METAL MATES HDP LUBRICANT

H.M.I.S. RATING
Health 1
Flammability 1
MATERIAL SAFETY DATA SHEET Reactivity 0
Personal Protection B

SECTION 1 — PRODUCT IDENTIFICATION

Product identifier: METAL MATES HDP LUBRICANT Manufacturer name and address:
Product use: Stamping Lubricant ITW Metal Mates, Inc.
Supplier name and address: See manufacturer. 3624 W. Lake Ave.
Emergency Telephone #: 800-452-5823 (Off-Hour Emergency Number - CHEMTREC - 1-800-424-9300). Glenview, IL 60026

SECTION 2 — CHEMICAL COMPOSITION/HAZARDOUS INGREDIENTS

Ingredients CAS # % (weight) OSHA/PEL ACGIH/TLV
Alkanolamine 00102-71-6 7 n/av 5 mg/m3 TWA
Phosphoric acid 07664-38-2 2 1 mg/m3 1 mg/m3

SECTION 3 — HAZARDS IDENTIFICATION

Emergency overview: No hazards resulting from the material supplied.
Routes of entry: Skin, eyes, respiratory tract, digestive system.
Signs and symptoms of short-term (acute) exposure:
Inhalation: May cause irritation to eyes, nose and throat. Inhalation of vapors or mist may cause headache, dizziness and drowsiness.
Skin contact: May cause mild to moderate irritation.
Eye contact: May cause mild to moderate irritation.
Ingestion: Harmful if swallowed. May cause irritation of the stomach.
Effects of long-term (chronic) exposure: None known for the product.

SECTION 4 — FIRST AID MEASURES

Inhalation: Move to fresh air. If irritation persists, consult physician.
Skin contact: Wash thoroughly with soap and water. Remove soiled clothing and wash before reuse. If irritation persists, consult physician.
Eye contact: Flush promptly with water for at least 15 minutes. If irritation persists, consult physician.
Ingestion: If swallowed, do not induce vomiting. Obtain medical attention immediately.

SECTION 5 — FIRE FIGHTING MEASURES

Fire hazards/conditions of flammability: Not a flammable product. However, may burn if heated to extreme temperatures. Refer to flash
point.
Flash point (Method): >93.3°C (>200°F) (Cleveland Open Cup)
Lower flammable limit (% by volume): n/av
Upper flammable limit (% by volume): n/av
Explosion data: Sensitivity to mechanical impact: None. Sensitivity to static discharge: None
Oxidizing properties: None.
Auto-ignition temperature: n/av
Suitable extinguishing media: Carbon dioxide, dry chemical, foam, fog, sand, earth.
Special fire-fighting procedures/equipment: Self contained breathing apparatus and protective clothing is recommended to protect fire
fighters from any hazardous combustion or decomposition products. Pressure build-up in the closed container may occur due to heat exposure.
Keep away from heat, sparks, flame or ignition sources.
Hazardous combustion products: Oxides of carbon and nitrogen.

SECTION 6 — ACCIDENTAL RELEASE MEASURES

Personal precautions: Use appropriate safety equipment. Avoid inhaling vapors. Avoid contact with eyes, skin and clothing.
Environmental precautions: Do not allow spilled product to enter drains, sewers, or waterways.
Spill response/Cleanup: Ventilate area. Eliminate all sources of heat and flame. Stop leak if safe to do so. Contain spill. Use absorbent
material, such as vermiculite or sand. Place in suitable container for later disposal.
Prohibited materials: None.

SECTION 7 — HANDLING AND STORAGE

Safe handling procedures: Use appropriate safety equipment. Use with adequate ventilation. Avoid inhaling vapors or mist. Avoid contact
with eyes, skin and clothing. Keep away from extreme heat. Keep container closed when not in use.
Storage requirements: Store away from extreme heat, flame, or ignition sources. Pressure build up may occur due to heat exposure or
temperature change. Release pressure by slowly opening container.
Incompatible materials: Strong oxidizers.
Special packaging materials: No special requirements.

SECTION 8 — EXPOSURE CONTROLS AND PERSONAL PROTECTION

General Hygiene: Avoid contact with eyes, skin and clothing. Do not eat, drink, or smoke while handling this product.
Ventilation and engineering controls: General ventilation should be sufficient.
Respiratory protection: Not normally required. Control vapor or mist concentrations below exposure limits through use of general or local
exhaust ventilation.
Protective gloves: Neoprene gloves are recommended.
Eye protection: Safety glasses are recommended.
Other protective equipment: Wear protective clothing suitable to prevent contact. Remove contaminated clothing and launder before
wearing. Availability of eye wash station, washing facilities and safety shower is recommended. Providing approved respirators for
emergencies, or when mist/vapor concentrations are unknown may be warranted.
Permissible exposure levels: Refer to Section 2.
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 METAL MATES HDP LUBRICANT
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
Physical form, color and odor: Tan creamy liquid, mild odor. Odor threshold: n/av
pH: 7.7 - 8.7 Boiling point: >93.3oC (>200oF)
Melting/freezing point: n/av Vapor pressure: n/av
Solubility in water: Emulsifies. Coefficient of oil/water distribution: n/av
Specific gravity or relative density (water = 1): 1.03 (Pounds/gallon: 8.6) Vapor density: n/av
Volatile organic compounds (VOC's): n/av Evaporation rate: n/av

SECTION 10 — REACTIVITY AND STABILITY DATA

Stability and reactivity: Stable. Hazardous polymerization will not occur.
Conditions to avoid: Extreme heat.
Materials to avoid: Strong oxidizers.
Hazardous decomposition products: Thermal decomposition or burning will produce carbon monoxide, carbon dioxide, and nitrogen oxides.

SECTION 11 — TOXICOLOGICAL INFORMATION

LD50: Not determined for the product. Alkanolamine: 4920 µL/kg (approximately = 5000 mg/kg) (oral, rat); >16mL/kg (approx. = >16 g/kg)
(dermal, rabbit)
Phosphoric acid: 1530 mg/kg (oral, rat); 2740 mg/kg (dermal, rabbit)
LC50: Not determined for the product. Phosphoric acid: >212 mg/m3/4Hrs.
Routes of exposure: Inhalation, ingestion, skin and eye contact.
Toxicological data: Not available.
Carcinogenicity: None of the ingredients in this product are listed by IARC, ACGIH, NTP or OSHA as carcinogenic.
Teratogenicity, mutagenicity, other reproductive effects: No data.
Sensitization to material: Contains 7% of Alkanolamine, which may cause skin sensitization in a small portion of individuals.
Conditions aggravated by exposure: None known.
Synergistic materials: None known.

SECTION 12 — ECOLOGICAL INFORMATION

Environmental effects: None reported.
Important environmental characteristics: None known.
Aquatic toxicity: No data.

SECTION 13 — WASTE DISPOSAL

Handling for disposal: Absorb on suitable material and follow procedures listed below.
Methods of disposal: Dispose of in a manner that is recommended by local, state, provincial and federal laws and regulations.

SECTION 14 — TRANSPORTATION INFORMATION

Transportation of Dangerous Goods (TDG) information:
Shipping description: Not regulated.
49 CFR information:
Shipping description: Not regulated.
International Dangerous Goods information:
IMO: Refer to the Regulations.
ICAO: Refer to the Regulations.
Other information: None

SECTION 15 — REGULATORY INFORMATION

WHMIS information: Class D2B
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and this MSDS
contains all the information required by the CPR.
CEPA information: No data.
TSCA information: All ingredients are included in the TSCA inventory.
SARA Title III: Contains no ingredients which exceed De Minimus reporting requirements.

SECTION 16 — OTHER INFORMATION

Prepared by: Metal Mates Inc., Leroy Hitchcock
Telephone number: 800-452-5823
Preparation date: December 19, 2005
Document ID: HDP.doc

Other Information:
References:
1. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Indices, 2004.
2. Canadian Centre for Occupational Health and Safety., CCInfoWeb databases, 2004.
3. US EPA Title III Lists of Lists - October 2001 version.
4. Material Safety Data Sheets from manufacturer.

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