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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

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Recycle Oil

COMPANY IDENTIFICATION EMERGENCY TELEPHONE NUMBERS

Chevron Products Company HEALTH (24 hr): (800)231-0623 or

a division of Chevron U.S.A. Inc.
6001 Bollinger Canyon Road
San Ramon, CA 94583
United States of America
www.chevronlubricants.com
(510)231-0623 (International)
TRANSPORTATION (24 hr): CHEMTREC
(800)424-9300 or (703)527-3887
Emergency Information Centers
are located in U.S.A.
Int'l collect calls accepted

PRODUCT INFORMATION: MSDS Request: (800)414-6737

email: lubemsds@Chevron.com
Product Information: (800)LUBE-TEK
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2. COMPOSITION/INFORMATION ON INGREDIENTS
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100.0 % Recycle Oil

CONTAINING

COMPONENTS AMOUNT LIMIT/QTY AGENCY/TYPE

LUBRICATING BASE OIL

SEVERELY REFINED PETROLEUM DISTILLATE
 > 50.00% 5 mg/m3 (mist) ACGIH TWA
10 mg/m3 (mist) ACGIH STEL
5 mg/m3 (mist) OSHA PEL

The BASE OIL may be a mixture of any of the following: CAS 64741884,
CAS 64741895, CAS 64741964, CAS 64741975, CAS 64742014, CAS 64742525,
CAS 64742536, CAS 64742547, CAS 64742558, CAS 64742570, CAS 64742627,
CAS 64742650, or CAS 72623837.

CAN CONTAIN

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DISTILLATES, SOLVENT-DEWAXED
Chemical Name: DISTILLATES, (PETROLEUM), SOLVENT-DEWAXED LIGHT PARAFFINIC
CAS64742569 5 mg/m3 (mist) ACGIH TWA
10 mg/m3 (mist) ACGIH STEL
5 mg/m3 (mist) OSHA PEL

POLYBUTENE
Chemical Name: POLYBUTENE
CAS9003285 NONE NA

WHITE MINERAL OIL

Chemical Name: WHITE MINERAL OIL
CAS8042475 5 mg/m3 (mist) ACGIH TWA
10 mg/m3 (mist) ACGIH STEL
5 mg/m3 (mist) OSHA PEL

HYDROTREATED, DISTILLATE, LT.

Chemical Name: DISTILLATES, HYDROTREATED LIGHT
CAS64742478 NONE NA

DISTILLATES, HYDROTREATED MIDD

Chemical Name: DISTILLATES, HYDROTREATED MIDDLE
CAS64742467 NONE NA

GAS OIL, LIGHT

Chemical Name: DISTILLATES, STRAIGHT RUN MIDDLE
CAS64741442 NONE NA

RAFFINATE, LOW-ASPHALTENE VACU

Chemical Name: RAFFINATE, LOW-ASPHALTENE VACUUM RESIDUES
CAS164907771 NONE NA

LOW-ASPHALTENE VACUUM RESIDUES

Chemical Name: LOW-ASPHALTENE VACUUM RESIDUES
CAS164907793 NONE NA

AMYL ACETATE
Chemical Name: ACETIC ACID, PENTYL ESTER
CAS628637 < 2.00% 100 ppm ACGIH TWA
525 mg/m3 OSHA PEL
5,000 LBS CERCLA 302.4 RQ

ASPHALT
Chemical Name: ASPHALT
CAS8052424 < 35.10% 0.5 mg/m3 ACGIH TWA
ALKYLBENZENE-MONO,BRANCHED
Chemical Name: ALKYLBENZENE-MONO,BRANCHED
CAS67774747 NONE NA

SYNTHETIC HYDROCARBON BASE OIL

Chemical Name: 1-DECENE, TRIMER, HYDROGENATED
CAS68649127 NONE NA

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SYNTHETIC HYDROCARBON BASE OIL

Chemical Name: SYNTHETIC HYDROCARBON BASE OILS
CAS103242 NONE NA

SYNTHETIC HYDROCARBON BASE OIL

Chemical Name: 1-DECENE, HOMOPOLYMER, HYDROGENATED
CAS68037014 NONE NA

SYNTHETIC HYDROCARBON BASE OIL

Chemical Name: SYNTHETIC HYDROCARBON BASE OIL
CAS27178161 NONE NA

HYDROTREATED LUB. OIL, SPENT

Chemical Name: SEVERELY HYDROTREATED LUBRICATING OIL, SPENT
CAS64742581 NONE NA

ADDITIVES
< 50.00%

MAY CONTAIN

CHLORINATED PARAFFIN
Chemical Name: CHLORINATED PARAFFIN
CAS63449398 5.00% NONE NA

ZINC ALKYL DITHIOPHOSPHATE

Chemical Name: PHOSPHORODITHIOIC ACID,O,O-DI-C1-14-ALKYL ESTERS, ZINC SALT
CAS68649423 < 25.00% NONE NA

ZINC ALKARYL DITHIOPHOSPHATE

Chemical Name: ZINC ALKARYL DITHIOPHOSPHATE
CAS54261675 < 5.00% NONE NA

TRICRESYL PHOSPHATE
Chemical Name: TRICRESYL PHOSPHATE
CAS1330785 1.00% NONE NA

BARIUM COMPOUND
< 4.00%

COMPOSITION COMMENT:
All the components of this material are on the Toxic Substances Control
Act Chemical Substances Inventory.

This product fits the ACGIH definition for mineral oil mist. The ACGIH
TLV is 5 mg/m3, the OSHA PEL is 5 mg/m3.
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3. HAZARDS IDENTIFICATION
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************************* EMERGENCY OVERVIEW *************************

Liquid.

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- COMBUSTIBLE LIQUID AND VAPOR

- HARMFUL OR FATAL IF SWALLOWED - CAN ENTER LUNGS AND
CAUSE DAMAGE
- INHALATION MAY CAUSE NERVOUS SYSTEM EFFECTS
- CAUSES EYE AND SKIN IRRITATION
- MAY CAUSE AN ALLERGIC SKIN REACTION

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IMMEDIATE HEALTH EFFECTS

EYE:
Contact with the eyes causes irritation.
SKIN:
Contact with the skin causes irritation. Contact with the skin may cause
an allergic skin reaction.
INGESTION:
Because of its low viscosity, this material can directly enter the lungs,
if swallowed, or if subsequently vomited. Once in the lungs it is very
difficult to remove and can cause severe injury or death.
INHALATION:
Breathing this material at concentrations above the recommended exposure
limit may cause central nervous system effects. Contains a
petroleum-based mineral oil. May cause respiratory irritation or other
pulmonary effects following prolonged or repeated inhalation of oil mist
at airborne levels above the recommended mineral oil mist exposure limit.
SIGNS AND SYMPTOMS OF EXPOSURE:
Eye irritation: may include pain, tearing, reddening, swelling, and
impaired vision. Symptoms of skin irritation or skin allergies may
include pain, itching, reddening, swelling, and blistering. Central
nervous system effects may include headache, dizziness, nausea, vomiting,
weakness, loss of coordination, blurred vision, drowsiness, confusion, or
disorientation. At extreme exposures, central nervous system effects may
include respiratory depression, tremors or convulsions, loss of
consciousness, coma or death.
CARCINOGENICITY:
Can cause cancer in laboratory animals, but is not considered to be a
human carcinogen. See Section 11 for additional information.
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4. FIRST AID MEASURES

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EYE:
Flush eyes with water immediately while holding the eyelids open. Remove
contact lenses, if worn, after initial flushing, and continue flushing for
at least 15 minutes. Get medical attention if irritation persists.
SKIN:
Wash skin immediately with soap and water and remove contaminated clothing
and shoes. Get medical attention if irritation persists. Discard
contaminated clothing and shoes or thoroughly clean before reuse.
INGESTION:
If swallowed, do not induce vomiting. Give the person a glass of water or
milk to drink and get immediate medical attention. Never give anything by
mouth to an unconscious person.

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INHALATION:
Move the exposed person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical
attention if breathing difficulties continue.
NOTE TO PHYSICIANS:
Ingestion of this product or subsequent vomiting may result in aspiration
of light hydrocarbon liquid, which may cause pneumonitis.
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5. FIRE FIGHTING MEASURES

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FIRE CLASSIFICATION:
Classification (29 CFR 1910.1200): Combustible liquid.
FLAMMABLE PROPERTIES:
FLASH POINT: NDA
AUTOIGNITION: NDA
FLAMMABILITY LIMITS (% by volume in air): Lower: NDA Upper: NDA
EXTINGUISHING MEDIA:
CO2, dry chemical, foam and water fog.
NFPA RATINGS: Health 2; Flammability 2; Reactivity 0.
FIRE FIGHTING INSTRUCTIONS:
Toxic fumes may be given off when material is exposed to fire. For fires
involving this material, do not enter any enclosed or confined fire space
without proper protective equipment, including self-contained breathing
apparatus.
COMBUSTION PRODUCTS:
Normal combustion forms carbon dioxide and water vapor and may produce
oxides of sulfur, nitrogen, phosphorus, antimony, calcium, barium, boron,
silica, copper, zinc, and toxic compounds of chlorine and selenium.
Heating this material may produce toxic gases. Incomplete combustion can
produce carbon monoxide.
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6. ACCIDENTAL RELEASE MEASURES

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CHEMTREC EMERGENCY NUMBER (24 hr): (800)424-9300 or (703)527-3887

International Collect Calls Accepted
ACCIDENTAL RELEASE MEASURES:
Eliminate all sources of ignition in the vicinity of the spill or released
vapor. Stop the source of the leak or release. Clean up releases as soon
as possible, observing precautions in Exposure Controls/Personal
Protection. Contain liquid to prevent further contamination of soil,
surface water or groundwater. Clean up small spills using appropriate
techniques such as sorbent materials or pumping. Where feasible and
appropriate, remove contaminated soil. Follow prescribed procedures for
reporting and responding to larger releases.
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7. HANDLING AND STORAGE

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Liquid evaporates and forms vapor (fumes) which can catch fire and burn
with explosive force. Invisible vapor spreads easily and can be set on

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fire by many sources such as pilot lights, welding equipment, and

electrical motors and switches. Fire hazard is greater as liquid
temperature rises above 85F.

The hydrocarbon solvent in this product may accumulate at flammable or

explosive levels in the headspace of storage containers. Do not use or
store near heat, sparks, or open flames. Use or store only in a
well-ventilated area. Keep container closed when material is not in use.

Avoid work practices that may release volatile components into the
atmosphere. Local air pollution regulations should be consulted to
determine if the release of volatile components is regulated or restricted
in the area in which this material is used.

Electrostatic charge may accumulate and create a hazardous condition when

handling this material. To minimize this hazard, bonding and grounding may
be necessary but may not, by themselves, be sufficient. Review all
operations which have the potential of generating an accumulation of
electrostatic charge and/or a flammable atmosphere (including tank and
container filling, splash filling, tank cleaning, sampling, gauging,
switch loading, filtering, mixing, agitation, and vacuum truck operations)
and use appropriate mitigating procedures. For more information, refer to
OSHA Standard 29 CFR 1910.106, "Flammable and Combustible Liquids",
National Fire Protection Association (NFPA) 77, "Recommended Practice on
Static Electricity", and/or the American Petroleum Institute (API)
Recommended Practice 2003, "Protection Against Ignitions Arising Out of
Static, Lightning, and Stray Currents".

Container is not designed to contain pressure. Do not use pressure to

empty container or it may rupture with explosive force. Empty containers
retain product residue (solid, liquid, and/or vapor) and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such
containers to heat, flame, sparks, static electricity, or other sources of
ignition. They may explode and cause injury or death. Empty containers
should be completely drained, properly closed, and promptly returned to a
drum reconditioner, or properly disposed of. Avoid contaminating soil or
releasing this material into sewage and drainage systems and bodies of
water. Do not get in eyes, on skin, or on clothing. Do not taste or
swallow. Wash thoroughly after handling. Do not breathe vapor or fumes.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

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GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3),
applicable exposure limits, job activities, and other substances in the
work place when designing engineering controls and selecting personal
protective equipment. If engineering controls or work practices are not
adequate to prevent exposure to harmful levels of this material, the
personal protective equipment listed below is recommended. The user should
read and understand all instructions and limitations supplied with the
equipment since protection is usually provided for a limited time or under
certain circumstances.

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ENGINEERING CONTROLS
Use process enclosures, local exhaust ventilation, or other engineering
controls to control airborne levels below the recommended exposure limits.

PERSONAL PROTECTIVE EQUIPMENT

EYE/FACE PROTECTION:
Wear eye protection such as safety glasses, chemical goggles, or face
shields if engineering controls or work practices are not adequate to
prevent eye contact.
SKIN PROTECTION:
Wear impervious protective clothing to prevent skin contact. Selection of
protective clothing may include gloves, apron, boots, and complete facial
protection and will depend on operations conducted. Users should
determine acceptable performance characteristics of protective clothing.
Consider physical requirements and other substances present when selecting
protective clothing. Suggested materials for protective gloves include:
<Viton> <Nitrile> <Silver Shield>
RESPIRATORY PROTECTION:
Determine if airborne concentrations are below the recommended exposure
limits. If not, wear a NIOSH approved respirator that provides adequate
protection from measured concentrations of this material. Use the
following respirators: Use a positive pressure, air-supplying respirator
if there is potential for uncontrolled release, exposure levels are not
known, or other circumstances where air-purifying respirators may not
provide adequate protection.
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9. PHYSICAL AND CHEMICAL PROPERTIES

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PHYSICAL DESCRIPTION:
Liquid.
pH: NA
VAPOR PRESSURE: NA
VAPOR DENSITY
(AIR=1): NA
BOILING POINT: NDA
FREEZING POINT: NA
MELTING POINT: NA
SOLUBILITY: Soluble in hydrocarbon solvents; insoluble in water.
SPECIFIC GRAVITY: NDA
DENSITY: NDA
VISCOSITY: NDA
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10. STABILITY AND REACTIVITY

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HAZARDOUS DECOMPOSITION PRODUCTS:

No data available.
CHEMICAL STABILITY:
Stable.
CONDITIONS TO AVOID:
No data available.
INCOMPATIBILITY WITH OTHER MATERIALS:

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May react with strong oxidizing agents, such as chlorates, nitrates,

peroxides, etc.
HAZARDOUS POLYMERIZATION:
Polymerization will not occur.
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11. TOXICOLOGICAL INFORMATION

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EYE EFFECTS:
The eye irritation hazard is based on an evaluation of the data for the
components.
SKIN EFFECTS:
The skin irritation hazard is based on an evaluation of the data for the
components.
ACUTE ORAL EFFECTS:
The acute oral toxicity is based on an evaluation of the data for the
components.
ACUTE INHALATION EFFECTS:
The acute respiratory toxicity is based on an evaluation of the data for
the components.
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains chlorinated paraffin. A similar chlorinated
paraffin caused an increase in tumors when given in very high oral doses
to mice and rats for the duration of their lifespans. The significance to
man of the results of this study is not known. We believe that low level
or infrequent exposure to this material is not likely to cause cancer or
other serious disease.

This product contains tricresylphosphate (TCP). When given to hens in

oral doses as low as 75 mg/kg, TCP caused delayed nerve damage
characterized by loss of coordination and difficulty in walking.
Continuous dermal exposure to 50 mg/kg of this material for 5 days/week
for 4 weeks caused similar nerve damage in hens. Evaluations of the
manufacturer's workers who make TCP and similar chemicals have not
demonstrated any unusual pattern of mortality or disease. We believe that
there is little to no risk of nerve damage to workers who handle this
product when the precautions outlined in this MSDS and on the product
label are strictly followed.

This product contains synthetic base oils not refined from petroleum base
stocks. The potential of base oil prepared by this process to cause
cancer has not been specifically addressed by the OSHA Hazard
Communication Standard (29 CFR 1910.1200), the International Agency for
Research on Cancer (IARC), nor the National Toxicology Program (NTP)
Annual Report. However, the process conditions, chemical analysis, and
the results of mutagenicity tests all support our opinion that these oils
should not cause skin cancer.

This product contains petroleum base oils which may be refined by various
processes including severe solvent extraction, severe hydrocracking, or
severe hydrotreating. None of the oils requires a cancer warning under
the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils
have not been listed in the National Toxicology Program (NTP) Annual
Report nor have they been classified by the International Agency for

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Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably

carcinogenic to humans (Group 2A), or possibly carcinogenic to humans
(Group 2B).

No association has been established between industrial exposure to

petroleum asphalt and cancer in humans. The International Agency for
Research on Cancer (IARC) reviewed the carcinogenic potential of asphalts
in monograph 35. They concluded that there was insufficient evidence that
undiluted, air-refined asphalt was carcinogenic to animals, while there
was only limited evidence that steam-refined asphalts were carcinogenic to
animals. Additionally, there was insufficient evidence to conclude that
asphalts were carcinogenic to human beings. Studies in which mice were
exposed to a variety of whole asphalts did not result in any increased
cancer rate; mice exposed to asphalts diluted with hydrocarbon solvents
had increased incidence of certain types of cancer. The petroleum solvent
contained in this product may increase the potential for cancer following
prolonged and repeated skin contact. Brief or intermittent skin contact
with this asphalt product is not expected to produce any delayed effects.
While normal handling of this product is not likely to cause cancer in
humans, skin contact and breathing of mists, fumes or vapors should be
reduced to a minimum.

This product contains a mixture of petroleum hydrocarbons called middle

distillates (which means they boil between approximately 350F and 700F).
Because of this broad description, many products are considered middle
distillates yet they are produced by a variety of different petroleum
refining processes. Examples of middle distillates include kerosene,
diesel fuel and jet fuel. Dermal treatment with some middle distillates
resulted in the formation of skin tumors when repeatedly applied to mice
over most of their lifetime. Other studies indicate that pure middle
distillates are not genotoxic and that chronic skin irritation is
necessary for the skin tumor response to occur. Petroleum middle
distillates are not listed as carcinogenic by the IARC, EPA, NTP, or OSHA.
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12. ECOLOGICAL INFORMATION

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ECOTOXICITY:
The toxicity of this material to aquatic organisms has not been evaluated.
Consequently, this material should be kept out of sewage and drainage
systems and all bodies of water.
ENVIRONMENTAL FATE:
This material is not expected to be readily biodegradable.
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13. DISPOSAL CONSIDERATIONS

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Place contaminated materials in disposable containers and dispose of in a

manner consistent with applicable regulations. Contact local
environmental or health authorities for approved disposal of this
material.

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14. TRANSPORT INFORMATION

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The description shown may not apply to all shipping situations.

Consult 49CFR, or appropriate Dangerous Goods Regulations, for
additional description requirements (e.g., technical name) and
mode-specific or quantity-specific shipping requirements.

DOT SHIPPING NAME: NONE

DOT HAZARD CLASS: NONE
DOT IDENTIFICATION NUMBER: NONE
DOT PACKING GROUP: N/A
ADDITIONAL INFO: LUBRICATING OIL FOR FURTHER PROCESSING - NOT HAZARDOUS
BY U.S. DOT
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15. REGULATORY INFORMATION

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SARA 311 CATEGORIES: 1. Immediate (Acute) Health Effects: YES

2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: YES
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:

01=SARA 313 11=NJ RTK 22=TSCA Sect 5(a)(2)

02=MASS RTK 12=CERCLA 302.4 23=TSCA Sect 6
03=NTP Carcinogen 13=MN RTK 24=TSCA Sect 12(b)
04=CA Prop 65-Carcin 14=ACGIH TWA 25=TSCA Sect 8(a)
05=CA Prop 65-Repro Tox 15=ACGIH STEL 26=TSCA Sect 8(d)
06=IARC Group 1 16=ACGIH Calc TLV 27=TSCA Sect 4(a)
07=IARC Group 2A 17=OSHA PEL 28=Canadian WHMIS
08=IARC Group 2B 18=DOT Marine Pollutant 29=OSHA CEILING
09=SARA 302/304 19=Chevron TWA 30=Chevron STEL
10=PA RTK 20=EPA Carcinogen 31=OSHA STEL

The following components of this material are found on the regulatory

lists indicated.

TRICRESYL PHOSPHATE
is found on lists: 18,28,
ZINC ALKARYL DITHIOPHOSPHATE
is found on lists: 01,11,
ACETIC ACID, PENTYL ESTER
is found on lists: 02,10,11,12,13,14,17,26,28,
DISTILLATES, (PETROLEUM), SOLVENT-DEWAXED LIGHT PARAFFINIC
is found on lists: 02,14,15,17,
PHOSPHORODITHIOIC ACID,O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS
is found on lists: 01,11,
WHITE MINERAL OIL
is found on lists: 14,15,17,

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ASPHALT
is found on lists: 02,10,11,13,14,
BARIUM COMPOUND
is found on lists: 01,
SEVERELY REFINED PETROLEUM DISTILLATE
is found on lists: 14,15,17,
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16. OTHER INFORMATION

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NFPA RATINGS: Health 2; Flammability 2; Reactivity 0;

HMIS RATINGS: Health 2*; Flammability 2; Reactivity 0;
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal
Protection Equipment Index recommendation, *- Chronic Effect
Indicator). These values are obtained using the guidelines or
published evaluations prepared by the National Fire Protection
Association (NFPA) or the National Paint and Coating Association
(for HMIS ratings).

REVISION STATEMENT:
This revision updates Section 2 (Composition) and Section 4 (First Aid
Measures), and Section 11 (Toxicological Information).

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:

TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit TPQ - Threshold Planning Quantity
RQ - Reportable Quantity PEL - Permissible Exposure Limit
C - Ceiling Limit CAS - Chemical Abstract Service Number
A1-5 - Appendix A Categories () - Change Has Been Proposed
NDA - No Data Available NA - Not Applicable
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Prepared according to the OSHA Hazard Communication Standard
(29 CFR 1910.1200) and the ANSI MSDS Standard (Z400.1) by the Toxicology
and Health Risk Assessment Unit, CRTC, P.O. Box 1627, Richmond, CA 94804

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The above information is based on the data of which we are aware and is
believed to be correct as of the date hereof. Since this information may
be applied under conditions beyond our control and with which we may be
unfamiliar and since data made available subsequent to the date hereof may
suggest modification of the information, we do not assume any responsibil-
ity for the results of its use. This information is furnished upon
condition that the person receiving it shall make his own determination
of the suitability of the material for his particular purpose.

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THIS IS THE LAST PAGE OF THIS MSDS
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Revision Number: 3 Revision Date: 03/06/02 MSDS Number: 005851