NEET JH SIR DPP Exercise Chemical Bonding

DPP EXERCISE
NEET
INORGANIC CHEMISTRY
BY
JITENDRA HIRWANI
CHEMICAL BONDING
ETOOSINDIA
INDIA’S NO. 1 ONLINE COACHING
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar,
Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA J.H. SIR
DPP - 1
1. Which of the following species contains three bond pairs and one lone pairs around the central atom ?
(1) NH2– (2) PCl3 (3) H2O (4) BF3
Ans. (2)
2. Which one of the following pairs of chemical species contains the ions having same hybridisation of the central
atoms ?
(1) NO2– and NH2– (2) NO2– and NO3– (3) NH4+ and NO3– (4) SCN– and NH2–
Ans. (2)
3. The geometry of electron pairs around S in SF6 is
A
(1) Octahedral (2) Trigonal bipyramidal (3) Square pyramidal (4) Pentagonal planar
I
Ans. (1)
4. The correct order of increasing bond angles in the following triatomic species is
(1) NO2+ < NO2– < NO2 (2) NO2– < NO2+ < NO2 (3) NO2– < NO2 < NO2+ (4) NO2+ < NO2 < NO2–
D
Ans. (3)
5. In the hydrocarbon
N
CH 3  CH  CH  CH 2  C  CH
I
6 5 4 3 2 1
The state of hybridization of carbons 1, 3 and 5 are in the following sequence

(1) sp3, sp2, sp (2) sp2, sp, sp3 (3) sp, sp3, sp2 (4) sp, sp2, sp3
Ans.
6.
(3)
O
(1) Nitrogen atom is smaller than boron atom
S
The BCl3 is a planar molecule whereas NCl3 is pyramidal because
(2) BCl3 has no lone pair but NCl3 has a lone pair of electrons
(3) B – Cl bond is more polar than N – Cl bond
O
(4) N – Cl bond is more covalent than B–Cl bond
Ans. (2)
T
7. Which of the following bonds has the highest bond energy ?
(1) S–S (2) O–O (3) Se–Se (4) Te–Te
E
Ans. (1)
8. The low density of ice compared to water is due to
(1) Dipole induced dipole interactions
(2) Induced dipole induced dipole interactions
(3) Hydrogen bonding interactions
(4) Dipole-dipole interactions
Ans. (3)
9. d-p bond present in
(1) CO32– (2) PO43– (3) NO3– (4) NO2–
Ans. (2)
10. Which compound has planar structure ?
(1) XeF4 (2) XeOF2 (3) XeO2F2 (4) XeO4
Ans. (1)
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 2
ETOOSINDIA J.H. SIR
DPP - 2
1. Which of the following pairs are isostructural ?
(1) XeF2, IF2– (2) NH3, BF3 (3) CO32–, SO32– (4) PCl5, ICl5
Ans. (1)
2. In which of the following bond angle is maximum ?
(1) NH3 (2) NH4+ (3) PCl3 (4) SCl2
Ans. (2)
3. Main axis of a diatomic molecule is z, orbital px and py overlap with each other to form which of the following
molecular orbitals ?
(1)  molecular orbital (2)  molecular orbital
A
(3) molecular orbital (4) No bond will form
I
Ans. (4)
4. Which one of the following statement is not correct for sigma- and pi-bonds formed between two carbon atoms ?
D
(1) Sigma-bond is stronger than a pi-bond
(2) Bond energies of sigma- and pi- bonds are of the order of 264 kJ/mol and 347 kJ/mol, respectively.
(3) Free rotation of atoms about a sigma-bond is allowed but not in case of a pi- bond.
N
(4) Sigma- bond determines the direction between carbon atoms but a pi-bond has no effect in this regard.
I
Ans. (2)
5. H2O is polar, whereas BeF2 is not. It is because
S
(1) The electronegativity of F is greater than that of O
(2) H2O involves hydrogen bonding whereas BeF2 is a discrete molecule
(3) H2O is linear and BeF2 is angular
O
(4) H2O is angular and BeF2 is linear
Ans. (4)
6. In BrF3 molecule, the lone pairs occupy equatorial positions to minimize
O
(1) Lone pair-bond pair repulsion only
(2) Bond pair-bond pair repulsion only
T
(3) Lone pair-lone pair repulsion and lone pair-bond pair repulsion
(4) Lone pair-lone pair repulsion only
E
Ans. (3)
7. The correct sequence of increasing covalent character is represented by
(1) LiCl < NaCl < BeCl2 (2) BeCl2 < LiCl < NaCl
(3) NaCl < LiCl < BeCl2 (4) BeCl2 < NaCl < LiCl
Ans. (3)
8. Which of the following would have a permanent dipole moment ?
(1) SiF4 (2) SF4 (3) XeF4 (4) BF3
Ans. (2)
9. Which of the following species has a linear shape ?
(1) O3 (2) NO2– (3) SO2 (4) NO2+
Ans. (4)
10. The correct order regarding the electronegativity of hybrid orbitals of carbon is
(1) sp < sp2 < sp3 (2) sp > sp2 < sp3 (3) sp > sp2 > sp3 (4) sp < sp2 > sp3
Ans. (3)
ETOOSINDIA J.H. SIR
DPP - 3
1. In which of the following molecules all the bonds are not equal ?
(1) NF3 (2) CIF3 (3) BF3 (4) PF3
Ans. (2)
2. The correct order of C – O bond order among CO, CO32–, CO2 is
(1) CO < CO32– < CO2 (2) CO32– < CO2 < CO (3) CO < CO2 < CO32– (4) CO2 < CO32– < CO
Ans. (2)
3. In a regular octahedral molecule, MX6 the number of X – M – X bonds at 180° is
(1) Three (2) Two (3) Six (4) Four
A
Ans. (1)
I
4. The table shown below gives the bond dissociation energies (Ediss) for single covalent bonds of carbon(C) atoms
with element A, B, Z and D. Which element has the smallest atoms ?
Bond Ediss(kJ mol–1)
D
C–A 240
C–B 328
N
C –Z 276
I
C –D 485
(1) Z (2) D (3) A (4) B
Ans. (2)
5.
Ans.
6.
Which one of the following has the strongest O – O bond ?
(1) O2+
(1)
O
(2) O2
S (3) O2– (4) O22–
N2 and O2 are converted into monoanious N2– and O2– respectively, which of the following statements is wrong ?
(1) In O2– , bond length increases
O
(2) N2– becomes diamagnetic
(3) In N2–, the N–N bond weakens
T
(4) In O2–, the O–O bond order decreases
Ans. (2)
E
7. Which species does not exhibit paramagnetism ?
(1) N2+ (2) O2– (3) CO (4) NO
Ans. (3)
8. In NO3– ion number of bond pair and lone pair of electrons on nitrogen atom are
(1) 2,2 (2) 3, 1 (3) 1, 3 (4) 4, 0
Ans. (4)
9. In an octahedral structure, the pair of d orbitals involved in sp3d2 hybridisation is
(1) d x 2  y2 ,d z2 (2) d xz ,d x 2  y2 (3) d z 2 ,d xz (4) dxy, dyz
Ans. (1)
10. Which one of the following species does not exist under normal conditions ?
(1) Li2 (2) Be2+ (3) Be2 (4) B2
Ans. (3)
ETOOSINDIA J.H. SIR
DPP - 4
1. The molecular orbital shown below can be described respectively as
+
+ -
- +
(1) * (2) * (3)  (4) *

Ans. (2)
A
2. The hybrid orbital having only 20% d character
I
(1) CCl4 (2) SF6 (3) SF4 (4) Cl2O
Ans. (3)
D
3. Which of the following molecule stablizes by removal of electron ?
(1) C2 (2) O2 (3) N2 (4) H2
N
Ans. (2)
I
4. Which of the following statement is correct ?
(1) The hybridisation of Cl in ClF3 is sp2
(2) The number of lone pairs and bond pairs in I3– are 2 and 2 respectively
S
(3) The shape of XeF6 is distored square bipyramidal
(4) Hybridisation of S is sp3 in SO2
O
Ans. (3)
5. The formal charges of oxygen labelled 3, 2, 1 in ozone respectively are
O
.. 1
O
2 3
T
O O
..
..
..
.. ..
(1) –1, +1, 0 (2) 0, 0, –1 (3) –1, 0, +1 (4) 0, +1, –1
E
Ans. (3)
6. Number of nodal planes in *2px are
(1) Zero (2) One (3) Two (4) Three
Ans. (3)
7. Which of the following is not a correct statement ?
(1) Multiple bonds are always shorter than corresponding single bonds
(2) The electron-deficient molecules can act as Lewis acids
(3) The canonical structures have no real existence
(4) Every AB5 molecules does in fact have square pyramid structure
Ans. (4)
ETOOSINDIA J.H. SIR
8. Some of the properties of the two species, NO3– and H3O+ are described below. Which one of them is correct ?
(1) Dissimilar hybridization for the central atom with different structures.
(2) Isostructural with same hybridization for the central atom.
(3) Isostructural with different hybridization for the central atom.
(4) Similar hybridization for the central atom with different structures.
Ans. (1)
9. The ground state electronic configuration of valence shell electrons in nitrogen molecule (N2) is written as kk, 2s2,
 2p2y 
*2s , 2
2  , 2px . Hence the bond order in nitrogen molecule is
2.
 2p z 
A
(1) 2 (2) 3 (3) 0 (4) 1
I
Ans. (2)
10. A certain diatomic molecule, AB has dipole moment 1.6 D and the internuclear distance is 100 pm. The percentage of
D
electronic charge existing on more electronegative atom is
(1) 33% (2) 25% (3) 50% (4) 10%
Ans. (1)
I N
O S
TO
E
ETOOSINDIA J.H. SIR
DPP-5
1. Which of the following is correct for XeO2F2 and PCl5 ?
(1) Both have same hybridisation and shape
(2) Both have same hybridisation but different geometry
(3) Both have different hybridisation but same shape
(4) Both have same hybridisation but different shape
Ans. (4)
2. The maximum number of 180° angle possible between X-M-X bond for compounds with sp3d2 and sp3d hybridisation
respectively are
(1) 3, 3 (2) 3, 1 (3) 1, 3 (4) 3, 0
Ans.
3.
(2)
Which of the following is correct representation of dipole moment of NH3 molecule ?
..
I A
D
..
N N
N
(1) H H (2) H H
I
H H
µ resultant µ resultant
(3) H
O
..
N
H
µresultant
H S (4) NH3 being symmetrical will not show dipole moment
Ans.
4.
(2)
TO
Incorrect statement regarding hybridization is
(1) It is not possible for isolated atoms
E
(2) Number of hybrid orbital formed is same as the number of orbitals combining
(3) Only the half filled orbitals and fully filled orbitals can participate not the empty orbital
(4) It is not a real physical process
Ans. (3)
Cl
5. Dipole moment of is 1.1 D hence dipole moment of given compound will be
ETOOSINDIA J.H. SIR
Cl
Cl
Cl Cl
(1) 1.1 D (2) 4.4 D (3) 3.3 D (4) 2.56 D

Ans. (1)
6. In hybrid state of N atom is
I A
D
N
N
(1) sp2 (2) sp3 (3) sp3d2 (4) sp
I
Ans. (2)
7. Which molecule contains both polar and nonpolar covalent bond ?
S
(1) NH4+ (2) HCl (3) CH4 (4) H2O2
Ans. (4)
8. The shape of I3– is
O
(1) Linear (2) Bent (3) Pyramidal (4) See saw
Ans. (1)
9. Which of the following statements are correct ?
I.
O Bond order of NO is 2.5

II. Bond order of NO+ is 3.0
T
III. Bond order of O2 is 1.5
IV. Bond order of CO is 3.0
E
(1) I, II, III (2) II, III, IV (3) I, II, IV (4) II, IV
Ans. (3)
10. Arrange the following species in increasing order bond angle
NF3, NCl3, NBr3, NI3
(1) NF3 < NCl3 < NBr3 < NI3 (1) NF3 < NBr3 < NI3 < NCl3
(3) NI3 < NBr3 < NCl3 < NF3 (1) NBr3 < NI3 < NF3 < NCl3
Ans. (1)
ETOOSINDIA J.H. SIR
DPP-6
1. How many bonds are formed by each oxygen atom in ice ?
(1) 4 (2) 2 (3) 3 (4) May be 1 or 2
Ans. (1)
2. o-nitrophenol is
(1) More volatile than p-nitrophenol
(2) Less volatile than p-nitrophenol
(3) Equally volatile as p-nitrophenol
(4) Non-volatile
A
Ans. (1)
I
3. Which of the following pair consists of only paramagnetic species ?
(1) H2, O2+ (2) N2, O2 (3) Co, N2 (4) H2+, O2–
Ans. (4)
D
4. Number of angles of 109°28’ is present in CCl4
(1) 2 (2) 4 (3) 6 (4) 8
N
Ans. (3)
I
5. Number of carbon atoms present in sp2 hybrid state of given molecule ?
CH=CH CH3
Ans.
6.
(1) 9
(2)
O
(2) 8
S (3) 3 (4) 2
According to octet rule the compound which contain ionic, covalent and coordinate bonds
O
(1) CaSO4 (2) NH4Cl (3) NaNO3 (4) All of these
Ans. (4)
T
7. Which of the following molecule is having least ionic character ?
(1) FeCl2 (2) ZnCl2 (3) MgCl2 (4) NaCl
E
Ans. (2)
8. The number of antibonding electron pairs in O2–
(1) 2 (2) 3 (3) 1 (4) 4
Ans. (2)
9. In the given structure of a compound, the correct various bond moments direction involving atoms are shown as
(1) Br N CH2 SiH2 CH2 O CH3 (2) Br N CH2 SiH2 CH2 O CH3
(3) Br N CH2 SiH2 CH2 O CH3 (4) Br N CH2 SiH2 CH2 O CH3
Ans. (3)
10. In PO43– ion, the effective charge on each oxygen atom and P–O bond order respectively are
(1) –0.75, 1.25 (2) –0.75, 1.0 (3) –0.75, 0.6 (4) –3, 1.25
Ans. (1)
ETOOSINDIA J.H. SIR
DPP-7
1. Which of the following is a polar molecules ?
(1) Para dichlorobenzene
(2) carbon tetrachloride
(3) Tetrachloroethene
(4) HO OH
A
Ans. (4)
I
2. In a regular trigonal bipyramidal MX5, the number of X – M – X bonds at 180° is
(1) One (2) Two (3) Six (4) Four
D
Ans. (1)
3. Example of super octet molecule is :
(1) SF6 (2) PCl5 (3) IF7 (4) All of these
N
Ans. (4)
4.
Ans.
5.
(1) –1 and 1.67
(4)
(2) – 5/6 and 1.67
S I
The average charge on each O atom and average bond order of I–O bond in
(3) –5/6 and 1.33
IO65– is :
(4) –5/6 and 1.167
Which of the following overlaps is incorrect [assuming z-axis to be the internuclear axis] ?
O
(a) 2 py + 2 py   2 py (b) 2 pz + 2 pz   2pz
(c) 2 px + 2 px   2 px (d) 1 s + 2 py  (1 s-2 py )
(1) ‘a’ & ‘b’ (2) ‘b’ & ‘d’ (3) only ‘d’ (4) None of these
O
Ans. (3)
6. In H2SO4 molecule
T
(1) S-atom is sp3d2 hybridised and there are 4 lone pair electrons on ‘O’ atoms.
(2) S-atom is sp3 hybridised and there are no lone pair of electrons in the molecule.
(3) S-atom is sp3 hybridised and there are 8 lone pair of electrons on the ‘O’ atoms.
Ans.
7.
Ans.
8.
E
(4) S-atom is sp2 hybridised and these are 8 lone pair of electrons ‘O’ atoms
(3)
The structure of F2SeO is analogous to :
(1) SO3
(4)
(2) CIO–3 (3) XeO3
Consider the following statement and arrange in the order of true / false.
(4) (2) and (3) both
S1 : In SnCl2 the bonding takes place in ground state and the bond angle Cl–Sn–Cl is slightly less than 120º.
S2 : The molecular geometry of XeF7+ is pentagonal bipyramidal having two different Xe–F bond lengths.
S3 : In SF4 , the bond angles, instead of being 90º and 180º are 89º and 177º respectively due to the presence of a lone
pair.
(1) T T T (2) F T T (3) T T F (4) T F T
Ans. (1)
ETOOSINDIA J.H. SIR
9. All the following species have all their bond lengths identical except :
(1) AsF3 (2) AsF4– (3) AsF4+ (4) AsF6–
Ans. (2)
10. In the thiocyanate ion, SCN– three resonating structure are possible with the electron-dot method as shown in
figure
1–
: :
S=C=N
:
(x) :
The decreasing order of % contribution in resonance hybrid is :
(1) y > x > z (2) y > z > x (3) z > x > y (4) cannot predicted
Ans. (1)
I A
N D
S I
O O
E T
ETOOSINDIA J.H. SIR
DPP-8
1. Which of the following should have pyramidal shape :
(1) [ClOF2]+ (2) ICl3 (3) [BrCl]– (4) All of these
Ans. (1)
2. Arrange the following in the increasing order of deviation from normal tetrahedral angle :
(1) P4 < PH3 < H2O (2) PH3 < H2O < P4 (3) P4 <H2O < PH3 (4) H2O < PH3 < P4
Ans. (4)
3. The hybridisation of P in phosphate ion (PO43–) is the same as :
(1)  in C4– (2) S in SO3 (3) N in NO3¯ (4) S in SO32–
Ans. (4)
A
4. Choose the molecules in which hybridisation occurs in the ground state ?
I
(a) BCl3 (b) NH3 (c) PCl3 (d) BeF2
The correct answer is :
(1) a, b, d (2) a, b, c (3) b, c (4) c, d
D
Ans. (3)
5. The bent or V–shape of the molecule can be resulted from which of the following hybridization.
N
(1) sp3 (2) sp2 (3) Both (1) and (2) (4) None of these
I
Ans. (3)
6. Identify the correct statement :
(1) single N–N bond is stronger than single P – P bond
Ans.
7.
(2) single N–N bond is weaker than single P – P bond
(3) N  N is weaker than P P
O
(4) None of these
(2) S
In O2F2, which of the following statement is incorrect.
O
(1) O–F bond length in O2F2 is longer than O–Fbond length in OF2.
(2) The O.N. of oxygen in O2F2 is +1.
T
(3) The O–O bond length in O2F2 is shorter than O–O bond length in H2O2.
(4) None of these
Ans. (4)
E
8. Which of the following pairs does not contain isomorphous species :
(1) BaSO4, KMnO4 (2) KClO4, KBF4
(3) FeSO4.7H2O, MgSO4.7H2O (4) NaClO3, NaNO3
Ans. (4)
9. To which of the following species is the octet rule applicable ?
(1) BrF5 (2) SF6 (3) IF7 (4) CO2
Ans. (4)
10. Which of the following are not characteristics of metallic solids ?
(1) high electrical conductivity
(2) malleable and ductile
(3) the free electrons give them lustrous appearance
(4) electrical conductivity increases on increasing temperature
Ans. (4)
ETOOSINDIA J.H. SIR
DPP-9
1. The correct order of increasing s character (in percentage) in the hybrid orbitals in below
molecules / ions is (assume all hybrid orbitals are exactly equivalent) :
SnCl2 XeF4 3– NCl3 HgCl2 (g)
I II III IV V
(1)  <  < V <  < V (2) V <  < V < 
(3)  <  <  < V < V (4) V <  <  < V
Ans. (1)
2. Incorrect order about bond angle is :
(1) H2O > H2S > H2Se > H2Te (2) C2H2 > C2H4 > CH4 > NH3
A
(3) SF6 < NH3 < H2O < OF2 (4) ClO2 > H2O > H2S > SF6
I
Ans. (3)
3. S1 : Oxidation number of N in N2O5 is 5
S2 : The anhydride of Hypochlorous acid is Cl 2O
D
S3 : As the electronegativity of central atom in a molecule having same hybridisation state and same terminal
atoms increases, bond angle increases.
S4 : For heteronuclear diatomic species A – B, the bond length decreases as the difference in electronegativity
N
values increases.
I
(1) T T T F (2) F T T T (3) F F T F (4) T T F T
Ans. (4)
S
4. The structure of O2F2– is analogous to :
(1) SF4 (2) XeO2F2 (3) F2SeO2 (4) (1) and (2) both
Ans. (4)
O
5. Which of the following about SF4, SOF4 and OCF2 molecules is correct.
(1) Equitorial FSF bond angle in SOF4 will be greater than in SF4 molecule
(2) Hybridisation states of sulphur in SF4 and SOF4 molecules will be different.
O
(3) The bond angle FCO will be < 120° in molecule OCF2
(4) The axial FSF bond angle in SF4 is exactly 180°
T
Ans. (1)
6. For B2H6
E
S1 : Each boron is sp3 hybridised
S2 : from terminal 'H' & two 'B' atom are in same plane but two bridge hydrogen in different plane.
S3 : It has 4  bond & 2 bridge bond
S4 : 8  bonds are present in it
(1) T T F F (2) T T T F (3) F F T F (4) F T F T
Ans. (2)
7. Identify the species containing Banana bonds
(1) (BeH2)n (2) BF3 (3) (AlCl3)2 (4) (BeCl2)n
Ans. (1)
ETOOSINDIA J.H. SIR
8. Which is not true about B2H6

(1) Both ‘B’ atoms are sp 3 hybridised
(2) Boron atom is in ground state
(3) Two hydrogens occupy special positions
(4) There are two, three centre two electron bonds
Ans. (2)
9. Which of the following compounds has coordinate (dative) bond
(1) CH3NC (2) CH3OH (3) CH3Cl (4) NH3
Ans. (1)
10. Which of the following statements regarding the structure of SOCl2 is not correct ?
A
(1) The sulphur is sp3 hybridised and it has a tetrahedral shape.
I
(2) The sulphur is sp3 hybridised and it has a trigonal pyramid shape.
(3) The oxygen -sulphur bond is p - d bond.
(4) It contain one lone pair of electrons in the sp3 hybrid orbital of sulphur.
Ans. (1)
N D
S I
O O
E T
ETOOSINDIA J.H. SIR
DPP-10
1. For BF3 molecule which of the following is true ?
(1) B-atom is sp2 hybridised.
(2) There is a P – P back bonding in this molecule.
(3) Observed B–F bond length is found to be less than the expected bond length.
(4) All of these
Ans. (4)
2. If Z-axis is the molecular axis, then -molecular orbitals are formed by the overlap of
(1) s + pz (2) px + py (3) pz + pz (4) px + px
Ans. (4)
A
3. Which of the following molecular orbitals has two nodal planes
I
(1)  2s (2)  2p y (3)  * 2p y (4) * 2p x
Ans. (3)
D
4. During the formation of a molecular orbital from atomic orbitals of the same atom, probability of electron density is
(1) none zero in the nodal plane (2) maximum in the nodal plane
(3) zero in the nodal plane (4) zero on the surface of the lobe
N
Ans. (3)
I
5. Which of the following statements is incorrect ?
(1) Among O2+, O2 and O2- the stability decreases as O2+ > O2 > O2-
(2) He2 molecule does not exist as the effect of bonding and anti-bonding orbitals cancel each other .
S
(3) C2 ,O22 - and Li2 are diamagnetic
(4) In F2 molecule, the energy of  2p z is more than 2p x and 2p y
O
Ans. (4)
6. Which of the following orders is correct in respect of bond dissociation energy ?
(1) N2+ > N2– (2) O2+ > O3 (3) NO+ > NO (4) All of those
O
Ans. (4)
7. S1  The HOMO in F2– is 2px = 2py molecular orbitals.
T
S2  Bond order of O2– is more then O2+ .
S3  NO+ is more stable than N2+
S4  C2 is more stable than C2+
Ans.
8.
Ans.
9.
E
State, in order, whether S1, S2, S3, S4 are true or false
(1) FFFT
(4)
(1) N2O3
(3)
(2) FTTT
(2) N2O22–
(3) FTFT
Which of the following species does not contain N – N covalent bond ?

(3) N2O5
Which statement is incorrect about pyrosilicate ion.

(4) N2O4
(4) FFTT
(1) sp3 hybridisation (2) One oxygen atom is shared between two tetrahydron
(3) there are eight Si–O bond (4) There is one Si-Si bond
Ans. (4)
10. The specie which does not contain an odd number of valence electrons and is diamagnetic:
(1) NO (2) NO2 (3) ClO2 (4) N2O4
Ans. (4)
ETOOSINDIA J.H. SIR
DPP-11
1. Which is correct about the cyclic silicate [Si6O18]n– :
(1) The value of n is 12
(2) each Si atom is bonded with three oxygen atoms
(3) each oxygen atom is bonded with two Si atoms
(4) all the above are correct.
Ans. (1)
2. Which of the following species do not contain S–S linkage?
(1) H2S2O5 (2) H2S2O7 (3) H2S2O3 (4) H2S4O6
Ans. (4)
A
3. Number of antibonding electrons in N2 is :
I
(1) 4 (2) 10 (3) 12 (4) 14
Ans. (1)
4. Consider the following statements.
D
S1 : Fluorine does not form any polyhalide because it does not have d-orbitals in valence shell.
S2 : In ClF3 , the three lone pairs of electrons occupy the equatorial position.
N
S3 : In B2 and N2 molecules mixing of s- and p- atomic orbitals takes place.
I
Of these statements :
(1) S1 , S2 and S3 are correct (2) S1 and S2 are correct
(3) S1 and S3 are correct (4) S2 and S3 are correct
Ans.
5.
(3)
O
(1) Tetrahedral hybridisation
S
In which of the following molecules/species all following characteristics are found ?
(2) Hybridisation can be considered to have taken place with the help of empty orbital(s).
(3) All bond lengths are identical i.e. all A – B bond lengths are identical.
O
(1) B2H6 (2) Al2Cl6 (3) BeCl2 (4) BF4–
Ans. (4)
T
6. Which of the following statement is false for trisilylamine ?
(1) Three sp2 orbitals are used for  bonding, giving a plane triangular structure.
(2) The lone pair of electrons occupy a p-orbital at right angles to the plane triangle and this overlaps with empty p–
E
orbitals on each of the three silicon atoms resulting in  bonding.
(3) The N–Si bond length is shorter than the expected N–Si bond length.
(4) It is a weaker Lewis base than trimethyl amine.
Ans. (2)
7. Gaseous SO3 molecule
(1) is planar triangular in shape with three -bonds from sp2 – p overlap and three -bonds formed by one p – p
overlap and two p – d overlap.
(2) is a pyramidal molecule with one double bond and two single bonds
(3) planar triangular in shape with two double bonds between S and O and one single bond
(4) is planar triangular in shape with three  bonds from sp2 – p overlap and three -bonds formed by two p – p
overlap and one p – d overlap.
Ans. (1)
ETOOSINDIA J.H. SIR
8. According to Molecular orbital theory which of the following is correct ?

(1) LUMO level for C2 molecule is  2p x orbital (2) In C2 molecules both the bonds are  bonds
(3) In C22– ion there is one  and two  bonds (4) All the above are correct
Ans. (4)
9. The correct order in which the O - O bond length increases in the following is :
(1) H2O2 < O2 < O3 (2) O2 < H2O2 < O3 (3) O2 < O3 < H2O2 (4) O3 < H2O2 < O2
Ans. (3)
10. Which of the following is a wrong order with respect to the property mentioned against each ?
(1) O22– > O2 > O2+ [Paramagnetic moment] (2) (NO)¯ > (NO) > (NO)+ [bond length]
(3) H2 > H2+ > He2+ [bond energy] (4) NO2+ > NO2 > NO2¯ [bond angle]
A
Ans. (1)
D I
I N
O S
TO
E
ETOOSINDIA J.H. SIR
DPP-12
1. Two types of carbon-carbon covalent bond lengths are present in
(1) diamond (2) graphite (3) C60 (4) benzene
Ans. (3)
2. In which of the following species peroxide group is not present :
(1) [B4O5(OH)4]2– (2) [S2O8]2– (3) CrO5 (4) HNO4
Ans. (1)
3. Which of the following is correct ?
(1) S3O9 – contains no S–S linkage. (2) S2O62– – contains –O–O– linkage.
(3) (HPO3)3 – contains P – P linkage (4) S2O82– contains S–S linkage
4. The percentage of s–character in the orbital forming P – S bonds in P4S3 is :
A
(1) 25 (2) 33 (3) 75 (4) 50
I
Ans. (1)
5. Consider the following statements ;
(I) The hybridisation found in cation of solid PCl5 is sp3.
D
(II) In AB2L2 type the BAB bond angle is always greater than the normal tetrahedral bond angle.
(III) In ClO3–, NH3 and XeO3, the hybridisation and the number of lone pairs on the central atoms are same.
(IV) In P4 molecule, there are six P – P bonds and four lone pairs of electrons.
N
of these statements :
I
(1) I, II and III are correct only (2) I, III and IV are correct only
(3) III and IV are correct only (4) All are correct
S
Ans. (2)
6. In the coordinate valency
(1) Electrons are equally shared by the atoms (2) Electrons of one atom are shared with two atoms
O
(3) Hydrogen bond is formed (4) None of the above
Ans. (4)
7. What is the nature of the bond between B and O in (C2H5 )2 OBH3
O
(1) Covalent (2) Co-ordinate covalent (3) Ionic bond (4) Banana shaped bond
Ans. (2)
T
8. Which of the following statements is correct ?
(1) N2F3+ is planar at each nitrogen atom. (2) In N3H, the H – N – N bond angle is exactly of 120°.
(3) The shape of N(SiMe3)3, is trigonal planar. (4) (1) and (3) both.
E
Ans. (4)
9. Which of the following statement is correct for the 1 : 1 complex of trimethyl amine and boron tri fluoride ?
(1) The B - F bond length in the complex is longer than that of in BF3.
(2) The N is pyramidal with sp3 hybridisation and B is planar with sp2 hybridisation.
(3) The coordination geometry of N and B both are tetrahedral with sp3 hybridisation each.
(4) (1) and (3) both.
Ans. (4)
10. The molecular orbital configuration of a diatomic molecule is
  2p2y
 1s 2 * 1s 2  2s 2 * 2s 2  2p 2x 
  2pz
2
Its bond order is

(1) 3 (2) 2.5 (3) 2 (4) 1
Ans. (1)
ETOOSINDIA J.H. SIR
DPP-13
1. The bond order of He 2 molecule ion is :
1 1
(1) 1 (2) 2 (3) (4)
2 4
Ans. (3)
2. Pick out the incorrect statement.
(1) N2 has greater dissociation energy than N2+ (2) O2 has lower dissociation energy than O2+
(3) Bond length in N2+ is less than N2 (4) Bond length in NO+ is less than in NO.
Ans. (3)
3. Which of the following is incorrect ?
A
(1) The O – O bond length in H2O2 is larger than that in O2F2.
I
(2) The O – O bond length in H2O2 is very slightly smaller than in O22– ion.
(3) O2– and O2+ species are paramagnetic and have same number of unpaired electrons.
(4) None
D
Ans. (4)
4. In a P4O6 molecule, the total number of P–O–P bonds is
N
(1) 4 (2) 6 (3) 2 (4) 3
I
Ans. (2)
5. The point of dissimilarity between (SO3)3 and (HPO3) (cyclic trimers) is.
(1) Both have six membered ring. (2) Both contain central atom in same hybridization
S
(3) Both contain planar ring. (4) Both are isoelectronic.
Ans. (3)
6. Which of the following statements is / are correct ?
O
(1) Hybridisation of carbon in C3O2 is sp2.
(2) In Cr2O72 –, six Cr – O bonds are identical.
(3) Three centre two electron bonds exist in B2H6 and Al2Cl6 .
O
(4) In AgI, the colour is attributed to charge transfer spectrum.
Ans. (2)
T
7. Which of the following is correct :
(1) N–O bond length in NO gaseous molecule will be greater than in NOCl gaseous molecule.
(2) Carbon-carbon bond length in CaC2 will be more than in C2H4
E
(3) O–O bond length in KO2 will be more than in Na2 O2 .
(4) All the four hydrogen atoms in CH4 are not coplanar
Ans. (4)
8. Which one of the following oxides is expected exhibit paramagnetic behaviour
(1) CO2 (2) SO2 (3) ClO2 (4) SiO2
Ans. (3)
9. Consider the following statements
1. Steric number ‘7’ gives ‘sp3d3 hybridisation.
2. In CF3 at least one bond angle is exactly 180°
3. Lone pair does not cause any distortion in the bond angle.
The above statements 1, 2, 3 respectively are (T = True, F = False)
(1) T F F (2) T T F (3) F T F (4) T T T
Ans. (1)
10. The number of  and  bonds in dicyanogen (CN) 2 are :
(1) 2 + 3 (2) 3 + 2 (3) 3 + 4 (4) 4 + 3
Ans. (3)

NEET JH SIR DPP Exercise Chemical Bonding

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NEET JH SIR DPP Exercise Chemical Bonding

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DPP EXERCISE

The state of hybridization of carbons 1, 3 and 5 are in the following sequence

S (3) O2– (4) O22–

(1) d x 2  y2 ,d z2 (2) d xz ,d x 2  y2 (3) d z 2 ,d xz (4) dxy, dyz

(1) * (2) * (3)  (4) *

(1) –1, +1, 0 (2) 0, 0, –1 (3) –1, 0, +1 (4) 0, +1, –1

5. Dipole moment of is 1.1 D hence dipole moment of given compound will be

(1) 1.1 D (2) 4.4 D (3) 3.3 D (4) 2.56 D

6. In hybrid state of N atom is

O Bond order of NO is 2.5

8. Which is not true about B2H6

(4) In F2 molecule, the energy of  2p z is more than 2p x and 2p y

Which of the following species does not contain N – N covalent bond ?

Which statement is incorrect about pyrosilicate ion.

8. According to Molecular orbital theory which of the following is correct ?

Its bond order is

1. The bond order of He 2 molecule ion is :

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