration in the pond will oxidize iron to a particulate form, which
will settle to the bottom of the pond or be removed by filtration.
Water from the holding pond will be pumped to the treatment system, which has the following
major components:
• absorbent media filtration to remove emulsified oil and some dissolved hydrocarbons
I
• activated carbon filtration to remove dissolved hydrocarbons
Two bag filters in series will remove suspended solids and oil that are not removed in the
holding pond. The disposable bag filters are designed to remove solids and oil droplets larger
than 5 microns in size.
Final removal of free and emulsified oil will be achieved using absorbent media filtration. As
well, some dissolved organics may also be removed. The main purpose of this treatment unit
is to prevent oil from entering the carbon adsorption units downstream. The absorbent media,
which consists of anthracite and clay, is sacrificial; once saturated with oil it is removed for
disposal and replaced with new media. The design hydraulic loading rate on the filtration unit
is 4 gpm/ft".
Activated carbon adsorption will be used for the removal of dissolved organics. Two vessels
in series designed for a hydraulic loading of 4 gpm/ft'' will provide over 30 minutes of contact
time between the water and activated carbon. EflIuent from the carbon adsorption vessels will
be monitored and tested to determine when the carbon is exhausted. Spent activated carbon
will be removed for reactivation and replaced with fresh carbon.
7 - 11
The treatment system is designed as a completely skid-mounted system suitable for relocation
to other sites. It is designed for manual, summer-only operation.
The estimated capital and operating costs for the ponds and treatment system are summarized
in Table 7.4. The total estimated cost is $2,180,000. As shown, over half of this cost is
associated with the construction of the ponds. However, these ponds could be used for storing
discharge water generated from future hydrostatic testing programs.
TABLE 7.4
SUMMARY OF CAPITAL AND OPERATING COSTS
Ponds $1400,000
Treatment svstem $780000
Oneratinz cost $150000
Total cost $2180000
A liquid petroleum pipeline company is constructing a treatment facility for water from its
hydrostatic testing program. Discharge water from hydrostatic testing will be transported to
an end-of-pipe facility for treatment and subsequent release to a municipal sanitary sewer.
The design flowrate for the system is 200 gpm.
The main contaminants of concern are: TSS, oil and grease, BTEX, phenol, and iron. The
expected untreated discharge water composition and the discharge criteria are summarized
in Table 7.5.
7 - 12
pH 6-9 6-9
The pretreatment processes for the hydrostatic test water consist of:
• surge tank and gravity separation for free oil and suspended solids removal
• chemical coagulation/flocculation for iron removal, suspended and oily solids
• dissolved air flotation for fine oil removal and oily solids
• granular media filtration for fine oil and suspended solids removal
As shown in Table 7.5, the main organic contaminants of concern are BTEX and phenol. In
general, GAC is effective at removing organic contaminants with high molecular weight, low
water solubility and low polarity. However, phenolic compounds have a relatively high
polarity, suggesting that GAC may not be the most efficient treatment option over an extended
period of time.
GAC was compared to advanced oxidation processes (AOP) for BTEX and phenol removal.
Based on proposals received from various suppliers, a UV/peroxide system appeared to be the
most technically feasible and cost effective. This system uses high intensity UV lamps
together with hydrogen peroxide. The feed water is dosed with hydrogen peroxide and mixed
before passing through two UV reactors in series. Pilot testing revealed that this system is
able to reduce the phenol concentration from 1 mglL to 0.02 mglL, which meets the discharge
criteria.
A UV/peroxide system was selected over GAC because it was found to be more cost effective.
The estimated capital and annual operating costs for a UV/peroxide system are $207,000 and
$20,390 respectively. The main operating costs for the UV/peroxide system are: electrical
power, lamp replacement, hydrogen peroxide and maintenance.
7 - 13
II
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I
Fisheries and Oceans Canada (DFO), Environment Canada and the National Energy Board
(NEB) are the only federal agencies which are involved in the approval or review of water
withdrawal and water discharge applications related to hydrostatic testing on a nation wide
basis. Other federal departments that may provide approvals for testing or input to CEM
include Parks Canada, Health and Welfare Canada, Indian and Northern Affairs Canada
(lNAC), Prairie Farm Rehabilitation Administration (PFRA) and Transport Canada.
DFO does not provide formal approval on matters related to hydrostatic testing but may be
involved in the review of the project through the Canadian Environmental Assessment Act
(CEM) process or when requested by any other federal agency. Navigable Waters Protection
Act (NWPA) approval is generally not required for hydrostatic testing, water withdrawal or
water discharge activities. However, if hydrostatic testing equipment or activities could affect
navigation, NWPA approval would be required.
The following sections ofthe federal Fisheries Act apply to hydrostatic testing:
• Section 30 - every water intake will have a fish guard or screen to prevent the
passage of fish;
DFO is responsible for Sections 30 and 35.1 ofthe Fisheries Act, while DFO and Environment
Canada are jointly responsible for Section 36.3 of the Fisheries Act. It should be noted,
however, that DFO authorization is required, to destroy fish by means other than fishing and
to alter fish habitat, under the Fisheries Act. If hydrostatic testing procedure threatens fish
or alters fish habitat, then DFO authorization may be required. DFO also requests that the
agency be contacted if interbasin transfer of water will occur as a result of a hydrostatic test.
8-1
For federally regulated pipelines, operation and maintenance activities including testing as
well as facilities applications, may require NEB approval pursuant to the various acts and
regulations that relate to these activities.
No agency specific regulations apply to hydrostatic testing on Indian Reservations, however, liii
the same regulationts) as the respective province or territory use will apply. Indian Oil and II
Gas Canada as well as (INAC) do not have specific requirements for hydrostatic testing. Ii
II
Hydrostatic testing on Indian Reserves may be subject to CEAA review. I,
ii
if
8.1 Withdrawal I,
DFO has outlined the national standard-of-practice for screening requirements for water II
intakes in the "Freshwater Intake End-of-Pipe Fish Screen Guideline" March 1995 (available
from DFO) that outlines mesh sizes, approach velocities and cleaning requirements of water
intake screens.
Federal water withdrawal limits have not been developed. However, DFO recommends water
withdrawal not exceed 10% of the natural streamflow. This 10% water withdrawal limit is
commonly recommended in most provinces and territories across Canada. It should be noted
that excessive water withdrawal could result in harmful alteration, disruption or destruction
offish habitat (HADD) and would require authorization from DFO.
Water withdrawal activities for federally regulated projects must, as a minimum, meet the
NEB Guidelines for Filing Requirements and the Onshore Pipeline Regulations.
8.2 Release
HADD could occur as a result of a test failure or release of hydrostatic test water with
contaminants. Fish habitat can be affected by alterations in temperature, hydrocarbon or
other contaminants, sedimentation due to excessive discharge rates and test additives. There
are no hard numbers on the allowable levels of contaminants in hydrostatic test water
discharge on a federal basis at this time. Release approval is not required unless hydrostatic
testing operations threaten fish or alters fish habitat, then DFO authorization is required.
8-2
The release of hydrostatic test water for federally regulated projects must, as a minimum,
meet the NEB Guidelines for Filing Requirements and the Onshore Pipeline Regulations.
There are no federal environmental requirements to monitor and provide records of the waters
used in hydrostatic testing. However, companies are recommended to monitor and retain
records of environmental matters to establish the sequence of events and demonstrate that
HADD or other impacts did not occur.
Each province and territory has different arrangements with DFO and Environment Canada
regarding the administration ofthe Fisheries Act Section 36(3) that applies to deposition of
a deleterious substance. Environment Canada may become involved if the spill occurs on
federal lands or if the company is regulated by federal agencies. Charges can be laid under
the Fisheries Act as the result of a spill.
Spill and spill reporting on federally regulated projects are regulated by the NEB.
8-3
I
I'
Ii
iI,l
I
The following outlines environmental regulatory requirements for hydrostatic testing in the
provinces and territories of Canada within which testing by CAPP and CEPA members are
most common. No information is provided for Nova Scotia, New Brunswick, Prince Edward
Island or Newfoundland.
Regulatory approvals are generally required for land application of discharge water, with
limitations on application rates and contaminant loadings. As well, there may be provisions
regarding the withdrawal and use of water, erosion control, flood prevention, interbasin
transfer, prevention of water reaching another water body, watercourse, etc. Discharges to
receiving waters may have limitations on the discharge flowrate as well as a number of water
quality parameters.
Table 9.1 provides a summary of the environmental regulatory requirements for hydrostatic
testing within each province and territory in Canada where CAPP and CEPA members operate
pipelines.
Appendix H identifies the agency contact for each applicable jurisdiction in Canada. Mapping,
is also provided in Appendix H, where available, of provincial regional jurisdictions.
9.1 Withdrawal
9.2 Release
9-1
In 1996, Alberta Environmental Protection (AEP) issued a Code of Practice for "Discharge of
Hydrostatic Test Water From Hydrostatic Testing of Petroleum Liquid and Natural Gas
Pipelines". This Code outlines minimum requirements for water quality that pipeline owners
and operators must meet when releasing hydrostatic test water to land or a receiving water.
The Code applies to hydrostatic testing of new and in-service liquid petroleum and natural gas
pipelines where test volumes are greater than 1,000 m", The Code includes registration,
reporting and recordkeeping requirements as well as requirements for the release of discharge
water to land or receiving waters. Release limits for a number of parameters for discharges
to land and receiving waters are identified in the Code in Appendix G. Release of test water
volume ofless than 1,000 m" are not subject to the Code but must meet Alberta Environmental
Protection and Enhancement Act requirements (i.e. no adverse impacts).
Hydrostatic test water discharge flow rate and volume limits are not specified except in
Ontario where the discharge rate must be equal to the water withdrawal rate. All
jurisdictions recommend some type of energy dissipater be utilized to prevent and reduce
erosion potential. Some jurisdictions do not permit the direct discharge of test water to a
watercourse and require test water be discharged over land before entering a water body or
discharged into a closed system such as a dugout or slough.
Many provincial agencies, on a case-by-case basis, require monitoring of the quality of the
discharge water. Alberta is the only jurisdiction that has water quality criteria specific to the
release of hydrostatic test water (Appendix G). Many provinces use the water quality criteria
for drinking water or freshwater aquatic life established by the Canadian Council of Ministers
for the Environment (CCME) for hydrostatic test releases.
Of the provincial jurisdictions, only Alberta requires the records or sample data be retained
for hydrostatic tests with test volumes greater than 1,000 m", However, monitoring and
analyses may be necessary to verify that the discharge water is compatible with the receiving
basin, soils or land use as well as to demonstrate regulatory compliance (see Section 5.0).
9-2
Most provinces and territories have a 24 hour spill reporting mechanism in place. The
requirements for reporting vary depending upon the jurisdiction, type of product spilled and
volume of the spill. Charges can be laid under the Fisheries Act as a result of a spill or an
incident ofHADD.
9-3
<1000 m3
Environmental
Protection and
Enhancement Act
(EPEA) applies
Saskatchewan Saskatchewan Water Corporation lor No y" y" 24weeks Form Temporary Approvals to Yes DFO fish screen NIA 1-(800) -667-7525
<0 withdrawaVuse 01 water Operate Works under guideiines (inSaskatchewan only)
theSaskatchewan water (306) 787-8000
on Corporation Act (outside
Saskatchewan)
Sasl<atchewan Environment and No No NlA 2-5 Weeks letter Perm~ pursuant to Requested lor all Asrequired by Permit wfth conditions
Resource Management lorwater Section 17(a) 01 the discharges, level of EMPA
discharge Environmental testing is dependant
Management and upon anticipated
Protection Act(EMPA) water qualIty
Regional Fisheries Biologist, No 24 weeks Form orleiter Shoreland Alteration
Saskatchewan Environment and Permit
Resource Management (il stream
bed orbank disturbance isinvolved)
Man~oba Water Resources Branch of y" NIA No 3 weeks tener letterofAuthorization Yes - DFO fish screen 10% 01 instantaneous Onasile-specific Asdetermined by Asrequired under the (204) 944-4888
Manitoba Department 01 Natural under theWater Rigrrts guidelInes and onasJte- dischaJ]e ofthesource basis by Manitoba Man~oba Environment Act
Resources Act specific basis byFisheries sneam Environment Environmental
Branch 01 Manitoba Surface Water
Department 01 NaturaJ Quality Objectives
Resources
NWT NWT Water Board 100m l/day y" y" 4---B months Form Water Use Type A Yes Ofa fish screen NtA Ona s~e-specific Onasite-specffic Asrequired by NWT (403) 920-8130
ucence guidelines basis bytheNWT basis bytheNWT Waters Act
Water Use Type B Water Board WatarBoard
Ucence under the
Northvlesl Territories
Waters Act(NWTVIIA)
Yukon Yukon Water Board 100 ml/day y" y" asmonths Form Water Use Type A Yes - DFO fish screen NtA Onasfla-specitic Ona s~e"speclfic Asrequired byYukcn (403) 667-7244
ucence guidelines basis bytheYukon basis bytheYukon WatarsAcl
Water Use Type B Water Board Water Board
ucence under theYukon
I","
- ~--~~~~-=-- ·0';:C=,"";',,,
10.0 Other Requirements
10.0 OTHER REQUIREMENTS
In addition to provincial and federal approvals, permission and approvals for hydrostatic
testing activities may also be required from other agencies and affected parties such as First
Nations organizations, landowners and muncipalities.
Permission may be required from the respective band and Treaty organization for hydrostatic
testing activities on Indian Reservations or Metis Settlements (also see Section 8.0).
Permission may also be required for access to water withdrawal and discharge sites, or if off
right-of-way overland piping is required.
Municipal approval is required to withdraw water from a community's potable water system
or to discharge water into a community's sewage system.
Access to water withdrawal sites in municipal areas may require municipal permission or
approval if off right-of-way or over land piping is needed. Road use approval is not required
on public roads if hydrostatic test water is trucked. However, if road damage occurs then the
municipality will require repair of the damage and/or compensation.
Access to a water withdrawal or release sites, if off right-of-way or over land water piping is
needed, will require landowner (including on Public lands, the Crown) approval or approval
of other industrial land users (eg. forestry company). Compensation may be required for
access off right-of-way. All damages to landowner property and private roads is the
responsibility of the company.
Release of hydrostatic test water requires landowner approval. If erosion occurs during
release, the company may be required to pay compensation and will be required to repair the
damages.
Approval may be required for access to and use of water from Irrigation Districts or other
water authorities.
10 - 1
11.0 References
11.0 REFERENCES
Alberta Environmental Protection (AEP). 1996. Code of Practice for Discharge of Hydrostatic
Test Water from Hydrostatic Testing of Petroleum Liquid and Natural Gas Pipelines.
American Water Works Association et al. 1995. Standard Methods for the Examination of
Water and Wastewater (ref. 19th edition).
Canadian Council of Ministers of the Environment. n.d. Canadian Water Quality Guidelines.
Prepared by the Task Force on Water Quality Guidelines.
Carter, M. (ed.) 1993. Soil Sampling and Methods of Analysis. Canadian Society of Soil
Science. Lewis Publishers. Boca Raton, Florida.
Franson, M.A.H. (ed.). 1995. Standard Methods for the Examination of Water and
Wastewater. 19th edition. American Public Health Association, Water Works
Association, Water Environment Association.
Gas Research Institute. 1995. General Demographics Survey for Hydrostatic Test Water
Discharges from Natural Gas Pipelines. GRI Chicago, IL.
w95/0366.
Gas Research Institute. 1996. Environmental Aspects of Hydrostatic Test Water Discharges:
Operations, Characterization, Treatment and Disposa1. April, 1996.
11 - 1
Interprovincial Pipe Line Inc. 1991. Environmental manual for pipeline construction.
Edmonton, Alberta
Metcalf and Eddy Inc. 3rd ed. 1991. Wastewater Engineering Treatment, Release and Reuse.
McGraw Hill.
McKeague, J.A. (ed.). 1991. Manual on Soil Sampling and Methods of Analysis, 2nd edition.
Canadian Society of Soil Science.
U.S. EPA. 1983. Methods for Chemical Analysis of Water and Wastes. EPA 600/4-79-020.
Revised March 1983. U.S. EPA Environmental Monitoring Laboratory. Cincinnati, Ohio.
U.S. EPA. 1990. EPA Technology Evaluation Report, Site Demonstration of the Ultrox
International Ultraviolet Radiation/Oxidation Technology. EPA 154015-891012.
Cincinnati, Ohio.
11- 2
J
II
II,.,
F
i
Ii
12.0 Appendix A
Water Handling Flow Diagrams
APPENDIX A
WATER HANDLING FLOW DIAGRAMS
A-I
Source
Suitability
Section 3.0
~ ~
Natural
(Surface,
Municipal Water
Supply
Other
(Man-Made)
I,
,j
,
Groundwater)
I I
Baseline
Sampling
Section 5.0
Environmental
Evaluation
(Section 3.0)
Agency and
Landowner Approvals
(Section B.O)
Water Withdrawal
(Section 3.0)
Water Treatment or
Additives
(Section 3.0)
InjectInto Pipeline
FIGURE 2
Service
Determination
J. J.
In-Service Liquid
New In-Service Gas
Petroleum
I I
Expected Water
Quality
(Section 4.0)
Contamination
Minimization
(Section 4.0)
Pre-Release Analysis
(Sectlon 5.0)
Hydrostatic Testing
FIGURE 3
Treatment
(Optional)
(SecUon 7.0)
Select
Receptor
(Section 6.0)
I
J. J.
Surface Water Offsite Disposal
Land
(Flowing or Standing) Facility
I
..
I
Meets Release
Meets Disposal
Criteria -
Facility Criteria
(Section 6.0)
1 ..
~o
I Further Treatment
f--
Ve, Ve, Required
Post-release
Evaluation Disposal Facility
(SecUon 5.0)
I
I
13.0 Appendix B
Hydrocarbon Spectrum Diagram
APPENDIXB
HYDROCARBON SPECTRUM DIAGRAM
Ii
i
I\i
,
;.,
ji
I'!
B-1
Petroleum Products
..
Furnace oil, diesel oil
Natural gas,
liquid gas
.. . ....Solvents
• Lubricating oils and greases
•
.. Gasoline
• Waxes and bottoms (heavy fuels, asphalts, waxes)
Stove oil, jet and turbofuels
.. •
I
I
.. Common PAH
•
......
BTEX
" C10 - napthalene " C20 - benzo(a)pyrene
Laboratory Analyses
..
Total Purgeables
. *******
I I I I 1****1 I I I I I I I I I I I I I
o 2 4 6 8 10 1216 18 20 14
22 24 26 28 30 32 34 36 38 40
Number of Carbon Atoms
NOTE:
****
~ Test recoveries in these ranges are insufficient
****
14.0 Appendix C
Example Chain of Custody Record
I
I
APPENDIXC I
EXAMPLE CHAIN OF CUSTODY RECORD
I
i
i
~
~'
C -1
SAMPLING PROGRAM
~0 Dale InvoIced:
0
u.
0 mspoetuem
a:
W Dtspese: Return:
~Dl ... g~
wa: SAMPLE DESCRIPTION !l! Dale:
~
STATiON
NUMBER
DATE TIME
~~ iii (This deecrfptlon will 2 SHIPPER ANO REFERENCE.
,."
8 "'"
iil~ appear on the repcn.)
SAMPLE REMARKS
I
i.'
15.0 Appendix D
Treatment Technology Summaries
APPENDIXD
TREATMENT TECHNOLOGY SUMWUUllES
• Gravity Separation
• Aeration
• Coalescence
• Floatation
• Filtration
• Granular Absorbent Media Filtration
• Granular Activated Carbon
• Advanced Oxidation Processes
• Air Stripping
• Chemical Precipitation
I
II
I
.1
D -1
I
Hydrostatic Test Water Management Guidelines, September, 1996
II
Treatment Technology: Gravity Separation
Process Description
Gravity separation can occur in ponds or tanks. However, gravity separation units are
typically constant level, atmospheric tanks that separate free oil and suspended solids based
on density differences. Free oil, which is lighter than water floats to the top of the tank and
is skimmed off. Suspended solids, which are heavier than water sink to the bottom of the
tank. The removal of oil may be enhanced by the addition of demulsifiers to break oil-in-water
emulsions and enhance droplet coalescence.
Gravity separation units may be as simple as modified storage tanks to purpose-built vessels
with specially designed inlets and outlets to provide uniform flow distribution. Examples of
gravity separation units include skim tanks and API separators. A schematic diagram of a
skim tank is shown in Figure D.1. Coagulants or flocculants may be added to enhance the
removal of oil and suspended solids.
Design Criteria
The surface area of the separation unit should be sized to provide sufficient residence time to
achieve the required phase separation. Units are normally sized to remove 150 micron oil
droplets. Residence times of 30-60 minutes are typical. The "API Manual on Release of j
;:
Refinery Wastes" discusses design criteria in detail.
Gravity separation is widely used throughout the oil industry for primary phase separation
of oil and suspended solids from produced waters. Gross free oil greater that 150 microns and
suspended solids are removed. Generally, emulsified oil, dissolved oil and finely dispersed
solids are not removed. However, some finer oil droplets and emulsified may be removed if
demulsifiers are added to enhance coalescence.
Pipeline companies have successfully used gravity separation in ponds and tanks to treat
hydrostatic discharge water for oil and suspended solids removal.
Advantages
Gravity separators are widely used and proven technology. The units are mechanically
reliable and require minimal servicing. They are also inexpensive. Gravity separators are
amenable to portable applications provided the tankage required does not exceed the
maximum allowable for transporting.
Disadvantages
Gravity separators require a relatively large amount of space. The skimmed oil phase aud the
suspended solids require proper release.
D -2
II l=-
t
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~
on
\\\\t l
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~, \
'tt'fil
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,~
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~
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<
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COHT....KIN....TED
( • ~
or
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OUTLET
\~ATEtl INLET
.
Canadian Association of
Petroleum Producers SKIM TANK FOR OIL AND WATER SEPARATION
and
Canadian Energy
Pipeline Association Date: September, 1996 Figure No. 0.1
0-3
Hydrostatic Test Water Management Guidelines, September, 1996
Treatment Technology: Aeration
Process Description
Aeration involves the introduction of air into the discharge water. This can be achieved by
storing discharge water in a pond or tank open to the atmosphere. In this case, aeration could
be enhanced with the addition of a mechanical aerator. Aeration may also be achieved in a
pond or tank by sparging; diffused air is introduced with an air pump. Alternatively, spray
aeration may be used as part of a release strategy (e.g. spray irrigation). The water is
discharged through an aeration bar, which is a pipe containing numerous small holes that
sprays the water into the air.
Design Criteria
The above aeration systems have limited design criteria. The design of spray irrigation i
systems are typically driven by water distribution and loading requirements or limitations.
Sparging is typically conducted until such time that the organics content is reduced to
acceptable levels. This requires ongoing monitoring and analyses. The extent of organics
removal from water in a pond exposed to the atmosphere will depend on many factors such as
the time of exposure, weather conditions (temperature and wind), and degree of mixing. For
enhanced aeration, mechanical aerators are sized based on the power rating.
All three forms of aeration mentioned above have been used by pipeline companies to treat
discharge water from in-service pipelines for the removal of BTEX compounds. Some
inorganice and metals may also be removed such as free chlorine and iron. Non-volatile
organics are not removed using aeration.
Advantages
Aeration is relatively simple and inexpensive means of reducing the concentration of volatile
organics in discharge waters. Aeration can readily be carried out at the dewatering location.
Disadvantages
Non-volatile compounds are not removed. Aeration releases volatile compounds to the
atmosphere, which may cause environmental or odour concerns. Natural aeration in a pond
or other contained area may require a long period of time for volatile organics to be removed.
D-4
Hydrostatic Test Water Management Guidelines, September, 1996
i
I
Treatment Technology: Coalescence I
Primary Contaminants Removed: Finely dispersed oil, some emulsified oil I
Secondary Contaminants Removed: Suspended solids ~,
f
Process Description
Coalescers are used to enhance gravity separation processes. Coalescers provide solid surfaces
which can be contacted and wetted by oil droplets. The droplets accumulate and create a thick
film, which is sheared off by other forces such as gravity or fluid flow. The larger oil droplets
separate from the water more effectively than smaller droplets.
Coalescing surfaces may be plates or filter media. Parallel plate and corrugated plate
coalescers are commonly available devices. A schematic diagram of a corrugated plate
separator is shown in Figure D.2. The corrugated plates are on an incline inside a tank,
providing a large coalescing surface area. Suspended solids settle to the bottom of the tank.
A loose media coalescer is a vessel containing a bed of filter media, which provides a
coalescing surface and also removes suspended solids. A schematic diagram of a coalescing
filter is shown in Figure D.3. The agglomerated oil droplets rise to the top of the vessel and
are collected. Backwashing may be required to remove accumulated oil and solids from the
media.
Design Criteria
Parallel plate and corrugated plate coalescers are sized based on required residence time to
achieve effective coalescence and gravity separation. Loose media coalescers are sized based I
'I
on hydraulic loading. Typical hydraulic loading rates are 350 to 900 roB/mll_d. Backwash
water rates are typically 475 to 1300 mB/mll_d. An air scour may also be used.
The use of coalescera, particularly corrugated plate separators is fairly common in the oil
industry. Oil removal efficiencies can be improved depending upon the nature of the oily
phase. Emulsified oil is not effectively removed without the addition of demulsifiers upstream
of the coalescer. Pipeline operators have used corrugated plate separators for oil removal from
hydrostatic test waters from in-service liquid petroleum pipelines.
Advantages
Coalescers improve gravity separation efficiency by removing finer oil droplets. They also
reduce the equipment size for gravity separation and/or increase the allowable throughput.
Coalescers are also relatively inexpensive and they are amenable portable applications.
Disadvantages
More routine maintenance is required that with a conventional gravity separation unit to keep
the coalescing media clean and free of oily solids buildup.
D -5
i
"o i
"-
•
••
:E
Source: Bradley, W. 1987. Two Oilfield Water Systems, Stream Flooding, Oil
Removal, Robert E. Krieger Publishing Company, Malabar, Florida.
Canadian Association of
Petroleum Producers CORRUGATED PLATE SEPARATOR
and
Canadian Energy
Pipeline Association Date: September, 1996 Figure No. D.2
D·.
Hydrostatic Test Water Management Guidelines, September, 1996
,-------------------,
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Canadian Association of
Petroleum Producers COALESCING FILTER
and
Canadian Energy
Pipeline Association Date: September, 1996 Figure No. D.3
D· 7
separation. Small air bubbles are introduced into the water, which contact and adhere to fine
oil droplets and oily particles. This results in an apparent reduction in specific gravity causing
the air/oil droplets to rise to the water surface to form a dense froth. The froth is removed by
skimming.
In IAF units, air is introduced either by an impeller or with a combination of centrifugal pump
and eductor. In DAF units, pressurized air is introduced in the water and air bubbles are
released upon depressurization. A schematic diagram of a DAF unit as shown in Figure DA.
Flotation units are widely used in the oil industry for fine oil and suspended solids removal
from produced water. They normally follow gross oil removal in a gravity separator (skim
tank). Oil removal efficiencies of 90 percent are typical. This includes finely dispersed oil
droplets. Emulsified oil may be removed if a demulsifier is added upstream. Flotation units
do not remove dissolved oil. Flotation units have been used by pipeline operators to treat
hydrostatic test waters.
Advantages
Disadvantages
Flotation units are susceptible to upsets by free oil slugs, which deteriorates the effluent i
quality. The oily froth also requires release. il
il
!i
D-8
~
o·
..
:;? ~ -~
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~
ti
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/'--
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~~ '~" suction
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i'.
~
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collector
lec
~ Settled
l
sludge
discharge
Canadian Association of
Petroleum Producers DISSOLVED AIR FLOATATION UNIT
and
Canadian Energy
Pipeline Association Date: September, 1996 Figure No. 0.4
. =."'
_~~~=,= ·__,, __ c,,~~ =~C'_C"'" n,.".= .ill. "."_ _ ,,__,, ·__w_=~ - - .. _--.-
Treatment Technology: Filtration (hay bales, cartridge and bag filters
and media filters)
A schematic diagram of a hay bale structure is provided in Figure D.5. It consists of hay bales
with an adsorbent boom for free oil removal. Hay bale structures are normally nsed as stand
alone treatment processes or with an aeration bar. Following treatment, the hay bales are
disposed of. H
\!
u
Depending on the nature of the discharge water, cartridge and bag filters may be used as a H
stand alone process; more typically they are used downstream of a gravity separation process ii
for the removal of finer oil and suspended solids and upstream of dissolved organics removal
treatment processes (e.g. activated carbon adsorption), which are sensitive to overloading by
free oil and solids. Cartridge and bag filters typically have a polypropylene filter media that
collects and traps suspended solids and oil droplets. Cartridge and bag filters are disposable.
Media filters contain a fixed bed of granular material (such as sand, anthracite, garnet, or
nutshells) that traps suspended solids and oil as water passes through it. Media filters can
be operated in an upflow or downflow mode and have a single or mixed media. Periodic
backwashing with treated water is required to remove trapped oil and suspended solids.
Simultaneous gas and water scouring is commonly used.
Design Criteria
A relatively standard design is used for the construction of a hay bale structures as shown in
Figure D.3. The number ofhay bale structures required for treatment will vary depending on
the volume of discharge water and concentration of contaminants (TSS and oil). Based on
information reported by the Gas Research Industry, one hay bale structure may treat between
10,000 US gallons and 300,000 US gallons. The key parameter affecting the life of a hay bale
structure is the free oil content of the discharge water.
Media filters are sized based on hydraulic loading rate, which varies depending upon the type
of filter. Hydraulic rates range from 175~350 m3/m2~d for conventional downflow filters to 600~
900 m S/m2wd for high-rate downflow filters. Backwash rates of700~900 m 3/m2 _d are common.
Hay bale structures are used to treat relatively uncontaminated discharge water from new and
in-service gas pipelines. They have successfully removed free oil from discharge waters and
larger suspended solids. Finer solids and dissolved organics are not removed.
Media filtration has been used to remove solids from discharge waters from in-service liquid
petroleum pipelines (downstream of oil removal processes). Dissolved organics are not
removed. Free or emulsified oil can be problematic and cause fouling of the filter media,
requiring more frequent backwashing.
Advantages
Filtration is widely used and a proven technology. The equipment is reliable, easy to operate
and amenable to portable applications.
Disadvantages
Media filters are susceptible to plugging if overloaded with oil and solids. Frequent
backwashing may be required in this case. The backwash water also requires release. Release
of filter media is required with hay bales, cartridge and bag filters.
D -11
ADSORBENT BOOM
PLAN I
NOT TO SCALE fi
OllTER HAY BA1..£ RING n
INNER HAY 84LE RING
ADSORBENT BOOM
SECTION A-A
NOT TO SCAlE
Canadian Association of
Petroleum Producers HAY BALE FIELD TREATMENT UNIT
and
Canadian Energy
Pipeline Association Date: September, 1996 Figure No. 0.5
D - 12
Process Description
Granular absorbent media filtration uses a granular absorbent in a filter column. The media
is comprised of approximately 30 percent active absorbent ingredient (metallo-activated clay)
and 70 percent anthracite material. The media selectively absorbs insoluble materials, such
as free and emulsified hydrocarbons. The affinity of the media increases with increasing
molecular weight and hydrophobicity of the absorbed material. The media may remove some
dissolved organics, but free and emulsified oils are preferentially removed. The manufacturer
claims an oil absorptive capacity oftwice the mass of the active media or 60 percent by weight.
Once the media has reached its maximum absorptive capacity it must be disposed of and
replaced. Routine backwashing is required to remove solids buildup.
Design Criteria
GAMF filters operate at a hydraulic loading rate of about 175~295 m3/m2~d (3~5 gpm/ft'') and
a contact time of about 15 minutes. This provides sufficient time for oil droplet adherence.
A backwash rate of 825 m3/m2~d is recommended by the manufacturer. Bed life depends on
the amount of insoluble hydrocarbons removed and can be estimated based on the influent
concentration, flowrate and media mass.
GAMF filtration is commonly used in wastewater treatment to prevent oil emulsions, droplets
and films from carrying over to downstream polishing treatment processes. Both free and
emulsified oils can be removed, however the filters should not be used for gross free oil
removal as the bed life will be greatly diminished. An absorption filter can effectively remove
all emulsified oil droplets leaving near-equilibrium concentrations of dissolved organics in
water. GAMF has been used by pipeline operators to treat discharge water from in-service
liquid petroleum pipelines.
Advantages
GAMF filters are proven technology and readily available. They remove finely dispersed and
emulsified oil droplets that could otherwise be problematic in downstream treatment
processes. They are relatively compact and applicable to start/stop operations. They are
amenable to portable applications.
Disadvantages
==========_ D-13
Hydrostatic Test Water Management Guidelines, September, 1996
I
Treatment Technology: Granular Activated Carbon (GAC) i,
Primary Contaminants Removed: Dissolved hydrocarbons
Secondary Contaminants Removed: None
Process Description
Granular activated carbon (GAC) is an adsorbent material that removes a wide range of
organics. However, it is best suited to hydrophobic, non-polar compounds in the mid-molecular
range (4 to 20 Carbon atoms). Activated carbon adsorption is normally carried out in packed
bed reactors or columns in series, as shown in the schematic diagram in Figure D.6. Water
is fed from the top of the column and as it moves down the bed, organics are selectively
adsorbed by the carbon. The bed eventually becomes saturated and organics "breakthrough"
the bottom of the bed. At this time the carbon must be replaced. Reactivation of spent carbon
is possible. Periodic backwashing may be required if there is a build up of solids in the bed.
Design Criteria
Hydraulic loading rates may vary depending on the objectives of treatment (e.g. types of
contaminants and extent of treatment). Typical hydraulic loading rates for wastewater
treatment range form 175 to 475 m3/m2~d (3 to 8 gpmlft2 ) . The bed height to diameter ratio
should be greater that 2:1 and as the ratio increases, performance increases. Backwash rates
of 590 to 885 m 3/m2_d (10 to 15 gpm/tt'') are typica1. Another important design criteria is the
I
s
empty bed contact time (EBCT). Typical EBCTs for the removal of dissolved organics from
wastewater are 15 to 30 minutes.
GAC adsorption is a widely used treatment technology for the removal of low level dissolved
organics from water. The technology is proven both technically and operationally. While GAC
is not applicable to all organics, it can be used to remove BTEX, PAR's and pheno1. It will not
successfully remove glycol or methanol because of their high water solubility. Free and
emulsified oil should be removed prior to GAC adsorption to avoid bed fouling. GAC has been
used by pipeline operators to treat discharge waters from in-service liquid petroleum pipelines.
Advantages
The main advantages of GAC adsorption include: low effluent organic concentrations
achievable, proven technology, easy to operate and low space requirements. GAC adsorption
is applicable to start/stop operations. The equipment is amenable to portable applications.
Disadvantages
Organic contaminants are not destroyed but transferred to another media, that requires
subsequent treatment (e.g. reactivation) or release. Operating costs may be high if
breakthrough occurs too quickly.
I.
I
L Ii
Canadian Association of
SCHEMATIC DIAGRAM OF GAC
Petroleum Producers
and ADSORPTION COLUMNS IN SERIES
Canadian Energy
Pipeline Association Date: September, 1996 Figure No. 0.6
D-15
Process Description
Advanced oxidation processes (AOP) include a family of chemical oxidation processes, that
destroy organic compounds. Production of the hydroxyl radical (OHO) as an intermediate is
common to all of them. OHo is a powerful oxidizing agent that reacts rapidly with organic
compounds, oxidizing them to CO2 and ~O. The hydroxyl radical can be generated by:
photolysis of hydrogen peroxide (H 202 ) , photolysis of ozone (Os) and reaction between ozone
and hydrogen peroxide. Photolysis reactions are carried out in the presence of ultraviolet (UV) ,..,
radiation and are the most common commercially available process. They are referred to as
UV/ozone, UV/peroxide and UV/ozone/peroxide processes. A schematic diagram of a I.
UV/peroxide system is shown in Figure D.7.
Design Criteria
AOP's are still somewhat of a blackbox technology and vendors supply package systems.
Operational variables, such as number and intensity ofUV lamps, ozone and peroxide doses
and retention time depend on the wastewater characteristics. Manufacturers claim typical
retention times of 1 to 5 minutes. Pilot testing is normally required to determine the correct
operating parameters.
Performance Review and Experience
Although AOP's have been widely used for water supply applications, they have only recently
been used for organics destruction in industrial wastewaters. The performance of an AOP I
system depends on the characteristics of the feed water and the design and operation of the I
system. AOP's have demonstrated effectiveness at destroying phenols, PAR's and BTEX.
Vendors claim high reductions of these contaminants. Natural water compounds such as II
carbonate, bicarbonate, nitrite and ammonium ions and other inorganics in the reduced state
(Fe 2+, cr'l+) also oxidize, becoming hydroxyl radical scavengers. This reduces the availability
of hydroxyl radicals for organic oxidation. Pretreatment to remove natural water compounds
and free and emulsified oil may be required. AOP's may oxidize and precipitate metals, such
as Mn and Fe as metal oxides. Glycols, amines and methanol will also be oxidized.
UV/peroxidation is being considered for the treatment of discharge water from an in-service
liquid petroleum pipeline.
Advantages
AOP's completely destroy organics rather than transferring them to another media. They also
have reduced waste generation and low space requirements. They can be cost competitive
with alternative technologies (e.g. GAC adsorption). AOP may be amenable to portable
applications. They also have instant on-off and turndown capabilities.
Disadvantages II
AOP's are susceptible to influent fluctuations and they may bave fairly stringent pretreatment II
requirements. Equipment reliability has been a problem with some systems. Equipment
operation may be operator intensive. As well, there may be special handling requirements for
the oxidant, which may be toxic or hazardous.
I I
D-16 ======__==== II
II
!
Hydrostatic Test Water Management Guidelines, September, 1996 I
!
'
/ _ 0...
I
o
o 0
o
o
0
0
o 0
o
o
0
0
o 0
o
o
0
0
, 0
o
o
0
0
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0700
0
o
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Canadian Association of
Petroleum Producers SCHEMATIC DIAGRAM OF AOP SYSTEM
and
Canadian Energy
Pipeline Association Date: September, 1996 Figure No. D.7
D ·17
Process Description
Air stripping operations involve passing air through a liquid with sufficient contact that the
volatile components are transferred from the liquid to the gas phase. The driving force is the
concentration differential between the liquid and gas phases. A schematic diagram of an air
stripping operation is shown in Figure D.B. Air enters at the bottom of the tower and water
near the top. The air leaving the top contains volatile components that are either released or
collected for further treatment.
Design Criteria
The design of a stripping process depends on the water feed rate and the volatile components
present in the water. Contact between the liquid and gas phases should be maximized.
Process control variables include: temperature, gas phase flowrate and liquid phase flowrate.
Packing media or plates may be included in the column design to improve liquid-gas contact.
Advantages
Stripping effectively removes volatile and semi-volatile compounds. It is also proven
technology. Air strippers are amenable to portable applications.
Disadvantages
Non-volatile compounds are not removed. Air stripping releases volatile compounds to the
atmosphere, unless off-gas treatment is provided. Air emissions may cause environmental or
odour concerns. Air stripping does not remove phenol.
D-18 ===========
Hydrostatic Test Water Management Guidelines, September, 1996
.1
ACCUMULA TERI
CON~S DECANTER
Overhead
'~ Product
»<:>
l
/'
!<, Reflux
Feed
PREHEATER
(S
[5\ AECTIFICA TION
SECTION
-
Inlet X -:/
1\ /
~ !l
STRIPPING
SECTION
/ \
.
<, /
I'~ AEBOILEA
/
Bottoms Product
""""
D·19
Hydrostatic Test Water Management Guidelines, September, 1996
Treatment Technology: Chemical precipitation
Primary Contaminants Removed: Trace metals
Secondary Contaminants Removed: Some suspended solids
Process Description
Chemicals can be added to wastewaters to precipitate metals from solution. The most common
method is by raising the pH and precipitating metals as hydroxides. Either lime or caustic is
added to the wastewater to raise the pH until it reaches the metal's minimum solubility. At
that point, small precipitates of metal hydroxide form. The solubilities of different metals
varies as a function of pH and waters containing several metals with different solubilities may
be difficult to treat. Once the metal hydroxides have precipitated, they are coagulated or
flocculated and settled in a clarifier or removed by filtration. The sludge is dewatered and ,.,
disposed of. The effluent pH is neutralized by acid addition. ,,
Metals can also be precipitated as sulphides, with the advantage of a wider range of minimum
solubilities. However, sulphide sludge is more difficult to dewater and the sludge may be
toxic.
Design Criteria
Chemical dose is dependent on the characteristics of the influent (metal concentrations and
pH) and flowrate. Lime or caustic can be added to elevate the pH to 9~10, which is sufficient
to remove Fe, Mn and Zn. Clarifiers are designed based on overflow rate, providing sufficient
residence time for phase separation. A typical overflow rate is 30 to 118 m 3/m2_d.
=========... D - 20 =========...
Hydrostatic Test Water Management Guidelines, September, 1996
16.0 Appendix E
Spill Contingency Plan
APPENDIXE
1.0 Purpose
This plan has not been prepared to replace the Spill Contingency Plans or Emergency
Response Plans of operating companies. This plans purpose is to ensure that measures are
available to deal with an accidental release of poor quality (e.g. saline, Bodie or hydrocarbon
contaminated) test water as well as additive or fuelllubricant spills in the absence of formal
company plans.
(b) the company's Spill Contingency Plan / Emergency Response Plan and,
if required, Oil Spill Cooperative Contingency Plan is implemented such
that necessary equipment is mobilized and measures are being imple-
mented to control and contain the spill. The Contractor will be required
to make all resources available to contain and clean-up a spill; and
E-l
5. Clean-up will not be attempted without competent advice from the company's
Environmental Staff or Spill Staff.
General clean-up guidelines for specific accidents are outlined below. However, the
first person on the scene will follow the actions listed in the Spill Scene Checklist.
Since impacts from small spot spills can generally be minimized if appropriate
actions are implemented, all small spills of fuels or noxious materials must be
reported immediately to the Chief / Environmental Inspector.
1. Suspend construction activity in the immediate vicinity of the spot spill until
permission to resume activity has been granted by the Chief I Environmental
Inspector.
E- 3
Hydrostatic Test Water Management Guidelines, September, 1996
APPENDIX E Cont'd
(b) If possible, cut off the source of the spill. While efforts
are immediately begun to contain the spill, immediately
notify the Chief Inspector and Environmental Inspector.
If the Chief Inspector cannot be immediately contacted,
notify the company's Environmental Staff or District
Superintendent. These people will, in turn, contact the
local police, provincial environmental government
agency, provincial or federal pipeline authority, and, if
required, the local Oil Spill Co-op.
(c) Once the source has been cut off, attempt to contain the
spilled area.
(d) Before any reports are filed, take notice of dangers to the
environment (e.g. proximity of watercourses) and clean- ,
!;
up actions that might be necessary.
(e) If any of the above are beyond the capabilities at hand,
do not hesitate to ask for qualified assistance.
,j
'I
II
I,
E-4
_
I
fO:
1"
Gasoline _
- Diesel _
- Lube Oil _
- Hydraulic Fluid _ ,I
i
Source of Spill: _
Land Use: _
E-5
[Note: Test water volumes by pipe sizes are provided in Table 2.1 of Section 2]
- F·1
Hydrostatic Test Water Management Guidelines, September, 1996
i
:
18.0 Appendix G
Alberta Environmental Protection
APPENDIXG
CODE OF PRACTICE
FOR DISCHARGE OF HYDROSTATIC TEST WATER
FROM HYDROSTATIC TESTING
OF PETROLEUM LIQUID AND NATURAL GAS PIPELINES
G-l
Alwra
i
and Natural Gas Pipelines
r,
i
.1'1'i\\j;1)"li>!);>j\li:'*.~llj1f'njf,N\l1hii\il'J\'1
,
I
1
Distribulsd by:
I Queen's PrinterBookstore Queen's Printer Bookstore
11510Kingsway AVenue MainFloor, McDougall Centre
Edmonton, Alberta T5G ZY5 455· 6th Street S.W.
427-4952 calgalY, Alberta TzP4EB
Fax: 452.0666 297-6251
CODE OF PRACTICE FOR DISCHARGE OF HYDROSTATIC TEST WATER FROM
I..
HYDROSTATIC TESTING OF PETROLEUM LIQUID AND NATURAL GAS PIPELINES
TABLE OF CONTENTS
Preface
2 Introduction
3 Definitions
4 Registration
10 Code Amendment
11 Effective Date
, --,
i
!i
f:
CODE OF PRACnCE FOR DISCHARGE OF HYDROSTATIC TEST WATER FROM
HYDROSTATIC TESTING OF PETROLEUM LIQUID AND NATURAL GAS PIPELINES
Preface
1(1) The Code of Practice for Discharge of Hydrostatic Test Water from Hydrostatic
Testing of Petroleum Liquid and Natural GIIS Pipelines is incorporated by the Substance Release
Regula/ion (A.R. I24f93), under the authority of section 36 ofthd.Environmental Proteclion and
Enhancement Act. Persons responsible for release of hydrostatic test water affected by this Code
must meet all its requirements to ensure that their activities are in compliance with Alberta's
environmental laws. In addition to the requirements of this Code of Practice, persons responsible
!
\c
e
must comply with all requirements of the Environmental Protection and Enhancement ACI, its
associated regulations and all other applicable laws.
(2) Persons responsible lor releases of hydrostatic test water affected by this Code must
I
register with Alberta Environmental Protection prior to commencing hydrostatic testing of liquid I
"
petroleum or natural gas pipelines. Section 4 of this Code deals with registration in greater I
detail.
Introduction
2(1) This Code of Practice outlines the minimum requirements persons responsible must
meet when releasing hydrostatic test water from the hydrostatic testing of new or in-service
liquid petroleum or natural gas pipelines and associated installations
(a) when the volume of hydrostatic test water is greater than or equal to 1000 m': and
(b) when the hydrostatic test water is to be released to
(i) land,
(ii) flowing water, or
(iii) standing water.
As well, persons responsible should consult with persons or parties lhat may be affected by the
release of hydrostatic test water.
(2) Hydrostatic test water that is directed to a facility approved by Alberta Environmental
Protection or the Alberta Energy and Utilities Board must meetthat facility's requirements.
Where the test volume uf Ihe hydrostatic test water is less than 1000 m', persons responsible
must comply with all requirements of the Environmental Protection and Enhancement Acl.
(3) Information on procedures for handling hydrostatic test water can be found in the
latest edition of flydroslatic Test Water Management Guidelines, published by the Canadian
Association of Petroleum Producers and the Canadian Energy Pipeline Association.
;',;
,I-".~
jc
(4) Questions or concerns regarding the application or contents of this Code of Practice
can be addressed to:
or:
or:
,.
I
II
!
Definitions
(a) "flowing water" means surface water such as a stream or river that has water flowing
in it prior to and during release of hydrostatic test water;
(b) "hydrostatic testing" means hydrostatic testing of new or in-service liquid petroleum
or natural gas pipelines that generates 1000 m' or greater of water;
\ (e) "hydrostatic test water" means water resulting from hydrostatic testing;
(d) "limits" means end-or-pipe limits for hydrostatic test water before
(i) dilution with the receiving water, or
(ii) application to land;
(e) "liquid petroleum pipeline" means a pipeline through which liquid petroleum product
has passed;
(f) "natural gas pipeline" means a pipeline through which natural gas product has passed;
(g) "new pipeline" means a liquid petroleum or natural gas pipeline that has never been in
service;
(h) "peatland" means peat covered terrain;
(i) "peat" means soil composed almost exclusively of organic matter derived from the
partial decomposition of vegetation which has grown in shallow water;
(D "pipeline" means a pip, tor the transmission ofliquid petroleum or natural gas "0'
installations in connection with that pipe;
(k) "receiving water" mews flowing water or standing water;
(I) "standing water" means surface water such as a lake, beaver pond, or slough that nes
water standing in it prior to and during release nfhydrostatic test water.
(2) Terms that arc defined in section I of the Environmental Protection and Enhancement
Ac{ and in the Substance Release Regulation (A.R. 124/93) have the same meaning when they
arc nscd in this Code of Practice, unless otherwise defined or modified within this Code of
Practice.
Registration
4 In addition to any information required by the Director under the Approvals and
Registration Procedure Regulation (A.lt. 113/93), a person responsible planning to release
hydrostatic test water to receiving water or to land shall complete the registration form attached
to this Code of Practice and forward it to the Director at least one week before commencing
hydrostatic testing.
5 The person responsible shall comply with all requirements of this Code of Practice.
,
Release of Hydrostatic Test Water to Receiving Water
!
6(1) The hydrostatic test water shall be sampled prior to release. A representative sample
of the hydrostatic test water shall be taken and analyzed for the parameters in Table I, according
to the analytical test methods in Table 3.
(2) I lydnl:;~ltil: [,.,,~j warcr rclcaxcx [0-receiving water xhall he controlled at all times [0
meet the applicable limits set out in Table I.
Table I \
Limits for Release of Hydrostatic Test Water to Receiving Water
'These limits are applicable only where a minimum ofa 2:1 dilution can be attained withtile receivingwater (for
example, 2 parts receiving water to I part Ilydrostatic releasewater).
'Monitor only if chlorineor chlorine productsused.
) Additives include, but are not limitedto blocides,corrosion inhibitors, detergents, antifreeze, oxygenscavengers
and leak detection tracers.
• The personresponsible shall demonstrate that the test water is non-toxicifadditives are used.
, New pipelines that havean intemalliner and where additives are not used are exempt from the monitoring
rcquired under Table l.
l':
Release of Hydrostatic Test Water to Land Imi!
7(1) Soil samples shall be taken and analyzed from the area of land that will receive the I
hydrostatic test water before carrying out the hydrostatic test. The samples shall be analyzed for
pI-I,electrical conductivity and sodium adsorption ratio according tu the analytical test methods
in Table 4.
(2) The hydrostatic test water shall be sampled prior to release. A representative sample [!
of the hydrostatic test water shall be taken and analyzed for the parameters in Table 2 according
to the analytical test methods in Table 3. Ii
(3) The hydrostatic test water shall meet the applicable limits set out in Table 2.
Ifi
I
Table 2 IIi
Limits for Release of Hydrostatic Test Water to Laud 1"
\ Total petroleum hydrocarbons (sum of lolaI purgeable and total extractable hydrocarbons).
'AS1'M Me/hod E J598-94 (Amcnc"" Society ofTesling and Materials).
, Additives include biocides. ecrroslon inhibitors, detergents, an.tifreeze, oxygen scavengers and lcak deteolion
traters.
(4) The rate of release of hydrostatic test water shall be controlled to prevent visible soil
erosion.
(5) Hydrostatic test water shall no! be released in a manner or \0 a location that resnlts in
I
'1
injury to veghation due 10standing water or saturated soil conditions.
(6) Hydmstutic test water shall not be released onto soiltluu has an electrical
conductivity exceeding 2 dS/m and a sodium adsorption ratio exceeding 6. I
I
I
(7) Hydrostatic lest water shall not be released to land where surface runoff of the
hydrostatic test water may reach an open water body unless the hydrostatic test water meets the
limits in Tables I and 2.
8(1) The person responsible shall use the analytical test methods in Tables 3 and 4 for the
monitoring requirements in this Code of Practice.
(2) Should the analytical test method be modified or an alternative test method developed
by the person responsible, validation of the modified or alternative test method shall be
performed by the person responsible. The validation process should include the determination of
precision and hias, method ruggedness and analysis of independently prepared unknown
samples, as specified in Method 1040 of Standard Methods for the Examination of Water and
Wastewater, published by the American Public Health Association, Water Works Association,
and Water Environment Association, as amended from time to time. Once the new or modified
method has been validated, it shall he tested for its equivalency to the recommended methods
listed below.
Table 3
Water lest methods
EPA U.S.E.P.A. 1983. Methods/of Chemical Analysis of Water and Wastes. TWA
60014-79-020, Revised March 1983, as amended from time to time. U.S.E.P.A.
I!
Environmental Monitoring Laboratory, Cincinnati, OH.
L
Green er al. Greene, J.e., C.L. Bartels, W.L. Warren-Hicks, u.n. Parkhurst, G.L. Linder, \ @
1989 S,A. Peterson, and W.E. Miller. 1989. Protocol for short term toxicity screening I
nf hazardous waste sites. EP /I. l'iOOf3-8R-029. 102p. R
Environment For rainbow trout: Environmental Protection Series Biological Test Method:
C<llloda Methods Reference Methadfor Determining the Acute Lethality ofEjJluenito Rainbow
Trout, Environment Canada, Report EPS IIRM113, July 1990, as amended
from time to time.
'~.
i'
,
Table 4
Soil and peat test methods
Carter, M. (cd.) 1993. Soil Sampling and Methods ofAnalysis, as amended from time to
time. Lewis Publishers. Boca Raton, Florida.
9(1) The person responsible shall immediately report any contravention of this Code
of Practice by telephone to the Director of Pollution Control Division at (403) 422-4505.
(2) The person responsible shall provide the Director of Pollution Control Division
with a written report of all contraventions of this Code within one week of discovery of the
contravention and shall include the following information:
(a) a summary of all contraventions of this Code;
(h) explanation as to why the contraventions occurred; and
(c) proposed preventative measures designed to prevent future contraventions.
(3) The person responsible shall keep on file for 5 years from completion ofthc
hydrostatic testing all results of the operation related to the hydrostatic testing, and shall
make these results available to Alberta Environmental Protection upon request.
(4) As part of the hydrostatic testing, the person responsible shall compile the
following information:
(a) a schematic diagram and details nfthe monitoring and release operation including
monitoring points, holding system, conveyance system, hydrostatic test water
release flow rate, and area of receiving land or receiving water;
(b) the name of the receiving water, if available, and estimated receiving stream flow
rate;
(c) photographs of the monitoring points, holding system, and conveyance system;
(d) if released to receiving water, photographs of the release during representative
periods of release into the receiving water and downstream, if applinable, to a
distance of at least 100 metres;
(e) if released to land, photographs of the release taken during representative periods
of release and photographs of the lund receiving the release taken 5 days after the
release is complete; and
(f) a record of all of the analytical results associated with the release of hydrostatic
test water.
Colle Amendment
10 This Code of Practice will be reviewed by September 30, 1997 and every 10
years thereafter. Alberta Environmental Protection will accept and compile written
comments received as of September 30, 1997 for the initial review. Subsequently, Alberta
Environmental Protection will accept and compile written comments on the contents of this
Code at any time, and will review all comments received at the next 10 year review. The
Director may institute a review and amendment of this Code of Practice at any time. All
proposed,amendments to this Code of Practice will be reviewed by government, the
industry, and the interested public. The Director shall have the final decision on
amendments made to this Code of Practice. Amendments to this Code of Practice shall
become effective when published by Alberta Environmental Protection.
Effective Date
i
Application Date: _
I
I
Person Responsible (Owner) Operator: same as owner nor: I
Company: Company:
Address:
City:
Address:
City:
\
,
Province: Province: r:
Postal Code: Postal Code:
f1
Y
Phone: Fax: Phone: Fax: 'I
i
Hydrostatic Test Contractor' Location of test section:
Company:
Address:
City:
Prom:
To: =
IIIITI
LSDSTRM
Province:
Postal Code:
Phone: Fax:
Length of test section:
Pipeline diameter:
Test water volume:
ri::
l::=:j m-
=
Test water source:
Location:
L5DSTRM
Date ofwithdrawal: _
Groundwater
H Surface Water
Municipal
Name of water body:
Muncipality or town:
Location: =
Test water release:
LSOsTRM
Date ctrelease: _
~
L,"d
Surface Water Name of water body:
Injection well Operator:
Other Description:
Additives Used:
Treatment
Methods:
(attach additional
sheet if necessary)
I acknowledge that I have reviewed a copy of the Code of Practice for Discharge of
Hydrostatic Test Water from Hydrostatic Testing of Petroleum Liquid and Natural Gas
Pipelines, and that 1am bound by the provisions of the Code of Practice and any
subsequent amendments to it.
Date
For office nse only:
Date Received: _
Registered By:
Registration Numbcr: _
~
II
!
19.0 Appendix H
Summary for Hydrostatic Testing Contacts
j
II
!
,I
i
I!,
APPENDIXH
SUMMARY FOR HYDROSTATIC TESTING CONTACTS
H -1
H-2
I Alberta I
Alberta Environmental Protection" Natural Resources Service - Water Management'
Regional Administrator - Northwest Boreal (403) 624-6167
Provincial Building (403) 624-6335 (fax)
9621 . 96A Avenue
l
Peace River, Alberta TOH2XO
!I
[
H-3
Deerfoot Square
1
0
3rd Floor ;
2938 - 11th Street N.E.
Calgary, Alberta T2E 7L 7 1!:;
~
(403) 297-7605
Regional Director (403) 297-5944 (fax)
201 Deerfoot Square
2938 - 11 Street N.E.
Calgary, Alberta T2E 7L7
II
'I
!
H-4
H- 5
I Manitoba I
Water Resources Branch (204) 945-6114
n
Manitoba Resources Branch i'
H-6
Approvals Branch
3rd Floor, 250 Daisville Avenue
Toronto, Ontario M4S lR2
(416) 440-3713
Conservation Authorities)
l
[
Ausable-Bayfield Conservation Authority (519) 235-2610 I
RR #3
Exeter, Ontario NOM 185
Cataraqut Region Conservation Authority (613) 546-4228 i
Box 160
1641 Perth Road
~'i
Glenburnie, Ontario KOHIS0 i
Catfish Creek Conservation Authority (519) 773-9037
RR #5 (519) 773-9605
Aylmer, Ontario N5H 2R4
Central Lake Ontario Conservation (905) 579-0411
Authority
300 Whiting Avenue
Oshawa, Ontario LIH 3T3
Credit Valley Conservation Authority (905) 670-1615
1255 Derry Road West
Meadowvale, Ontario L5N 6R4
Crown Valley Conservation Authority (613) 472-3137
Box 416
Marmora, Ontario KOK 2MO
Essex Region Conservation Authority (519) 776-5209
360 Fairview Avenue West
Essex, Ontario N8M lY6
Ganaraska Region Conservation Authority (905) 885-8173
Box 328
Port Hope, Ontario LIA 3W4
Grand River Conservation Authority (519) 621-2761
Box 729
400 Clyde Road
Cambridge, Ontario NIR 5W6
H-7
H-8
I Quebec I
Commission de Protection du Territoire (418) 643-3314
Agricole du Quebec
200-A chemin Ste - Fay _2e etage
Quebec, Quebec GIR 4X6
Minstere de l'Environnement et de Ia faune
Bas Saint Laurent
v (418) 727-3511
212, rue Belzile
Rimousld, Quebec G5L 3e3
Saguenay - Lac-Saint-Jean (418) 695-7883
3950, boul. Harvey, 4 9 etage
Jonqiriere, Quebec G7X BL6
Quebec (418) 622-5151
9530, rue de la Faune
Charlesbourg, Quebec G1G 5H9
Mauricie ~ Bois-Francs (819) 373-4444 ,i
100, rue Laviolette, 1er etage I]
'I'rois-Rivieres, Quebec G9A 589 :1
Estrie (819) 821-2020 II..,
700, rue Goretti
Sherbrooke, Quebec JIE 3H4 I
H-9
H-10
H-ll ===========
Hydrostatic Test Water Management Guidelines, September, 1996
ALBERTA NATURAL RESOURCES SERVICE WATER MANAGEMENT REGIONS
REGIONAL BOUNDARIES JULY, 1990
M.D. 22
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