Appendix A

Thermophysical Properties
of Carbon Dioxide

317

© 2000 by CRC Press LLC

318 Natural Extracts Using Supercritical Carbon Dioxide

TABLE A.1
Densities (gm·cm–3) of Pure CO2 Calculated by P-R EOS
T, °C/P, bar 50 55 60 65 70 75 80 85 90 95 100

–10 1.014 1.018 1.021 1.025 1.029 1.032 1.036 1.039 1.043 1.046 1.049
–5 0.978 0.983 0.987 0.992 0.996 1.000 1.004 1.008 1.012 1.016 1.020
0 0.940 0.944 0.950 0.955 0.960 0.965 0.970 0.975 0.979 0.984 0.988
5 0.894 0.901 0.907 0.914 0.920 0.926 0.932 0.938 0.944 0.949 0.954
10 0.117 0.856 0.860 0.867 0.876 0.884 0.891 0.898 0.905 0.911 0.918
15 0.156 0.208 0.800 0.813 0.824 0.834 0.844 0.853 0.860 0.869 0.877
20 0.144 0.171 0.235 0.744 0.761 0.776 0.789 0.801 0.813 0.823 0.832
25 0.134 0.160 0.195 0.269 0.673 0.700 0.722 0.740 0.755 0.769 0.781
28 0.130 0.153 0.183 0.225 0.586 0.639 0.671 0.695 0.715 0.732 0.747
30 0.127 0.145 0.171 0.205 0.272 0.578 0.629 0.661 0.685 0.705 0.723
35 0.121 0.140 0.163 0.191 0.226 0.281 0.417 0.534 0.589 0.625 0.651
40 0.116 0.130 0.149 0.171 0.197 0.231 0.276 0.356 0.497 0.516 0.630
45 0.111 0.127 0.145 0.165 0.188 0.215 0.247 0.287 0.337 0.398 0.457
50 0.107 0.119 0.135 0.153 0.172 0.194 0.219 0.249 0.285 0.328 0.386

T, °C/P, bar 110 120 130 140 150 160 170 180 190 200

0 0.997 1.005 1.012 1.020 1.027 1.033 1.039 1.045 1.051 1.057
5 0.964 0.973 0.982 0.990 0.998 1.006 1.013 1.020 1.026 1.032
10 0.929 0.940 0.950 0.959 0.968 0.977 0.985 0.992 1.00 1.007
15 0.891 0.904 0.916 0.927 0.937 0.946 0.955 0.964 0.972 0.980
20 0.849 0.865 0.879 0.891 0.903 0.914 0.925 0.934 0.943 0.952
25 0.803 0.822 0.839 0.854 0.868 0.880 0.892 0.903 0.913 0.923
30 0.751 0.775 0.796 0.814 0.830 0.845 0.858 0.870 0.882 0.893
35 0.692 0.723 0.749 0.770 0.790 0.807 0.822 0.836 0.849 0.862
40 0.685 0.665 0.698 0.724 0.747 0.767 0.785 0.801 0.816 0.829
50 0.504 0.584 0.583 0.622 0.655 0.682 0.705 0.726 0.745 0.762
55 0.397 0.467 0.524 0.569 0.606 0.637 0.664 0.687 0.708 0.727
60 0.359 0.436 0.469 0.518 0.559 0.593 0.623 0.648 0.671 0.692
65 0.317 0.371 0.423 0.472 0.514 0.550 0.582 0.610 0.635 0.657
70 0.294 0.347 0.386 0.431 0.473 0.511 0.544 0.573 0.600 0.623
75 0.274 0.314 0.357 0.398 0.438 0.475 0.508 0.539 0.566 0.591
80 0.248 0.265 0.332 0.371 0.408 0.443 0.476 0.506 0.534 0.560
85 0.244 0.279 0.318 0.358 0.399 0.438 0.474 0.507 0.537 0.563
90 0.232 0.265 0.299 0.336 0.373 0.410 0.445 0.477 0.507 0.534
100 0.214 0.242 0.271 0.301 0.333 0.365 0.396 0.426 0.455 0.482

© 2000 by CRC Press LLC

Appendix A Thermophysical Properties of Carbon Dioxide 319

TABLE A.1 (continued)

Densities (gm·cm–3) of Pure CO2 Calculated by P-R EOS
T, °C/P, bar 220 240 260 280 300 320 340 360 380 400

5 1.044 1.055 1.066 1.075 1.085 1.093 1.101 1.109 1.117 1.124
10 1.020 1.032 1.043 1.054 1.063 1.073 1.082 1.090 1.098 1.106
15 0.992 1.008 1.020 1.032 1.042 1.052 1.062 1.071 1.080 1.088
20 0.968 0.983 0.996 1.009 1.020 1.031 1.041 1.051 1.060 1.069
25 0.941 0.957 0.972 0.985 0.998 1.010 1.021 1.031 1.041 1.050
30 0.913 0.930 0.946 0.961 0.975 0.987 0.999 1.011 1.021 1.031
35 0.884 0.903 0.921 0.937 0.952 0.965 0.978 0.990 1.001 1.012
40 0.854 0.875 0.894 0.912 0.928 0.942 0.956 0.969 0.981 0.992
50 0.792 0.818 0.840 0.861 0.879 0.896 0.912 0.926 0.940 0.952
60 0.728 0.758 0.785 0.809 0.830 0.849 0.867 0.883 0.898 0.912
70 0.665 0.700 0.730 0.757 0.780 0.802 0.821 0.839 0.856 0.872
80 0.605 0.643 0.676 0.706 0.732 0.755 0.777 0.797 0.815 0.832
90 0.581 0.620 0.652 0.675 0.703 0.724 0.743 0.760 0.775 0.789
100 0.530 0.571 0.606 0.636 0.662 0.685 0.706 0.724 0.741 0.756

TABLE A.2
Liquid, ρL and Vapor Densities, ρV (g·cm–3) at Boiling
Point, TB(°C) and Saturation Pressure, PS (bar) of CO2
TB PS ρL ρV PS TB ρV ρL

–10 26.50 0.983 0.033 30 –5.57 0.082 0.960

–5 30.47 0.957 0.084 35 0.15 0.098 0.928
0 34.86 0.928 0.097 40 5.30 0.115 0.896
2 36.73 0.916 0.104 42 7.23 0.123 0.883
4 38.68 0.904 0.111 44 9.08 0.130 0.870
6 40.72 0.891 0.118 46 10.88 0.139 0.857
8 42.825 0.877 0.126 48 12.62 0.147 0.843
10 45.01 0.863 0.135 50 14.03 0.156 0.830
12 47.28 0.848 0.143 52 15.94 0.165 0.816
14 49.63 0.832 0.154 54 17.52 0.175 0.801
16 52.07 0.815 0.166 56 19.06 0.185 0.786
18 54.61 0.797 0.178 58 20.56 0.197 0.769
20 57.24 0.776 0.193 60 22.02 0.209 0.753
22 59.97 0.753 0.209 62 23.43 0.223 0.735
24 62.81 0.727 0.229 64 24.81 0.238 0.715
26 65.77 0.696 0.254 66 26.15 0.256 0.693
28 68.85 0.655 0.287 68 27.46 0.277 0.667
30 72.06 0.592 0.346 70 28.73 0.304 0.636
31.1 73.8 0.468 0.468 73.8 31.1 0.468 0.468

© 2000 by CRC Press LLC