Topper's Choice - Prof.

Pawan Babel CHEMISTRY (PAPER – I)

SOLUTION

21. (B)
0.6 mole of Cl ions  0.3 mole of MgCl2
0.2 mole of SO 24 ions  0.2 mole of MgSO 4
No. of moles of Mg 2  0.3  0.2  0.5

22. (C)
wt. of NaOH
% purity   100
wt. of sample
3  40
  100  12%
1000

23. (C)
Wt. of C2 H 5 OH needed  1.2  46 gm
1.2  46
Volume of C2 H 5 OH needed  ml
0.7893
 70 ml

24. (C)
wt. of C8 H18 taken  0.8  1425 gm
0.8  1425
no. of moles of C8 H18 taken   10
114
25
C8 H8  O 2  8CO 2  9H 2 O
2
25
No. of moles of O2 required  10   125
2

25. (A)
FeO & Fe 2 O3
x gm y gm
16 48
Wt. of oxygen  x y  2.5
72 160
56 112
Wt. of Iron  x y7
72 160
On solving x  4.5 & y  5
x : y  4.5 : 5
 9 :10

26. (B)
o
 x  1A

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m y  0.25 m x
 y  0.75  c
h h
y  
m y y  0.25 m x  0.75 x 
1
  x
0.25  0.75
16 o
 y   1  5.3 A
3

27. (C)
n 2 can’t be greater than 4
1 1 1 1 1 5
 R 2  2 R    R
 2 3   4 9  36
1 1 1  1 1  3R
 R 2  2R  
 2 4   4 16  16

28. (D)
Probability of d x2  y2 is maximum along x & y axis.
x  a, y  a, z  0 us xy plane hence probability = 0

29. (C)
For same orbit, s is closer to nucleus.

30. (C)
PX , PY , PZ have same  value but different m values.

31. (A)
C H N O
% 70.8 6.2 4.1 18.9
70.8 6.2 4.1 18.9
Relative no. of mole  5.9  6.2  0.293  1.18
12 1 14 16
Simple ratio 20 21 1 4
Empirical formula  C20 H 21 NO 4

32. (AB)
If wt. of solution  100 gm
Then wt. of CH 3COOH  10 gm
10
Mole fraction of CH 3COOH  60
10 90

60 18

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1
6 1
 
1 31
5
6
10  1000
Molality   1.85 mol kg
60  90
10
ppm concentration   106
100
 105

33. (ABCD)
Assuming molarity & molality sample
In all cases molarity remains less than 4.
M V  M 2 V2
M 1 1
V1  V2

34. (BCD)
NaNO 2  NH 4 Cl  NH 4 NO 2  NaCl
Initial 0.5 1 0 0
Final 0 1 – 0.5 = 0.5 0.5 0.5

NH 4 NO 2   N 2  2H 2 O
Initial 0.5 0 0
Final 0 0.5 1
1
  22.4 L  11.2 L
2
1
  28 gm  14 gm
2

35. (BC)
CaSO3  H 2O  SO 2  Ca  HSO3  2
12
No. of moles of CaSO3   0.1 mole
120
No. of moles of SO 2 required  0.1 mole
Wt. of SO 2 required  0.1 64 gm
 6.4 gm

36. (BD)
E 2  E1  10.2 eV
E3  E 2  1.89 eV

37. (AD)
No. of radial nodes in 3s  3  0  1  2

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No. of radial nodes in 4d 2z  4  2  1  1

No. of radial nodes in 4d xy  4  2  1  1
No. of radial nodes in 4p x  4  1  1  2

38. (ABC)
n  4, m  2
 can’t be 0 & 1
  2, 3
1 1
But s can be  &
2 2

39. (AC)
(C) 2Px and 2Pz are degenerate orbitals
(D) For hydrogen & hydrogen like species energy of electron is determined by n only.
Hence 3s and 3p are degenerate orbitals.

40. (BC)
According to selection rule, for transition   1
i.e., np  ns & nd  np are possible.

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SOLUTION

21. (D)
12
Wt. of Carbon   5.28 gm
44
12 5.28 5.28
No. of moles of C     0.12
44 12 44
2
Wt. of Hydrogen  1.08  gm
18
2 1
No. of moles of H  1.08    0.12
18 1
C : H  1:1
Empirical formula  CH

22. (D)
12x  6y  2z
4
xyz
12x  6y  2z  4x  4y  4z
8x  2y  2z
x : y : z ratio can be 1:1: 5, 1: 2 : 6 or 2 :1: 9

23. (D)
Assume wt. of solution = 100 gm
Than wt. of HClO4  70gm
100
Volume of solution  ml
1.664
70  1000
Molarity   11.6 M
100
100.5 
1.664

24. (B)
N 2  3H 2  2NH3
Initial 1 4 0
Final 1 – x 4 – 3x 2x
Since 1 mole of HCl is required for aqueous solution, NH 3 formed should be 1 mole as
NH3  HCl  NH 4Cl
1
2x  1  x 
2
1 1
No. of moles of N 2 left  1  
2 2
5
5
Mole fraction of H 2  2 
1 5 6

2 2

25. (D)
C3 H 8  g   5O 2  g   3CO 2  g   4H 2 O   
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If no. of moles of CO2 formed is 0.1

4 4
Then no. of moles of H 2O formed  0.1  0.
3 3
0.4
No. of water molecules   6.02 1023
3
0.4  6.02 1023
No. of drops   47.2
3 1.7 1021

26. (A)
1  1 1  8R
R  
4  4 36  36
36
4 
8R
1  1 1  45R
R  
5  4 49  4  49
4  49
5 
45R
36 4  49 o
 4  5    131A
8R 45R

27. (A)
n 1
  11  0
1 1
j 0  
2 2
1 1
m ,
2 2

28. (D)
4s 3d
Mn   Ar 

29. (D)
Ni 2    Ar 
1
Total spin  S   2  1
2

30. (C)
3d 4s
Ti   Ar 
3
Paramagnetic
3d 4s
Fe   Ar 
2
Paramagnetic
3d 4s
Zn   Ar  Paramagnetic

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3d 4s
Fe   Ar 
3
Paramagnetic

31. (3)
3d
V 2
  Ar 
Unpaired electrons  3

32. (6)
Outermost electron has n  4 &   0 for s & d block elements of 4th period.
i.e. 12 elements.

33. (0)
Xe  1s 2 2s2 2p6 3s 2 3p 6 4s2 3d10 4p6 5s 2 4d10 5p6
n  4 &   3 for up orbital. No electron present in up orbital.

34. (6)
Outermost electron quantum no. n  4 &   1
i.e. outermost electron in up orbital.
Hence p block elements of 4th periods.

35. (4)
If electron is ionized by 1 eV then
22
E  1 eV or 13.6  2  1 
n
1
13.6  2  1
n
2
n  13.6
n  13.6
n  3.6

36. (4)
no. of atoms  56
0.33  100
68000
0.33  680
No. of atoms  4
56

37. (1)
18x
13  100
24  32  64  18x
x 1

38. (5)
If wt. of solution initially = 100 gm
If wt. of sucrose = 40 gm
If wt. of water initially = 60 gm
On heating wt. of water decreases.
If wt. of solution finally = x gm
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40
Then, 100  50
x
x  80 gm
Wt. lost  100  80  20 gm
4x  20  x  5

39. (8)
Wt. of solution = 314 gm
Wt. of CH3OH  64 gm
Wt. of solvent = 314 – 64 = 250 gm
64 1000
Molality   8m
32  250

40. (6)
7XeF6  3I2  6IF7  3Xe
n XeF6 7

n IF7 6
21 7

3x 6
x6

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