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● Scientific Method: Several interrelated steps are involved in the scientific method.
Some of the most significant steps are as follows:
✓ The systematic observations
✓ Reasoning
✓ Mathematical prediction
✓ Theoretical prediction
● Scope and Excitement of Physics: The scope of Physics is very broad and covers a
wide range of magnitude of physical quantities such as length, mass, time, energy,
etc. It deals with the macroscopic world l galaxies and universe as well as
microscopic world like nucleus of an atom and fundamental particles like electrons,
protons, neutrons etc. Immense excitement is involved in the study of physics since
it explains every naturally occurring phenomena with a set of rules, so that clear
understanding can be achieved. The challenge to carry out imaginative new
experiments to unlock the secrets of nature, to verify or refute theories, is really
exciting.
● There are four fundamental forces in nature that govern the diverse phenomena of
the microscopic and macroscopic world. These are the ‘gravitational force’, the
‘electromagnetic force’, the ‘strong nuclear force’, and the ‘weak nuclear force’.
Unification of forces is a basic quest in physics. The electromagnetic and the weak
nuclear forces have now been unified and are seen as aspects of a single ‘electro-
weak’ force. Attempts are being made to unify electro-weak and the strong force.
● Unit: The unit of a physical quantity is an arbitrarily chosen standard which is widely
accepted by the society and in terms of which other quantities of similar nature may
be measured.
✓ To express any measurement made we need the numerical value (n) and the
unit (μ). Measurement of physical quantity = Numerical value x Unit
For example: Length of a rod = 8 m
where 8 is a numerical value and m (metre) is unit of length.
● Derived Physical Quantity/Units: All those physical quantities, which can be derived
from the combination of two or more fundamental quantities or can be expressed in
terms of basic physical quantities, are called derived physical quantities.
✓ The units of all other physical quantities, which car. be obtained from
fundamental units, are called derived units. For example, units of velocity,
density and force are m/s, kg/m3, kg m/s2 respectively and they are examples
of derived units.
● Systems of Units: Earlier three different units systems were used in different
countries. These were CGS, FPS and MKS systems. Now-a-days internationally SI
system of units is followed. In SI unit system, seven quantities are taken as the base
quantities.
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✓ CGS System. Centimetre, Gram and Second are used to express length, mass
and time respectively.
✓ FPS System. Foot, pound and second are used to express length, mass and
time respectively.
✓ MKS System. Length is expressed in metre, mass is expressed in kilogram and
time is expressed in second. Metre, kilogram and second are used to express
length, mass and time respectively.
✓ SI Units. Length, mass, time, electric current, thermodynamic temperature,
Amount of substance and luminous intensity are expressed in metre,
kilogram, second, ampere, kelvin, mole and candela respectively.
● Advantages of SI Unit System: SI Unit System has following advantages over the
other Besides the above mentioned seven units, there are two supplementary base
units. These are systems of units:
✓ It is internationally accepted,
✓ It is a rational unit system,
✓ It is a coherent unit system,
✓ It is a metric system,
✓ It is closely related to CGS and MKS systems of units,
✓ Uses decimal system, hence is more user friendly
● Other Important Units of Length: For measuring large distances e.g., distances of
planets and stars etc., some bigger units of length such as astronomical unit, light
year, parsec etc. are used.
✓ The average separation between the Earth and the sun is called one
astronomical unit.
✓ 1 AU = 1.496 x 1011 m.
✓ The distance travelled by light in vacuum in one year is called light year.
✓ 1 light year = 9.46 x 1015 m.
✓ The distance at which an arc of length of one astronomical unit subtends an
angle of one second at a point is called parsec.
✓ 1 parsec = 3.08 x 1016 m
✓ Size of a tiny nucleus = 1 fermi = If = 10-15 m
✓ Size of a tiny atom = 1 angstrom = 1A = 10-10 m
● Parallax Method: This method is used to measure the distance of planets and stars
from earth.
✓ Parallax. Hold a pen in front of your eyes and look at the pen by closing the
right eye and then the left eye. What do you observe? The position of the
pen changes with respect to the background. This relative shift in the position
of the pen (object) w.r.t. background is called parallax.
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● Estimation of Molecular Size of Oleic Acid: For this 1 cm3 of oleic acid is dissolved in
alcohol to make a solution of 20 cm3. Then 1 cm3 of this solution is taken and diluted
to 20 cm3, using alcohol. So, the concentration of the solution is as follows:
✓ After that some lycopodium powder is lightly sprinkled on the surface of
water in a large trough and one drop of this solution is put in water. The oleic
acid drop spreads into a thin, large and roughly circular film of molecular
thickness on water surface. Then, the diameter of the thin film is quickly
measured to get its area A. Suppose n drops were put in the water. Initially,
the approximate volume of each drop is determined (V cm3).
Volume of n drops of solution = nV cm3
The solution of oleic acid spreads very fast on the surface of water and forms
a very thin layer of thickness t. If this spreads to form a film of area A cm 2, If
we assume that the film has mono-molecular thickness, this becomes the size
or diameter of a molecule of oleic acid. The value of this thickness comes out
to be of the order of 10-9 m.
● Dimensions: The dimensions of a physical quantity are the powers to which the
fundamental units of mass, length and time must be raised to represent the given
physical quantity.
■ For a number greater than 1, without any decimal, the trailing zeroes
are not significant.
■ For a number with a decimal, the trailing zeros are significant.
● Error: The measured value of the physical quantity is usually different from its true
value. The result of every measurement by any measuring instrument is an
approximate number, which contains some uncertainty. This uncertainty is called
error. Every calculated quantity, which is based on measured values, also has an
error.
● Point Object: If the length covered by the objects are very large in comparison to the
size of the objects, the objects are considered point objects.
● Total Path Length (Distance): For a particle in motion the total length of the actual
path traversed between initial and final positions of the particle is known as the
‘total path length’ or distance covered by it.
● Average Speed and Average Velocity: Average Speed. It is the ratio of total path
length traversed and the corresponding time interval.
● Unit Vector: A unit vector is a vector of unit magnitude and points in a particular
direction. It is used to specify the direction only. Unit vector is represented by
putting a cap (^) over the quantity.
● Coplanar Vectors: Vectors are said to be coplanar if they lie in the same plane or
they are parallel to the same plane, otherwise they are said to be non-coplanar
vectors.
● Displacement Vector: The displacement vector is a vector which gives the position of
a point with reference to a point other than the origin of the coordinate system.
● Triangle Law of Vector Addition: If two vectors are represented both in magnitude
and direction by the two sides of a triangle taken in the same order, then the
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● Lami’s Theorem: Lami’s theorem states, “If a particle under the simultaneous action
of three forces is in equilibrium, then each force has a constant ratio with the sine of
the angle between the other two forces”.
● Projectile Motion: The projectile is a general name given to an object that is given an
initial inclined velocity and which subsequently follows a path determined by the
gravitational force acting on it and by the frictional resistance of the air. The path
followed by a projectile is called its trajectory.
● Uniform Circular Motion: When a body moves in a circular path with a constant
speed, then the motion of the body is known as uniform circular motion.
✓ The time taken by the object to complete one revolution on its circular path
is called time period.
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● Dynamics: is the branch of physics in which we study the motion of a body by taking
into consideration the cause i.e., force which produces the motion.
● Force: Force is an external cause in the form of push or pull, which produces or tries
to produce motion in a body at rest, or stops/tries to stop a moving body or
changes/tries to change the direction of motion of the body.
✓ The inherent property, with which a body resists any change in its state of
motion is called inertia. Heavier the body, the inertia is more and lighter the
body, lesser the inertia.
● Law of inertia: states that a body has the inability to change its state of rest or
uniform motion (i.e., a motion with constant velocity) or direction of motion by
itself.
● Linear Momentum: The linear momentum of a body is defined as the product of the
mass of the body and its velocity.
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● Impulse: Forces acting for short duration are called impulsive forces. Impulse is
defined as the product of force and the small time interval for which it acts.
✓ Impulse of a force is a vector quantity and its SI unit is 1 Nm.
✓ If force of an impulse is changing with time, then the impulse is measured by
finding the area bound by force-time graph for that force.
✓ Impulse of a force for a given time is equal to the total change in momentum
of the body during the given time. Thus, we have
● Friction: The opposition to any relative motion between two surfaces in contact is
referred to as friction. It arises because of the ‘inter meshing’ of the surface
irregularities of the two surfaces in contact.
● Static and Dynamic (Kinetic) Friction: The frictional forces between two surfaces in
contact (i) before and (ii) after a relative motion between them has started, are
referred to as static and dynamic friction respectively. Static friction is always a little
more than dynamic friction.
The magnitude of kinetic frictional force is also proportional to normal force.
● Limiting Frictional Force: This frictional force acts when body is about to move. This
is the maximum frictional force that can exist at the contact surface. We calculate its
value using laws of friction.
● Laws of Friction:
✓ The magnitude of limiting frictional force is proportional to the normal force
at the contact surface.
✓ The magnitude of limiting frictional force is independent of area of contact
between the surfaces.
● Coefficient of Friction: The coefficient of friction (μ) between two surfaces is the
ratio of their limiting frictional force to the normal force between them.
● Angle of Friction: It is the angle which the resultant of the force of limiting friction F
and the normal reaction R makes with the direction of the normal reaction.
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● Angle of Repose: Angle of repose (α) is the angle of an inclined plane with the
horizontal at which a body placed over it just begins to slide down without any
acceleration. Angle of repose is given by α = tan-1 (μ)
● Motion on a Rough Inclined Plane: Suppose a motion up the plane takes place
under the action of pull P acting parallel to the plane.
● Centripetal Force: Centripetal force is the force required to move a body uniformly
in a circle.
● Centrifugal Force: Centrifugal force is a force that arises when a body is moving
actually along a circular path, by virtue of tendency of the body to regain its natural
straight line path.
The magnitude of centrifugal force is same as that of centripetal force.
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● Work is said to be done when a force applied on the body displaces the body
through a certain distance in the direction of applied force.
It is measured by the product of the force and the distance moved in the direction of
the force, i.e., W = F-S
● If an object undergoes a displacement ‘S’ along a straight line while acted on a force
F that makes an angle 0 with S then,
The work done W by the agent is the product of the component of force in the
direction of displacement and the magnitude of displacement.
● If we plot a graph between force applied and the displacement, then work done can
be obtained by finding the area under the F-s graph.
● Energy: The energy of a body is its capacity to do work. Anything which is able to do
work is said to possess energy. Energy is measured in the same unit as that of work,
namely, Joule.
● Kinetic Energy:: The energy possessed by a body by virtue of its motion is known as
its kinetic energy.
For an object of mass m and having a velocity v, the kinetic energy is given by:
K.E. or K = 1/2 mv2
● Equivalence of Mass and Energy: According to Einstein, mass and energy are
interconvertible. That is, mass can be converted into energy and energy can be
converted into mass.
● Collision between particles have been divided broadly into two types.
(i) Elastic collisions (ii) Inelastic collisions
✓ Elastic Collision: A collision between two particles or bodies is said to be
elastic if both the linear momentum and the kinetic energy of the system
remain conserved.
■ Example: Collisions between atomic particles, atoms, marble balls and
billiard balls.
■ Example: When we drop a ball of wet putty on to the floor then the
collision between ball and floor is an inelastic collision.
● Collision is said to be one dimensional, if the colliding particles, move along the
same straight line path both before as well as after the collision.
✓ In one dimensional elastic collision, the relative velocity of approach before
collision is equal to. the relative velocity of separation after collision.
● A rigid body is a body with a perfectly definite and unchanging shape. The distances
between all pairs of particles of such a body do not change.
● Centre of Mass: For a system of particles, the centre of mass is defined as that point
where the entire mass of the system is imagined to be concentrated, for
consideration of its translational motion.If all the external forces acting on the
body/system of bodies were to be applied at the centre of mass, the state of rest/
motion of the body/system of bodies shall remain unaffected.
● The centre of mass of a body or a system is its balancing point. The centre of mass of
a two- particle system always lies on the line joining the two particles and is
somewhere in between the particles.
● Torque: Torque is the moment of force. Torque acting on a particle is defined as the
product of the magnitude of the force acting on the particle and the perpendicular
distance of the application of force from the axis of rotation of the particle.
● Axis of Rotation: A rigid body is said to be rotating if every point mass that makes it
up, describes a circular path of a different radius but the same angular speed. The
circular paths of all the point masses have a common centre. A line passing through
this common centre is the axis of rotation.
✓ A rigid body is said to be in equilibrium if under the action of forces/torques,
the body remains in its position of rest or of uniform motion.
✓ For translational equilibrium, the vector sum of all the forces acting on a body
must be zero. For rotational equilibrium, the vector sum of torques of all the
forces acting on that body about the reference point must be zero. For
complete equilibrium, both these conditions must be fulfilled.
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● Couple: Two equal and opposite forces acting on a body but having different lines of
action, form a couple. The net force due to a couple is zero, but they exert a torque
and produce rotational motion.
● Moment of Inertia: The rotational inertia of a rigid body is referred to as its moment
of inertia. The moment of inertia of a body about an axis is defined as the sum of the
products of the masses of the particles constituting the body and the square of their
respective perpendicular distance from the axis.
● Radius of Gyration: The distance of a point in a body from the axis of rotation, at
which if whole of the mass of the body were supposed to be concentrated, its
moment of inertia about the axis of rotation would be the same as that determined
by the actual distribution of mass of the body is called radius of gyration.
✓ If we consider that the whole mass of the body is concentrated at a distance
K from the axis of rotation, then moment of inertia I can be expressed as I =
MK2
● Rolling Motion: The combination of rotational motion and the translational motion
of a rigid body is known as rolling motion.
Chapter 8: Gravitation.
● Kepler’s Laws of Planetary Motion: Johannes Kepler formulated three laws which
describe planetary motion. They are as follows:
✓ Law of orbits. Each planet revolves around the sun in an elliptical orbit with
the sun at one of the foci of the ellipse.
✓ Law of areas. The speed of planet varies in such a way that the radius, vector
drawn from the sun to planet sweeps out equal areas in equal times.
● Newton’s Law of Gravitation: Newton’s law of gravitation states that every particle
in the universe attracts every other particle with a force directly proportional to the
product of their masses and inversely proportional to the square of the distance
between them. The direction of the force is along the line joining the particles.
● Mass and Mean Density of Earth: Mass and Mean density of Earth is given in the
following manner.
● Gravitational Field: The space around a body within which its gravitational force of
attraction is experienced by other bodies is called gravitational field.
● Gravitational Potential Energy: The work done in carrying a mass ‘m’ from infinity to
a point at distance r is called gravitational potential energy. Gravitational potential
energy = gravitational potential x mass of the body.
It is a scalar quantity and measured in joule.
● Escape Velocity: The minimum velocity required to project a body vertically upward
from the surface of earth so that it comes out of the gravitational field of earth is
called escape velocity.
● Geostationary Satellite: The satellite having the same time period of revolution as
that of the earth is called geostationary satellite. Such satellites should rotate in the
equatorial plane from west to east. The orbit of a geostationary satellite is called
‘parking orbit’. These satellites are used for communication purposes.
A geostationary satellite revolves around the earth in a circular orbit at a height of
about 36,000 km from the surface of earth.
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● Intermolecular Force: In a solid, atoms and molecules are arranged in such a way
that each molecule is acted upon by the forces due to the neighbouring molecules.
These forces are known as intermolecular forces.
● Elasticity: The property of the body to regain its original configuration (length,
volume or shape) when the deforming forces are removed, is called elasticity.
The change in the shape or size of a body when external forces act on it is
determined by the forces between its atoms or molecules. These short range atomic
forces are called elastic forces.
● Perfectly elastic body: A body which regains its original configuration immediately
and completely after the removal of deforming force from it, is called perfectly
elastic body. Quartz and phosphor bronze are the examples of nearly perfectly
elastic bodies.
● Plasticity: The inability of a body to return to its original size and shape even on
removal of the deforming force is called plasticity and such a body is called a plastic
body.
● Stress: Stress is defined as the ratio of the internal force F, produced when the
substance is deformed, to the area A over which this force acts. In equilibrium, this
force is equal in magnitude to the externally applied force.
● Strain: It is defined as the ratio of the change in size or shape to the original size or
shape. It has no dimensions, it is just a number.
✓ Strain is of three types:
■ Longitudinal strain: If the deforming force produces a change in
length alone, the strain produced in the body is called longitudinal
strain or tensile strain.
■ Volumetric strain: If the deforming force produces a change in
volume alone, the strain produced in the body is called volumetric
strain.
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■ Shear strain: The angle tilt caused in the body due to tangential stress
expressed is called shear strain.
● The maximum stress to which the body can regain its original status on the removal
of the deforming force is called elastic limit.
● Hooke’s Law: Hooke’s law states that, within elastic limits, the ratio of stress to the
corresponding strain produced is a constant. This constant is called the modulus of
elasticity.
● Young’s Modulus: For a solid, in the form of a wire or a thin rod, Young’s modulus of
elasticity within elastic limit is defined as the ratio of longitudinal stress to
longitudinal strain.
● Bulk Modulus: Within elastic limit the bulk modulus is defined as the ratio of
longitudinal stress and volumetric strain.
● Poisson’s Ratio: The ratio of change in diameter (ΔD) to the original diameter (D) is
called lateral strain. The ratio of change in length (Δl) to the original length (l) is
called longitudinal strain. The ratio of lateral strain to the longitudinal strain is called
Poisson’s ratio.
● Elastic Fatigue: It is the property of an elastic body by virtue of which its behaviour
becomes less elastic under the action of repeated alternating deforming forces.
Relations between Elastic Moduli For isotropic materials (i.e., materials having the
same properties in all directions), only two of the three elastic constants are
independent. For example, Young’s modulus can be expressed in terms of the bulk
and shear moduli.
● Breaking Stress: The ultimate tensile strength of a material is the stress required to
break a wire or a rod by pulling on it. The breaking stress of the material is the
maximum stress which a material can withstand. Beyond this point breakage occurs.
Hence, the elastic potential energy of a wire (energy density) is equal to half the
product of its stress and strain.
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● Heat is the form of energy transferred between two (or more) systems or a system
and its surroundings by virtue of temperature difference. The SI unit of heat energy
transferred is expressed in joule (J).
● The two familiar temperature scales are the Fahrenheit temperature scale and the
Celsius temperature scale. The ice and steam point have values 32°F and 212°F
respectively, on the Fahrenheit scale and 0°C and 100°C on the Celsius scale. On the
Fahrenheit scale, there are 180 equal intervals between two reference points, and
on the Celsius scale, there are 100.
● An ideal gas obeys the following law. That is PV = gRT, where P,V and T are the
pressure, volume and temperature of the gas respectively, g is the number of moles
in an ideal gas and R = 8.31 J mol-1 K-1 is known as universal gas constant. The
equation, PV – gRT is known as ideal gas equation.
● The absolute minimum temperature for an ideal gas, inferred by extrapolating the
straight line P – T graph is found to be – 273.15 °C and is designated as absolute
zero. Absolute temperature scale (T) and Celsius scale are related by
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t° C = T – 273.15.
● Thermal Expansion: The increase of size of a body due to the increase in the
temperature is called thermal expansion. Three types of expansions can take place in
solids viz. linear, superficial and volume expansion,
● For a given solid, the three coefficients of expansion α , β, γ are not constant. Their
values depend on the temperature range.
● Liquids have volume expansion only. If we do not take into account the expansion of
solid container, then the expansion of liquid is called apparent expansion. On the
other hand, if we take into account the expansion of solid too, it is referred as the
real expansion of liquid. It is found that γr = γa + γg.
where, γr= real expansion coefficient of liquid, γa = apparent expansion coefficient of
liquid and γg = volume expansion coefficient of container vessel (glass).
● Thermal Stress: When a rod is held between two fixed supports and its temperature
is increased, the fixed supports do not allow the rod to expand, which results in a
stress which is called thermal stress.
● Thermal Capacity: The thermal capacity of a body is the quantity of heat required to
raise the temperature of the whole of the body through a unit degree. It is measured
in calorie per °C or joule per K.
● Specific Heat Capacity: The specific heat capacity (also referred to as specific heat)
of a substance is the amount of heat required to raise the temperature of a unit
mass of substance through 1 °C. It is measured in cal g-1(°C)-1 or J kg-1 K-1.
● Transition of matter from one state (solid, liquid and gas) to another is called a
change of state.
● The change of state from solid to liquid is called melting and from liquid to solid is
called fusion. It is observed that the temperature remains constant until the entire
amount of the solid substance melts i.e., both the solid and liquid states of the
substance co-exist in thermal equilibrium during the change of state from solid to
liquid.
● The temperature at which a solid melts is called its melting point. The value of
melting point of a solid is characteristic of the substance and depends on pressure
also.
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● Melting of ice under increased pressure and refreezing on reducing the pressure is
called regelation.
● The change of state from liquid to vapour (or gas) is called vaporisation. The
temperature at which the liquid and vapour states of a substance co-exist is called its
boiling point.
● The change from solid state to vapour state without passing through the liquid state
is called sublimation.
● Latent Heat: Latent heat of a substance is the amount of heat energy required to
change the state of unit mass of the substance from solid to liquid or from liquid to
gas/vapour without any change in temperature.
● The latent heat of fusion (Lf) is the heat per unit mass required to change a
substance from solid into liquid at the same temperature and pressure. The latent
heat of vaporization (Lv) is the heat per unit mass required to change a substance
from liquid to vapour state without change in temperature and pressure.
● Heat Transfer: Heat can be transferred from one place to another by three different
methods, namely, conduction, convection and radiation. Conduction usually takes
place in solids, convection in liquids and gases, and no medium is required for
radiation.
✓ Conduction: According to Maxwell, conduction is the flow of heat through an
unequally heated body from places of higher temperature to those of lower
temperature. Rate of heat transfer is given by where K is called Thermal
Conductivity and A is area of cross-section.
✓ Convection: Maxwell defines convection as the flow of heat by the motion of
the hot body itself carrying its heat with it.
✓ Radiation: Radiation is the mode of heat transfer in which heat travels
directly from one place to another without the agency of any intervening
medium.
● thermal conductivity: is defined as heat energy transferred in unit time from unit
area having a unit difference in temperature over unit length. It is expressed in Js -1
m-1 °C-1 or W-1 K-1.
● Newton’s Law of Cooling: Newton’s law of cooling states that the rate of loss of heat
of a body is directly proportional to the difference in temperature of the body and
the surroundings, provided the difference in temperature is small, not more than 40
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°C.
– ve sign implies that as time passes, temperature T decreases.
✓ Wien's Displacement Law: This law states that as the temperature increases,
the maximum value of the radiant energy emitted by the black body, move
towards shorter wavelengths. Wein found that “The product of the peak
wavelength ( λm) and the Kelvin temperature (T) of the black body should
remain constant.” λm x T= b,
Where b is constant known as Wien's constant. Its value is 2.898 x 10-3 mk.
✓ Stefan’s Law: This law states that the thermal radiations energy emitted per
second from the surface of a black body is directly proportional to its surface
area A and to the fourth power of its absolute temperature T.
Emission coefficient or degree of blackness of a body is represented
by a dimensionless quantity ε, 0 < ε < 1. If ε = 1 then the body is perfectly
black body. Hence Let us consider an object at absolute temperature T and
To be the temperature of the surroundings. H1 = Rate of energy emitted by
the body.
✓ The Solar Constant: The average energy emitted from the surface of the sun,
absorbed per unit area, per minute by the earth is constant which is called as
solar constant which is represented by S whose value is 8.135 jm-2 min-1.
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● The branch of physics which deals with the study of transformation of heat into
other forms of energy and vice-versa is called thermodynamics.
● Thermodynamics is a macroscopic science. It deals with bulk systems and does not
go into the molecular constitution of matter.
● First Law of Thermodynamics: The first law of thermodynamics is simply the general
law of conservation of energy applied to any system. According to this law, “the total
heat energy change in any system is the sum of the internal energy change and the
work done.”
✓ When a certain quantity of heat dQ is subjected to a system, a part of it is
used in increasing the internal energy by dU and a part is used in performing
external work dW, hence
dQ = dU + dW
✓ For gases, the specific heat capacity depends on the process or the conditions
under which heat capacity transfer takes place. There are mainly two
principal specific heat capacities for a gas. These are specific heat capacity at
constant volume and specific heat capacity at constant pressure.
✓ From First Law of Thermodynamics we find a relation between two principal
specific heats of an ideal gas. According to the relation
Cp-Cυ = R
✓ Here Cp and Cυ are molar specific heats under constant pressure and
constant volume condition respectively.
✓ The specific heat capacity of a gas at constant pressure is greater than the
specific heat capacity of the gas at constant volume i.e. Cp > Cυ. Reason is
that when heat supplied to a gas at constant volume, no work would be done
by the gas against the external pressure and all the energy is used to raise the
temperature of the gas. On the other hand when the heat is supplied to the
gas at constant pressure, its volume increases and the heat energy supplied
to it is used to increase the temperature of the gas as well as in doing the
work against the external pressure.
✓ The difference, between the two specific heats is the thermal equivalent of
the work done in expanding the gas against the external pressure.
● Equation of State: The equation of state represents the connection between the
state variables of a system. For example, the those equation of state of an
ideal/perfect gas in represented as PV = μRT.
✓ where g is number of moles of the gas and R is gas constant for one mole of
the gas.
✓ Thermodynamic state variables are of two kinds, extensive and intensive.
Extensive variables indicate the size of the system but intensive variables do
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not indicate the size. Volume, mass, internal energy of a system are extensive
variables but pressure, temperature and density are intensive variables.
● Quasi-Static Processes: Processes that are sufficiently slow and do not involve
accelerated motion of piston and/or large temperature gradient are quasi-static
processes.
In this process, the change in pressure or change in volume or change in
temperature of the system is very small.
● Isothermal Process: A change in pressure and volume of a gas without any change in
its temperature, is called an isothermal change. In such a change, there is a free
exchange of heat between the gas and its surroundings.
● P-V Diagram: A graph representing the variation of pressure with the variation of
volume is called P-V diagram. The work done by the thermodynamic system is equal
to the area under P-V diagram.
● Reversible Process: A process which can retrace so that the system passes through
the same states is called a reversible process, otherwise it is irreversible.
✓ Irreversibility arises mainly from two causes:
✓ (i) Many processes like free expansion or an explosive chemical reaction take
the system to non-equilibrium states.
✓ (ii) Most processes involve friction, viscosity and other dissipative effects.
from a cold body to a hot body. In other words heat cannot flow itself
from a colder body to a hotter body.
✓ A heat engine is a device by which a system is made to undergo a cyclic
process that results
✓ in conversion of heat to work. Basically, a heat engine consists of: (i) a heat
source, (ii) a heat sink, and (iii) a working substance.
● Refrigerator: The process of removing heat from bodies colder than their
surroundings is called refrigeration and the device doing so is called refrigerator.
✓ In the refrigerator, heat is absorbed at low temperature and rejected at
higher temperature with the help of external mechanical work. Thus, a
refrigerator is a heat engine working backward and hence it is also called
heat pump.
✓ Refrigerator works on the reverse process of Carnot engine. By the work
done on the system, heat is extracted from low temperature sink T2 and
passed on to high temperature source T1.
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● Ideal Gas: An ideal gas or a perfect gas is that gas which strictly obeys gas laws such
as Boyle’s law, Charles's law, Gay Lussac’s law etc.
✓ An ideal gas has following characteristics:
■ Molecule of an ideal gas is a point mass with no geometrical
dimensions.
■ There is no force of attraction or repulsion amongst the molecules of
the gas.
● Boyle’s Law: According to this law, the volume (V) of a fixed mass of a gas is
inversely proportional to the pressure (P) of the gas, provided temperature of the
gas is kept constant.
● Charles's Law: According to this law, the volume (V) of a given mass of a gas is
directly proportional to the temperature of the gas, provided pressure of the gas
remains constant.
● Gay Lussac’s Law (or Pressure Law): According to this law, the pressure P of a given
mass of a gas is directly proportional to its absolute temperature T, provided the
volume V of the gas remains constant.
● Avogadro's Law: Equal volumes of all gases under S.T.P. contain the same number of
molecules equalling 6.023 x 1023.
● Dalton’s Law of Partial Pressures According to this law, the resultant pressure
exerted by a mixture of non-interacting gases is equal to the sum of their individual
pressures. i-e., P = P1 + P2 + ————-Pn
✓ Root mean square speed of gas molecules is defined as the square root of the
mean of the squares of the speeds of gas molecules.
● Kinetic Interpretation of Temperature: The total average kinetic energy of all the
molecules of a gas is proportional to its absolute temperature (T). Thus, the
temperature of a gas is a measure of the average kinetic energy ‘IT of the molecules
of the gas.
U = 3/2 RT
✓ According to this interpretation of temperature, the average kinetic energy U
is zero at T = 0, i.e., the motion of molecules ceases altogether at absolute
zero.
● Mean Free Path: Mean free path of a molecule in a gas is the average distance
travelled by the molecule between two successive collisions
✓ Smaller the number of molecules per unit volume of the gas, larger is the
mean free path.
✓ Smaller the diameter, larger is the mean free path.
✓ Smaller the density, larger is the mean free path. In the case of vacuum, ρ =
0, λ —>∞
✓ Smaller the pressure of a gas, larger is the mean free path.
✓ Higher the temperature of a gas, larger is the mean free path.
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● Characteristics of SHM:
✓ The displacement x in SHM at time t is given by X = A sin (wt+Q).
✓ Where the three constants A, w and Q characterize the SHM, i.e., they
distinguish one SHM from another. A SHM can also be described by a cosine
function as follows: X = A cos (wt+Q).
✓ The displacement of an oscillating particle at any instant is equal to the
change in its position vector during that time. The maximum value of
displacement in an oscillatory motion on either side of its mean position is
called “displacement amplitude” or “simple amplitude”
✓ Thus, amplitude A = x (max).
● Phase: The quantity (wt+Q) is called the phase of SHM at time t, it describes the
state of motion at that instant. The quantity Q is the phase at time f=0 and is called
the phase constant or initial phase or epoch of the SHM. The phase constant is the
time-independent term in the cosine or sine function.
✓ The force responsible for maintaining the SHM is called restoring force.
✓ If the displacement (x) from the equilibrium position is small, the restoring
force (F) acting on the body is given by F = -kx.
✓ Where k is a force constant.
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● Energy in SHM: When a body executes SHM, its energy changes between kinetic and
potential, but the total energy is always constant.
● Springs in Series: If two springs, having spring constant k1 and k2, are joined in series,
the spring constant of the combination is given by
● Springs in Parallel: If two springs, having spring constant k1 and k2, are joined in
parallel, the spring constant of the combination is given by
● When a system is compelled to oscillate with a frequency other than its natural
frequency, it is said to execute forced oscillations.
● The two or more oscillations linked to together in such a way that the exchange of
energy takes place between them are called coupled oscillators. The oscillations
produced by coupled oscillators are known as “coupled oscillations”.
● Wave: Wave is a form of disturbance which travels through a material medium due
to the repeated f periodic motion of the particle of the medium about their mean
positions without any actual transportation of matter.
● Characteristics of wave:
The characteristics of waves are as follows:
✓ The particles of the medium traversed by a wave execute relatively small
vibrations about their mean positions but the particles are not permanently
displaced in the direction of propagation of the wave.
✓ Each successive particle of the medium executes a motion quite similar to its
predecessors along/perpendicular to the line of travel of the wave.
✓ During wave motion only transfer of energy takes place but not that of a
portion of the medium.
✓ Electromagnetic waves
These are the waves which require no material medium. Common examples
of electromagnetic waves are visible light, ultraviolet light, radio waves,
microwaves etc.
✓ Matter waves
These waves are associated with moving particles of matter, like electrons,
protons, neutrons etc.
■ Transverse wave motion,
■ Longitudinal wave motion.
● Wavelength: The distance travelled by the disturbance during the time of one
vibration by a medium particle is called the wavelength. In case of a transverse wave
the wavelength is equal to distance from centre of one compression to another.
● Wave Velocity: Wave velocity is the time rate of propagation of wave motion in the
given medium. It is different from particle velocity. Wave velocity depends upon the
nature of medium.
Wave velocity (u) = frequency (v) x wavelength (lambda)
● Time period: The time taken by a particle to complete one vibration is called time
period.
T = 1/v, it is expressed in seconds.
● Factors Influencing Velocity of Sound: The velocity of sound in any gaseous medium
is affected by a large number of factors like density, pressure, temperature,
humidity, wind velocity etc.
✓ The velocity of sound in a gas is inversely proportional to the square root of
density of the gas.
✓ The velocity of sound is independent of the change in pressure of the gas,
provided temperature remains constant.
✓ The velocity of sound in a gas is directly proportional to the square root of its
absolute temperature.
✓ The velocity of sound in moist air is greater than the velocity of sound in dry
air.
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● Relation between phase and path difference: A wave motion can be reflected from
a rigid as well as from a free boundary. A travelling wave, at a rigid boundary or a
closed end, is reflected with a phase reversal but the reflection at an open boundary
takes place without any phase change.
● Standing waves or Stationary waves: When two sets of progressive wave trains of
the same type (i.e., both longitudinal or both transverse) having the same amplitude
and time period/frequency/ wavelength travelling with same speed along the same
straight line in opposite directions superimpose, a new set of waves are formed.
These are called stationary waves or standing waves.
● Progressive Waves: The disturbance progresses onwards, it being handed over from
particle to particle. Each particle executes the same type of vibration as the
preceding once, though at a different time.
The waves are in the form of crests and troughs, i.e., sine/cosine functions, which
move onwards with a definite velocity.
Every particle has the same amplitude, which it attains in its own time depending
upon the progress of the wave.