P/Kpa xi yi fi=yi*P f2=y2*P Yi Y2 lnY1

12.3 0 0 0 12.3 #DIV/0! 1 #DIV/0!

15.51 0.0895 0.2716 4.212516 11.297484 1.30416231 1.00878049 0.26556093
18.61 0.1981 0.4565 8.495465 10.114535 1.18827182 1.02546442 0.1725
21.63 0.3193 0.5934 12.835242 8.794758 1.11382833 1.05042012 0.10780303
24.01 0.4232 0.6815 16.362815 7.647185 1.07133546 1.07788203 0.06890596
25.92 0.5119 0.744 19.28448 6.63552 1.04384477 1.10525132 0.04291079
27.96 0.6096 0.805 22.5078 5.4522 1.02306024 1.13542083 0.02279837
30.12 0.7135 0.8639 26.020668 4.099332 1.01050294 1.16327757 0.01044817
31.75 0.7934 0.9048 28.7274 3.0226 1.00326865 1.18944742 0.00326332
34.15 0.9102 0.959 32.74985 1.40015 0.99697806 1.26763177 -0.0030265
36.09 1 1 36.09 0 1 #DIV/0! 0

Chart Title
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.1
0.05 f(x) = - 0.2723707696x^2 + 0.2494794757x + 0.0140459209
R² = 0.9868952278
0
0 0.2 0.4 0.6 0.8 1 1.2
-0.05
lnY2 �^𝐸/𝑅� �^𝐸/𝑥1𝑥2𝑅�
0 #DIV/0! #DIV/0!
0.00874216 0.03172744 0.38934275 Chart Title
0.0251456 0.05433651 0.34204799 40
0.0491902 0.06790528 0.31242721 35
0.07499804 0.07241987 0.29667902
30
0.10007275 0.07081155 0.28340671
0.12700336 0.06348 0.26673631 25
0.15124151 0.05078546 0.24843959 20
0.17348885 0.03843192 0.23446042
15
0.23715042 0.01854137 0.22684477
#DIV/0! #DIV/0! #DIV/0! 10

0
0 0.2 0.4 0.6 0.8 1 1.2
e

0.8 1 1.2
problema 12.16
A)BURBUJA P
componente Ai Bi Ci T xi Pisat A12
acetona 14.3145 2756.22 228.06 333.15 0.3 12128.2205 0.15713594
agua 16.3872 3885.79 230.17 0.7 13216.0154

DATOS
V1 74.05
V2 18.07
a12 291.37
a21 1448.01
R 1.987

B) ROCIO P
componente Ai Bi Ci T Yi Pisat Gi=G1=G2=1
acetona 14.3145 2756.22 228.06 60 0.3 115.155691
agua 16.3872 3885.79 230.17 0.7 20.0008402

DATOS
V1 74.05
V2 18.07
a12 291.37
a21 1448.01
R 1.987

C.
componente Ai Bi Ci T ZI Pisat A12
acetona 14.3145 2756.22 228.06 333.15 0.3 12128.2205 0.15713594
agua 16.3872 3885.79 230.17 0.7 13216.0154

DATOS
V1 74.05 P=0.5(PB+PR)PB 19506.055 134.6224
V2 18.07 81.4967 PR 13545.067 28.371
a12 291.37
a21 1448.01
R 1.987

D A dilucion infinita se tiene

componente Ai Bi Ci T ZI Pisat G1∞
acetona 14.3145 2756.22 228.06 60 0.3 115.155691 10.9225952
agua 16.3872 3885.79 230.17 0.7 20.0008402

DATOS
V1 74.05 P=0.5(PB+PR)PB 19506.055 134.6224
V2 18.07 81.4967 PR 13545.067 28.371
a12 291.37
a21 1448.01
R 1.987
 A21 gama i gama 2 P=xi*pist*gama
0.45981037 2.17228169 1.25413649 19506.0545

PSUP XSUP A12 A21 Gi G2 P XI

26.593129 0.06927959 0.02118511 2.1765E-05 1.22209412 1.05686273 28.371034 0.06047924
0.93072041 0.93952076
1

A21 X1 X2 gama i gama 2 K1 K2 V

0.45981037 0.00214418 0.99785582 10.6585426 1.0000262 1586.18884 162.170513 0.08763235
0.2 0.8 2.99008752 1.12856162 444.980482 183.014623
0.3 0.7 2.17228169 1.25413649 323.275807 203.378631
0.4 0.6 1.72196291 1.42034491 256.260019 230.332029
0.5 0.5 1.44486664 1.63889601 215.022956 265.773644

A dilucion infinita se tiene

G2∞ ALFA12 X1--0ALFA12 X2--0
5.05210593 62.8873077 1.13963221
sumaX=1
-0.0474177
comp Vi xi temp aij A B C
propanol 1 75.14 0.3 60 775.48 16.1154 3483.67 205.807
agua 2 18.07 0.7 1351.9 16.3872 3885.7 230.17

1.987
Pat Aij gamma presion yi
20.2749674 0.07452843 2.12464489 12.9231318 0.41256509
20.0070447 0.53948486 1.31387505 18.4007298 0.58743491
31.3238616
comp Vi xi temp aij A B C
propanol 1 75.14 0.04220431 60 775.48 16.1154 3483.67 205.807
agua 2 18.07 0.95779569 1351.9 16.3872 3885.7 230.17

R 1.987
Pat Aij gamma presion yi
20.2749674 0.07452843 9.74414914 8.33798119 0.300000005
20.0070447 0.53948486 1.01527073 19.455289 0.699999995
27.7932702
comp Vi xi temp aij A B C
propanol 1 75.14 0.08045188 60 775.48 16.1154 3483.67 205.807
agua 2 18.07 0.91954812 1351.9 16.3872 3885.7 230.17

1.987
Presion 24.3781435
Z1 0.3
z2 0.7
29.5585659
Pat Aij gamma presion yi ki V L
20.2749674 0.07452843 6.35182917 10.3608449 0.3505192 4.35688016 0.81293849 0.18706151
20.0070447 0.53948486 1.04349957 19.197721 0.6494808 0.70630431 0.81293849 0.18706151
29.5585659
comp Vi xi temp aij A B C
propanol 1 75.14 0.43854527 60 775.48 16.1154 3483.67 205.807
agua 2 18.07 0.56145473 1351.9 16.3872 3885.7 230.17

1.987
Pat Aij gamma presion yi alfa error
20.2749674 0.07452843 1.55381636 13.8157442 0.43854527 21.5548354 3.080362E-09
20.0070447 0.53948486 1.57462418 17.6878319 0.56145473 0.21667552
31.5035761
tiempo UNT
0 600 t VS UNT
144 455
700
262 373 f(x) = 3256.5110065078 x^-0.3880478612
R² = 0.9391922736
390 356 600
f(x) = 0.000542419x^2 - 0.8606773746x + 585.2174246513
508 302 R² = 0.9797906818
500
628 252
754 240 400

300

200

100

0
0 100 200 300 400 500 600
 t VS UNT
78 x^-0.3880478612

606773746x + 585.2174246513

300 400 500 600 700 800

12.18
BURBUJA T
component A B C TSUP x t Psat
metanol 16.5785 3638.27 239.5 350 0.3 59.3900165 81.9324695
benceno 13.7819 2726.81 217.572 0.7 51.2374406

P 101.33
v1 40.73
v2 83.71
a12 1734.43
a21 183.04
R 1.987

BURBUJA T
component A B C tsat y t0 Psat
metanol 16.5785 3638.27 239.5 64.7001891 0.3 75.4103452 101.33
benceno 13.7819 2726.81 217.572 80.000412 0.7

P 101.33
v1 40.73
v2 83.71
a12 1734.43
a21 183.04
R 1.987
A12 A21 gama1 gama 2 y
0.16972524 0.37396614 2.29725511 1.25179216 0.55724795
0.44307745
1.00032541

A12 A21 gama1 gama 2

2.8423E-06 0.11716495 2.98145021 1.42688148
comp Vi xi temp aij A B C
propanol 1 75.14 0.3 87.957695 775.48 16.1154 3483.67 205.807
agua 2 18.07 0.7 361.107695 1351.9 16.3872 3885.7 230.17

R 1.987
Pat Aij gamma presion yi
70.5760682 0.08160403 1.99848409 42.3135449 0.41758162
64.9048488 0.63189873 1.29896644 59.0164543 0.58241838
101.329999
comp Vi xi temp aij A B C
propanol 1 75.14 0.04814721 91.1309156 775.48 16.1154 3483.67 205.807
agua 2 18.07 0.95185279 364.280916 1351.9 16.3872 3885.7 230.17

R 1.987

89.5443053
Pat Aij gamma presion yi
80.1114624 0.08237592 7.88122284 30.3990044 0.3
73.2261461 0.64235532 1.01765409 70.9310107 0.7
101.330015
nombre:
junior galvez veengas
ejercicios resueltos de cap 12 de introduccion a la termodinamica en ingenieria quimica. J.M. SMITH
n ingenieria quimica. J.M. SMITH
comp Vi xi temp aij A B C
propanol 1 75.14 0.08974345 89.5443053 775.48 16.1154 3483.67 205.807
agua 2 18.07 0.91025655 1351.9 16.3872 3885.7 230.17

R 1.987

Z1 0.3
z2 0.7

T 89.5443053
Pat Aij gamma presion yi ki V L
75.2183649 0.08199075 5.26016193 35.5079627 0.35041918 3.90467699 0.80658277 0.19341723
68.9606987 0.63712845 1.04858977 65.8220015 0.64958082 0.71362389 0.80658277 0.19341723
101.329964
comp Vi xi temp aij A B C
propanol 1 75.14 0.45456058 87.7374456 775.48 16.1154 3483.67 205.807
agua 2 18.07 0.54543942 360.887446 1351.9 16.3872 3885.7 230.17

1.987
Pat Aij gamma presion yi alfa error
69.9508882 0.08155022 1.44858735 46.0606113 0.45456059 23.1184469 -1.13E-09
64.3579302 0.63117254 1.5744753 55.2693604 0.54543941 0.2323934
101.329972
 A) BURB T
comp. A B C a12 a21 V1 V2
1 14.2456 2662.78 219.69 -31.19 813.18 79.84 40.73
2 16.5785 3638.27 239.5

R 1.987
X1 0.3
X2 0.7
A12 A21 Tasumida(K) GAMA1 GAMA2 P1SAT P2SAT P
0.53626659 0.53320004 314.343934 1.38230018 -0.2733436 10503.2231 22233.9362 101.33

T
41.343934
comp Vi xi temp bij A B C
propanol 1 75.14 0.3 60 500.4 16.1154 3483.67 205.807
agua 2 18.07 0.7 333.15 1636.57 16.3872 3885.7 230.17

R 1.987
alfa 0.5081
Pat Tij Gij Yi Presion y
20.2749674 0.75592658 0.68107265 2.01865108 12.2784254 0.39549486
20.0070447 2.47227571 0.28474442 1.34004955 18.7673019 0.60450514
31.0457273
comp Vi xi temp bij A B C
propanol 1 75.14 0.03705001 60 500.4 16.1154 3483.67 205.807
agua 2 18.07 0.96294999 333.15 1636.57 16.3872 3885.7 230.17

R 1.987
alfa 0.5081
Pat Tij Gij Yi Presion y
20.2749674 0.75592658 0.68107265 11.1072795 8.34365176 0.3
20.0070447 2.47227571 0.28474442 1.01052317 19.4685207 0.7
27.8121724
comp Vi xi temp bij A B C
propanol 1 75.14 0.05971999 60 500.4 16.1154 3483.67 205.807
agua 2 18.07 0.94028001 333.15 1636.57 16.3872 3885.7 230.17

R 1.987
alfa 0.5081

presion 29.4289499
z1 0.3
0.7
Pat Tij Gij Yi Presion y k v
20.2749674 0.75592658 0.68107265 8.37942963 10.1459888 0.34476248 5.77298245 0.84296208
20.0070447 2.47227571 0.28474442 1.02502156 19.2829353 0.65523752 0.69685362 0.84296208
29.4289241
comp Vi xi temp bij A B C
propanol 1 75.14 0.41870664 60 500.4 16.1154 3483.67 205.807
agua 2 18.07 0.58129336 333.15 1636.57 16.3872 3885.7 230.17

R 1.987
alfa 0.5081
Pat Tij Gij Yi Presion y error
20.2749674 0.75592658 0.68107265 1.53750795 13.05231 0.41870664 2.5104E-11
20.0070447 2.47227571 0.28474442 1.55809736 18.1206134 0.58129336
31.1729235
comp Vi xi temp bij A B C
propanol 1 75.14 0.3 87.6960118 500.4 16.1154 3483.67 205.807
agua 2 18.07 0.7 360.846012 1636.57 16.3872 3885.7 230.17

R 1.987
alfa 0.5081
Pat Tij Gij Yi Presion y
69.8337942 0.69790695 0.70144939 2.0074636 42.0566399 0.41504629
64.2554746 2.28252114 0.31356488 1.31780565 59.2733593 0.58495371
101.329999
comp Vi xi temp bij A B C
propanol 1 75.14 0.04187525 91.125448 500.4 16.1154 3483.67 205.807
agua 2 18.07 0.95812475 364.275448 1636.57 16.3872 3885.7 230.17

R 1.987
alfa 0.5081
Pat Tij Gij Yi Presion y
80.0941579 0.69133657 0.70379503 9.06360753 30.3990046 0.3
73.2110776 2.26103257 0.31700725 1.01120054 70.9310109 0.7
101.330016
comp Vi xi temp bij A B C
propanol 1 75.14 0.06957965 89.4107299 500.4 16.1154 3483.67 205.807
agua 2 18.07 0.93042035 362.56073 1636.57 16.3872 3885.7 230.17

R 1.987
alfa 0.5081

presion 29.4289499
z1 0.3
0.7

89.4107299
Pat Tij Gij Yi Presion y k v
74.8180077 0.69460623 0.70262678 6.85315435 35.6762253 0.35207964 5.06009496 0.81564728
68.6112752 2.27172604 0.3152895 1.02845412 65.6537615 0.64792036 0.69637381 0.81564728
101.329987
comp Vi xi temp bij A B C
propanol 1 75.14 0.44618283 87.5286787 500.4 16.1154 3483.67 205.807
agua 2 18.07 0.55381717 360.678679 1636.57 16.3872 3885.7 230.17

R 1.987
alfa 0.5081
Pat Tij Gij Yi Presion y error
69.362559 0.69823074 0.701334 1.46087459 45.2117061 0.44618283 2.147E-10
63.8430882 2.28358009 0.31339621 1.5871726 56.1182939 0.55381717
101.33
comp A B C T P sat V xi
acetona 14.3145 2756.22 228.06 65 135.575914 74.05 0.3
metanol 16.5785 3638.27 239.5 102.530309 40.73 0.4
agua 16.3872 3885.7 230.17 25.101354 18.07 0.3
comp Vi xi temp aij A B C
propanol 1 75.14 0.3 60 775.48 16.1154 3483.67 205.807
agua 2 18.07 0.7 1351.9 16.3872 3885.7 230.17

R 1.987

x1 x2 gamma 1 gamma 2 presion 1 presion 2

0 1 21.2655796 1 0 20.0070447
0.1 0.9 5.37523343 1.06087159 10.8982682 19.1024148
0.2 0.8 3.01260803 1.17122974 12.2161059 18.7462766
0.3 0.7 2.12464489 1.31387505 12.9231318 18.4007298
0.43854527 0.56145473 1.55381637 1.57462417 13.8157442 17.687832
0.5 0.5 1.40521795 1.72077057 14.2453741 17.2137669
0.6 0.4 1.23550957 2.0130843 15.0299497 16.1103471
0.7 0.3 1.12451144 2.39696904 15.9596029 14.38688
0.8 0.2 1.05352295 2.91447816 17.0881148 11.662019
0.9 0.1 1.01327884 3.63470176 18.4897758 7.27196405
1 0 1 4.67679072 20.2749674 0
Pat Aij gamma presion yi
20.2749674 0.07452843 2.12464489 12.9231318 0.41256509
20.0070447 0.53948486 1.31387505 18.4007298 0.58743491
31.3238616
33

presion sis y1 y2 31

20.0070447 0 1
29
30.000683 0.36326734 0.63673266
30.9623825 0.3945467 0.6054533
27
31.3238616 0.41256509 0.58743491
31.5035761 0.43854527 0.56145473 1.4078E-13 25
31.4591409 0.45282146 0.54717854
31.1402968 0.48265275 0.51734725 23
30.3464829 0.52591277 0.47408723
28.7501338 0.59436645 0.40563355 21
25.7617399 0.71772232 0.28227768
19
20.2749674 1 0 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.5 0.6 0.7 0.8 0.9 1
comp Vi xi temp aij A B C
propanol 1 75.14 0.3 87.957695 775.48 16.1154 3483.67 205.807
agua 2 18.07 0.7 361.107695 1351.9 16.3872 3885.7 230.17

R 1.987

x1 x2 tempera Psat 1 Psat 2 A12 A21

0 1 99.9991103 112.577221 101.329999 0.08450029 0.6715103
0.1 0.9 89.3337155 74.5879826 68.4104843 0.08193951 0.63643447
0.2 0.8 88.3473872 71.693593 65.8820467 0.08169916 0.63318347
0.3 0.7 87.95757 70.5757121 64.9045373 0.081604 0.63189832
0.4 0.6 87.7669603 70.0343978 64.430996 0.08155743 0.63126986
0.5 0.5 87.7604969 70.016103 64.4149894 0.08155585 0.63124855
0.6 0.4 88.0112094 70.7286686 65.0383199 0.0816171 0.63207517
0.7 0.3 88.6660385 72.6182869 66.6902148 0.08177687 0.63423388
0.8 0.2 89.9930811 76.5765057 70.1455712 0.08209986 0.63860717
0.9 0.1 92.4996531 84.5420856 77.0806887 0.08270695 0.64686203
1 0 97.1994119 101.330005 91.6277632 0.08383481 0.66231795
33

31

29

27

25

23

21

19
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
 Pat Aij gamma presion yi
70.5760682 0.08160403 1.99848409 42.3135449 0.41758162
64.9048488 0.63189873 1.29896644 59.0164543 0.58241838
101.329999

gamma 1 gamma 2 presion 1 presion 2 presion sis y1

16.4362625 1 0 101.329999 101.329999 0
4.8559641 1.05751084 36.2196566 65.110346 101.330003 0.35744257
2.79078947 1.16332256 40.0163449 61.3136567 101.330002 0.39491112
1.99848462 1.29896651 42.3133425 59.016174 101.329517 0.41758161
1.59295113 1.46682387 44.6245493 56.7053538 101.329903 0.44038875
1.35415817 1.67425463 47.406439 53.923547 101.329986 0.46784215
1.20320807 1.93229221 51.0607828 50.2692157 101.329998 0.50390589
1.10554282 2.25581127 56.1978382 45.1321615 101.33 0.55460217
1.04422328 2.66300651 63.9703761 37.3596225 101.329999 0.63130738
1.01055071 3.17061079 76.8906585 24.4392863 101.329945 0.75881477
1 3.77414832 101.330005 0 101.330005 1
105

100

95

90

85

80
0 0.2 0.4 0.6 0.8 1 1.2
3 0.4 0.5 0.6 0.7 0.8 0.9 1
8 1 1.2