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REACTIONS
Introduction
Metals differ in their reactivity with other chemicals such
as air, water and acids. Some metals such as sodium are
so reactive that they cannot exist as the free element in
nature. Gold is so unreactive that native gold is commonly
found in natural deposits. The reactivity of metals
influences their uses. Reactivity is a chemical property
that will be examined in this section.
In this chapter
7.1 Metals and their reactivity page 128
7.2 Reactivity and uses of metals page 132
Figure 7.1
Sodium must be stored away from air and water as it
is a very reactive metal.
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Remember Reactions of metals
Before beginning this section, The reactivity of metals can be determined
you should be able to:
• explain the relationship experimentally by observing the speed
between the reactivity of an of reaction of the metals with common
element and the likelihood of
it existing as an uncombined chemical reagents such as water, oxygen
element. and dilute acids.
Key content
By the end of this section, you Reaction with water
should be able to: Results of experiments to compare the
• describe observable changes
when metals react with dilute reactions of a selection of common metals
acid, water and oxygen with water, hot water and steam are shown
• describe and justify the
criteria used to place metals in table 7.1. It shows that either oxides or
into an order of activity based hydroxides are formed.
on their ease of reaction with
oxygen, water and dilute acids
• identify the reaction of metals Table 7.1 Reactivity of metals with water
with acids as requiring the
transfer of electrons K, Na, Ca react with cold water to form
• perform a first-hand hydroxide ions and release
investigation incorporating hydrogen gas
information from secondary
sources to determine the
metal activity series Mg reacts with hot water to form
• construct word and balanced hydroxide ions and release
chemical equations for the
reaction of metals with water, hydrogen gas
oxygen and dilute acid
• construct half-equations
to represent the electron Al, Zn, Fe react with steam at red heat to
transfer reactions occurring form oxide ions and release
when metals react with hydrogen gas
dilute hydrochloric and dilute
sulfuric acids Figure 7.2 Magnesium burns
• present information by using Sn, Pb, Cu, no reaction brightly in air or oxygen.
symbols and formulae to Hg, Ag, Au
express relationships and
using appropriate units for
physical quantities. The reaction rate is highest for active metals. Unreactive metals such
as copper and gold do not react; they are inert. Potassium, sodium and
calcium are the most reactive metals with water. The following equations
inert: describes a substance
that does not react with other illustrate some of the reactions described in table 7.1.
substances • Sodium + water
Word equation:
sodium metal + water sodium hydroxide solution + hydrogen gas
Balanced chemical equation:
2Na(s) + 2H2O(l) 2NaOH(aq) + H2(g)
• Iron + steam
Word equation:
iron metal + steam iron oxide solid + hydrogen gas
Balanced chemical equation:
Fe(s) + H2O(g) FeO(s) + H2(g)
Figure 7.3
Magnesium reacts with hot water, forming bubbles of hydrogen gas on its surface.
128 METALS
Reaction with oxygen
Experiments can be conducted to observe the reaction of metals with air
(21% oxygen). The metals are normally heated (e.g. in a Bunsen flame)
to initiate the reaction. The hot metals can also be plunged into gas jars of
oxygen. The results of such experiments are shown in table 7.2.
Sn, Pb, Cu, Hg become coated with oxide layers during heating
Ag, Au no reaction
Potassium, sodium and calcium are highly reactive to oxygen while silver
and gold are unreactive. The following equations illustrate some of the r
eactions in table 7.2.
• Calcium + oxygen
Word equation:
calcium metal + oxygen gas calcium peroxide solid
Balanced chemical equation:
Ca(s) + O2(g) CaO2(s)
• Mercury + oxygen
Word equation:
mercury metal + oxygen gas mercury (II) oxide solid
Balanced chemical equation:
2Hg(s) + O2(g) 2HgO(s)
Al, Zn, Fe, Sn, Pb bubble moderately to very slowly as hydrogen is released;
Figure 7.4 reaction is faster in warm acid; lead stops reacting when
Calcium burns in oxygen with coated with insoluble PbCl2 or PbSO4
a bright white flame.
Cu, Hg, Ag, Au no reaction
130 METALS
Electron loss: Mg(s) Mg2+(aq) + 2e–
Electron gain: 2H+(aq) + 2e– H2(g)
SYLLABUS FOCUS
11. WRITING HALF-EQUATIONS AND IONIC EQUATIONS
Half-equations help us understand the electron transfer process between
metals and non-metals. Generally:
• metals lose electrons to form metal ions (cations)
• non-metals gain electrons to form non-metal ions (anions)
• hydrogen ions gain electrons to form hydrogen gas.
Using these generalisations, we can write half-equations for the reactions
between metals and dilute acids. Half-equations must be balanced in
terms of atoms and charges.
Ionic equations are created by summing two half-equations so that the
number of electrons lost by the metal equals the number of electrons
gained by the non-metal or hydrogen ion.
Example: Reaction of aluminium with hot sulfuric acid
Aluminium atoms will lose three electrons and the hydrogen ions will
gain two electrons.
Electron loss: Al(s) Al3+(aq) + 3e– (1)
Electron gain: +
2H (aq) + 2e – H2(g) (2)
To balance the electrons, multiply half-equation (1) by 2 and half-
equation (2) by 3, and then add the two half-equations. Check that the
atoms and charges balance.
Electron loss: 2Al(s) 2Al3+(aq) + 6e–
Electron gain: 6H+(aq) + 6e– 3H2(g)
Ionic equation: +
2Al(s) + 6H (aq) 2Al3+(aq) + 3H2(g)
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Remember Relating reactivity to use
Before beginning this section, Knowledge of a metal’s reactivity is important in designing ways to use it. If
you should be able to: a metal readily oxidises (corrodes), it is unsuitable as a structural material
• explain the relationship
between the reactivity of an unless it can be protected from the environment. New metals and alloys are
element and the likelihood of constantly being investigated. Titanium is one example. It has an activity
it existing as an uncombined similar to aluminium but it has greater tensile strength. It can withstand
element
• describe observable changes shearing forces for a longer time than many conventional metals.
when metals react with dilute Titanium alloys are used in the engines of commercial jets. The chemi-
acid, water and oxygen.
cal industry makes increasing use of titanium because of its resistance to
Key content corrosion. Pumps, pipes and reaction vessels made of titanium are used in
By the end of this section, you
should be able to: some chemical industries.
• outline examples of the
selection of metals for
different purposes based
on their reactivity, with
a particular emphasis on
current developments in the
use of metals
• identify the importance of
first ionisation energy in
determining the relative
reactivity of metals
• outline the relationship
between the relative activities
of metals and their positions
in the periodic table
• present information clearly
and succinctly using a variety
of pictorial representations to
show relationships.
Figure 7.6
The fuel tanks on Skylab space
station were made of titanium.
132 METALS
Table 7.5 lists some common uses of metals that are related to their
chemical reactivity. Other uses are related to their physical properties.
Zinc coating protects the Cu high corrosion resistance water pipes, electrical wires and wrapping
iron from rusting.
for optic fibre cables. Copper does not
Figure 7.8 corrode readily in the environment.
The zinc coating on galvanised iron
protects the metal from corrosion.
SAMPLE PROBLEM 7.1 Account for the use of calcium rather than copper as a dehydrating
agent for some petroleum solvents.
Calcium is a very active metal that reacts with water and removes it
SOLUTION from the organic solvent. Copper is very unreactive and does not
remove water from the solvent.
Ionisation energy
The reactivity of metals is related to their tendency to lose valence elec-
trons to form ions that have a stable electron configuration. The tendency
of gaseous atoms to lose electrons is measured by a quantity called the
ionisation energy (I ). This energy must be supplied to overcome the
ionisation energy: the minimum attractive force that binds the electrons to the nucleus.
energy required to remove an
electron completely from a Electrons can be removed sequentially according to the strength of the
gaseous atom force that binds them to the nucleus. The energy required to remove the
most loosely bound electron is called the first ionisation energy (I1). The
successive ionisation energies (I1, I2, I3 etc.) reflect the positions of the
electrons in their shells.
Ionisation energies are measured in the gaseous state as the symbol (g)
indicates in the following examples for an element E.
I1 I2 I3 I4 I5 I6 I7
134 METALS
in the gaseous state. We now need to consider the possibility that the ioni-
1000 sation energy of a gaseous metal atom may be related to the activity series.
Table 7.7 shows the first ionisation energy data for selected metals.
900
I1, First ionisation energy (kJ)
600
This table shows that very reactive metals, such as potassium and sodium,
500 have very low ionisation energies and that magnesium and zinc, which
are less reactive than sodium, have higher ionisation energies. Beyond this,
400 however, the data does not show a simple relationship between the activity
series and ionisation energy. Other factors come into play when determining
0 the relative reactivity of metals.
K Na Mg Zn Fe Cu Ag Au
Relative activity
Decr Reactivity and the periodic table
activity
Figure 7.11 compares the positions of the metals in the activity series with
Figure 7.10 their locations in the periodic table. The following observations can be
Relationship between first ionisation
made:
energy and relative activity
of selected metals • The most active metals, such as potassium and sodium, are in group
I on the left side of the table. In general, their reactivity increases down
the group. Thus, caesium and francium are highly reactive metals.
• The next most active metals, such as calcium and magnesium, belong in
group II. Again, reactivity increases down the group.
• Metals of moderate reactivity, such as zinc and iron, lie at the edge of
the metal zone of the periodic table.
• There is no general pattern for the remaining elements, except that the
least reactive, such as gold and mercury, are located in the lower central
region called the transition metals. Other metals in this region, such as
osmium, iridium and platinum, are also quite unreactive.
Figure 7.11
Metal reactivity and the Very reactive metals Unreactive metals Low reactivity, soft metals
periodic table (K, Na, Ba, Ca, Mg) (Hg, Ag, Pt Au) (Sn, Pb)
600
500
400
300
0
Li Na K Rb Cs
Group I metals
Increasing
activity
Figure 7.12
Relationship between first ionisation
energy of group I metals
and reactivity
Figure 7.13
Copper is an unreactive metal that is highly ductile and has a high electrical conductivity.
136 METALS
5. Which of the following metals has the (c) Gallium metal also ionises when placed
smallest first ionisation energy? in dilute hydrochloric acid. Write a half-
A Magnesium equation for the ionisation of gallium in
B Sodium this case.
C Aluminium (d) Write the net ionic equation for
D Rubidium the reaction of gallium with dilute
hydrochloric acid.
6. Gallium is chemically similar to aluminium.
(a) Gaseous gallium atoms can be ionised 7. The successive ionisation energies
in three successive steps to form the (in MJ/mol) for two multi-electron elements
stable Ga3+(g) ion. Write each of the half- X and Y are shown in table 7.9:
equations for the stepwise ionisation. (a) Use this data to determine the number of
(b) Identify the ionisation step that requires valence electrons for each element.
the greatest amount of energy. Justify (b) Classify X and Y as metals or non-metals.
your response. Justify your answer.
(c) Predict the chemical formula of a
compound formed between X and Y.
Table 7.9 Successive ionisation energies (MJ/mol)
X 0.60 1.15 4.92 6.48 8.15 10.50 12.33 14.21 18.19 20.39 57.06 63.34
Y 1.26 2.30 3.83 5.16 6.55 9.37 11.03 33.61 38.61 43.97 51.07 57.10
SUMMARY
• Metals react with dilute hydrochloric or sulfuric acid to release
www.jaconline.com.au/chemnsw/chemistry1
hydrogen gas and form ionic salts.
• The order of the activity of metals can be determined by the rate
at which they react with other substances including oxygen, water
and dilute acids.
• The ease or difficulty of thermal decomposition of metallic
compounds can be related to the activity series.
• The most reactive metals are located in groups I and II of the
periodic table. The least reactive metals are located in the lower
periods of the transition metals.
• The reactivity of metals can be understood in terms of the ease
with which they lose electrons. The reactivity of metals is related to
their uses.
• Ionisation energy is the energy required to remove successive
electrons from gaseous atoms.
7.1
Analysing second-hand data
PRACTICAL
ACTIVITIES The following second-hand data is supplied for you
to analyse.
THE ACTIVITY SERIES Part C: Reaction with oxygen (air)
OF METALS Table 7.10 shows the effect of heating a strip of
each metal in air in a Bunsen burner flame.
138 METALS
PRACTICAL ACTIVITIES
Results and analysis 4. (a) Identify the gas that produces a positive
glowing splint test.
1. Use your tabulated results of parts A and B
(b) Use the data on sodium carbonate
to rank (where possible) the selected metals
and silver carbonate as well as your
from most reactive to least reactive.
experimental results to establish an activity
2. Process the data from part C and explain series for Cu, Zn, Mg, Fe, Na and Ag.
whether it is consistent with your ranked order (c) Write a balanced chemical equation
established in parts A and B. for the thermal decomposition of silver
3. Examine the data in table 7.11. carbonate based on the experimental data.
(a) Identify the gas that produces a positive
limewater test.
Conclusions
(b) Explain whether the data is consistent with Write a brief conclusion for this experiment.
the following generalisation: