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IEEE TRANSACTIONS ON INDUSTRY APPLICATIONS, VOL. 40, NO.

4, JULY/AUGUST 2004 1003

Static Discharge Hazard During Refueling


at Retail Gasoline Stations
Robert E. Nabours, Life Senior Member, IEEE

Abstract—Gasoline refueling stations have existed since the ad- stored followed closely on the heels of the studies of generating
vent of the automobile in the early 1900s. This paper explores the frictional electricity. Several investigators found that it could be
origin of the static electrical discharge hazard that can exist during stored in a bottle, given certain conditions. They discovered also
the refueling process. It has recently (1993) been discovered that a
source of hazardous static electricity exists that is beyond the pre-
that the amount of charge that could be stored in a bottle de-
viously known causes for this hazard. The controlled harmless dis- pended upon the area of the surface, not on the volume or mass
charge of static electrical charge is examined along with the sci- of the bottle. Probably the best remembered example came from
entific explanation for the newly discovered hazard. A refueling the university town of Leyden, TheNetherlands, home of the
fire at a commercial gas station is used to illustrate the forensic Leyden jar. If the vehicle has a metal fuel tank and is grounded,
engineering investigative process that leads to the identity of the the charge dissipates to ground via the conductive parts of the
cause for this fire. Conditions that promote this new static dis-
charge hazard are enumerated as well as suggestions for remedial
car body through the tires, and through the filling nozzle and
action on the part of the motorist to decrease the fire hazard during hose to ground (earth).
refueling. If the fuel tank is made of nonconductive plastic, or metal
Index Terms—Fire hazard at gasoline stations, gasoline refu-
with a nonconductive coating, the charge accumulates and re-
eling, static electricity. mains on the interior wall of the tank. Obviously the tank is
a type of Leyden jar. Because of the electric field effect orig-
inating from these charges, opposite polarity charges are at-
I. INTRODUCTION tracted as surface charges on the conductive parts of the car
adjacent to the fuel tank. This is known as electrostatic induc-
F OR OVER 60 years equipment manufacturers of automo-
tive and petroleum products have recognized that a static
electric discharge hazard can exist during the refueling process,
tion. This equipotential charge is dissipated from the car body
to ground (earth) if the vehicle is grounded.
particularly for vehicles equipped with pneumatic rubber tires. Thus, conductive parts of the vehicle, which are not con-
nected to ground, can become electrostatically charged through
II. ELECTROSTATIC CHARGING PROCESS IN REFUELING electrostatic induction or directly from contact with charged fuel
or with any charged body. This will occur even when other non-
Fuels become electrically charged while flowing through conductive parts of the vehicle are grounded. To visualize the
pipes and hoses. This phenomenon attracted much study in phenomenon, think of it as charging a capacitor.
the early 1700s when it was called frictional electricity. A Since the charge accumulated in the gas tank and on the ve-
more common term now is triboelectricity. Back then, they hicle varies with fuel flow velocity as well as conductivity, sci-
experimented with rubbing various nonconductive materials entists at the DGMK German Society for Petroleum and Coal
to accumulate a static charge. The same principal applies to Science and Technology, Hamburg, Germany, conducted ex-
gasoline flowing into the gas tank of a car. The quantity of periments on various fuels with different conductivities while
electric charge transferred depends on the fuel flow velocity filling tanks at different rates. The tests showed that when fu-
and on the conductivity of the fuel. Low-conductivity fuels can eling a tank to 13.2 gal at 11.9 gal/min, depending upon the fuel
retain a charge for longer times than high-conductivity fuels. conductivity, the accumulated charge varied from less than 1 C
Leaded gasoline can have more than twice the conductivity of (10 C) to 6 C. Under these conditions the maximum undis-
unleaded gasoline. [1, p. 8] Conductivity varies by a factor of sipated voltage present on the vehicle due to maximum charge
50 : 1 for unleaded gas from different companies in Germany. would be approximately 6000 V.
It also varies at different times from the same company and at
different filling station locations.
During vehicle refueling, charged gasoline accumulates in the III. PROCESS FOR CONTROLLED DISCHARGING
fuel tank. Investigating the ways by which electricity could be
Charged insulators can cause brush discharges in air and
gasoline–air mixtures from a conductor when its voltage
Paper ICPSD-03-12, presented at the 2003 IEEE/IAS Industrial and Com- exceeds a certain value. Brush discharges are an intermittent
mercial Power Systems Technical Conference, St. Louis, MO, May 4–7, and ap-
proved for publication in the IEEE TRANSACTIONS ON INDUSTRY APPLICATIONS
discharge of electricity having the form of a mobile brush, but
by the Power Systems Engineering Committee of the IEEE Industry Applica- remain too low for the formation of an actual spark [2, p. 107].
tions Society. Manuscript submitted for review May 7, 2003 and released for The quantity of charge that accumulates in a vehicle’s fuel tank
publication March 29, 2004. is, however, insufficient to produce incendive brush discharges
The author is with R. E. Nabours Consulting Electrical Engineers, Inc.,
Tucson, AZ 85718 USA (e-mail rencee@comcast.net). [1, p. 4]. Moreover, the excessively rich gasoline–air mixture
Digital Object Identifier 10.1109/TIA.2004.830755 in the tank is not ignitable.
0093-9994/04$20.00 © 2004 IEEE
1004 IEEE TRANSACTIONS ON INDUSTRY APPLICATIONS, VOL. 40, NO. 4, JULY/AUGUST 2004

Potentially ignitable brush discharges can occur between a V. ENGINEERING ANALYSIS OF STATIC ELECTRIC DISCHARGE
plastic inlet tube that has been charged by flowing gasoline and AND GASOLINE VAPOR EXPLOSION
a metallic filling nozzle. These discharges can be tolerated only In the German study [1], it was experimentally determined for
if the fuel–air mixture in the entire inlet tube is outside the range six different vehicle types and four different articles of clothing
of an explosive fuel-to-air ratio. that a person can receive a charge from the insulating seats while
As has been described above, during the process of filling the exiting the vehicle under very dry weather conditions of from
vehicle’s fuel tank with gasoline, an electrical charge is carried 1000 to 10 000 V.
into the tank producing a charge on the vehicle. In order to elim- The energy stored in a charged body can be expressed by [3,
inate this accumulated static charge harmlessly, gasoline-dis- p. 6], [4]
pensing pumps have, for over 60 years, been required by the
National Electrical Code (NEC) to be grounded, i.e., connected
electrically to earth. The discharge path for accumulated fuel
charge does not require a direct low-resistance metallic connec-
tion (bond) through metal filling nozzle hose and pump. In fact, where is the energy in joules (J), is the capacitance coupling
modern vehicles have increasingly been equipped with plastic the person to the vehicle in farads (F), and is the voltage across
insulated parts such as filler caps and tank inserts with flaps for the discharge gap between person and car in volts.
unleaded gas. Today, the typical resistance of the nozzle-hose- The capacitance of the person charged by exiting a standard
ground path is on the order of or less [1, p. 29]. size automobile at a distance of approximately 50 cm (10 m)
If the accumulated static charge were to be dissipated by an to the car has been measured between 170 pF (10 F) and 200
arc (spark) discharge to ground occurring in the vicinity of the pF. With a 10 000-V accumulated charge, an energy of 8.5 mJ
vehicle’s filling pipe, the accumulated gasoline vapor could be (10 J) to 10 mJ can be dissipated. The effective spark energy
ignited by this spark. The critical factor in static fuel discharge is lower by a factor of 2–4 [5] because part of the discharge is
is the time required to transfer the charge from the vehicle. This converted to heat due to the effect in the human body ohmic
time duration is called relaxation time and can be shown to be resistance and part of the discharge is converted into stored en-
the product of the resistance and capacitance of the vehicle to ergy in the circuit inductance.
ground. As long as the relaxation time is less than 0.01 s, there The MIE of a fuel material is the quantity of electrical energy,
is an insignificant probability of an incendive spark. supplied as a spark, which causes combustible vapors to ignite
[6]. A spark that has enough energy to ignite the combustible
IV. PROCESS FOR INADVERTENT DISCHARGE vapor is said to be incendive.
In general, the MIE of a fuel varies with pressure, ambient
As recently as 1993 it became known in Germany [1, p. 1] temperature, and the fuel-to-air mixture ratio. Also, when there
that another source of static electricity exists, under certain is a concentration of oxygen in the environment, such as in hos-
conditions as stated below, that can ignite these gasoline vapors. pitals, the MIE can be many times less than the MIE in air.
In the U.S. over 180 reports of refueling fires that exclude A typical MIE for gasoline vapor in air is 0.25 mJ. This ap-
other sources of ignition such as gas flow generated static, plies for vapor concentrations between 1.4%–7.6% by volume
sparks from running motors, and smoking have been logged (vapor to air). [7, p. 119]
from 1992 through 2003 by the Petroleum Equipment Institute Values for the accumulated charge on a person’s body due to
(www.pei.org) and since 1993 by the National Highway Traffic the triboelectric effect vary from 1000 to over 15 000 V. The en-
Safety Administration (NHTSA). ergy available in the capacitive model of the human body when
These fires have involved almost every automotive manufac- charged to 5000 V is between 2.125–5.0 mJ. The effective spark
turer, both U.S. and foreign, and the vehicles involved have in- energy capable of delivery by the human body when charged to
cluded large and small passenger cars, SUVs, and pickup trucks. 5000 V is between 0.53–1.25 mJ, so that a person’s static spark
They have occurred in 39 states and resulted in many major discharge is from 2 to 5 times the MIE for gasoline vapor in air.
burns and two deaths. Some of these fires occurred prior to be- Thus, there is substantial scientific verification for the hy-
ginning refueling upon removing the gas cap. pothesis that a person can acquire a static charge sufficient to
This newly recognized source of static electricity occurs ignite gasoline vapor in air especially if the discharged static
during the refueling process in the following manner. When spark occurs near the vapor accumulation.
the vehicle operator initiates an automated refuel leaving the
pump hose and nozzle unattended and then reenters the vehicle
VI. AN INVESTIGATED FIRE CASE
to slide across the seats, a static charge can accumulate on the
person’s body due to the triboelectric effect [2, p. 972] caused A refueling fire was recorded by a video surveillance camera
by friction between two electrically dissimilar materials. This at a commercial gas station in 2002. The weather was mild,
charge, if not harmlessly discharged through the operator’s 70 F with low humidity ( 20%). A motorist was removing
shoes, for example, remains until the operator approaches the the fueling nozzle from the fuel tank opening of his 1994 Geo
pump nozzle. A spark discharge through air can result when Tracker when a deflagrating explosion and fire erupted. The fire
the operator’s hand is very close to the grounded nozzle. was enhanced when the startled man pulled the nozzle from the
Asparkdischargeofstaticelectricitynearthefilleropeningwill tank while depressing the trigger so that gasoline was spilled on
likely ignite combustible gasoline vapors when the discharge en- the driveway and on the motorist.
ergy exceeds the minimum ignition energy (MIE) of the vapor, in The gas station pump dispenser’s insurance company retained
which case a deflagrating explosion and gasoline fire will result. this engineer to investigate the fire for causation. The police de-
NABOURS: STATIC DISCHARGE HAZARD DURING REFUELING AT RETAIL GASOLINE STATIONS 1005

partment furnished 52 photographs taken by the fire investiga- • If re-entering the vehicle, repeat the discharge action upon
tors after the incident along with a videotape recorded by the leaving the vehicle and before approaching the refueling
service station’s security camera. area.
In order for the fire to occur in the manner consistent with the • Re-upholster or treat the vehicle’s upholstery with a non-
fact evidence in this incident there are only three reasonably likely static generating material.
proximate causes for the ignition of the gasoline vapor at the tank • Install a conductive filler cap connected to the vehicle’s
filleropening:1)anopenflamesuchasacigarettelighterormatch; metallic body in a dissipative manner.
2) a spark from the engine compartment with the motor running;
and 3) a static electric discharge at the nozzle and filler opening. IX. POSTSCRIPT
The police department investigators determined that the mo-
torist was a nonsmoker (which is also confirmed by the videotape) Since April 2002, when the author began this investigation
and none of the eyewitnesses could recall him smoking or lighting and research into the static discharge hazard involving gasoline
a cigarette as he was filling his tank. The vehicle’s motor was not refueling, the Petroleum Equipment Institute (PEI) and the
running. American Petroleum Institute (API) have issued safe refueling
Theaccumulationofastaticelectricchargeduetogasolineflow guidelines to their members that provide information on
through the hose and nozzle was considered as a cause. Therefore, avoiding potential problems with static electricity at the pump.
an investigation of the grounding of the hose, nozzle, and pump There also has been an industry-wide movement toward
was conducted; it was also verified with a local Geo dealer that posting warnings on gasoline pumps that state: “WARNING”
the fuel tank in this vehicle was most likely metal. Since proper “Static electricity can ignite gasoline vapors” “Stay near your
grounding was found, any electrical charge accumulated through vehicle and do not re-enter it while fueling” “If you do re-enter
gasoline flow would likely be drained harmlessly to ground. your vehicle during fueling, touch a metal part of your vehicle
The accumulation of a static electric charge by the motorist before touching the gasoline nozzle to discharge any potential
was, however, a highly likely explanation for this fire. The static buildup.”
weather conditions were very dry, the motorist reentered his car One retail gas company in Florida has designed a sign made
momentarily and exited without touching the door or vehicle of dissipative materials to serve as a warning and a place where
before reaching the gas tank and pump nozzle. His approach a person may discharge their static without a spark and away
to the right-rear area of the car required a minimum time for from the fume area of the nozzle (StaTouch).
his shoes to be in grounded contact. A person can acquire and There have been suggested changes to the NFPA 30A-2000
retain a static electric charge of thousands of volts under these Code for Motor Fuel Dispensing Facilities and Repair Garages
conditions [5, p. 106]. This charge will be discharged with an to require warning signs regarding the static electricity hazard
incendive spark when the person’s hand comes very close (less in gas dispensing areas, and some of the national brand gasoline
than 0.2 cm) to the grounded dispenser nozzle. retailers have started to display such warnings on their pumps.

VII. CONCLUSION REFERENCES


Under the right set (or wrong set) of conditions the gasoline re- [1] “Avoidance of Ignition of gasoline/air mixture during refueling of motor
vehicles at filling stations,” DGMK German Soc. Petroleum and Coal
fueling process can be extremely hazardous. It has for years been Sci. Technol., Hamburg, Germany, DGMK Project 508,, Feb. 1996.
recognized that a running motor, open flame, or high-tempera- [2] IEEE Standard Dictionary of Electrical and Electronics Terms,
ture materials such as smoking material should be avoided in the ANSI/IEEE Std. 100-1984.
[3] Static Electricity, ANSI/NFPA 77, 1993.
vicinity of the refueling point. We also have recognized the danger [4] Nabours, Fish , and Hill, Electrical Injuries Engineering, Medical and
presented by static electric discharge during refueling and have Legal Aspects, 2nd ed. Tucson, AZ: Lawyers & Judges Publishing,
codified, e.g., the NEC, standards that minimize the accumula- 2004, p. 154.
[5] T. H. Pratt, Electrostatic Ignitions of Fires and Explosions. New York:
tion of static electricity in the fueling area due to fuel flow. American Institute of Chemical Engineers, 2000, p. 53.
In order to address the danger of human static electricity during [6] R. Noon, Engineering Analysis of Fire and Explosions. Boca Raton,
FL: CRC Press, 1995, p. 62.
gasoline refueling it should be recognized that conditions that in- [7] Guide for Fire and Explosion Investigations 1995 Edition, NFPA 921,
creasethestaticdischargehazardduringautomotiverefuelingare 1995.
as follows:
• dry weather;
• static-producing clothing and seat upholstery; Robert E. Nabours (S’57–M’57–SM’83–LS’97) re-
ceived the B.S.E.E. degree from the University of Ari-
• rubber-soled or nonconductive synthetic-soled shoes; zona, Tucson, in 1957, the M.S. degree in electrical
• reentering the vehicle during automated refueling. engineering from Stanford University, Stanford, CA,
in 1959, and the Ph.D. degree in electrical engineering
VIII. PERSONAL SAFETY PROCEDURES from the University of Arizona in 1965.
He was an Instructor in electrical engineeering at
Remedial actions that can be taken by the motorist to decrease the University of Arizona, a Project Leader in adap-
the static hazard during refueling are the following. tive communications research for Bell Aerosystems
Company, and the Chief Engineer for Burr-Brown Re-
• Discharge any static accumulation when leaving the ve- search Corporation. He has practiced consulting en-
hicle by touching the metal parts of the vehicle well away gineering since 1958, serving as a forensic electrical engineering expert in court
from the refueling area. over 50 times. He has authored 12 papers and three books on forensic electrical
engineering.
• Avoid automated refueling or do not re-enter the vehicle Dr. Nabours is a Registered Professional Engineer in the States of Arizona,
during refueling. California, and New Mexico.

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